CN109266946A - A kind of preparation method of the high entropy amorphous-dendrite composite material of Ti base - Google Patents
A kind of preparation method of the high entropy amorphous-dendrite composite material of Ti base Download PDFInfo
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- 239000002131 composite material Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 238000002844 melting Methods 0.000 claims abstract description 49
- 230000008018 melting Effects 0.000 claims abstract description 49
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 40
- 239000000956 alloy Substances 0.000 claims abstract description 40
- 238000005266 casting Methods 0.000 claims abstract description 13
- 239000000126 substance Substances 0.000 claims abstract description 13
- 238000003723 Smelting Methods 0.000 claims abstract description 11
- 239000010936 titanium Substances 0.000 claims description 79
- 239000010949 copper Substances 0.000 claims description 47
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 22
- 229910052802 copper Inorganic materials 0.000 claims description 17
- 229910052719 titanium Inorganic materials 0.000 claims description 15
- 239000002994 raw material Substances 0.000 claims description 14
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 11
- 229910052786 argon Inorganic materials 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- 239000007789 gas Substances 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- 229910052735 hafnium Inorganic materials 0.000 claims description 10
- 229910052726 zirconium Inorganic materials 0.000 claims description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 229910052790 beryllium Inorganic materials 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 7
- 229910052758 niobium Inorganic materials 0.000 claims description 7
- 238000004381 surface treatment Methods 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 3
- 238000007499 fusion processing Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 238000001304 sample melting Methods 0.000 claims description 2
- 230000007306 turnover Effects 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 7
- 230000006835 compression Effects 0.000 abstract description 3
- 238000007906 compression Methods 0.000 abstract description 3
- 238000009776 industrial production Methods 0.000 abstract description 2
- 238000005275 alloying Methods 0.000 abstract 1
- 229910000808 amorphous metal alloy Inorganic materials 0.000 description 19
- 239000002178 crystalline material Substances 0.000 description 8
- 238000011065 in-situ storage Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 210000001787 dendrite Anatomy 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- 229910017532 Cu-Be Inorganic materials 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000013459 approach Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229910052571 earthenware Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000004807 localization Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000005300 metallic glass Substances 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000399 optical microscopy Methods 0.000 description 1
- 239000000075 oxide glass Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
- C22C30/02—Alloys containing less than 50% by weight of each constituent containing copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/03—Making non-ferrous alloys by melting using master alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
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- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
The present invention provides a kind of preparation methods of the high entropy amorphous-dendrite composite material of Ti base, mainly using vacuum arc furnace ignition to pre-designed alloy proportion Ti20Zr20Hf20Nb10Cu10Be20Carry out alloying, comprising the following steps: according to Ti25Zr25Hf25Nb25Atom ratio weighs each simple substance element of the purity more than or equal to 99.9% and melting obtains the first intermediate alloy, then according to Ti16.67Zr16.67Hf16.67Cu16.67Be33.32Atom ratio weighs each simple substance element and melting obtains the second intermediate alloy, finally by the first intermediate alloy and the second intermediate alloy mixed smelting and inhales casting and obtains high entropy amorphous-dendrite composite material Ti20Zr20Hf20Nb10Cu10Be20.Preparation method of the present invention is simple, easily operated, and obtained composite material compression performance significantly improves, and this method is suitable for industrial production and popularization.
Description
Technical field
The present invention relates to amorphous composite material or technical field of high-entropy, specially a kind of high entropy amorphous-dendrite of Ti base
The preparation method of composite material.
Background technique
Amorphous alloy, also known as glassy metal are a kind of materials with many novel performances.Amorphous state refers in substance
Portion's atomic structure is in the ordered state of longrange disorder, shortrange order.Different from conventional oxide glass, atom in amorphous alloy
Between associative key be metallic bond, and non-covalent bond.Since its unique disordered structure makes it not have crystalline material Dislocations, sky
The defects of position, therefore, amorphous alloy, have excellent mechanics, physical and chemical properties, such as high intensity (about 1/50 Young
Modulus), high corrosion resistance, the superplasticity under excellent magnetic performance and certain temperature.These excellent physical chemistry and power
Characteristic and good forming characteristic are learned, so that amorphous alloy is in electronics, electric power, chemical industry, Aeronautics and Astronautics, machinery and microelectronics
Equal fields have wide application space.However the room temperature brittle failure of amorphous alloy and stability seriously constrain its engineer application.
Traditional amorphous alloy usually has a host element, in recent years, by five kinds or five kinds or more elements according to etc.
