CN109294154A - A kind of waterproof footwear and processing technology - Google Patents

A kind of waterproof footwear and processing technology Download PDF

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Publication number
CN109294154A
CN109294154A CN201811070014.5A CN201811070014A CN109294154A CN 109294154 A CN109294154 A CN 109294154A CN 201811070014 A CN201811070014 A CN 201811070014A CN 109294154 A CN109294154 A CN 109294154A
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Prior art keywords
parts
waterproof footwear
waterproof
agent
raw material
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CN201811070014.5A
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Chinese (zh)
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CN109294154B (en
Inventor
杨仙岳
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Zhejiang Red Dragonfly Footwear Co Ltd
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Wenzhou Polytechnic
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B1/00Footwear characterised by the material
    • A43B1/14Footwear characterised by the material made of plastics
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of waterproof footwear, the formula of raw material by weight is as follows: 60-80 parts of ABS resin, 12-20 parts of polyurethane resin, 40-50 parts of natural rubber, 12-20 parts of neoprene, 12-20 parts of glass fibre, 8-12 parts of white carbon black, 8-12 parts of mineral powder, 3-5 parts of pigment, 7-9 parts of methyl p-hydroxybenzoate, 7-9 parts of silicone oil, 7-9 parts of atoleine, 3-5 parts of silane coupling agent, 3-5 parts of plasticizer, 3-5 parts of softening agent, 3-5 parts of anti-aging agent.The present invention also provides a kind of processing technologys of waterproof footwear.The present invention passes through the addition of plurality of raw materials and matches again, and waterproof footwear is made to have the function of waterproof, and footwear material waterproof practical application value is high to be also easy to use simultaneously, and has the effect of certain environmentally friendly fanout free region, can be widely used.

