CN109267055B - Environment-friendly chromium-free passivator and preparation method thereof - Google Patents
Environment-friendly chromium-free passivator and preparation method thereof Download PDFInfo
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- CN109267055B CN109267055B CN201811385279.4A CN201811385279A CN109267055B CN 109267055 B CN109267055 B CN 109267055B CN 201811385279 A CN201811385279 A CN 201811385279A CN 109267055 B CN109267055 B CN 109267055B
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- 238000002360 preparation method Methods 0.000 title description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 44
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims abstract description 34
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims abstract description 34
- 239000008367 deionised water Substances 0.000 claims abstract description 24
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 24
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 17
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 17
- 239000004471 Glycine Substances 0.000 claims abstract description 17
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 claims abstract description 17
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229920000805 Polyaspartic acid Polymers 0.000 claims abstract description 17
- 150000001412 amines Chemical class 0.000 claims abstract description 17
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims abstract description 17
- 229910000271 hectorite Inorganic materials 0.000 claims abstract description 17
- 239000001254 oxidized starch Substances 0.000 claims abstract description 17
- 235000013808 oxidized starch Nutrition 0.000 claims abstract description 17
- 239000000467 phytic acid Substances 0.000 claims abstract description 17
- 229940068041 phytic acid Drugs 0.000 claims abstract description 17
- 235000002949 phytic acid Nutrition 0.000 claims abstract description 17
- 108010064470 polyaspartate Proteins 0.000 claims abstract description 17
- 239000001509 sodium citrate Substances 0.000 claims abstract description 17
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims abstract description 17
- 239000011684 sodium molybdate Substances 0.000 claims abstract description 17
- 235000015393 sodium molybdate Nutrition 0.000 claims abstract description 17
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011592 zinc chloride Substances 0.000 claims abstract description 17
- 235000005074 zinc chloride Nutrition 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims description 26
- 238000002156 mixing Methods 0.000 claims description 21
- 238000003756 stirring Methods 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 12
- 235000015165 citric acid Nutrition 0.000 claims description 7
- 235000011083 sodium citrates Nutrition 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 5
- 230000007797 corrosion Effects 0.000 abstract description 7
- 238000005260 corrosion Methods 0.000 abstract description 7
- 230000001681 protective effect Effects 0.000 abstract description 4
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 229910000831 Steel Inorganic materials 0.000 description 27
- 239000010959 steel Substances 0.000 description 27
- 241001163841 Albugo ipomoeae-panduratae Species 0.000 description 11
- 230000007935 neutral effect Effects 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 10
- 239000007921 spray Substances 0.000 description 10
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
- 229910001335 Galvanized steel Inorganic materials 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 5
- 239000008397 galvanized steel Substances 0.000 description 5
- 238000002161 passivation Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005246 galvanizing Methods 0.000 description 2
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical group C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 231100000171 higher toxicity Toxicity 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/40—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Abstract
The invention provides a novel environment-friendly chromium-free passivator which comprises the following raw material components in parts by weight: 30-35 parts of water-based acrylic resin, 15-20 parts of hectorite, 3.5-4 parts of citric acid, 10-12 parts of phytic acid, 7-8 parts of zinc chloride, 3-5 parts of ethylene glycol phenyl ether, 8-12 parts of glycine, 3.5-4 parts of sodium molybdate, 8-12 parts of polyaspartic acid, 4-6 parts of oxidized starch, 4-7 parts of sodium citrate, 3-3.5 parts of amine oxide and 50-55 parts of deionized water; the passivator provided by the invention can form a compact protective film on the surface of a plated part, and the formed protective film has excellent adhesive force and can be closely attached to the surface of the plated part, so that the corrosion resistance and the wear resistance of the plated part are greatly improved.
Description
Technical Field
The invention relates to the technical field of post-treatment of material surfaces, in particular to a novel environment-friendly chromium-free passivator.
Background
The galvanization and the hot galvanizing are effective ways for improving the corrosion resistance of the surface of the steel material, are widely applied to various aspects in life at present, but in a humid environment, particularly in a damp and hot environment, a galvanized layer is easy to corrode, so that a grayish or white loose corrosion product, namely white rust, is formed on the surface of the plating layer, and red rust appears after a long time, so that the corrosion resistance is lost; in order to improve the corrosion resistance of the coating, the surface of the steel material is electroplated with zinc or hot galvanized and then passivated, so that a compact passive film is formed on the surface of the coating, the corrosion resistance of the coating is improved, and the service life of a workpiece is prolonged.
