A kind of waterproof footwear and processing technology
Technical field
The present invention relates to footwear preparation technical field more particularly to a kind of waterproof footwears and processing technology.
Background technique
Shoes are products during development of human civilization, with the improvement of living standards, work of the shoes not just to protection
With requirement of the people to shoes is higher and higher;Waterproofness and light comfort are requirement of many consumers to shoes, at present mostly
The vamp of number shoes is that have skin or textile chemical fiber cloth to be formed, and although leather has certain waterproofness, but leather is generally thicker,
Keep shoes itself heavier, in addition the pore of leather can also immerse a little rainwater, and waterproof effect is poor, and be easily deformed after leather soaking, shadow
Ring service life.For this purpose, we have proposed a kind of waterproof footwear and processing technologys.
Summary of the invention
The invention proposes a kind of waterproof footwear and processing technologys, to solve the problems mentioned in the above background technology.
The invention proposes a kind of waterproof footwear, the formula of raw material by weight is as follows: 60-80 parts of ABS resin, polyurethane tree
12-20 parts of rouge, 40-50 parts of natural rubber, 12-20 parts of neoprene, 12-20 parts of glass fibre, 8-12 parts of white carbon black, mineral powder
8-12 parts, 3-5 parts of pigment, 7-9 parts of methyl p-hydroxybenzoate, 7-9 parts of silicone oil, 7-9 parts of atoleine, silane coupling agent 3-5
Part, 3-5 parts of plasticizer, 3-5 parts of softening agent, 3-5 parts of anti-aging agent.
Preferably, ABS resin, polyurethane resin, natural rubber, neoprene weight ratio be 65-75:14-18:43-
48:14-18.
Preferably, glass fibre, white carbon black, mineral powder, pigment weight ratio be 14-18:9-11:9-11:3.5-4.5.
Preferably, methyl p-hydroxybenzoate, silicone oil, atoleine weight ratio be 7.5-8.5:7.5-8.5:7.5-
8.5。
Preferably, silane coupling agent, plasticizer, softening agent, anti-aging agent weight ratio be 3.5-4.5:3.5-4.5:3.5-
4.5:3.5-4.5.
Preferably, the formula of raw material by weight is as follows:
65-75 parts of ABS resin, 14-18 parts of polyurethane resin, 43-48 parts of natural rubber, 14-18 parts of neoprene, glass
14-18 parts of fiber, 9-11 parts of white carbon black, 9-11 parts of mineral powder, 3.5-4.5 parts of pigment, methyl p-hydroxybenzoate 7.5-8.5
Part, 7.5-8.5 parts of silicone oil, 7.5-8.5 parts of atoleine, 3.5-4.5 parts of silane coupling agent, 3.5-4.5 parts of plasticizer, softening agent
3.5-4.5 3.5-4.5 parts of part, anti-aging agent.
Preferably, the formula of raw material by weight is as follows:
It is 70 parts of ABS resin, 16 parts of polyurethane resin, 45 parts of natural rubber, 16 parts of neoprene, 16 parts of glass fibre, white
It is 10 parts of carbon black, 10 parts of mineral powder, 4 parts of pigment, 8 parts of methyl p-hydroxybenzoate, 8 parts of silicone oil, 8 parts of atoleine, silane coupled
4 parts of agent, 4 parts of plasticizer, 4 parts of softening agent, 4 parts of anti-aging agent.
The present invention also provides a kind of processing technologys of waterproof footwear, include the following steps:
S1, in proportion by ABS resin, polyurethane resin, natural rubber, neoprene part, glass fibre, white carbon black and
Mineral powder, which is placed in super mixer, carries out premix 20-30min, then again be added methyl p-hydroxybenzoate, silicone oil and
Atoleine after mixing to it forms mixture;
S2, mixture obtained in S1 is placed in double screw extruder, then adds silane coupling agent, plasticising thereto
Agent, softening agent and anti-aging agent, after mixing, through double screw extruder under conditions of temperature is 160-180 degrees Celsius
It squeezes out, then cooling granulation, obtains waterproof footwear material raw material;
S3, the waterproof footwear material raw material in S2 is added in mixer, mixing under conditions of temperature is 160-180 degrees Celsius
35-55min, it is primary to project, it is poured into waterproof shoe mould, and need to guarantee one-time cast-forming, is cooled and shaped, can access
Waterproof footwear.
Preferably, the twin screw extruder is preheated to 80-100 degrees Celsius in advance, then carries out extrusion process again.
