CN109290050A - A kind of low Fe-spodumene preparation method - Google Patents
A kind of low Fe-spodumene preparation method Download PDFInfo
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- CN109290050A CN109290050A CN201811131821.3A CN201811131821A CN109290050A CN 109290050 A CN109290050 A CN 109290050A CN 201811131821 A CN201811131821 A CN 201811131821A CN 109290050 A CN109290050 A CN 109290050A
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- spodumene
- concentrate
- flotation
- low
- iron
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- 229910052642 spodumene Inorganic materials 0.000 title claims abstract description 52
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000012141 concentrate Substances 0.000 claims abstract description 39
- 238000005188 flotation Methods 0.000 claims abstract description 37
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 claims abstract description 31
- 229910052742 iron Inorganic materials 0.000 claims abstract description 24
- 238000007885 magnetic separation Methods 0.000 claims abstract description 22
- 238000002156 mixing Methods 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 15
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 10
- 239000011707 mineral Substances 0.000 claims abstract description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract description 7
- 239000010802 sludge Substances 0.000 claims abstract description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000005642 Oleic acid Substances 0.000 claims abstract description 3
- 239000011575 calcium Substances 0.000 claims abstract description 3
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 3
- 238000003756 stirring Methods 0.000 claims description 17
- 238000013329 compounding Methods 0.000 claims description 7
- 239000000686 essence Substances 0.000 claims description 5
- 238000004513 sizing Methods 0.000 claims description 5
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 claims description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 claims description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract description 11
- 229910052744 lithium Inorganic materials 0.000 abstract description 11
- QSNQXZYQEIKDPU-UHFFFAOYSA-N [Li].[Fe] Chemical compound [Li].[Fe] QSNQXZYQEIKDPU-UHFFFAOYSA-N 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 238000011084 recovery Methods 0.000 abstract description 2
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical group [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 4
- 238000000227 grinding Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910001576 calcium mineral Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 241001131796 Botaurus stellaris Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229910052586 apatite Inorganic materials 0.000 description 1
- 210000001367 artery Anatomy 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 229910002106 crystalline ceramic Inorganic materials 0.000 description 1
- 239000011222 crystalline ceramic Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000002223 garnet Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 1
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical class [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 1
- 239000003758 nuclear fuel Substances 0.000 description 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229910052613 tourmaline Inorganic materials 0.000 description 1
- 239000011032 tourmaline Substances 0.000 description 1
- 229940070527 tourmaline Drugs 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B9/00—General arrangement of separating plant, e.g. flow sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/02—Froth-flotation processes
- B03D1/025—Froth-flotation processes adapted for the flotation of fines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention discloses a kind of low Fe-spodumene preparation methods, this method be will be levigate after spodumene ore pulp in be added neopelex carry out reverse flotation, by the sludge and the impure minerals emersion such as iron, calcium in ore, sodium hydroxide, oleic acid are separately added into ore pulp again and carries out spodumene direct flotation with the collecting agent that compounds that hexadecyltrimethylammonium chloride forms, it is stirred and sizes mixing after addition polyoxyethyl propyl polyoxyethanyl glycerin ether in the spodumene rough concentrate of emersion, then carry out wet type low intensity magnetic separation and High gradient high intensity magnetic separation Iron removal by two steps.The final spodumene concentrate product F e handled by this method2O3The advantages of grade can be down to 0.15~0.25%, reach low iron lithium concentrate to the quality requirement of iron content, while this method also has the lithium concentrate rate of recovery high, and process is simple, be convenient for industrial realization.
Description
Technical field
The present invention relates to a kind of low Fe-spodumene preparation methods, belong to Mineral Processing Engineering technical field.
Background technique
Lithium is known as " the new energy metal in century ", " push the world advance important element ", is a kind of important rare
Metal, lithium and its compound can be used as the molten of the heat carrier of nuclear reactor, the protective materials of thermal neutron, moderator and nuclear fuel
Agent, high-energy fuel can also be used to produce high performance lubricant, high-power battery material etc..There are two main classes in the source of lithium: a kind of
For salt lake bittern lithium；Another kind of is ore lithium, and spodumene mine is the Typical Representative of ore lithium.Spodumene mine obtains after ore dressing is handled
The low Fe-spodumene arrived can replace lithium carbonate, and novel cooperation is widely used as in the industries such as electronics, vessel, glass, micro-crystalline ceramic
Material has powerful fluxing capabilities, can reduce production energy consumption, and the product generated is made to have the lower coefficient of expansion.
