CN109283297A - Hydrogen on-line analysis separate calibrations sampling system - Google Patents

Hydrogen on-line analysis separate calibrations sampling system Download PDF

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Publication number
CN109283297A
CN109283297A CN201811308688.4A CN201811308688A CN109283297A CN 109283297 A CN109283297 A CN 109283297A CN 201811308688 A CN201811308688 A CN 201811308688A CN 109283297 A CN109283297 A CN 109283297A
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interface
sensing unit
valve
threeway
purity
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CN201811308688.4A
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CN109283297B (en
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汪献忠
李建国
宋跃峰
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Henan Relations Co Ltd
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Henan Relations Co Ltd
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004Gaseous mixtures, e.g. polluted air
    • G01N33/0009General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G01N33/0036General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component
    • G01N33/005H2
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N35/00Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor
    • G01N35/10Devices for transferring samples or any liquids to, in, or from, the analysis apparatus, e.g. suction devices, injection devices
    • G01N35/1009Characterised by arrangements for controlling the aspiration or dispense of liquids
    • G01N35/1011Control of the position or alignment of the transfer device

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Combustion & Propulsion (AREA)
  • Food Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

Hydrogen on-line analysis separate calibrations sampling system comprising sample gas air inlet pipeline, calibration gas air inlet pipeline, purity determination calibration switching valve, oxygen measurement calibration switching valve, pressure reducer, humidity sensing unit, purity sensing unit, oxygen sensor unit, humidity sensing unit protection valve, purity sensing unit protection valve, oxygen sensor cell protection valve, emptying pipeline, the first threeway, the second threeway, third threeway, the first regulating flow quantity meter, the second regulating flow quantity meter, automatic drained oil filter group and sampling line;The present invention is that collection gas sampling, calibration, analysis (or detection) and sensing unit are protected in integrated multi-functional sampling system.The present invention can make sample gas meet the requirement of each sensing unit in-site measurement well, ensure that the work that each sensing unit can be steady in a long-term.