Proposed by the invention a kind of waterproof footwear and processing technology, beneficial effect are: the present invention passes through plurality of raw materials
It adds and matches again, waterproof footwear is made to have the function of waterproof, footwear material waterproof practical application value is high to be also easy to use simultaneously,
And there is the effect of certain environmentally friendly fanout free region, can be widely used, and improve prepared waterproof footwear material in people's lives
Application range, technique proposed by the invention is easy to operate, processing cost is low, significant effect, prepared waterproof footwear material
Measure, function it is more, can durable water resistant, be easy to use.
Specific embodiment
It is next combined with specific embodiments below that the present invention will be further described.
Embodiment 1
The invention proposes a kind of waterproof footwear, the formula of raw material by weight is as follows: 60 parts of ABS resin, polyurethane resin
12 parts, 40 parts of natural rubber, 12 parts of neoprene, 12 parts of glass fibre, 8 parts of white carbon black, 8 parts of mineral powder, 3 parts of pigment, to hydroxyl
7 parts of yl benzoic acid methyl esters, 7 parts of silicone oil, 7 parts of atoleine, 3 parts of silane coupling agent, 3 parts of plasticizer, 3 parts of softening agent, anti-aging agent 3
Part.
The present invention also provides a kind of processing technologys of waterproof footwear, include the following steps:
S1, in proportion by ABS resin, polyurethane resin, natural rubber, neoprene part, glass fibre, white carbon black and
Mineral powder, which is placed in super mixer, carries out premix 20min, and methyl p-hydroxybenzoate, silicone oil and liquid are then added again
Paraffin after mixing to it forms mixture;
S2, mixture obtained in S1 is placed in double screw extruder, then adds silane coupling agent, plasticising thereto
Agent, softening agent and anti-aging agent are squeezed out under conditions of temperature is 160 degrees Celsius by double screw extruder after mixing,
Then cooling granulation obtains waterproof footwear material raw material;
S3, the waterproof footwear material raw material in S2 is added in mixer, mixing under conditions of temperature is 160 degrees Celsius
35min, it is primary to project, it is poured into waterproof shoe mould, and need to guarantee one-time cast-forming, is cooled and shaped, can access anti-
Water shoes.
The twin screw extruder is preheated to 80 degrees Celsius in advance, then carries out extrusion process again.
Embodiment 2
The invention proposes a kind of waterproof footwear, the formula of raw material by weight is as follows: 65 parts of ABS resin, polyurethane resin
14 parts, it is 43 parts of natural rubber, 14 parts of neoprene, 14 parts of glass fibre, 9 parts of white carbon black, 9 parts of mineral powder, 3.5 parts of pigment, right
7.5 parts of methyl hydroxybenzoate, 7.5 parts of silicone oil, 7.5 parts of atoleine, 3.5 parts of silane coupling agent, 3.5 parts of plasticizer, softening
3.5 parts of agent, 3.5 parts of anti-aging agent.
The present invention also provides a kind of processing technologys of waterproof footwear, include the following steps:
S1, in proportion by ABS resin, polyurethane resin, natural rubber, neoprene part, glass fibre, white carbon black and
Mineral powder, which is placed in super mixer, carries out premix 23min, and methyl p-hydroxybenzoate, silicone oil and liquid are then added again
Paraffin after mixing to it forms mixture;
S2, mixture obtained in S1 is placed in double screw extruder, then adds silane coupling agent, plasticising thereto
Agent, softening agent and anti-aging agent are squeezed out under conditions of temperature is 165 degrees Celsius by double screw extruder after mixing,
Then cooling granulation obtains waterproof footwear material raw material;
S3, the waterproof footwear material raw material in S2 is added in mixer, mixing under conditions of temperature is 165 degrees Celsius
40min, it is primary to project, it is poured into waterproof shoe mould, and need to guarantee one-time cast-forming, is cooled and shaped, can access anti-
Water shoes.
The twin screw extruder is preheated to 85 degrees Celsius in advance, then carries out extrusion process again.
Embodiment 3
The invention proposes a kind of waterproof footwear, the formula of raw material by weight is as follows: 70 parts of ABS resin, polyurethane resin
16 parts, it is 45 parts of natural rubber, 16 parts of neoprene, 16 parts of glass fibre, 10 parts of white carbon black, 10 parts of mineral powder, 4 parts of pigment, right
8 parts of methyl hydroxybenzoate, 8 parts of atoleine, 4 parts of silane coupling agent, 4 parts of plasticizer, 4 parts of softening agent, is prevented always 8 parts of silicone oil
4 parts of agent.