Spodumene deposit is generally granitic pegmatite-type, often with feldspar, quartz, mica, apatite, garnet, hornblend,
The mineral association such as tourmaline, iron and manganese oxides.In addition to containing useful composition Li in spodumene mine2Outside O, also contain a large amount of SiO2、
Al2O3、Fe2O3Equal components.Since iron-bearing mineral and spodumene mineral have similar floatability, the lithium obtained after flotation is smart
Iron-bearing mineral is also enriched in mine, Fe in spodumene concentrate2O3Grade is usually above head grade, some regional spodumene mines
Fe in flotation concentrate2O3Grade is up to 5% or more.The low iron lithium concentrate Fe of lithium concentrate quality requirements of the national standard level-one2O3Grade is not
Greater than 0.15%, the low iron lithium concentrate Fe of second level2O3Grade is not more than 0.20%, the low iron lithium concentrate Fe of three-level2O3Grade is not more than
0.25%.Iron in spodumene ore is often present in spodumene mineral or arteries and veins in the form of isomorph, micro- or submicroscopic inclusion enclave
Among stone ore object, the iron in lithium concentrate can not be effectively removed using simple magnetic concentration working, it is often necessary to chloridising roasting, pickling
Etc. chemical methodes iron could be down under qualified level, these method high production cost, and have very big pollution to environment,
Production application has significant limitation.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of preparation methods of low Fe-spodumene, this preparation method is not
It is related to complicated chemical reaction, can be only realized by way of physical upgrading.
In order to solve the above technical problems, the present invention provides a kind of novel preparation method of low Fe-spodumene, this method includes
Following steps:
(1) the levigate extremely -0.074mm grade of spodumene raw ore is accounted for 60~80%；
(2) neopelex is added, dosage is 50~200g/t, and stirring is sized mixing 5 minutes；
(3) reverse flotation is carried out, by the particulate sludge and the impure minerals emersion such as iron, manganese, calcium in ore pulp；
(4) sodium hydroxide is added in ore pulp, dosage is 600~1500g/t, and stirring is added after twenty minutes by oleic acid and hexadecane
The compounding collecting agent of base trimethyl ammonium chloride composition, compounding mass ratio are 16:1, and dosage is 100~400g/t, stir and size mixing 5
Minute；
(5) one thick, two essences are carried out, two sweep direct flotation, obtain spodumene flotation concentrate；
(6) dosage is added in flotation concentrate to size mixing 5 points to be stirred after the polyoxyethyl propyl polyoxyethanyl glycerin ether of 3~5g/t
Clock；
(7) the spodumene flotation concentrate after sizing mixing carries out wet type low intensity magnetic separation and High gradient high intensity magnetic separation Iron removal by two steps, obtains final
Low Fe-spodumene concentrate product.
The neopelex being related in step (2) is anion collecting agent, is had to iron, calcium mineral stronger
Collecting performance, while there is very strong frothing capacity.Micro-size fraction sludge is easy to be attached on bubble, and on a large amount of bubbles
It is floating.Therefore reverse flotation is carried out after neopelex being added, a large amount of sludges can be not only removed, play desliming；And
And also do not enter these mineral in spodumene flotation concentrate most of iron, manganese, calcium mineral emersion, it is low Fe-spodumene system
Standby important step.
The polyoxyethyl propyl polyoxyethanyl glycerin ether being related in step (6) plays defoaming to spodumene flotation concentrate and dispersion is made
With the generation of reduction hydrophobicity floc sedimentation can greatly improve the effect of magnetic separation separation.
The spodumene concentrate Fe handled using the method for the present invention2O3Grade can be down to 0.15~0.25%, reach low iron
Lithium concentrate is to the quality requirement of iron content, while this method also has the lithium concentrate rate of recovery high, and process is simple, is convenient for industrial realization
The advantages of.
Detailed description of the invention
Attached drawing 1 is low Fe-spodumene preparation technology flow chart.
Specific embodiment
Below according to embodiment, the present invention will be further described.