The traditional galvanizing process mostly adopts solution which takes hexavalent chromium or trivalent chromium as a main component for passivation treatment, but because the hexavalent chromium has higher toxicity to human bodies, governments of various countries have strict limitation on the use of the hexavalent chromium, and particularly, parts and products which are treated by the hexavalent chromium passivation technology are definitely forbidden to be used in the EU ROHS instruction; although the toxicity of the trivalent chromium is low, the trivalent chromium is oxidized into the hexavalent chromium after being used for a period of time, so the problem of the toxicity of the hexavalent chromium cannot be fundamentally solved by using the trivalent chromium passivation process.
Therefore, a new and environment-friendly chromium-free passivation solution needs to be developed to meet the requirement of passivation of galvanized parts.
Disclosure of Invention
In view of the above, the invention provides a novel environment-friendly chromium-free passivator.
The invention provides a novel environment-friendly chromium-free passivator which comprises the following raw material components in parts by weight: 30-35 parts of water-based acrylic resin, 15-20 parts of hectorite, 3.5-4 parts of citric acid, 10-12 parts of phytic acid, 7-8 parts of zinc chloride, 3-5 parts of ethylene glycol phenyl ether, 8-12 parts of glycine, 3.5-4 parts of sodium molybdate, 8-12 parts of polyaspartic acid, 4-6 parts of oxidized starch, 4-7 parts of sodium citrate, 3-3.5 parts of amine oxide and 50-55 parts of deionized water.
Further, the paint comprises the following raw material components in parts by weight: 32 parts of water-based acrylic resin, 18 parts of hectorite, 3.5 parts of citric acid, 11 parts of phytic acid, 8 parts of zinc chloride, 4 parts of ethylene glycol phenyl ether, 10 parts of glycine, 3.5 parts of sodium molybdate, 10 parts of polyaspartic acid, 5 parts of oxidized starch, 6 parts of sodium citrate, 3.5 parts of amine oxide and 53 parts of deionized water.
The invention also provides a preparation method of the novel environment-friendly chromium-free passivator, which comprises the following steps:
(1) mixing 1/2 volume of deionized water with waterborne acrylic resin, glycine, polyaspartic acid, oxidized starch and hectorite, heating to 55-60 ℃, and stirring at the speed of 800-;
(2) mixing the rest deionized water with citric acid, phytic acid, zinc chloride, sodium molybdate, sodium citrate and amine oxide, and stirring at the speed of 200-300rpm for 15-20min to prepare a mixture II;
(3) mixing the mixture I and the mixture II with ethylene glycol phenyl ether, heating to 45-50 ℃, stirring at the speed of 800 plus one-step at 1000rpm for 120min, cooling and standing.
The invention has the beneficial effects that:
according to the passivator formula provided by the invention, the organic component and the inorganic component are compounded according to a specific dosage, and a specific process is used for preparation, so that mutual cooperation among the components is realized, a plated part can be sufficiently cleaned in the passivator, reactions such as chelation, complexation and oxidation can be carried out on the surface of the plated part, and finally a compact protective film can be formed on the surface of the plated part, and the formed protective film has excellent adhesive force and can be tightly attached to the surface of the plated part, so that the corrosion resistance and the wear resistance of the plated part are greatly improved; meanwhile, the passivator provided by the invention does not contain heavy metals such as chromium and the like, has excellent stability, no harm to the environment and human bodies, simple production process, small environmental pollution and easy operation, and meets the standard of environmental protection.
Detailed Description
The following are specific examples:
example one
The novel environment-friendly chromium-free passivator provided by the embodiment comprises the following raw material components in parts by weight: 32 parts of water-based acrylic resin, 18 parts of hectorite, 3.5 parts of citric acid, 11 parts of phytic acid, 8 parts of zinc chloride, 4 parts of ethylene glycol phenyl ether, 10 parts of glycine, 3.5 parts of sodium molybdate, 10 parts of polyaspartic acid, 5 parts of oxidized starch, 6 parts of sodium citrate, 3.5 parts of amine oxide and 53 parts of deionized water.
