CN109281230A - A kind of preparation method of tapa dragon flying around silk and its mechanism dragon flying around paper - Google Patents

A kind of preparation method of tapa dragon flying around silk and its mechanism dragon flying around paper Download PDF

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Publication number
CN109281230A
CN109281230A CN201811125397.1A CN201811125397A CN109281230A CN 109281230 A CN109281230 A CN 109281230A CN 201811125397 A CN201811125397 A CN 201811125397A CN 109281230 A CN109281230 A CN 109281230A
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Prior art keywords
flying around
tapa
dragon flying
paper
fiber filament
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CN201811125397.1A
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CN109281230B (en
Inventor
陈杰
童树华
孟育
张求荣
詹卫民
夏新兴
徐玉清
王励稼
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Zhejiang Jinchang Specialty Paper Co Ltd
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Zhejiang Jinchang Specialty Paper Co Ltd
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C5/00Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21DTREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
    • D21D1/00Methods of beating or refining; Beaters of the Hollander type
    • D21D1/02Methods of beating; Beaters of the Hollander type
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D21F11/02Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the Fourdrinier type
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/46Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/46Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/53Polyethers; Polyesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06Paper forming aids
    • D21H21/08Dispersing agents for fibres
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paper (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Nonwoven Fabrics (AREA)

Abstract

The present invention relates to the preparation methods of a kind of tapa dragon flying around silk and its mechanism dragon flying around paper.The first step of the invention is pectic substance and hemicellulose using sodium hydroxide and hydrogen peroxide and adjusting temperature removal tapa and improves tapa whiteness to prepare tapa fiber filament, tapa fiber filament is discongested and thickener and lubricant is added by second step, cationic substance, dispersing agent is configured to suspension, third step dilutes dragon flying around silk suspension and passing through fourdrinier wire dehydration makes dragon flying around silk be transferred to long net surface, 4th step discongests wood pulp, simultaneously filler is added in defibrination, retention agent etc. shapes on paper machine is made base paper, 5th step pressurizes the dragon flying around silk of forming with base paper compound, dragon flying around silk is transferred to base paper surface, by squeezing, it is dry, the workshop sections such as roll paper prepare dragon flying around paper.The dragon flying around paper appearance is beautiful and generous, novel in design compared to traditional printing product, has very high artistic value.

Description

A kind of preparation method of tapa dragon flying around silk and its mechanism dragon flying around paper
Technical field
The invention belongs to speciality paper manufacturing fields, and in particular to a kind of preparation of tapa dragon flying around silk, transfer forming and compound The method of molding preparation dragon flying around paper.
Background technique
Dragon flying around paper is a kind of high-grade special paper, and raw material uses natural plant fibre, and appearance has high ornamental value and skill Art value is the new special material for top grade packaging, for interior decoration decoration and building materials, clothes after also may be machined The industries such as dress, artifacts.It is used for the production of handicraft paper product currently on the market, also serves as invitation card, lampshade, decorative art of book, gift Product carton etc. uses.
Dragon flying around paper is according to plants on surface fiber filament type, form, color, texture are different and it is very characteristic.Appearance and tradition Product is printed compared to more beautiful and original, novel in design, and there is high artistic value.In the world, Japan and South Korea exist at present It maintains the leading position in the exploitation of dragon flying around paper, domestic mechanism dragon flying around paper exploitation has been achieved with certain achievement.
Summary of the invention
In view of the deficiencies of the prior art, the present invention provides the preparation sides of a kind of tapa dragon flying around silk and its mechanism dragon flying around paper Method.
Specific method of the invention is:
(1) prepared by tapa fiber filament: tapa being split and is divided into 1-10mm wide, 5-500mm long, it is dense to be then soaked in quality Degree is to be warming up to 90-150 DEG C in the sodium hydroxide solution of 2%-20%, keeps the temperature 50-120min, removes pectic substance and hemicellulose Deng.Then, it is washed with water to neutrality, being added with water to mass concentration is 3%-15%, and sodium hydroxide and the 2%-8% that 1%-8% is added are bis- Oxygen water (being the mass percent relative to tapa) is warming up to 60-120 DEG C, keeps the temperature 60-120min, washing, removing remnants Pectic substance, lignin etc. improve tapa whiteness to 85 degree or more, tapa fiber filament are made.