Embodiment 1:
Contain Li in the spodumene mine of Sichuan2O grade is 1.38%, and -0.074mm grain size content accounts for 70% after ore grinding, and 100 g/t are added
The neopelex of dosage, stirring are sized mixing 5 minutes, and reverse flotation is carried out.The hydroxide of 800 g/t dosages is added in ore pulp
The compounding collecting agents of 200 g/t dosages is added in sodium, stirring after twenty minutes, and stirring is sized mixing 5 minutes, carries out one thick, two essences, two sweeps just
Flotation obtains spodumene flotation concentrate.It is laggard that the polyoxyethyl propyl polyoxyethanyl glycerin ether that dosage is 3g/t is added in flotation concentrate
Row stirring is sized mixing 5 minutes, and the spodumene flotation concentrate after sizing mixing carries out wet type low intensity magnetic separation and High gradient high intensity magnetic separation Iron removal by two steps,
The magnetic field strength of two stages of magnetic separation is respectively 0.6T and 1.2T, obtains final low Fe-spodumene concentrate product.Reverse flotation is obtained respectively
To impurity mine, the tailing of direct flotation, low intensity magnetic separation be filtered containing iron ore, high intensity magnetic separation containing iron ore and low Fe-spodumene concentrate, dry
Dry, weighing, chemical examination, obtain the production target that low Fe-spodumene is prepared using the method for the present invention, and data are as shown in the table.
Embodiment 2:
Contain Li in certain Australian spodumene mine2O grade is 1.62%, and -0.074mm grain size content accounts for 80% after ore grinding, is added 200
The neopelex of g/t dosage, stirring are sized mixing 5 minutes, and reverse flotation is carried out.The hydrogen of 1500 g/t dosages is added in ore pulp
The compounding collecting agent of 400 g/t dosages is added in sodium oxide molybdena, stirring after twenty minutes, and stirring is sized mixing 5 minutes, carries out thick, two essences, two
Direct flotation is swept, spodumene flotation concentrate is obtained.The polyoxyethyl propyl polyoxyethanyl glycerin ether that dosage is 5g/t is added in flotation concentrate
After be stirred and size mixing 5 minutes, the spodumene flotation concentrate after sizing mixing carries out wet type low intensity magnetic separation and two sections of High gradient high intensity magnetic separation
Except iron, the magnetic field strength of two stages of magnetic separation is respectively 0.6T and 1.2T, obtains final low Fe-spodumene concentrate product.It counter will float respectively
Obtained impurity mine, the tailing of direct flotation, low intensity magnetic separation is selected to carry out containing iron ore, high intensity magnetic separation containing iron ore and low Fe-spodumene concentrate
Filter, drying, weighing, chemical examination, obtain the production target that low Fe-spodumene is prepared using the method for the present invention, and data such as following table is such as shown.
Embodiment 3:
Contain Li in the spodumene mine of Xinjiang2O grade is 1.45%, and -0.074mm grain size content accounts for 60% after ore grinding, and 50 g/t are added
The neopelex of dosage, stirring are sized mixing 5 minutes, and reverse flotation is carried out.The hydroxide of 600 g/t dosages is added in ore pulp
The compounding collecting agents of 100 g/t dosages is added in sodium, stirring after twenty minutes, and stirring is sized mixing 5 minutes, carries out one thick, two essences, two sweeps just
Flotation obtains spodumene flotation concentrate.It is laggard that the polyoxyethyl propyl polyoxyethanyl glycerin ether that dosage is 3g/t is added in flotation concentrate
Row stirring is sized mixing 5 minutes, and the spodumene flotation concentrate after sizing mixing carries out wet type low intensity magnetic separation and High gradient high intensity magnetic separation Iron removal by two steps,
The magnetic field strength of two stages of magnetic separation is respectively 0.6T and 1.2T, obtains final low Fe-spodumene concentrate product.Reverse flotation is obtained respectively
To impurity mine, the tailing of direct flotation, low intensity magnetic separation be filtered containing iron ore, high intensity magnetic separation containing iron ore and low Fe-spodumene concentrate, dry
Dry, weighing, chemical examination, obtain the production target that low Fe-spodumene is prepared using the method for the present invention, and data are as shown in the table.