The amorphous alloy that the atomic ratio alloyizations such as atomic ratio or approximation are formed is known as high entropy amorphous alloy.High entropy amorphous alloy is in addition to having
Other than the advantages of amorphous alloy mentioned above, it is higher that high entropy effect has high entropy amorphous compared to traditional amorphous alloy
Intensity, by taking Ti-Zr-Ni-Cu-Be system as an example, Ti20Zr20Ni20Cu20Be20High entropy amorphous compressive strength up to 2300MPa,
And traditional amorphous alloy compressive strength maximum of same system only 2000MPa；High entropy amorphous is another compared to what traditional amorphous had
One advantage is that its thermal stability is more preferable, i.e., high entropy amorphous is changed into required for crystal structure as amorphous structure under the same terms
Time it is longer.These excellent physical and mechanical properties make high entropy amorphous alloy become a kind of potential Engineered Wood Products
Material.
High entropy amorphous alloy can be used as a kind of new structural material and use, it is necessary to it is required that it is with certain plasticity,
To guarantee the safety used.But until 2017, existing document showed that almost all of high entropy amorphous alloy all has
Very low plasticity.It has been generally acknowledged that the main reason for limiting high entropy amorphous plasticity is that it lacks the dislocation movement by slip, twin in crystalline material
The Plastic Deformation Mechanisms such as raw, the single shear-deformable of height localization can occur for high entropy amorphous in deformation process, and along cutting
It cuts band and brittle fracture occurs.Its plastic strain is almost nil in a stretched state for usually most of high entropy amorphous alloy, compresses shape
Plastic strain is again smaller than 2% under state.Just because of being difficult to obtain high tough high entropy non-crystalline material, in recent years to the high entropy amorphous of raising
The research of alloy ductility is more and more.
In general, it is a kind of effective of the high tough non-crystalline material of acquisition that the second phase, which is precipitated, in introducing original position in traditional non crystalline structure
Approach.Principle is to inhibit the unstable propagation of single shear band using generated in-situ second phase, promotes its multiple bifurcated and extension,
This process makes in amorphous alloy there are the shear band of a large amount of different orientations to provide effective plastic deformation ability.Institute
It is the raising for being very beneficial for mechanical property so that the second phase dendrite to be formed in situ in amorphous alloy.
Since the amorphous formation ability of high entropy amorphous is much smaller than traditional amorphous alloy, it is with Ti-Zr-Ni-Cu-Be system
Example, Ti20Zr20Ni20Cu20Be20High entropy amorphous maximum critical dimension is only 3mm, and Ti40Zr25Ni3Cu12Be20Traditional amorphous
Maximum critical dimension can reach 14mm.By introducing the preparation in situ that the second phase is precipitated and obtains high tough material in non crystalline structure
Method requires amorphous system to have good amorphous formation ability, therefore passes through in the limited high entropy amorphous of amorphous formation ability
It is more difficult that second phase of introducing in situ prepares dendrite amorphous composite material.
Summary of the invention
The purpose of the present invention is to solve the deficiencies of above-mentioned technology, provide a kind of high entropy amorphous-dendrite composite wood of Ti base
The preparation method of material, this method is easy to operate, easily prepared, molten by mixing the first intermediate alloy and the second intermediate alloy
Refining, makes to be uniformly distributed the dendrite phase being precipitated in situ on amorphous phase matrix, effectively increases the pressure of high entropy amorphous-dendrite composite material
Contracting plasticity, suitable for commercially producing.