Description

A kind of waterproof footwear and processing technology
Technical field
The present invention relates to footwear preparation technical field more particularly to a kind of waterproof footwears and processing technology.
Background technique
Shoes are products during development of human civilization, with the improvement of living standards, work of the shoes not just to protection With requirement of the people to shoes is higher and higher;Waterproofness and light comfort are requirement of many consumers to shoes, at present mostly The vamp of number shoes is that have skin or textile chemical fiber cloth to be formed, and although leather has certain waterproofness, but leather is generally thicker, Keep shoes itself heavier, in addition the pore of leather can also immerse a little rainwater, and waterproof effect is poor, and be easily deformed after leather soaking, shadow Ring service life.For this purpose, we have proposed a kind of waterproof footwear and processing technologys.
Summary of the invention
The invention proposes a kind of waterproof footwear and processing technologys, to solve the problems mentioned in the above background technology.
The invention proposes a kind of waterproof footwear, the formula of raw material by weight is as follows: 60-80 parts of ABS resin, polyurethane tree 12-20 parts of rouge, 40-50 parts of natural rubber, 12-20 parts of neoprene, 12-20 parts of glass fibre, 8-12 parts of white carbon black, mineral powder 8-12 parts, 3-5 parts of pigment, 7-9 parts of methyl p-hydroxybenzoate, 7-9 parts of silicone oil, 7-9 parts of atoleine, silane coupling agent 3-5 Part, 3-5 parts of plasticizer, 3-5 parts of softening agent, 3-5 parts of anti-aging agent.
Preferably, ABS resin, polyurethane resin, natural rubber, neoprene weight ratio be 65-75:14-18:43- 48:14-18.
Preferably, glass fibre, white carbon black, mineral powder, pigment weight ratio be 14-18:9-11:9-11:3.5-4.5.
Preferably, methyl p-hydroxybenzoate, silicone oil, atoleine weight ratio be 7.5-8.5:7.5-8.5:7.5- 8.5。
Preferably, silane coupling agent, plasticizer, softening agent, anti-aging agent weight ratio be 3.5-4.5:3.5-4.5:3.5- 4.5:3.5-4.5.
Preferably, the formula of raw material by weight is as follows:
65-75 parts of ABS resin, 14-18 parts of polyurethane resin, 43-48 parts of natural rubber, 14-18 parts of neoprene, glass 14-18 parts of fiber, 9-11 parts of white carbon black, 9-11 parts of mineral powder, 3.5-4.5 parts of pigment, methyl p-hydroxybenzoate 7.5-8.5 Part, 7.5-8.5 parts of silicone oil, 7.5-8.5 parts of atoleine, 3.5-4.5 parts of silane coupling agent, 3.5-4.5 parts of plasticizer, softening agent 3.5-4.5 3.5-4.5 parts of part, anti-aging agent.
Preferably, the formula of raw material by weight is as follows:
It is 70 parts of ABS resin, 16 parts of polyurethane resin, 45 parts of natural rubber, 16 parts of neoprene, 16 parts of glass fibre, white It is 10 parts of carbon black, 10 parts of mineral powder, 4 parts of pigment, 8 parts of methyl p-hydroxybenzoate, 8 parts of silicone oil, 8 parts of atoleine, silane coupled 4 parts of agent, 4 parts of plasticizer, 4 parts of softening agent, 4 parts of anti-aging agent.
The present invention also provides a kind of processing technologys of waterproof footwear, include the following steps:
S1, in proportion by ABS resin, polyurethane resin, natural rubber, neoprene part, glass fibre, white carbon black and Mineral powder, which is placed in super mixer, carries out premix 20-30min, then again be added methyl p-hydroxybenzoate, silicone oil and Atoleine after mixing to it forms mixture;
S2, mixture obtained in S1 is placed in double screw extruder, then adds silane coupling agent, plasticising thereto Agent, softening agent and anti-aging agent, after mixing, through double screw extruder under conditions of temperature is 160-180 degrees Celsius It squeezes out, then cooling granulation, obtains waterproof footwear material raw material;
S3, the waterproof footwear material raw material in S2 is added in mixer, mixing under conditions of temperature is 160-180 degrees Celsius 35-55min, it is primary to project, it is poured into waterproof shoe mould, and need to guarantee one-time cast-forming, is cooled and shaped, can access Waterproof footwear.
Preferably, the twin screw extruder is preheated to 80-100 degrees Celsius in advance, then carries out extrusion process again.
Proposed by the invention a kind of waterproof footwear and processing technology, beneficial effect are: the present invention passes through plurality of raw materials It adds and matches again, waterproof footwear is made to have the function of waterproof, footwear material waterproof practical application value is high to be also easy to use simultaneously, And there is the effect of certain environmentally friendly fanout free region, can be widely used, and improve prepared waterproof footwear material in people's lives Application range, technique proposed by the invention is easy to operate, processing cost is low, significant effect, prepared waterproof footwear material Measure, function it is more, can durable water resistant, be easy to use.