(2) it prepares tapa dragon flying around silk suspension: tapa fiber filament being put into one kind and is discongested in sub-wire equipment, water tune is added It is 0.1%-1% to mass concentration, starts and discongest equipment, makes fiber filament in fluffy, no bulk slurry group wadding coagulation drop, and slowly stir Dynamic holding fiber filament is in suspended dispersion always, and under water flow drive, fiber filament direction is consistent with water (flow) direction.It is added Mass percent of the thickener and lubricant A(of 0.5%-5% relative to tapa), the viscosity of water is improved, and promote fiber filament Between mutually wadding it is poly-, and equipment agitation is discongested by control, and by the speed of control water flow, so that fiber filament suitably wad a quilt with cotton and gather.It is fine Dimension silk forms certain fibre bundle after agitation.Then be added 0.1%-1% cationic substance B, the material surface have compared with Strong cationic charge interacts with anionic charge with filament surface, fibre bundle inner tight is promoted to combine, and Promote single fiber filament and fibre bundle wadding poly-, forms the fibre bundle of stable structure.The dispersing agent C of 0.5%-5% is added, The dispersing agent neutral, will not destroy the rock-steady structure of fibre bundle, be also prevented from the fibre bundle wadding group of being polymerized to.With blender Stirring, flow shear promote fibre bundle at " streamlined " and " shuttle shape " shape, and such as flowing water curve, form is graceful, the fibre Tieing up tow is " dragon flying around silk ".The length of dragon flying around silk can be adjusted as needed, and range can reach 5mm-100mm.
(3) dragon flying around silk Top wire former: " dragon flying around silk " suspension is diluted to a certain concentration, is flowed, is driven naturally by water " dragon flying around silk " is laid in long net surface, and by dehydration, " dragon flying around silk " transfer is on the surface of fourdrinier wire." dragon flying around silk " because water flow drives, Form graceful tracing pattern.
(4) base paper prepare: wood pulp through discongesting, defibrination, certain paper making additive, including filler, retention agent etc. is added, so Base paper is made in Top wire former afterwards.
(5) composite molding prepares dragon flying around paper: " the dragon flying around silk " of forming is compound with base paper, after certain pressure is compound, Dragon flying around silk is transferred to base paper surface, and using squeezing, drying, the workshop sections such as roll paper prepare dragon flying around paper.
Furtherly, chemicals A is in the agent of oxidized starch gluing, the agent of polyvinyl alcohol gluing or water-based polyurethane adhesive It is one or more.
Furtherly, cationic substance B is one or both of cationic policapram, cationic polyphosphate.
Furtherly, chemicals C dispersing agent is glyceryl monostearate, polyacrylamide and its derivative, alkylnaphthalene sulphur One or more of sour sodium, or cooperate in any proportion.
Furtherly, dragon flying around paper fiber surface " dragon flying around silk " close structure, is evenly distributed.
Furtherly, base paper is quantitative according to requiring 15-300g/m2
Beneficial effects of the present invention: with traditional printing condition ratio, the resulting dragon flying around paper of the present invention is beautiful and generous, design is new Grain husk has very high artistic value.
Detailed description of the invention
Fig. 1 is to utilize the preparation-obtained dragon flying around paper of the method for the present invention;
Fig. 2 is the partial enlarged view of Fig. 1.
Specific embodiment
The principle of the method for the present invention: tapa contains a large amount of pectic substances, lignin and hemicellulose, need to use sodium hydroxide and double Oxygen water is removed, and retains cellulose components, then is discongested sub-wire and formed under chemical assistant and flow shear effect Graceful " streamlined " and " shuttle type " shape is transferred to long net surface through fourdrinier wire dehydration, under a certain pressure, by what is prepared Base paper and dragon flying around silk pressurization is compound that dragon flying around silk is made to be transferred to base paper surface, forms dragon flying around paper.