To achieve the above object, the technical solution adopted by the present invention is that:
A kind of preparation method of the high entropy amorphous-dendrite composite material of Ti base, comprising the following steps:
The surface treatment of S1, raw material: each simple substance element ti, Zr, Hf, Nb, Cu and Be are cleaned and dried respectively,
Then according to Ti20Zr20Hf20Nb10Cu10Be20The atomic percent of middle each element calculates the quality of each element and weighing；
S2, alloy melting: by S1 treated Ti, Zr, Hf and Nb raw material according to Ti25Zr25Hf25Nb25Atomic ratio claim
It measures and mixes, be filled with high-purity argon gas to 0.2~0.3Mpa progress melting, first to the melting of titanium ingot 2~3 times to inhale after extracting vacuum
Remaining oxygen in furnace is received, melting then is carried out to the raw material in furnace, obtains the first intermediate alloy Ti25Zr25Hf25Nb25；
By Ti, Zr, Hf, Cu and Be of S1 processing according to Ti16.67Zr16.67Hf16.67Cu16.67Be33.32Atomic ratio claim
It measures and mixes, be filled with high-purity argon gas to 0.2~0.3Mpa progress melting, first to the melting of titanium ingot 2~3 times to inhale after extracting vacuum
Remaining oxygen in furnace is received, melting then is carried out to the raw material in furnace, obtains the second intermediate alloy Ti16.67Zr16.67Hf16.67
Cu16.67Be33.32；
Melting is carried out after first intermediate alloy and the second intermediate alloy are mixed according to the mass ratio of 3.33:5, is obtained
Ti20Zr20Hf20Nb10Cu10Be20；
S3, casting: the Ti that S2 is obtained is inhaled20Zr20Hf20Nb10Cu10Be20It is placed in water jacketed copper crucible, is filled after extracting vacuum
Enter high-purity argon gas to 0.1~0.3Mpa carry out melting, first to the melting of titanium ingot 2~3 times to absorb remaining oxygen in furnace, then
Melting is carried out to the alloy in furnace, carries out suction casting after 90~120s, is taken out after natural cooling in furnace and inhales casting sample to get Ti is arrived
The high entropy amorphous of base-dendrite composite material Ti20Zr20Hf20Nb10Cu10Be20。
Preferably, the purity of each simple substance element ti, Zr, Hf, Nb, Cu and Be are more than or equal to 99.9%.
Preferably, in S2, melting prepares the first intermediate alloy, the second intermediate alloy and Ti20Zr20Hf20Nb10Cu10Be20
When, after completing in sample melting and thoroughly cooling down, by its turn-over, the fusion process of first time is repeated, carries out second of melting, is melted
The refining time is 8~10min, and the number for repeating melting is 3~4 times.
Preferably, in S2, the smelting time of the first intermediate alloy and the second intermediate alloy is 8~10min, and melting electric current is
120~150A.
Preferably, in S2, Ti20Zr20Hf20Nb10Cu10Be20Smelting time be 8~10min, melting electric current be 120~
150A。
Preferably, in S3, the time of natural cooling is 15~18min.
Compared with prior art, beneficial effects of the present invention are as follows:
The present invention is by by the first intermediate alloy Ti25Zr25Hf25Nb25With the second intermediate alloy Ti16.67Zr16.67Hf16.67
Cu16.67Be33.32Mixed smelting obtains novel high entropy amorphous-dendrite composite material, which is formed by two-phase is compound, amorphous
The dendrite phase being precipitated in situ, the excellent material performance are uniform-distribution on phase matrix, compression plasticity significantly improves, this method operation
Simply, easily prepared, it is suitable for industrial production and popularization.
Detailed description of the invention
Fig. 1 is the schematic illustration of tissue of the high entropy amorphous-dendrite composite material of Ti base prepared by the embodiment of the present invention 1；
Fig. 2 is that the high entropy amorphous-dendrite composite material of Ti base of the preparation of the embodiment of the present invention 1 and the pressure of comparative example are answered
Stress-strain curve schematic diagram.
Specific embodiment
Below by specific embodiment example, the present invention will be described in detail.The scope of the present invention is not limited to the tool
Body embodiment.
Embodiment 1
A kind of high entropy amorphous of Ti base-dendrite composite material Ti20Zr20Hf20Nb10Cu10Be20Preparation method, including it is following
Step:
The surface treatment of S1, raw material: by purity more than or equal to 99.9% each simple substance element ti, Zr, Hf, Nb, Cu with