Specific embodiment
It is next combined with specific embodiments below that the present invention will be further described.
Embodiment 1
The invention proposes a kind of waterproof footwear, the formula of raw material by weight is as follows: 60 parts of ABS resin, polyurethane resin 12 parts, 40 parts of natural rubber, 12 parts of neoprene, 12 parts of glass fibre, 8 parts of white carbon black, 8 parts of mineral powder, 3 parts of pigment, to hydroxyl 7 parts of yl benzoic acid methyl esters, 7 parts of silicone oil, 7 parts of atoleine, 3 parts of silane coupling agent, 3 parts of plasticizer, 3 parts of softening agent, anti-aging agent 3 Part.
The present invention also provides a kind of processing technologys of waterproof footwear, include the following steps:
S1, in proportion by ABS resin, polyurethane resin, natural rubber, neoprene part, glass fibre, white carbon black and Mineral powder, which is placed in super mixer, carries out premix 20min, and methyl p-hydroxybenzoate, silicone oil and liquid are then added again Paraffin after mixing to it forms mixture;
S2, mixture obtained in S1 is placed in double screw extruder, then adds silane coupling agent, plasticising thereto Agent, softening agent and anti-aging agent are squeezed out under conditions of temperature is 160 degrees Celsius by double screw extruder after mixing, Then cooling granulation obtains waterproof footwear material raw material;
S3, the waterproof footwear material raw material in S2 is added in mixer, mixing under conditions of temperature is 160 degrees Celsius 35min, it is primary to project, it is poured into waterproof shoe mould, and need to guarantee one-time cast-forming, is cooled and shaped, can access anti- Water shoes.
The twin screw extruder is preheated to 80 degrees Celsius in advance, then carries out extrusion process again.
Embodiment 2
The invention proposes a kind of waterproof footwear, the formula of raw material by weight is as follows: 65 parts of ABS resin, polyurethane resin 14 parts, it is 43 parts of natural rubber, 14 parts of neoprene, 14 parts of glass fibre, 9 parts of white carbon black, 9 parts of mineral powder, 3.5 parts of pigment, right 7.5 parts of methyl hydroxybenzoate, 7.5 parts of silicone oil, 7.5 parts of atoleine, 3.5 parts of silane coupling agent, 3.5 parts of plasticizer, softening 3.5 parts of agent, 3.5 parts of anti-aging agent.
The present invention also provides a kind of processing technologys of waterproof footwear, include the following steps:
S1, in proportion by ABS resin, polyurethane resin, natural rubber, neoprene part, glass fibre, white carbon black and Mineral powder, which is placed in super mixer, carries out premix 23min, and methyl p-hydroxybenzoate, silicone oil and liquid are then added again Paraffin after mixing to it forms mixture;
S2, mixture obtained in S1 is placed in double screw extruder, then adds silane coupling agent, plasticising thereto Agent, softening agent and anti-aging agent are squeezed out under conditions of temperature is 165 degrees Celsius by double screw extruder after mixing, Then cooling granulation obtains waterproof footwear material raw material;
S3, the waterproof footwear material raw material in S2 is added in mixer, mixing under conditions of temperature is 165 degrees Celsius 40min, it is primary to project, it is poured into waterproof shoe mould, and need to guarantee one-time cast-forming, is cooled and shaped, can access anti- Water shoes.
The twin screw extruder is preheated to 85 degrees Celsius in advance, then carries out extrusion process again.
Embodiment 3
The invention proposes a kind of waterproof footwear, the formula of raw material by weight is as follows: 70 parts of ABS resin, polyurethane resin 16 parts, it is 45 parts of natural rubber, 16 parts of neoprene, 16 parts of glass fibre, 10 parts of white carbon black, 10 parts of mineral powder, 4 parts of pigment, right 8 parts of methyl hydroxybenzoate, 8 parts of atoleine, 4 parts of silane coupling agent, 4 parts of plasticizer, 4 parts of softening agent, is prevented always 8 parts of silicone oil 4 parts of agent.
The present invention also provides a kind of processing technologys of waterproof footwear, include the following steps:
S1, in proportion by ABS resin, polyurethane resin, natural rubber, neoprene part, glass fibre, white carbon black and Mineral powder, which is placed in super mixer, carries out premix 25min, and methyl p-hydroxybenzoate, silicone oil and liquid are then added again Paraffin after mixing to it forms mixture;