The method for preparing the novel environment-friendly chromium-free passivator provided by the embodiment comprises the following steps:
(1) mixing 1/2 volumes of deionized water with water-based acrylic resin, glycine, polyaspartic acid, oxidized starch and hectorite, heating to 60 ℃, and stirring at 900rpm for 85min to obtain a mixture I;
(2) mixing the rest deionized water with citric acid, phytic acid, zinc chloride, sodium molybdate, sodium citrate and amine oxide, and stirring at the speed of 250rpm for 20min to obtain a mixture II;
(3) and mixing the mixture I and the mixture II with ethylene glycol phenyl ether, heating to 50 ℃, stirring at 900rpm for 110min, cooling and standing.
Cooling the hot-galvanized steel plate to room temperature, then treating the steel plate for 80s at 30 ℃ by using the passivator obtained in the embodiment, washing the steel plate with water, and drying the steel plate by using a blower; rubbing the passivated steel plate on the surface of the test piece back and forth for 10 times at a certain pressure by using a sand-free rubber, wherein the film layer is not abraded and falls off; the white rust time of the passivated steel plate exceeds 130 hours in a neutral salt spray test.
In the case of the passivator prepared in the embodiment, the passivating process is repeated after 60 days, and the time of white rust generation of the obtained sample can still be kept over 120 hours in a neutral salt spray test.
Example two
The novel environment-friendly chromium-free passivator provided by the embodiment comprises the following raw material components in parts by weight: 30 parts of water-based acrylic resin, 20 parts of hectorite, 3.5 parts of citric acid, 12 parts of phytic acid, 7 parts of zinc chloride, 5 parts of ethylene glycol phenyl ether, 8 parts of glycine, 4 parts of sodium molybdate, 8 parts of polyaspartic acid, 6 parts of oxidized starch, 4 parts of sodium citrate, 3.5 parts of amine oxide and 50 parts of deionized water.
The method for preparing the novel environment-friendly chromium-free passivator provided by the embodiment comprises the following steps:
(1) mixing 1/2 volumes of deionized water with water-based acrylic resin, glycine, polyaspartic acid, oxidized starch and hectorite, heating to 60 ℃, and stirring at 800rpm for 90min to obtain a mixture I;
(2) mixing the rest deionized water with citric acid, phytic acid, zinc chloride, sodium molybdate, sodium citrate and amine oxide, and stirring at the speed of 300rpm for 15min to obtain a mixture II;
(3) and mixing the mixture I and the mixture II with ethylene glycol phenyl ether, heating to 45 ℃, stirring at the speed of 1000rpm for 100min, cooling and standing.
Cooling the hot-galvanized steel plate to room temperature, then treating the steel plate for 80s at 30 ℃ by using the passivator obtained in the embodiment, washing the steel plate with water, and drying the steel plate by using a blower; rubbing the passivated steel plate on the surface of the test piece back and forth for 10 times at a certain pressure by using a sand-free rubber, wherein the film layer is not abraded and falls off; the white rust time of the passivated steel plate exceeds 130 hours in a neutral salt spray test.
In the case of the passivator prepared in the embodiment, the passivating process is repeated after 60 days, and the time of white rust generation of the obtained sample can still be kept over 120 hours in a neutral salt spray test.
EXAMPLE III
The novel environment-friendly chromium-free passivator provided by the embodiment comprises the following raw material components in parts by weight: 30 parts of water-based acrylic resin, 15 parts of hectorite, 3.5 parts of citric acid, 10 parts of phytic acid, 7 parts of zinc chloride, 3 parts of ethylene glycol phenyl ether, 8 parts of glycine, 3.5 parts of sodium molybdate, 8 parts of polyaspartic acid, 4 parts of oxidized starch, 4 parts of sodium citrate, 3 parts of amine oxide and 50 parts of deionized water.