And Be uses acetone and EtOH Sonicate to clean 20min respectively, and is dried up using hair dryer, then weighs respectively according to following quality
Treated each element simple substance: 4.73g Ti, 9.02g Zr, 17.63g Hf, 4.59g Nb, 3.14g Cu and 0.89g Be；
S2, alloy melting: according to Ti25Zr25Hf25Nb25Atomic ratio weigh 4.76g Ti respectively, 8.89g Zr,
17.40g Hf and 9.05g Nb are put into water jacketed copper crucible and are placed in vacuum arc furnace ignition, close fire door, extract vacuum to 1*
10-3MPa is then charged with 0.3MPa high-purity argon gas, after the starting the arc, absorbs remaining oxygen in furnace to titanium ingot melting 3 times, then right
Mixed raw material carries out melting, and melting electric current is 150A, and smelting time 8min obtains the first intermediate alloy
Ti25Zr25Hf25Nb25；
According to Ti16.67Zr16.67Hf16.67Cu16.67Be33.32Atomic ratio weigh 4.79g Ti, 9.12g Zr respectively,
17.84g Hf, 6.35g Cu and 0.90g Be are put into water jacketed copper crucible and are placed in vacuum arc furnace ignition, close fire door, extract
Vacuum is to 1*10-3MPa is then charged with 0.3MPa high-purity argon gas, after the starting the arc, absorbs remaining oxygen in furnace to titanium ingot melting 3 times
Gas then refines mixed raw material, and melting electric current is 120A, smelting time 8min, obtains the second intermediate alloy Ti16.6 7Zr16.67Hf16.67Cu16.67Be33.32；
First intermediate alloy and the second intermediate alloy are mixed according to the mass ratio of 3.33:5 and use vacuum arc furnace ignition into
Row melting, melting electric current are 150A, and smelting time 10min obtains Ti20Zr20Hf20Nb10Cu10Be20；
S3, casting: the Ti that S2 is obtained is inhaled20Zr20Hf20Nb10Cu10Be20It is placed in water jacketed copper crucible, by water jacketed copper crucible
It is placed in vacuum arc furnace ignition, closes fire door, be filled with 0.1MPa high-purity argon gas after extracting vacuum, it is molten to titanium ingot first after the starting the arc
3 times are refined to absorb remaining oxygen in furnace, melting then is carried out to the alloy in furnace, carries out suction casting after 90s, the furnace after 15min
Interior natural cooling is taken out and inhales casting sample to get the high entropy amorphous of Ti base-dendrite composite material Ti is arrived20Zr20Hf20Nb10Cu10Be20。
Comparative example
Ti20Zr20Hf20Cu20Be20The preparation method of high entropy non-crystalline material, comprising the following steps:
The surface treatment of S1, raw material: each simple substance element ti, Zr, Hf, Cu and Be by purity more than or equal to 99.9%
20min is cleaned using acetone and EtOH Sonicate respectively, and is dried up using hair dryer, then weighs processing according to following quality respectively
Each element simple substance afterwards: 3.681g Ti, 7.014g Zr, 13.725g Hf, 4.886g Cu and 0.693g Be；
S2, alloy melting: according to Ti20Zr20Hf20Cu20Be20Atomic ratio weigh 3.681g Ti, 7.014g respectively
Zr, 13.725g Hf, 4.886g Cu and 0.693g Be are put into water jacketed copper crucible and are placed in vacuum arc furnace ignition, close furnace
Door extracts vacuum to 1*10-3MPa is then charged with 0.3MPa high-purity argon gas, residual in furnace to absorb to the melting of titanium ingot 3 times after the starting the arc
The oxygen stayed then carries out melting to mixed raw material, and melting electric current is 120A, and smelting time 10min obtains alloy
Ti20Zr20Hf20Cu20Be20
S3, casting: the Ti that S2 is obtained is inhaled20Zr20Hf20Cu20Be20Alloy is placed in water jacketed copper crucible, by water-cooled copper earthenware
Crucible is placed in vacuum arc furnace ignition, closes fire door, 0.1MPa high-purity argon gas is filled with after extracting vacuum, after the starting the arc, first to titanium ingot
To absorb remaining oxygen in furnace, melting then is carried out to the alloy in furnace melting 3 times, suction casting is carried out after 90s, after 15min
Natural cooling in furnace is taken out and inhales casting sample to get Ti is arrived20Zr20Hf20Cu20Be20High entropy non-crystalline material.
We carry out physical property characterization to sample prepared by embodiment 1, and Fig. 1 is the high entropy amorphous-branch of Ti base made from embodiment 1
Crystal composite material Ti20Zr20Hf20Nb10Cu10Be20Institutional framework under low power optical microscopy, Fig. 2 are made from embodiment 1
The high entropy amorphous of Ti base-dendrite composite material Ti20Zr20Hf20Nb10Cu10Be20With comparative example Ti20Zr20Hf20Cu20Be20Sample
Compression stress strain curve schematic diagram.
