CN109281059A - A kind of reinforced oil absorbent material and preparation method thereof - Google Patents
A kind of reinforced oil absorbent material and preparation method thereof Download PDFInfo
- Publication number
- CN109281059A CN109281059A CN201810890012.4A CN201810890012A CN109281059A CN 109281059 A CN109281059 A CN 109281059A CN 201810890012 A CN201810890012 A CN 201810890012A CN 109281059 A CN109281059 A CN 109281059A
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- China
- Prior art keywords
- parts
- oil absorbent
- absorbent material
- preparation
- reinforced oil
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Classifications
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D1/00—Treatment of filament-forming or like material
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/12—Stretch-spinning methods
- D01D5/14—Stretch-spinning methods with flowing liquid or gaseous stretching media, e.g. solution-blowing
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
Abstract
The invention discloses a kind of reinforced oil absorbent materials, are made of the raw material of following mass fraction: 50-100 parts of polypropylene, 50-70 parts of butadiene rubber, 10-15 parts of crosslinking agent, 15-25 parts of thermoplastic elastomer (TPE), 15-20 parts of sodium chloride, 1-5 parts of gelatin, 30-50 parts of deionized water, 10-17 parts of surfactant.The invention also discloses a kind of preparation methods of reinforced oil absorbent material, comprising: raw material preparation；Liquid material is made in melting extrusion；Spinneret networking.Fiber filament drafting is formed micrometer fibers twine with high velocity, hot air by the reinforced oil absorbent material and preparation method thereof；Trimming processing is carried out to the cloth after pressing, rewinding is coiled.The present invention has rational design, easy to operate, and oil absorbing effect is good, intensity is high, can guarantee that oil absorbent material is not stratified in water.
Description
Technical field
The invention belongs to oil absorption material technical fields, and in particular to a kind of reinforced oil absorbent material and preparation method thereof.
Background technique
Oil absorbent material be a kind of fiber made of inertia polypropylene melt-blown and non-woven fabrics it is specially treated after be made, effectively inhale
Attached liquid body simultaneously keeps it here.The polypropylene fibre handled through surface activation process agent that adsorption production is all wrapped around with sewer
Or in non-woven fabrics, outer cloth and its tough and tensile durable has the powerful extremely strong adsorptivity of capillary attraction power bring.To,
It absorbs leakage liquid and flows to oil absorbent material, it is reusable after effectively preventing the diffusion of leakage, product to be twisted, squeezed, it can return
Receive the leakage fluid of 72%-90%.The advantages of this material there are also it is fire-retardant, do not generate dust, without storage limitation time etc..
Currently, it is unreasonable to there is design in common oil absorbent material and preparation method thereof in the market；And oil absorbing effect is poor, by force
Spend low, easy layering in water, the short defect of service life.
Summary of the invention
The purpose of the present invention is to provide a kind of reasonable, easy to operate, the reinforced suctions that oil absorbing effect is good, intensity is high of design
Oily cotton and preparation method thereof.
A kind of reinforced oil absorbent material, the raw material composition including following mass fraction: 50-100 parts of polypropylene, butadiene rubber
50-70 parts, 10-15 parts of crosslinking agent, 15-25 parts of thermoplastic elastomer (TPE), 15-20 parts of sodium chloride, 1-5 parts of gelatin, deionized water 30-
50 parts, 10-17 parts of surfactant.
Preferably, the thermoplastic elastomer (TPE) includes one of TPE, TPU, SBS, SEBS or several.
Preferably, the surfactant is stearic acid or neopelex.
Preferably, the crosslinking agent is prepared by following weight percent: organic acid 17-20%, inorganic base 5-7%, being had
Machine amine 13-15%, ion salt 5-9%, aldehyde 2-4%, surplus are water.
Preferably, the raw material composition including following mass fraction: 50 parts of polypropylene, 50 parts of butadiene rubber, crosslinking agent 10
Part, 15 parts of thermoplastic elastomer (TPE), 15 parts of sodium chloride, 1 part of gelatin, 30 parts of deionized water, 10 parts of surfactant.