The method for preparing the novel environment-friendly chromium-free passivator provided by the embodiment comprises the following steps:
(1) mixing 1/2 volumes of deionized water with water-based acrylic resin, glycine, polyaspartic acid, oxidized starch and hectorite, heating to 55 ℃, and stirring at 800rpm for 80min to obtain a mixture I;
(2) mixing the rest deionized water with citric acid, phytic acid, zinc chloride, sodium molybdate, sodium citrate and amine oxide, and stirring at 200rpm for 15min to obtain a mixture II;
(3) and mixing the mixture I and the mixture II with ethylene glycol phenyl ether, heating to 45 ℃, stirring at 800rpm for 100min, cooling and standing.
Cooling the hot-galvanized steel plate to room temperature, then treating the steel plate for 80s at 30 ℃ by using the passivator obtained in the embodiment, washing the steel plate with water, and drying the steel plate by using a blower; rubbing the passivated steel plate on the surface of the test piece back and forth for 10 times at a certain pressure by using a sand-free rubber, wherein the film layer is not abraded and falls off; the white rust time of the passivated steel plate exceeds 120 hours in a neutral salt spray test.
The passivating agent prepared in the embodiment is used, the passivating process is repeated after 60 days, and the time of white rust of the obtained sample in a neutral salt spray test can be still kept to be more than 110 hours.
Example four
The novel environment-friendly chromium-free passivator provided by the embodiment comprises the following raw material components in parts by weight: 35 parts of water-based acrylic resin, 20 parts of hectorite, 4 parts of citric acid, 12 parts of phytic acid, 8 parts of zinc chloride, 5 parts of ethylene glycol phenyl ether, 12 parts of glycine, 4 parts of sodium molybdate, 12 parts of polyaspartic acid, 6 parts of oxidized starch, 7 parts of sodium citrate, 3.5 parts of amine oxide and 55 parts of deionized water.
The method for preparing the novel environment-friendly chromium-free passivator provided by the embodiment comprises the following steps:
(1) mixing 1/2 volumes of deionized water with water-based acrylic resin, glycine, polyaspartic acid, oxidized starch and hectorite, heating to 60 ℃, and stirring at 1000rpm for 90min to obtain a mixture I;
(2) mixing the rest deionized water with citric acid, phytic acid, zinc chloride, sodium molybdate, sodium citrate and amine oxide, and stirring at the speed of 300rpm for 20min to obtain a mixture II;
(3) and mixing the mixture I and the mixture II with ethylene glycol phenyl ether, heating to 50 ℃, stirring at 1000rpm for 120min, cooling and standing.
Cooling the hot-galvanized steel plate to room temperature, then treating the steel plate for 80s at 30 ℃ by using the passivator obtained in the embodiment, washing the steel plate with water, and drying the steel plate by using a blower; rubbing the passivated steel plate on the surface of the test piece back and forth for 10 times at a certain pressure by using a sand-free rubber, wherein the film layer is not abraded and falls off; the white rust time of the passivated steel plate exceeds 150 hours in a neutral salt spray test.
In the case of the passivator prepared in the embodiment, the passivating process is repeated after 60 days, and the time for white rust of the obtained sample in a neutral salt spray test can be still kept to be more than 140 hours.
EXAMPLE five
The novel environment-friendly chromium-free passivator provided by the embodiment comprises the following raw material components in parts by weight: 35 parts of water-based acrylic resin, 15 parts of hectorite, 4 parts of citric acid, 10 parts of phytic acid, 8 parts of zinc chloride, 3 parts of ethylene glycol phenyl ether, 12 parts of glycine, 3.5 parts of sodium molybdate, 12 parts of polyaspartic acid, 4 parts of oxidized starch, 7 parts of sodium citrate, 3 parts of amine oxide and 55 parts of deionized water.
The method for preparing the novel environment-friendly chromium-free passivator provided by the embodiment comprises the following steps:
(1) mixing 1/2 volumes of deionized water with water-based acrylic resin, glycine, polyaspartic acid, oxidized starch and hectorite, heating to 55 ℃, and stirring at 1000rpm for 90min to obtain a mixture I;
(2) mixing the rest deionized water with citric acid, phytic acid, zinc chloride, sodium molybdate, sodium citrate and amine oxide, and stirring at 200rpm for 20min to obtain a mixture II;
(3) and mixing the mixture I and the mixture II with ethylene glycol phenyl ether, heating to 50 ℃, stirring at 800rpm for 120min, cooling and standing.