It will be seen from figure 1 that sample tissue made from embodiment 1 by two phase compositions, is evenly distributed on amorphous phase matrix
The dendrite phase of growth in situ；Figure it is seen that the yield strength of sample made from embodiment 1 is compared to pure in comparative example
Non-crystalline material improves 200MPa or so, and plastic strain improves the amorphous-dendrite composite wood illustrated in embodiment 1 close to 8 times
The plasticity of material is obviously improved compared to pure non-crystalline material.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the principle of the present invention, it can also make several improvements and retouch, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (6)
1. a kind of preparation method of the high entropy amorphous-dendrite composite material of Ti base, which comprises the following steps:
The surface treatment of S1, raw material: each simple substance element ti, Zr, Hf, Nb, Cu and Be are cleaned and dried respectively, then
According to Ti20Zr20Hf20Nb10Cu10Be20The atomic percent of middle each element calculates the quality of each element and weighing；
S2, alloy melting: by S1 treated Ti, Zr, Hf and Nb raw material according to Ti25Zr25Hf25Nb25Atomic ratio weigh simultaneously
Mixing is filled with high-purity argon gas to 0.2~0.3MPa progress melting, first to the melting of titanium ingot 2~3 times to absorb furnace after extracting vacuum
Then interior remaining oxygen carries out melting to the raw material in furnace, obtains the first intermediate alloy Ti25Zr25Hf25Nb25；
By Ti, Zr, Hf, Cu and Be raw material of S1 processing according to Ti16.67Zr16.67Hf16.67Cu16.67Be33.32Atomic ratio weigh
And mix, high-purity argon gas is filled with to 0.2~0.3MPa progress melting, first to the melting of titanium ingot 2~3 times to absorb after extracting vacuum
Then remaining oxygen in furnace carries out melting to the raw material in furnace, obtains the second intermediate alloy Ti16.67Zr16.67Hf16.67Cu16.6 7Be33.32；
Melting is carried out after first intermediate alloy and the second intermediate alloy are mixed according to the mass ratio of 3.33:5, is obtained
Ti20Zr20Hf20Nb10Cu10Be20；
S3, casting: the Ti that S2 is obtained is inhaled20Zr20Hf20Nb10Cu10Be20It is placed in water jacketed copper crucible, is filled with height after extracting vacuum
Pure argon is to 0.1~0.3MPa progress melting, first to the melting of titanium ingot 2~3 times to absorb remaining oxygen in furnace, then to furnace
Interior alloy carries out melting, carries out suction casting after 90~120s, takes out after natural cooling in furnace and inhales casting sample to get high to Ti base
Entropy amorphous-dendrite composite material Ti20Zr20Hf20Nb10Cu10Be20。
2. a kind of preparation method of the high entropy amorphous-dendrite composite material of Ti base according to claim 1, which is characterized in that
Each simple substance element ti, Zr, Hf, Nb, Cu and Be purity be more than or equal to 99.9%.
3. a kind of preparation method of the high entropy amorphous-dendrite composite material of Ti base according to claim 1, which is characterized in that
In S2, melting prepares the first intermediate alloy, the second intermediate alloy and Ti20Zr20Hf20Nb10Cu10Be20When, it is complete in sample melting
At and thoroughly cool down after, by its turn-over, repeat the fusion process of first time, carry out second of melting, smelting time is 2~
3min, the number for repeating melting are 3~4 times.
4. a kind of preparation method of the high entropy amorphous-dendrite composite material of Ti base according to claim 1, which is characterized in that
In S2, the smelting time of the first intermediate alloy and the second intermediate alloy is 8~10min, and melting electric current is 120~150A.
5. a kind of preparation method of the high entropy amorphous-dendrite composite material of Ti base according to claim 1, which is characterized in that
In S2, Ti20Zr20Hf20Nb10Cu10Be20Smelting time be 8~10min, melting electric current be 120~150A.
6. a kind of preparation method of the high entropy amorphous-dendrite composite material of Ti base according to claim 1, which is characterized in that
In S3, the time of natural cooling is 15~18min.
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| CN109881076A (en) * | 2019-03-12 | 2019-06-14 | 西北工业大学 | A kind of resistant amorphous-dendrite composite material and preparation method |
| US20220056566A1 (en) * | 2019-04-30 | 2022-02-24 | Oregon State University | Cu-based bulk metallic glasses in the cu-zr-hf-al and related systems |
| CN114214574A (en) * | 2021-11-05 | 2022-03-22 | 中国科学院金属研究所 | High-entropy metal glass composite material and preparation method and application thereof |
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Cited By (4)
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|---|---|---|---|---|
| CN109881076A (en) * | 2019-03-12 | 2019-06-14 | 西北工业大学 | A kind of resistant amorphous-dendrite composite material and preparation method |
| US20220056566A1 (en) * | 2019-04-30 | 2022-02-24 | Oregon State University | Cu-based bulk metallic glasses in the cu-zr-hf-al and related systems |
| US11821064B2 (en) * | 2019-04-30 | 2023-11-21 | Oregon State University | Cu-based bulk metallic glasses in the Cu—Zr—Hf—Al and related systems |
| CN114214574A (en) * | 2021-11-05 | 2022-03-22 | 中国科学院金属研究所 | High-entropy metal glass composite material and preparation method and application thereof |
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