Technical solution of the present invention:
(1) prepared by tapa fiber filament: tapa being split and is divided into 1-10mm wide, 5-500mm long, it is dense to be then soaked in quality Degree is to be warming up to 90-150 DEG C in the sodium hydroxide solution of 2%-20%, keeps the temperature 50-120min, removes pectic substance and hemicellulose Deng, be washed with water to neutrality, be added with water to mass concentration be 3%-15%, the sodium hydroxide and 2%-8% hydrogen peroxide of 1%-8% is added (being the mass percent relative to tapa) is warming up to 60-120 DEG C, keeps the temperature 60-120min, and washing removes remaining pectin Matter, lignin etc. improve tapa whiteness to 85-90 degree, tapa fiber filament are made.
(2) it prepares tapa dragon flying around silk suspension: tapa fiber filament being put into one kind and is discongested in sub-wire equipment, water tune is added It is 0.1%-1% to mass concentration, starts and discongest equipment, makes fiber filament in fluffy, no bulk slurry group wadding coagulation drop, and slowly stir Dynamic holding fiber filament is in suspended dispersion always, and under water flow drive, fiber filament direction is consistent with water (flow) direction, is added Mass percent of the thickener and lubricant A(of 0.5%-5% relative to tapa), the viscosity of water is improved, and promote fiber filament Between mutually wadding it is poly-, and equipment agitation is discongested by control, and by the speed of control water flow, so that fiber filament suitably wad a quilt with cotton and gather.It is fine Dimension silk forms certain fibre bundle after agitation.Then matter of the cationic substance B(of 0.1%-1% relative to tapa is added Measure percentage), it is allowed to interact with filament surface anionic charge, promotes fibre bundle inner tight to combine, and promote Single fiber filament and fibre bundle wadding are poly-, form the fibre bundle of stable structure.The dispersing agent C for adding 0.5%-5% is (opposite In the mass percent of tapa), while not destroying fibre bundle rock-steady structure, prevent the fibre bundle wadding group of being polymerized to.So It is stirred afterwards by blender, flow shear promotes fibre bundle at " streamlined " and " shuttle shape " shape, such as flowing water curve, shape State is graceful, which is " dragon flying around silk ", as depicted in figs. 1 and 2.
(3) dragon flying around silk Top wire former: " dragon flying around silk " suspension is diluted to a certain concentration, is flowed, is driven naturally by water " dragon flying around silk " is laid in long net surface, and by dehydration, " dragon flying around silk " transfer is on the surface of fourdrinier wire." dragon flying around silk " because water flow drives, Form graceful tracing pattern.
(4) base paper prepare: wood pulp through discongesting, defibrination, certain paper making additive, including filler, retention agent etc. is added, so 15-300g/m is made in Top wire former afterwards2Quantitative base paper.
(5) composite molding prepares dragon flying around paper: " the dragon flying around silk " of forming is compound with base paper, after certain pressure is compound, Dragon flying around silk is transferred to base paper surface, and using squeezing, drying, the workshop sections such as roll paper prepare dragon flying around paper.
Furtherly, chemicals A is in the agent of polyvinyl alcohol gluing, the agent of oxidized starch gluing or water-based polyurethane adhesive It is one or more.
Furtherly, cationic substance B is one or both of cationic polyphosphate, cationic policapram.
Furtherly, chemicals C dispersing agent is glyceryl monostearate, polyacrylamide and its derivative, alkylnaphthalene sulphur One or more of sour sodium, or cooperate in any proportion.
Furtherly, dragon flying around paper fiber surface " dragon flying around silk " close structure, is evenly distributed.
Embodiment 1
(1) prepared by tapa fiber filament: tapa being split and is divided into 1mm wide, 5mm long, being then soaked in mass concentration is 2% Sodium hydroxide solution in, be warming up to 90 DEG C, keep the temperature 50min, remove pectic substance and hemicellulose etc..Then, it is washed with water to Neutrality, being added with water to mass concentration is 3%, and the sodium hydroxide and 2% hydrogen peroxide for being added 1% (are the quality hundred relative to tapa Divide ratio), 60 DEG C, heat preservation 60min are warming up to, washing removes remnants pectic substance, lignin etc., improves tapa whiteness to 85 degree, makes Obtain tapa fiber filament.