Preferably, the raw material composition including following mass fraction: 100 parts of polypropylene, 70 parts of butadiene rubber, crosslinking agent 15
Part, 25 parts of thermoplastic elastomer (TPE), 20 parts of sodium chloride, 5 parts of gelatin, 50 parts of deionized water, 17 parts of surfactant.
A kind of preparation method of reinforced oil absorbent material, including following preparation step:
Step 1: raw material preparation takes above-mentioned mass fraction raw material to carry out mixed processing；
Step 2: melting extrusion melts mixed raw material, controls melt index 1200, and liquid material is made, by liquid original
Material is sent into pressure extrusion device, is extruded into fiber filament by the spray head of pressure extrusion device；
Step 3: fiber filament drafting is formed micrometer fibers twine with high velocity, hot air, micrometer fibers twine is sprayed by spinneret networking
On receiver board；
Step 4: reinforcing into cloth, and micrometer fibers twine is sent into drum roll, is pressed, micrometer fibers non-woven fabrics is made；
Step 5: fervent rewinding, rewinding carry out trimming processing to the cloth after pressing, trimming treated cloth are carried out
It is coiled to carry out rewinding after stitching processing for stitching processing.
Preferably, mixed processing uses dispersator to be stirred mixed processing in the step 1, and the stirring is mixed
Close speed be 850-900 revs/min, it is described be stirred the time be 5-10 minutes.
Preferably, the pressure extrusion device in the step 2 is metering pump.
Preferably, the high velocity, hot air temperature in the step 3 is 250-300 DEG C.
Beneficial effects of the present invention:
A kind of oil absorbent material of the invention and preparation method thereof, design is reasonable, easy to operate, and intensity is high, and thermoplastic is added in the feed
Property elastomer, butadiene rubber and gelatin, cooperate crosslinking agent and surfactant, organic matter can be carried out effectively to stop and inhale
It is attached, and the intensity of oil absorbent material is effectively increased, it can guarantee that oil absorbent material is not stratified in water, not broken；Make during the preparation process
Mixed processing is carried out with dispersator, mixing effectively is stirred to raw material, effectively increases production efficiency.
Specific embodiment
For convenient for those skilled in the art understand that the present invention program, now in conjunction with specific embodiment to technical solution of the present invention
It is further described in detail.
A kind of reinforced oil absorbent material, the raw material composition including following mass fraction: 50-100 parts of polypropylene, butadiene rubber
50-70 parts, 10-15 parts of crosslinking agent, 15-25 parts of thermoplastic elastomer (TPE), 15-20 parts of sodium chloride, 1-5 parts of gelatin, deionized water 30-
50 parts, 10-17 parts of surfactant.
The thermoplastic elastomer (TPE) includes one of TPE, TPU, SBS, SEBS or several.The surfactant is hard
Resin acid or neopelex.
The crosslinking agent is prepared by following weight percent: organic acid 17-20%, inorganic base 5-7%, organic amine 13-
15%, ion salt 5-9%, aldehyde 2-4%, surplus are water.
Preferably, the crosslinking agent is prepared by following weight percent: organic acid 19%, inorganic base 6%, organic amine
14%, ion salt 6%, aldehyde 3%, surplus are water.
A kind of preparation method of reinforced oil absorbent material, including following preparation step:
Step 1: raw material preparation takes above-mentioned mass fraction raw material to carry out mixed processing；
Step 2: melting extrusion melts mixed raw material, controls melt index 1200, and liquid material is made, by liquid original
Material is sent into pressure extrusion device, is extruded into fiber filament by the spray head of pressure extrusion device；
Step 3: fiber filament drafting is formed micrometer fibers twine with high velocity, hot air, micrometer fibers twine is sprayed by spinneret networking
On receiver board；
Step 4: reinforcing into cloth, and micrometer fibers twine is sent into drum roll, is pressed, micrometer fibers non-woven fabrics is made；
Step 5: fervent rewinding, rewinding carry out trimming processing to the cloth after pressing, trimming treated cloth are carried out
It is coiled to carry out rewinding after stitching processing for stitching processing.