。
Claims (1)
1. a kind of low Fe-spodumene preparation method, which is characterized in that described method includes following steps:
(1) the levigate extremely -0.074mm grade of spodumene raw ore is accounted for 60~80%；
(2) neopelex is added, dosage is 50~200g/t, and stirring is sized mixing 5 minutes；
(3) reverse flotation is carried out, by the particulate sludge and the impure minerals emersion such as iron, manganese, calcium in ore pulp；
(4) sodium hydroxide is added in ore pulp, dosage is 600~1500g/t, and stirring is added after twenty minutes by oleic acid and hexadecane
The compounding collecting agent of base trimethyl ammonium chloride composition, compounding mass ratio are 16:1, and dosage is 100~400g/t, stir and size mixing 5
Minute；
(5) one thick, two essences are carried out, two sweep direct flotation, obtain spodumene flotation concentrate；
(6) dosage is added in flotation concentrate to size mixing 5 points to be stirred after the polyoxyethyl propyl polyoxyethanyl glycerin ether of 3~5g/t
Clock；
(7) the spodumene flotation concentrate after sizing mixing carries out wet type low intensity magnetic separation and High gradient high intensity magnetic separation Iron removal by two steps, obtains final
Low Fe-spodumene concentrate product.
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|---|---|
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Family
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109939813A (en) * | 2019-04-24 | 2019-06-28 | 葫芦岛八家矿业股份有限公司 | The secondary enrichment comprehensive recovering process of sulphur silver ferrimanganic valuable element in a kind of tailing |
| CN113245065A (en) * | 2021-06-09 | 2021-08-13 | 东北大学 | Micro-fine particle quartz reverse flotation combined collecting agent and reverse flotation method |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2748938A (en) * | 1952-06-23 | 1956-06-05 | Armour & Co | Flotation of spodumene |
| US6422393B1 (en) * | 2000-04-14 | 2002-07-23 | Jeffrey Van Jahnke | Recovery from fine froth flotation feed (slimes) |
| CN102909136A (en) * | 2012-10-29 | 2013-02-06 | 江西理工大学 | Ore dressing method of spodumene quarry |
| CN103418488A (en) * | 2013-08-23 | 2013-12-04 | 中国地质科学院矿产综合利用研究所 | Comprehensive recovery process of lithium polymetallic ore associated with fine niobium and tantalum |
| CN103977905A (en) * | 2014-05-27 | 2014-08-13 | 四川天齐盛合锂业有限公司 | Spodumene ore processing method |
| CN107159446A (en) * | 2017-06-19 | 2017-09-15 | 西南科技大学 | A kind of method of pegmatite type spodumene efficient flotation separation |
| CN108525858A (en) * | 2018-04-19 | 2018-09-14 | 江西金辉再生资源股份有限公司 | The method of tantalum niobium ore dressing plant tailings recycling lepidolite concentrate |
-
2018
- 2018-09-27 CN CN201811131821.3A patent/CN109290050A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2748938A (en) * | 1952-06-23 | 1956-06-05 | Armour & Co | Flotation of spodumene |
| US6422393B1 (en) * | 2000-04-14 | 2002-07-23 | Jeffrey Van Jahnke | Recovery from fine froth flotation feed (slimes) |
| CN102909136A (en) * | 2012-10-29 | 2013-02-06 | 江西理工大学 | Ore dressing method of spodumene quarry |
| CN103418488A (en) * | 2013-08-23 | 2013-12-04 | 中国地质科学院矿产综合利用研究所 | Comprehensive recovery process of lithium polymetallic ore associated with fine niobium and tantalum |
| CN103977905A (en) * | 2014-05-27 | 2014-08-13 | 四川天齐盛合锂业有限公司 | Spodumene ore processing method |
| CN107159446A (en) * | 2017-06-19 | 2017-09-15 | 西南科技大学 | A kind of method of pegmatite type spodumene efficient flotation separation |
| CN108525858A (en) * | 2018-04-19 | 2018-09-14 | 江西金辉再生资源股份有限公司 | The method of tantalum niobium ore dressing plant tailings recycling lepidolite concentrate |
Non-Patent Citations (2)
| Title |
|---|
| 庄杜娟: ""某锂辉石矿选矿工艺试验研究"", 《新疆有色金属》 * |
| 赖复兴: ""不加温浮选锂辉石矿和低铁锂辉石选矿扩大试验"", 《新疆有色金属》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109939813A (en) * | 2019-04-24 | 2019-06-28 | 葫芦岛八家矿业股份有限公司 | The secondary enrichment comprehensive recovering process of sulphur silver ferrimanganic valuable element in a kind of tailing |
| CN113245065A (en) * | 2021-06-09 | 2021-08-13 | 东北大学 | Micro-fine particle quartz reverse flotation combined collecting agent and reverse flotation method |
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