S2, mixture obtained in S1 is placed in double screw extruder, then adds silane coupling agent, plasticising thereto Agent, softening agent and anti-aging agent are squeezed out under conditions of temperature is 170 degrees Celsius by double screw extruder after mixing, Then cooling granulation obtains waterproof footwear material raw material;
S3, the waterproof footwear material raw material in S2 is added in mixer, mixing under conditions of temperature is 170 degrees Celsius 45min, it is primary to project, it is poured into waterproof shoe mould, and need to guarantee one-time cast-forming, is cooled and shaped, can access anti- Water shoes.
The twin screw extruder is preheated to 90 degrees Celsius in advance, then carries out extrusion process again.
Embodiment 4
The invention proposes a kind of waterproof footwear, the formula of raw material by weight is as follows: 75 parts of ABS resin, polyurethane resin 18 parts, 48 parts of natural rubber, 18 parts of neoprene, 18 parts of glass fibre, 11 parts of white carbon black, 11 parts of mineral powder, 4.5 parts of pigment, It is 8.5 parts of methyl p-hydroxybenzoate, 8.5 parts of silicone oil, 8.5 parts of atoleine, 4.5 parts of silane coupling agent, 4.5 parts of plasticizer, soft 4.5 parts of agent, 4.5 parts of anti-aging agent.
The present invention also provides a kind of processing technologys of waterproof footwear, include the following steps:
S1, in proportion by ABS resin, polyurethane resin, natural rubber, neoprene part, glass fibre, white carbon black and Mineral powder, which is placed in super mixer, carries out premix 27min, and methyl p-hydroxybenzoate, silicone oil and liquid are then added again Paraffin after mixing to it forms mixture;
S2, mixture obtained in S1 is placed in double screw extruder, then adds silane coupling agent, plasticising thereto Agent, softening agent and anti-aging agent are squeezed out under conditions of temperature is 175 degrees Celsius by double screw extruder after mixing, Then cooling granulation obtains waterproof footwear material raw material;
S3, the waterproof footwear material raw material in S2 is added in mixer, mixing under conditions of temperature is 175 degrees Celsius 50min, it is primary to project, it is poured into waterproof shoe mould, and need to guarantee one-time cast-forming, is cooled and shaped, can access anti- Water shoes.
The twin screw extruder is preheated to 95 degrees Celsius in advance, then carries out extrusion process again.
Embodiment 5
The invention proposes a kind of waterproof footwear, the formula of raw material by weight is as follows: 80 parts of ABS resin, polyurethane resin 20 parts, it is 50 parts of natural rubber, 20 parts of neoprene, 20 parts of glass fibre, 12 parts of white carbon black, 12 parts of mineral powder, 5 parts of pigment, right 9 parts of methyl hydroxybenzoate, 9 parts of atoleine, 5 parts of silane coupling agent, 5 parts of plasticizer, 5 parts of softening agent, is prevented always 9 parts of silicone oil 5 parts of agent.
The present invention also provides a kind of processing technologys of waterproof footwear, include the following steps:
S1, in proportion by ABS resin, polyurethane resin, natural rubber, neoprene part, glass fibre, white carbon black and Mineral powder, which is placed in super mixer, carries out premix 30min, and methyl p-hydroxybenzoate, silicone oil and liquid are then added again Paraffin after mixing to it forms mixture;
S2, mixture obtained in S1 is placed in double screw extruder, then adds silane coupling agent, plasticising thereto Agent, softening agent and anti-aging agent are squeezed out under conditions of temperature is 180 degrees Celsius by double screw extruder after mixing, Then cooling granulation obtains waterproof footwear material raw material;
S3, the waterproof footwear material raw material in S2 is added in mixer, mixing under conditions of temperature is 180 degrees Celsius 55min, it is primary to project, it is poured into waterproof shoe mould, and need to guarantee one-time cast-forming, is cooled and shaped, can access anti- Water shoes.
The twin screw extruder is preheated to 100 degrees Celsius in advance, then carries out extrusion process again.
The present invention passes through the addition of plurality of raw materials and matches again, and waterproof footwear is made to have the function of waterproof, footwear material waterproof Practical application value is high to be also easy to use simultaneously, and has the effect of certain environmentally friendly fanout free region, can be widely used, and improve The application range of prepared waterproof footwear material in people's lives, technique proposed by the invention, easy to operate, processing cost Low, significant effect, prepared waterproof footwear material is high-quality, function is more, and energy durable water resistant is easy to use.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and sends out Bright design is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (9)