(2) it prepares tapa dragon flying around silk suspension: tapa fiber filament being put into one kind and is discongested in sub-wire equipment, water tune is added It is 0.1% to mass concentration, starts and discongest equipment, makes fiber filament in fluffy, no bulk slurry group wadding coagulation drop, and slowly stir Keep fiber filament is in suspended dispersion always, and under water flow drive, fiber filament direction is consistent with water (flow) direction.It is added 0.5% Thickener and lubricant polyethylene alcohol adhesive (mass percent relative to tapa), improve the viscosity of water, and promote fibre It ties up mutually to wad a quilt with cotton between silk and gather, and equipment agitation is discongested by control, and pass through the speed for controlling water flow, fiber filament is made suitably to wad a quilt with cotton It is poly-.Fiber filament forms certain fibre bundle after agitation.Then 0.1% cationic substance cation polyphosphate is added, makes Interact with filament surface anionic charge, promote fibre bundle inner tight to combine, and promote single fiber filament It is poly- with fibre bundle wadding, form the fibre bundle of stable structure.The dispersing agent glyceryl monostearate for adding 0.5% is not being broken While bad fibre bundle rock-steady structure, the fibre bundle wadding group of being polymerized to is prevented.Then it is stirred by blender, flow shear promotees Make fibre bundle at " streamlined " and " shuttle shape " shape, such as flowing water curve, form is graceful, which is " dragon flying around Silk ".
(3) dragon flying around silk Top wire former: " dragon flying around silk " suspension is diluted to a certain concentration, is flowed, is driven naturally by water " dragon flying around silk " is laid in long net surface, and by dehydration, " dragon flying around silk " transfer is on the surface of fourdrinier wire." dragon flying around silk " because water flow drives, Form graceful tracing pattern.
(4) base paper prepare: wood pulp through discongesting, defibrination, certain paper making additive, including filler, retention agent etc. is added, so 15g/m is made in Top wire former afterwards2Quantitative base paper.
(5) composite molding prepares dragon flying around paper: " the dragon flying around silk " of forming is compound with base paper, after certain pressure is compound, Dragon flying around silk is transferred to base paper surface, and using squeezing, drying, the workshop sections such as roll paper prepare dragon flying around paper.
Embodiment 2
(1) prepared by tapa fiber filament: tapa being split and is divided into 5mm wide, 200mm long, being then soaked in mass concentration is In 10% sodium hydroxide solution, 120 DEG C are warming up to, keeps the temperature 80min, removes pectic substance and hemicellulose etc..Then, it is washed with water It washs to neutrality, being added with water to mass concentration is 12%, and the sodium hydroxide and 5% hydrogen peroxide for being added 5% (are relative to tapa Mass percent), 100 DEG C are warming up to, 100min is kept the temperature, washing removes remaining pectic substance, lignin etc., improves tapa whiteness To 88 degree, tapa fiber filament is made.
(2) it prepares tapa dragon flying around silk suspension: tapa fiber filament being put into one kind and is discongested in sub-wire equipment, water tune is added It is 0.5% to mass concentration, starts and discongest equipment, makes fiber filament in fluffy, no bulk slurry group wadding coagulation drop, and slowly stir Keep fiber filament is in suspended dispersion always, and under water flow drive, fiber filament direction is consistent with water (flow) direction.3% increasing is added Thick dose and the lubrication agent of oxidized starch gluing (mass percent relative to tapa), improve the viscosity of water, and promote fiber filament Between mutually wadding it is poly-, and equipment agitation is discongested by control, and by the speed of control water flow, so that fiber filament suitably wad a quilt with cotton and gather.It is fine Dimension silk forms certain fibre bundle after agitation.Then be added 0.5% cationic substance cation policapram, be allowed to The interaction of filament surface anionic charge, promotes fibre bundle inner tight to combine, and promotes single fiber filament and fibre It is poly- to tie up tow wadding, forms the fibre bundle of stable structure.The dispersing agent glyceryl monostearate for adding 0.5%, is not destroying fibre While tieing up tow rock-steady structure, the fibre bundle wadding group of being polymerized to is prevented.Then it is stirred by blender, flow shear promotes fibre Tow is tieed up into " streamlined " and " shuttle shape " shape, such as flowing water curve, form is graceful, which is " dragon flying around silk ".