Description

Hydrogen on-line analysis separate calibrations sampling system
Technical field
The invention belongs to hydrogen online measuring technique fields, and in particular to the hydrogen of a kind of pair of generator hydrogen quality is online Analyze separate calibrations sampling system.
Background technique
State time generator group mostly uses greatly hydrogen-cooled technology at present, " GB26164.1-2010 electric industry safety code first Point heating power and machinery ", the specifications normative document such as " GB 4962-2008 hydrogen uses act of technique for security " is to generator hydrogen The on-line checking of hydrogen purity, humidity and oxygen content is provided in system, and these contents are Compulsory Feature.
For enable generating set it is safe and reliable, it is economical, steadily run, hydrogen quality in raising machine (such as purity, Humidity and oxygen content) measurement accuracy be very necessary.Therefore, scene is real online to hydrogen purity, humidity and oxygen content When monitoring sensing unit maintenance more stringent requirements are proposed, due to sensor self-characteristic determine drift and problem of aging without Method avoids, and periodically irregular calibration and comparison are necessary.
Summary of the invention
In order to solve shortcoming in the prior art, the hydrogen for providing a kind of generator hydrogen quality divides the present invention online Separate calibrations sampling system is analysed, which mainly completes gas sampling, hydrogen humidity is pressing measurement, hydrogen purity and oxygen content normal The gas circuit protection of pressure measurement, the separate calibrations of purity and oxygen content sensing unit and sensing unit.
In order to solve the above technical problems, the present invention adopts the following technical scheme: hydrogen on-line analysis separate calibrations sampling system System comprising sample gas air inlet pipeline, calibration gas air inlet pipeline, purity determination calibration switching valve, oxygen measurement calibration are cut Valve, pressure reducer, humidity sensing unit, purity sensing unit, oxygen sensor unit, humidity sensing unit protection valve, purity is changed to pass Feel cell protection valve, oxygen sensor cell protection valve, emptying pipeline, the first threeway, the second threeway, third threeway, first adjustable Throttle meter, the second regulating flow quantity meter, automatic drained oil filter group and sampling line;
Humidity sensing unit protects valve, purity sensing unit protection valve, the construction of oxygen sensor cell protection valve identical, all has A interface, B interface, C interface and D interface, wherein A interface is air inlet, and the channel internal A-B, C-D can be cut by rotating valve shaft Change the channel A-D, B-C into;
The inlet end of sample gas air inlet pipeline is connect with generator hydrogen main pipeline, the gas outlet of sample gas air inlet pipeline with Automatic drained oil filter group air inlet is connected, and automatic drained oil filter group gas outlet is connected to first interface of the first threeway, Second interface of the first threeway and the air inlet of sampling line connect, the third interface and humidity sensing unit of the first threeway The A interface of valve is protected to be connected, humidity sensing unit is serially connected between the B interface and C interface of humidity sensing unit protection valve, wet The D interface of degree sensing unit protection valve is connected with the air inlet of pressure reducer;First of the gas outlet of pressure reducer and the second threeway Interface is connected, and gas is divided into two-way by the second threeway, the second interface and third interface of the second threeway are surveyed with purity respectively First interface of amount calibration switching valve is connected with first interface of oxygen measurement calibration switching valve;
The air inlet of calibration gas air inlet pipeline is used to connect external Standard Gases gas source, the gas outlet of calibration gas air inlet pipeline It is connected with first interface of third threeway;Gas is divided into two-way, the second interface of third threeway and by third threeway Three interfaces calibrate second interface phase of switching valve with second interface of purity determination calibration switching valve and oxygen measurement respectively Even;
The third interface of purity determination calibration switching valve is connected with the air inlet of the first regulating flow quantity meter, the first adjustable throttling The gas outlet of meter is connected with the A interface of purity sensing unit protection valve 5B, and it is single that purity sensing unit is series at purity sensing Between the B interface and C interface of member protection valve, the D interface of purity sensing unit protection valve is connected with emptying pipeline;
The third interface of oxygen measurement calibration switching valve is connected with the air inlet of the second regulating flow quantity meter, the second adjustable throttling The gas outlet of meter is connected with the A mouth of oxygen sensor cell protection valve, and oxygen sensor unit is series at oxygen sensor unit guarantor It protects between the B interface and C interface of valve, the D interface of oxygen sensor cell protection valve 5C is connected by the 4th threeway with emptying pipeline.
Sampling valve is provided on sampling line, the gas outlet of sampling line is sample tap.
It further include the mounting rack for part each in fixed installation system, mounting rack is provided with the peace for fixing and mounting bracket Fill hole.