1. a kind of waterproof footwear, which is characterized in that the formula of its raw material by weight is as follows: 60-80 parts of ABS resin, polyurethane resin 12-20 parts, 40-50 parts of natural rubber, 12-20 parts of neoprene, 12-20 parts of glass fibre, 8-12 parts of white carbon black, mineral powder 8- 12 parts, 3-5 parts of pigment, 7-9 parts of methyl p-hydroxybenzoate, 7-9 parts of silicone oil, 7-9 parts of atoleine, 3-5 parts of silane coupling agent, 3-5 parts of plasticizer, 3-5 parts of softening agent, 3-5 parts of anti-aging agent.
2. waterproof footwear according to claim 1, which is characterized in that ABS resin, polyurethane resin, natural rubber, neoprene rubber The weight ratio of glue is 65-75:14-18:43-48:14-18.
3. waterproof footwear according to claim 1, which is characterized in that the weight of glass fibre, white carbon black, mineral powder, pigment Than for 14-18:9-11:9-11:3.5-4.5.
4. waterproof footwear according to claim 1, which is characterized in that methyl p-hydroxybenzoate, silicone oil, atoleine weight Amount is than being 7.5-8.5:7.5-8.5:7.5-8.5.
5. waterproof footwear according to claim 1, which is characterized in that silane coupling agent, plasticizer, softening agent, anti-aging agent Weight ratio is 3.5-4.5:3.5-4.5:3.5-4.5:3.5-4.5.
6. according to waterproof footwear described in claim 2-5, which is characterized in that the formula of its raw material by weight is as follows:
65-75 parts of ABS resin, 14-18 parts of polyurethane resin, 43-48 parts of natural rubber, 14-18 parts of neoprene, glass fibre 14-18 parts, 9-11 parts of white carbon black, 9-11 parts of mineral powder, 3.5-4.5 parts of pigment, 7.5-8.5 parts of methyl p-hydroxybenzoate, silicon 7.5-8.5 parts oily, 7.5-8.5 parts of atoleine, 3.5-4.5 parts of silane coupling agent, 3.5-4.5 parts of plasticizer, softening agent 3.5- 4.5 parts, 3.5-4.5 parts of anti-aging agent.
7. waterproof footwear according to claim 1, which is characterized in that the formula of its raw material by weight is as follows:
70 parts of ABS resin, 16 parts of polyurethane resin, 45 parts of natural rubber, 16 parts of neoprene, 16 parts of glass fibre, white carbon black 10 parts, 10 parts of mineral powder, 4 parts of pigment, 8 parts of methyl p-hydroxybenzoate, 8 parts of silicone oil, 8 parts of atoleine, silane coupling agent 4 Part, 4 parts of plasticizer, 4 parts of softening agent, 4 parts of anti-aging agent.
8. a kind of processing technology of waterproof footwear according to claim 1, which comprises the steps of:
S1, in proportion by ABS resin, polyurethane resin, natural rubber, neoprene part, glass fibre, white carbon black and mineral Powder, which is placed in super mixer, carries out premix 20-30min, and methyl p-hydroxybenzoate, silicone oil and liquid are then added again Paraffin after mixing to it forms mixture;
S2, mixture obtained in S1 is placed in double screw extruder, then adds silane coupling agent, plasticizer, soft thereto Agent and anti-aging agent are squeezed out under conditions of temperature is 160-180 degrees Celsius by double screw extruder after mixing, Then cooling granulation obtains waterproof footwear material raw material;
S3, the waterproof footwear material raw material in S2 is added in mixer, mixing 35- under conditions of temperature is 160-180 degrees Celsius 55min, it is primary to project, it is poured into waterproof shoe mould, and need to guarantee one-time cast-forming, is cooled and shaped, can access anti- Water shoes.
9. the processing technology of waterproof footwear according to claim 8, which is characterized in that the twin screw extruder is pre- in advance Then heat carries out extrusion process to 80-100 degrees Celsius again.
CN201811070014.5A 2018-09-13 2018-09-13 Waterproof shoe and processing technology Active CN109294154B (en)

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CN201811070014.5A CN109294154B (en) 2018-09-13 2018-09-13 Waterproof shoe and processing technology

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113667297A (en) * 2021-09-03 2021-11-19 惠州市良化新材料有限公司 Low-water-absorption nylon composite material

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107674363A (en) * 2017-10-25 2018-02-09 晋江创纪鞋材有限公司 A kind of waterproof footwear material and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107674363A (en) * 2017-10-25 2018-02-09 晋江创纪鞋材有限公司 A kind of waterproof footwear material and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113667297A (en) * 2021-09-03 2021-11-19 惠州市良化新材料有限公司 Low-water-absorption nylon composite material
CN113667297B (en) * 2021-09-03 2024-03-26 惠州市良化新材料有限公司 Nylon composite material with low water absorption rate

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Effective date of registration: 20240228

Address after: 325000 No. 2357, Shuangta Road, Oubei street, Yongjia County, Wenzhou City, Zhejiang Province

Patentee after: Zhejiang Red Dragonfly Footwear Co.,Ltd.

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Address before: 325000 Wenzhou City National University Science Park incubator, No. 38 Dongfang South Road, Ouhai District, Wenzhou, Zhejiang

Patentee before: WENZHOU VOCATIONAL & TECHNICAL College

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