(3) dragon flying around silk Top wire former: " dragon flying around silk " suspension is diluted to a certain concentration, is flowed, is driven naturally by water " dragon flying around silk " is laid in long net surface, and by dehydration, " dragon flying around silk " transfer is on the surface of fourdrinier wire." dragon flying around silk " because water flow drives, Form graceful tracing pattern.
(4) base paper prepare: wood pulp through discongesting, defibrination, certain paper making additive, including filler, retention agent etc. is added, so 150g/m is made in Top wire former afterwards2Quantitative base paper.
(5) composite molding prepares dragon flying around paper: " the dragon flying around silk " of forming is compound with base paper, after certain pressure is compound, Dragon flying around silk is transferred to base paper surface, and using squeezing, drying, the workshop sections such as roll paper prepare dragon flying around paper.
Embodiment 3
(1) prepared by tapa fiber filament: tapa being split and is divided into 10mm wide, 500mm long, being then soaked in mass concentration is In 20% sodium hydroxide solution, 150 DEG C are warming up to, keeps the temperature 120min, removes pectic substance and hemicellulose etc..Then, it is washed with water It washs to neutrality, being added with water to mass concentration is 15%, and the sodium hydroxide and 8% hydrogen peroxide for being added 8% (are relative to tapa Mass percent), 120 DEG C are warming up to, 120min is kept the temperature, washing removes remaining pectic substance, lignin etc., improves tapa whiteness To 90 degree, tapa fiber filament is made.
(2) it prepares tapa dragon flying around silk suspension: tapa fiber filament being put into one kind and is discongested in sub-wire equipment, water tune is added It is 1% to mass concentration, starts and discongest equipment, makes fiber filament in fluffy, no bulk slurry group wadding coagulation drop, and slowly agitation is protected Hold fiber filament is in suspended dispersion always, and under water flow drive, fiber filament direction is consistent with water (flow) direction.5% thickening is added Agent and lubricant water-based polyurethane adhesive (mass percent relative to tapa), improve the viscosity of water, and promote fiber Mutually wadding is poly- between silk, and discongests equipment agitation by control, and by the speed of control water flow, so that fiber filament is suitably wadded a quilt with cotton poly-. Fiber filament forms certain fibre bundle after agitation.Then 1% cationic substance cation polyphosphate and cation is added Policapram mixture is allowed to interact with filament surface anionic charge, fibre bundle inner tight is promoted to combine, and Promote single fiber filament and fibre bundle wadding poly-, forms the fibre bundle of stable structure.Add 0.5% dispersing agent tristearin Sour monoglyceride prevents the fibre bundle wadding group of being polymerized to while not destroying fibre bundle rock-steady structure.Then pass through blender Stirring, flow shear promote fibre bundle at " streamlined " and " shuttle shape " shape, and such as flowing water curve, form is graceful, the fibre Tieing up tow is " dragon flying around silk ".
(3) dragon flying around silk Top wire former: " dragon flying around silk " suspension is diluted to a certain concentration, is flowed, is driven naturally by water " dragon flying around silk " is laid in long net surface, and by dehydration, " dragon flying around silk " transfer is on the surface of fourdrinier wire." dragon flying around silk " because water flow drives, Form graceful tracing pattern.
(4) base paper prepare: wood pulp through discongesting, defibrination, certain paper making additive, including filler, retention agent etc. is added, so 300g/m is made in Top wire former afterwards2Quantitative base paper.