By adopting the above technical scheme, humidity sensing unit protection valve, purity sensing unit protection valve, oxygen pass in the present invention Three sensing units are measuring state when the inside of sense cell protection valve is in A-B, C-D connected state, and inside is in A-D, B-C Three sensing units are in by guard mode when connected state, and sensing unit is isolated with gas circuit, can also remove sensing unit at this time It repairs.
The present invention is that collection gas sampling, calibration, analysis (or detection) and sensing unit are protected in integrated multi-functional sampling System.
When normal work, the gas that samples from generator hydrogen main pipeline is followed by sample gas air inlet pipeline, automatic Draining oil filter group, humidity sensing unit protect the D of A interface, humidity sensing unit, humidity sensing unit protection the valve 5A of valve to connect Mouth, pressure reducer, are divided into two-way by the second threeway, sequentially enter purity determination calibration switching valve, the first regulating flow quantity all the way The A interface of meter, purity sensing unit protection valve, enters finally into and carries out hydrogen purity measurement in purity sensing unit;Another way Sequentially enter oxygen measurement calibration switching valve, the second regulating flow quantity meter, oxygen sensor cell protection valve A interface, it is most laggard Enter into oxygen sensor unit and carries out the measurement of oxygen content in hydrogen;Respectively from the outlet of purity sensing unit protection valve after measurement The gas outlet D of mouth D and oxygen sensor cell protection valve imports emptying pipeline.
Purity determination calibrates switching valve and oxygen measurement calibration switching valve is used to the sample gas and calibration gas of switch sampling Body.When being calibrated to a certain sensing unit in purity sensing unit and oxygen sensor unit, rotates corresponding measurement purity and survey Amount calibration switching valve or oxygen measurement calibrate switching valve to align mode, connect calibration gas air inlet pipeline, and calibrating gas is from school The air inlet of quasi- gas inlet pipeline enters, and calibrates switching valve or oxygen measurement calibration switching valve, the followed by purity determination After one regulating flow quantity meter or the second regulating flow quantity meter, purity sensing unit protection valve or oxygen sensor cell protection valve respectively Sensing unit is calibrated inside into purity sensing unit and oxygen sensor unit, and humidity sensing unit is still within pair The monitoring state of sample gas.
When needed, the external standard of sample tap (humidity, purity, oxygen) instrument, and sampling valve is opened, it equally can be to sampling Gas is detected, so as to the testing number with humidity sensing unit, purity sensing unit and oxygen sensor unit in the present invention According to being compared, the reliability and accuracy of detection data are judged.
In conclusion the invention has the following advantages:
1, the present invention can make sample gas meet the requirement of each sensing unit in-site measurement well, ensure that each sensing unit can be grown Phase stable work.
2, the present invention automatic drained oil filter group is provided in gas circuit, can automatic pollution discharge, prevent sensing unit oily pollution, Ensure the service life of each sensing unit in hydrogen quality system, reduce maintenance, reduces maintenance cost.
3, the present invention provides calibration gas air inlet pipeline, uses convenient for the independent calibration of purity and oxygen content sensing unit;
4, the carbon dioxide gas when entering the gas for having injury to sensing unit in system such as in hydrogen replacement process, this hair It is bright sensing unit and isolation of system to be opened, protect sensing unit not to be damaged;Sensing unit can also prevent when removing maintenance Gas leakage.
5, the present invention provides sampling valve and sample tap, and access master meter is facilitated to be compared with the data of on-line monitoring, Judge the reliability and accuracy of detection data.
Detailed description of the invention
Fig. 1 is structural schematic diagram of the invention.
Specific embodiment
As shown in Figure 1, hydrogen on-line analysis separate calibrations sampling system of the invention comprising sample gas air inlet pipeline 1, calibration gas air inlet pipeline 2, purity determination calibration switching valve 3A, oxygen measurement calibration switching valve 3B, pressure reducer 4, humidity pass Feel unit 6, purity sensing unit 7, oxygen sensor unit 8, humidity sensing unit protection valve 5A, purity sensing unit and protects valve 5B, oxygen sensor cell protection valve 5C, emptying pipeline 9, the first threeway 12, the second threeway 17, third threeway 16, first are adjustable Flowmeter 13A, the second regulating flow quantity meter 13B, automatic drained oil filter group 14 and sampling line 18;
Humidity sensing unit protects valve 5A, purity sensing unit protection valve 5B, the construction of oxygen sensor cell protection valve 5C identical, A interface, B interface, C interface and D interface are all had, wherein A interface is air inlet, and the channel internal A-B, C-D can pass through rotation Valve shaft switches to the channel A-D, B-C;