In order to improve the mixed effect of raw material and the production efficiency of product, mixed processing is using dispersion in the step 1
Blender is stirred mixed processing, and the speed that is stirred is 850-900 revs/min, described to be stirred the time as 5-
10 minutes.
In order to which the metering of raw material extrusion is accurate, the pressure extrusion device in the step 2 is metering pump.
In order to effectively improve spinneret effect and efficiency, the compactness of micron limit net, the high speed in the step 3 are improved
Hot air temperature is 250-300 DEG C.
In order to prepare different colours oil absorbent material material mixing ratio are as follows:
White oil absorbent material: white materbatch: 5kg/100kg polypropylene, hydrophilic master batch: 2kg/100kg polypropylene.
Grey oil absorbent material: grey Masterbatch: 5kg/100kg polypropylene, hydrophilic master batch: 2kg/100kg polypropylene.
Blue oil absorbent material: grey Masterbatch: 5kg/100kg polypropylene, hydrophilic master batch: 2kg/100kg polypropylene.
Yellow oil absorbent material: yellow Masterbatch: 5kg/100kg polypropylene, hydrophilic master batch: 2kg/100kg polypropylene
Embodiment 1:
The present invention is a kind of oil absorbent material, raw material including following mass fraction composition: 50 parts of polypropylene, 50 parts of butadiene rubber,
10 parts of crosslinking agent, 15 parts of thermoplastic elastomer (TPE), 15 parts of sodium chloride, 1 part of gelatin, 30 parts of deionized water, 10- parts of surfactant.
Embodiment 2:
The present invention is a kind of oil absorbent material, raw material including following mass fraction composition: 100 parts of polypropylene, 70 parts of butadiene rubber,
15 parts of crosslinking agent, 25 parts of thermoplastic elastomer (TPE), 20 parts of sodium chloride, 5 parts of gelatin, 50 parts of deionized water, 17 parts of surfactant.
The present invention program is exemplarily described invention above in conjunction with specific embodiment, it is clear that the present invention is specific
Realization is not subject to the restrictions described above, as long as using the various insubstantial of inventive concept and technical scheme of the present invention progress
Property improve, or it is not improved the conception and technical scheme of invention are directly applied into other occasions, in protection of the invention
Within the scope of.
Claims (10)
1. a kind of reinforced oil absorbent material, which is characterized in that the raw material composition including following mass fraction: 50-100 parts of polypropylene,
50-70 parts of butadiene rubber, 10-15 parts of crosslinking agent, 15-25 parts of thermoplastic elastomer (TPE), 15-20 parts of sodium chloride, 1-5 parts of gelatin,
30-50 parts of deionized water, 10-17 parts of surfactant.
2. a kind of reinforced oil absorbent material according to claim 1, which is characterized in that the thermoplastic elastomer (TPE) include TPE,
One of TPU, SBS, SEBS or several.
3. a kind of reinforced oil absorbent material according to claim 1, which is characterized in that the surfactant be stearic acid or
Neopelex.
4. according to right want 1 described in a kind of reinforced oil absorbent material, which is characterized in that the crosslinking agent is by following weight percent
Be prepared: organic acid 17-20%, inorganic base 5-7%, organic amine 13-15%, ion salt 5-9%, aldehyde 2-4%, surplus are water.
5. a kind of reinforced oil absorbent material according to claim 1, which is characterized in that the raw material group including following mass fraction
At: 50 parts of polypropylene, 50 parts of butadiene rubber, 10 parts of crosslinking agent, 15 parts of thermoplastic elastomer (TPE), 15 parts of sodium chloride, 1 part of gelatin,
30 parts of deionized water, 10 parts of surfactant.
6. a kind of reinforced oil absorbent material according to claim 1, which is characterized in that the raw material group including following mass fraction
At: 100 parts of polypropylene, 70 parts of butadiene rubber, 15 parts of crosslinking agent, 25 parts of thermoplastic elastomer (TPE), 20 parts of sodium chloride, 5 parts of gelatin,
50 parts of deionized water, 17 parts of surfactant.