(5) composite molding prepares dragon flying around paper: " the dragon flying around silk " of forming is compound with base paper, after certain pressure is compound, Dragon flying around silk is transferred to base paper surface, and using squeezing, drying, the workshop sections such as roll paper prepare dragon flying around paper.

Claims (2)

1. a kind of mechanism dragon flying around Preparation Method made of paper based on tapa dragon flying around silk, it is characterised in that:
The preparation of tapa fiber filament: the first step tapa is split and is divided into 1-10mm wide, 5-500mm long, is then soaked in matter It measures in the sodium hydroxide solution that concentration is 2%-20%, is warming up to 90-150 DEG C, keep the temperature 50-120min, remove pectic substance and half fiber Dimension element, is washed with water to neutrality, and being added with water to mass concentration is 3%-15%, and addition is relative to the mass percent of tapa The hydrogen peroxide that the sodium hydroxide of 1%-8% and mass percent relative to tapa are 2%-8%, is warming up to 60-120 DEG C, heat preservation 60-120min, washing remove remaining pectic substance and lignin, improve tapa whiteness to 85-90 degree, tapa fiber filament is made;
Second step prepares tapa dragon flying around silk suspension: tapa fiber filament investment being discongested in sub-wire equipment, matter is added with water to Amount concentration is 0.1%-1%, starts and discongests equipment, makes fiber filament in fluffy, no bulk slurry group wadding coagulation drop, and slowly agitation is protected Hold fiber filament is in suspended dispersion always, and under water flow drive, fiber filament direction is consistent with water (flow) direction, is added relative to structure The mass percent of bark is the thickened lubricant A of 0.5%-5%, improves the viscosity of water, and it is poly- to promote mutually to wad a quilt with cotton between fiber filament, And the speed of equipment agitation and control water flow is discongested by control, so that fiber filament is suitably wadded a quilt with cotton poly-;
Fiber filament forms certain fibre bundle after agitation;Then being added relative to the mass percent of tapa is 0.1%- 1% cationic substance B is allowed to interact with filament surface anionic charge, fibre bundle inner tight is promoted to combine, And promote single fiber filament and fibre bundle wadding poly-, form the fibre bundle of stable structure;
The dispersing agent C for being 0.5%-5% relative to the mass percent of tapa is added, fibre bundle rock-steady structure is not being destroyed While, prevent the fibre bundle wadding group of being polymerized to;Then it is stirred by blender, flow shear promotes fibre bundle at " streamline Type " and " shuttle shape " shape, the fibre bundle are " dragon flying around silk ";
Dragon flying around silk Top wire former: " dragon flying around silk " suspension is diluted to a certain concentration, is flowed, driven naturally by water by third step " dragon flying around silk " is laid in long net surface, and by dehydration, " dragon flying around silk " transfer is on the surface of fourdrinier wire;
4th step, base paper preparation: wood pulp through discongesting, defibrination, certain paper making additive, including filler, retention agent is added, then 15-300g/m is made in Top wire former2Quantitative base paper;
5th step, composite molding prepare dragon flying around paper: " the dragon flying around silk " of forming is compound with base paper, after certain pressure is compound, Dragon flying around silk is transferred to base paper surface, and using including squeezing, drying, roll paper prepares dragon flying around paper.
2. a kind of mechanism dragon flying around Preparation Method made of paper based on tapa dragon flying around silk according to claim 1, which is characterized in that The thickened lubricant A is one of the agent of polyvinyl alcohol gluing, the agent of oxidized starch gluing or water-based polyurethane adhesive Or it is a variety of, the cationic substance B is one or both of cationic polyphosphate, cationic policapram, described Dispersing agent C is one or more of glyceryl monostearate, polyacrylamide and its derivative, Negel.
CN201811125397.1A 2018-09-26 2018-09-26 Paper mulberry bark hairtail silk and preparation method of machine-made hairtail paper thereof Active CN109281230B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110576695A (en) * 2019-08-28 2019-12-17 蔡明明 novel writing brush and manufacturing method thereof

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