The inlet end of sample gas air inlet pipeline 1 is connect with generator hydrogen main pipeline, the gas outlet of sample gas air inlet pipeline 1 It is connected with 14 air inlet of automatic drained oil filter group, 14 gas outlet of automatic drained oil filter group is connected to the first of the first threeway 12 Second interface of a interface, the first threeway 12 is connect with the air inlet of sampling line 18, the third interface of the first threeway 12 It is connected with the A interface of humidity sensing unit protection valve 5A, humidity sensing unit 6 is serially connected with humidity sensing unit protection valve 5A's Between B interface and C interface, the D interface of humidity sensing unit protection valve 5A is connected with the air inlet of pressure reducer 4;Pressure reducer 4 goes out Port is connected with first interface of the second threeway 17, and gas is divided into two-way by the second threeway 17, and the of the second threeway 17 Two interfaces and third interface calibrate switching valve 3B with first interface of purity determination calibration switching valve 3A and oxygen measurement respectively First interface be connected;
The air inlet of calibration gas air inlet pipeline 2 is used to connect external Standard Gases gas source, the outlet of calibration gas air inlet pipeline 2 Mouth is connected with first interface of third threeway 16;Gas is divided into two-way by third threeway 16, the second of third threeway 16 Interface and third interface calibrate switching valve 3B's with second interface of purity determination calibration switching valve 3A and oxygen measurement respectively Second interface is connected;
The third interface of purity determination calibration switching valve 3A is connected with the air inlet of the first regulating flow quantity meter 13A, and first can The gas outlet for adjusting flowmeter 13A is connected with the A interface of purity sensing unit protection valve 5B, and purity sensing unit 7 is series at Purity sensing unit is protected between the B interface and C interface of valve 5B, and purity sensing unit protects the D interface and emptying pipeline 9 of valve 5B It is connected;
The third interface of oxygen measurement calibration switching valve 3B is connected with the air inlet of the second regulating flow quantity meter 13B, and second can The gas outlet for adjusting flowmeter 13B is connected with the A mouth of oxygen sensor cell protection valve 5C, and oxygen sensor unit 8 is series at oxygen Gas sensing unit is protected between the B interface and C interface of valve 5C, and the D interface of oxygen sensor cell protection valve 5C passes through the 4th threeway 19 are connected with emptying pipeline 9.
Sampling valve 11 is provided on sampling line 18, the gas outlet of sampling line 18 is sample tap 10.
The invention also includes the mounting rack 15 for each part in fixed installation system, mounting rack 15 is provided with for fixing The mounting hole of mounting rack 15.
Humidity sensing unit protection valve 5A, purity sensing unit protect valve 5B, oxygen sensor cell protection valve in the present invention Three sensing units are measuring state when the inside of 5C is in A-B, C-D connected state, when inside is in A-D, B-C connected state Three sensing units are in by guard mode, and sensing unit is isolated with gas circuit, can also be removed sensing unit at this time and be repaired.
When normal work, the gas that samples from generator hydrogen main pipeline is followed by sample gas air inlet pipeline 1, automatic Draining oil filter group 14, the A interface of humidity sensing unit protection valve 5A, humidity sensing unit 6, humidity sensing unit protection valve 5A D interface, pressure reducer 4, divided by the second threeway 17 for two-way, sequentially enter purity determination calibration switching valve 3A, first all the way The A interface of regulating flow quantity meter 13A, purity sensing unit protection valve 5B, enter finally into and carry out hydrogen in purity sensing unit 7 Purity determination;Another way sequentially enters oxygen measurement calibration switching valve 3B, the second regulating flow quantity meter 13B, oxygen sensor unit The A interface for protecting valve 5C enters finally into the measurement that oxygen content in hydrogen is carried out in oxygen sensor unit 8;After measurement respectively from Purity sensing unit protects the gas outlet D of the gas outlet D and oxygen sensor cell protection valve 5C of valve 5B to import emptying pipeline 9.
Purity determination calibrates switching valve 3A and oxygen measurement calibration switching valve 3B is used to sample gas and the school of switch sampling Quasi- gas.When calibrating to a certain sensing unit in purity sensing unit 7 and oxygen sensor unit 8, corresponding measurement is rotated Purity determination calibrates switching valve 3A or oxygen measurement calibrates switching valve 3B to align mode, connects calibration gas air inlet pipeline 2, mark Quasi- gas enters from the air inlet of calibration gas air inlet pipeline 2, calibrates switching valve 3A or oxygen measurement followed by purity determination Calibrate switching valve 3B, the first regulating flow quantity meter 13A or the second regulating flow quantity meter 13B, purity sensing unit protection valve 5B or It respectively enters after oxygen sensor cell protection valve 5C and sensing unit is carried out inside purity sensing unit 7 and oxygen sensor unit 8 Calibration, and humidity sensing unit 6 is still within the monitoring state to sample gas.
Sampling valve 11 is provided on sampling line 18, the gas outlet of sampling line 18 is sample tap 10.
When needed, the external standard of sample tap 10 (humidity, purity, oxygen) instrument, and sampling valve 11 is opened, it equally can be right Sample gas is detected, so as to humidity sensing unit 6, purity sensing unit 7 and the oxygen sensor unit 8 in the present invention Detection data is compared, and judges the reliability and accuracy of detection data.
The present embodiment not makes any form of restriction shape of the invention, material, structure etc., all according to this hair Bright technical spirit any simple modification, equivalent change and modification to the above embodiments, belong to the technology of the present invention side The protection scope of case.