The present invention also provides a kind of processing technologys of waterproof footwear, include the following steps:
S1, in proportion by ABS resin, polyurethane resin, natural rubber, neoprene part, glass fibre, white carbon black and
Mineral powder, which is placed in super mixer, carries out premix 25min, and methyl p-hydroxybenzoate, silicone oil and liquid are then added again
Paraffin after mixing to it forms mixture;
S2, mixture obtained in S1 is placed in double screw extruder, then adds silane coupling agent, plasticising thereto
Agent, softening agent and anti-aging agent are squeezed out under conditions of temperature is 170 degrees Celsius by double screw extruder after mixing,
Then cooling granulation obtains waterproof footwear material raw material;
S3, the waterproof footwear material raw material in S2 is added in mixer, mixing under conditions of temperature is 170 degrees Celsius
45min, it is primary to project, it is poured into waterproof shoe mould, and need to guarantee one-time cast-forming, is cooled and shaped, can access anti-
Water shoes.
The twin screw extruder is preheated to 90 degrees Celsius in advance, then carries out extrusion process again.
Embodiment 4
The invention proposes a kind of waterproof footwear, the formula of raw material by weight is as follows: 75 parts of ABS resin, polyurethane resin
18 parts, 48 parts of natural rubber, 18 parts of neoprene, 18 parts of glass fibre, 11 parts of white carbon black, 11 parts of mineral powder, 4.5 parts of pigment,
It is 8.5 parts of methyl p-hydroxybenzoate, 8.5 parts of silicone oil, 8.5 parts of atoleine, 4.5 parts of silane coupling agent, 4.5 parts of plasticizer, soft
4.5 parts of agent, 4.5 parts of anti-aging agent.
The present invention also provides a kind of processing technologys of waterproof footwear, include the following steps:
S1, in proportion by ABS resin, polyurethane resin, natural rubber, neoprene part, glass fibre, white carbon black and
Mineral powder, which is placed in super mixer, carries out premix 27min, and methyl p-hydroxybenzoate, silicone oil and liquid are then added again
Paraffin after mixing to it forms mixture;
S2, mixture obtained in S1 is placed in double screw extruder, then adds silane coupling agent, plasticising thereto
Agent, softening agent and anti-aging agent are squeezed out under conditions of temperature is 175 degrees Celsius by double screw extruder after mixing,
Then cooling granulation obtains waterproof footwear material raw material;
S3, the waterproof footwear material raw material in S2 is added in mixer, mixing under conditions of temperature is 175 degrees Celsius
50min, it is primary to project, it is poured into waterproof shoe mould, and need to guarantee one-time cast-forming, is cooled and shaped, can access anti-
Water shoes.
The twin screw extruder is preheated to 95 degrees Celsius in advance, then carries out extrusion process again.
Embodiment 5
The invention proposes a kind of waterproof footwear, the formula of raw material by weight is as follows: 80 parts of ABS resin, polyurethane resin
20 parts, it is 50 parts of natural rubber, 20 parts of neoprene, 20 parts of glass fibre, 12 parts of white carbon black, 12 parts of mineral powder, 5 parts of pigment, right
9 parts of methyl hydroxybenzoate, 9 parts of atoleine, 5 parts of silane coupling agent, 5 parts of plasticizer, 5 parts of softening agent, is prevented always 9 parts of silicone oil
5 parts of agent.
The present invention also provides a kind of processing technologys of waterproof footwear, include the following steps:
S1, in proportion by ABS resin, polyurethane resin, natural rubber, neoprene part, glass fibre, white carbon black and
Mineral powder, which is placed in super mixer, carries out premix 30min, and methyl p-hydroxybenzoate, silicone oil and liquid are then added again
Paraffin after mixing to it forms mixture;
S2, mixture obtained in S1 is placed in double screw extruder, then adds silane coupling agent, plasticising thereto
Agent, softening agent and anti-aging agent are squeezed out under conditions of temperature is 180 degrees Celsius by double screw extruder after mixing,
Then cooling granulation obtains waterproof footwear material raw material;
S3, the waterproof footwear material raw material in S2 is added in mixer, mixing under conditions of temperature is 180 degrees Celsius
55min, it is primary to project, it is poured into waterproof shoe mould, and need to guarantee one-time cast-forming, is cooled and shaped, can access anti-
Water shoes.
The twin screw extruder is preheated to 100 degrees Celsius in advance, then carries out extrusion process again.
The present invention passes through the addition of plurality of raw materials and matches again, and waterproof footwear is made to have the function of waterproof, footwear material waterproof
Practical application value is high to be also easy to use simultaneously, and has the effect of certain environmentally friendly fanout free region, can be widely used, and improve
The application range of prepared waterproof footwear material in people's lives, technique proposed by the invention, easy to operate, processing cost
Low, significant effect, prepared waterproof footwear material is high-quality, function is more, and energy durable water resistant is easy to use.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and sends out
Bright design is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.