7. a kind of preparation method of reinforced oil absorbent material, which is characterized in that including following preparation step:
Step 1: raw material preparation takes above-mentioned mass fraction raw material to carry out mixed processing；
Step 2: melting extrusion melts mixed raw material, controls melt index 1200, and liquid material is made, by liquid original
Material is sent into pressure extrusion device, is extruded into fiber filament by the spray head of pressure extrusion device；
Step 3: fiber filament drafting is formed micrometer fibers twine with high velocity, hot air, micrometer fibers twine is sprayed by spinneret networking
On receiver board；
Step 4: reinforcing into cloth, and micrometer fibers twine is sent into drum roll, is pressed, micrometer fibers non-woven fabrics is made；
Step 5: fervent rewinding, rewinding carry out trimming processing to the cloth after pressing, trimming treated cloth are carried out
It is coiled to carry out rewinding after stitching processing for stitching processing.
8. a kind of preparation method of reinforced oil absorbent material according to claim 7, which is characterized in that mixed in the step 1
It closes processing and mixed processing is stirred using dispersator, the speed that is stirred is 850-900 revs/min, described to stir
Mixing incorporation time is 5-10 minutes.
9. a kind of preparation method of reinforced oil absorbent material according to claim 7, which is characterized in that in the step 2
Pressure extrusion device is metering pump.
10. a kind of preparation method of reinforced oil absorbent material according to claim 7, which is characterized in that in the step 3
High velocity, hot air temperature be 250-300 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810890012.4A CN109281059A (en) | 2018-08-07 | 2018-08-07 | A kind of reinforced oil absorbent material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810890012.4A CN109281059A (en) | 2018-08-07 | 2018-08-07 | A kind of reinforced oil absorbent material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109281059A true CN109281059A (en) | 2019-01-29 |
Family
ID=65182984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810890012.4A Pending CN109281059A (en) | 2018-08-07 | 2018-08-07 | A kind of reinforced oil absorbent material and preparation method thereof |
Country Status (1)
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1694918A (en) * | 2001-09-04 | 2005-11-09 | 格雷斯公司 | Superabsorbent-hydrophobic polymer two-phase compositions |
| CN104790124A (en) * | 2015-04-28 | 2015-07-22 | 深圳市东城绿色投资有限公司 | Nanofiber non-woven fabric and preparation method thereof |
| US20170253732A1 (en) * | 2016-03-03 | 2017-09-07 | Kraiburg Tpe Gmbh & Co. Kg | Thermoplastic Elastomer Composition Comprising An Elastomer, A Non-Elastomeric Polyolefin, And A Polyolefin Block Copolymer-Based Thermoplastic Elastomer |
| CN107208336A (en) * | 2014-11-21 | 2017-09-26 | 纳幕尔杜邦公司 | For breathing equipment and the melt-spun filter medium of mask |
-
2018
- 2018-08-07 CN CN201810890012.4A patent/CN109281059A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1694918A (en) * | 2001-09-04 | 2005-11-09 | 格雷斯公司 | Superabsorbent-hydrophobic polymer two-phase compositions |
| CN107208336A (en) * | 2014-11-21 | 2017-09-26 | 纳幕尔杜邦公司 | For breathing equipment and the melt-spun filter medium of mask |
| CN104790124A (en) * | 2015-04-28 | 2015-07-22 | 深圳市东城绿色投资有限公司 | Nanofiber non-woven fabric and preparation method thereof |
| US20170253732A1 (en) * | 2016-03-03 | 2017-09-07 | Kraiburg Tpe Gmbh & Co. Kg | Thermoplastic Elastomer Composition Comprising An Elastomer, A Non-Elastomeric Polyolefin, And A Polyolefin Block Copolymer-Based Thermoplastic Elastomer |
Non-Patent Citations (1)
| Title |
|---|
| 关志宇: "《药物制剂辅料与包装材料》", 31 January 2017 * |
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Application publication date: 20190129 |