Cooling the hot-galvanized steel plate to room temperature, then treating the steel plate for 80s at 30 ℃ by using the passivator obtained in the embodiment, washing the steel plate with water, and drying the steel plate by using a blower; rubbing the passivated steel plate on the surface of the test piece back and forth for 10 times at a certain pressure by using a sand-free rubber, wherein the film layer is not abraded and falls off; the white rust time of the passivated steel plate exceeds 135 hours in a neutral salt spray test.
The passivating agent prepared in the embodiment is used, the passivating process is repeated after 60 days, and the time of white rust of the obtained sample in a neutral salt spray test can be still kept to be more than 125 hours.
Finally, the above embodiments are only for illustrating the technical solutions of the present invention and not for limiting, although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions may be made to the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention, and all of them should be covered in the claims of the present invention.
Claims (3)
1. An environment-friendly chromium-free passivator is characterized in that: the material comprises the following raw materials in parts by weight: 30-35 parts of water-based acrylic resin, 15-20 parts of hectorite, 3.5-4 parts of citric acid, 10-12 parts of phytic acid, 7-8 parts of zinc chloride, 3-5 parts of ethylene glycol phenyl ether, 8-12 parts of glycine, 3.5-4 parts of sodium molybdate, 8-12 parts of polyaspartic acid, 4-6 parts of oxidized starch, 4-7 parts of sodium citrate, 3-3.5 parts of amine oxide and 50-55 parts of deionized water.
2. The environment-friendly chromium-free passivator according to claim 1, characterized in that: the material comprises the following raw materials in parts by weight: 32 parts of water-based acrylic resin, 18 parts of hectorite, 3.5 parts of citric acid, 11 parts of phytic acid, 8 parts of zinc chloride, 4 parts of ethylene glycol phenyl ether, 10 parts of glycine, 3.5 parts of sodium molybdate, 10 parts of polyaspartic acid, 5 parts of oxidized starch, 6 parts of sodium citrate, 3.5 parts of amine oxide and 53 parts of deionized water.
3. A method for preparing the environment-friendly chromium-free passivator according to claim 1, which is characterized in that: the method comprises the following steps:
(1) mixing 1/2 volume of deionized water with waterborne acrylic resin, glycine, polyaspartic acid, oxidized starch and hectorite, heating to 55-60 ℃, and stirring at the speed of 800-;
(2) mixing the rest deionized water with citric acid, phytic acid, zinc chloride, sodium molybdate, sodium citrate and amine oxide, and stirring at the speed of 200-300rpm for 15-20min to prepare a mixture II;
(3) mixing the mixture I and the mixture II with ethylene glycol phenyl ether, heating to 45-50 ℃, stirring at the speed of 800 plus one-step at 1000rpm for 120min, cooling and standing.
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| JP3857866B2 (en) * | 2000-02-29 | 2006-12-13 | 日本ペイント株式会社 | Non-chromate metal surface treatment agent, surface treatment method and treated painted steel |
| CN101429661B (en) * | 2008-12-05 | 2010-06-09 | 常熟华冶薄板有限公司 | Molybdate passivating liquid for continuous hot-dipping galvanizing steel plate |
| CN101886260A (en) * | 2010-07-08 | 2010-11-17 | 南通飞拓生物科技有限公司 | Composite film chromium-free passivant |
| CN102134713A (en) * | 2011-03-04 | 2011-07-27 | 江苏大中制漆有限公司 | Chrome-free fingerprint resistant water-based paint |
| CN108018567A (en) * | 2016-10-31 | 2018-05-11 | 河南智联寰宇知识产权运营有限公司 | Water-base metal derusting rust-proofing liquid and preparation method thereof |
| CN107699883A (en) * | 2017-09-27 | 2018-02-16 | 荆门市拓达科技有限公司 | A kind of green Chrome-free antirust passivating solution and preparation method thereof |
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2018
- 2018-11-20 CN CN201811385279.4A patent/CN109267055B/en active Active
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Denomination of invention: Environmental friendly chromium free passivator and its preparation method Effective date of registration: 20220412 Granted publication date: 20201110 Pledgee: China Construction Bank Corporation Chongqing Beibei sub branch Pledgor: CHONGQING GUANGREN TOWER MANUFACTURING Co.,Ltd. Registration number: Y2022500000018 |
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