Claims (3)

1. hydrogen on-line analysis separate calibrations sampling system, it is characterised in that: including sample gas air inlet pipeline, calibration gas into Air pipe, purity determination calibration switching valve, oxygen measurement calibration switching valve, pressure reducer, humidity sensing unit, purity sensing are single Member, oxygen sensor unit, humidity sensing unit protection valve, purity sensing unit protection valve, oxygen sensor cell protection valve, emptying Pipeline, the first threeway, the second threeway, third threeway, the first regulating flow quantity meter, the second regulating flow quantity meter, automatic oil draining mistake Filter group and sampling line;
Humidity sensing unit protects valve, purity sensing unit protection valve, the construction of oxygen sensor cell protection valve identical, all has A interface, B interface, C interface and D interface, wherein A interface is air inlet, and the channel internal A-B, C-D can be cut by rotating valve shaft Change the channel A-D, B-C into;
The inlet end of sample gas air inlet pipeline is connect with generator hydrogen main pipeline, the gas outlet of sample gas air inlet pipeline with Automatic drained oil filter group air inlet is connected, and automatic drained oil filter group gas outlet is connected to first interface of the first threeway, Second interface of the first threeway and the air inlet of sampling line connect, the third interface and humidity sensing unit of the first threeway The A interface of valve is protected to be connected, humidity sensing unit is serially connected between the B interface and C interface of humidity sensing unit protection valve, wet The D interface of degree sensing unit protection valve is connected with the air inlet of pressure reducer;First of the gas outlet of pressure reducer and the second threeway Interface is connected, and gas is divided into two-way by the second threeway, the second interface and third interface of the second threeway are surveyed with purity respectively First interface of amount calibration switching valve is connected with first interface of oxygen measurement calibration switching valve;
The air inlet of calibration gas air inlet pipeline is used to connect external Standard Gases gas source, the gas outlet of calibration gas air inlet pipeline It is connected with first interface of third threeway;Gas is divided into two-way, the second interface of third threeway and by third threeway Three interfaces calibrate second interface phase of switching valve with second interface of purity determination calibration switching valve and oxygen measurement respectively Even;
The third interface of purity determination calibration switching valve is connected with the air inlet of the first regulating flow quantity meter, the first adjustable throttling The gas outlet of meter is connected with the A interface of purity sensing unit protection valve 5B, and it is single that purity sensing unit is series at purity sensing Between the B interface and C interface of member protection valve, the D interface of purity sensing unit protection valve is connected with emptying pipeline;
The third interface of oxygen measurement calibration switching valve is connected with the air inlet of the second regulating flow quantity meter, the second adjustable throttling The gas outlet of meter is connected with the A mouth of oxygen sensor cell protection valve, and oxygen sensor unit is series at oxygen sensor unit guarantor It protects between the B interface and C interface of valve, the D interface of oxygen sensor cell protection valve 5C is connected by the 4th threeway with emptying pipeline.
2. hydrogen on-line analysis separate calibrations sampling system according to claim 1, it is characterised in that: set on sampling line It is equipped with sampling valve, the gas outlet of sampling line is sample tap.
3. hydrogen on-line analysis separate calibrations sampling system according to claim 1, it is characterised in that: further include for solid Determine the mounting rack of each part in installation system, mounting rack is provided with the mounting hole for fixing and mounting bracket.
CN201811308688.4A 2018-11-05 2018-11-05 Independent calibration sampling system for hydrogen online analysis Active CN109283297B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110174444A (en) * 2019-06-12 2019-08-27 贵州电网有限责任公司 A kind of cooling water conductivity table mounting structure of deicing device

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JP2000171358A (en) * 1998-12-02 2000-06-23 Shimadzu Corp Gas analyzer
CN205706657U (en) * 2016-06-30 2016-11-23 安徽江淮汽车股份有限公司 A kind of Pneumatic braking system aerating device
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CN206074570U (en) * 2016-10-12 2017-04-05 河南省日立信股份有限公司 Oxygen analyzer in online hydrogen
CN106645587A (en) * 2017-01-16 2017-05-10 清华大学 Gas sensor evaluation and calibration system
CN206281835U (en) * 2016-12-07 2017-06-27 河南省日立信股份有限公司 The on-line analysis of generator hydrogen quality and sampling system
CN206281839U (en) * 2016-12-14 2017-06-27 河南省日立信股份有限公司 Hydrogen analytical sampling system in the online hydrogen purity of hydrogen generator station or oxygen
CN209167263U (en) * 2018-11-05 2019-07-26 河南省日立信股份有限公司 Hydrogen on-line analysis separate calibrations sampling system

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000171358A (en) * 1998-12-02 2000-06-23 Shimadzu Corp Gas analyzer
CN106405001A (en) * 2016-06-17 2017-02-15 大唐国际发电股份有限公司张家口发电厂 An on-line oxygen content monitoring device for hydrogen
CN205706657U (en) * 2016-06-30 2016-11-23 安徽江淮汽车股份有限公司 A kind of Pneumatic braking system aerating device
CN206074570U (en) * 2016-10-12 2017-04-05 河南省日立信股份有限公司 Oxygen analyzer in online hydrogen
CN206281835U (en) * 2016-12-07 2017-06-27 河南省日立信股份有限公司 The on-line analysis of generator hydrogen quality and sampling system
CN206281839U (en) * 2016-12-14 2017-06-27 河南省日立信股份有限公司 Hydrogen analytical sampling system in the online hydrogen purity of hydrogen generator station or oxygen
CN106645587A (en) * 2017-01-16 2017-05-10 清华大学 Gas sensor evaluation and calibration system
CN209167263U (en) * 2018-11-05 2019-07-26 河南省日立信股份有限公司 Hydrogen on-line analysis separate calibrations sampling system

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110174444A (en) * 2019-06-12 2019-08-27 贵州电网有限责任公司 A kind of cooling water conductivity table mounting structure of deicing device

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