CN109266456A - A kind of environment protection multifunctional agent for carbon hydrogen detergent - Google Patents
A kind of environment protection multifunctional agent for carbon hydrogen detergent Download PDFInfo
- Publication number
- CN109266456A CN109266456A CN201810878655.7A CN201810878655A CN109266456A CN 109266456 A CN109266456 A CN 109266456A CN 201810878655 A CN201810878655 A CN 201810878655A CN 109266456 A CN109266456 A CN 109266456A
- Authority
- CN
- China
- Prior art keywords
- agent
- carbon hydrogen
- hydrogen detergent
- environment protection
- detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 48
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 46
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 45
- 239000001257 hydrogen Substances 0.000 title claims abstract description 45
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 44
- 239000003599 detergent Substances 0.000 title claims abstract description 44
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims abstract description 12
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims abstract description 10
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 10
- 239000010452 phosphate Substances 0.000 claims abstract description 10
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 9
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 9
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 9
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000005642 Oleic acid Substances 0.000 claims abstract description 9
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 239000012459 cleaning agent Substances 0.000 claims description 9
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 4
- 239000003849 aromatic solvent Substances 0.000 claims description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 3
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 claims 2
- 150000002191 fatty alcohols Chemical class 0.000 claims 1
- 150000003014 phosphoric acid esters Chemical class 0.000 claims 1
- 229940051841 polyoxyethylene ether Drugs 0.000 claims 1
- 229920000056 polyoxyethylene ether Polymers 0.000 claims 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract description 7
- 239000004215 Carbon black (E152) Substances 0.000 abstract description 6
- 229930195733 hydrocarbon Natural products 0.000 abstract description 6
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 150000001408 amides Chemical class 0.000 abstract description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 description 7
- 239000002253 acid Substances 0.000 description 4
- -1 carbon hydrocarbon Chemical class 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical class CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- HEDRZPFGACZZDS-UHFFFAOYSA-N chloroform Substances ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005555 metalworking Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/78—Neutral esters of acids of phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
- C11D2111/44—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
- C11D2111/46—Specific cleaning or washing processes applying energy, e.g. irradiation
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
A kind of environment protection multifunctional agent for carbon hydrogen detergent, which is characterized in that each component including following parts by weight: agent for carbon hydrogen detergent 48-80%;Oleic acid 8-40%;Triisopropanolamine 6-25%;Aliphatic alcohol polyoxyvinethene phosphate 6-20%.The present invention provides a kind of agent for carbon hydrogen detergent with surface-active, by adding triisopropanolamine and oleic acid in hydrocarbon solvent, the hydroxyl in oleic acid molecular is replaced by the amino in triisopropanolamine molecule and generates acid amide type surfactant under certain condition, and make agent for carbon hydrogen detergent that there is surface-active in hydrocarbon solvent by aliphatic alcohol polyoxyvinethene phosphate solubilising, to both enhance agent for carbon hydrogen detergent to the solvability of polar substances, again emulsified solution can be formed with water well, and it can simply be washed with water and just get rid of agent for carbon hydrogen detergent, reduce the burden of later process.
Description
Technical field
The present invention relates to a kind of cleaning agents, and in particular to a kind of environment protection multifunctional agent for carbon hydrogen detergent.
Background technique
In industrial cleaning agent field, halogenated hydrocarbons cleaning agent such as trichloroethanes, chloroform methyl bromofom etc. can consume ozone
Layer substance, has biggish toxicity and corrosivity, thus causes biggish destruction to environment and human health.For this purpose, with people
Environmental consciousness enhancing, also have developed the carbon hydrocarbon cleaning agent of alternative halogenated hydrocarbons cleaning agent.However, the application actually makes
Being constituted with middle discovery agent for carbon hydrogen detergent ingredient is mainly alkane derivative, this cleaning agent belongs to non-polar compound, to mineral
The apolar substances such as matter oil have good dissolubility, are usually used in the cleaning of process of metal working greasy dirt.But have smell larger,
Volatilization not exclusively has the shortcomings that a small amount of residual.After having cleaned, need to reach by drying or aqueous cleaning agent cleaning
The purpose for removing agent for carbon hydrogen detergent, there is energy consumption height, waste big disadvantage.
Summary of the invention
The present invention solves the technical problem of: a kind of environment protection multifunctional agent for carbon hydrogen detergent is provided.
In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is that: a kind of environment protection multifunctional hydrocarbon cleaning
Agent, which is characterized in that each component including following parts by weight: agent for carbon hydrogen detergent 48-80%;Oleic acid 8-40%;Triisopropanolamine
6-25%;Aliphatic alcohol polyoxyvinethene phosphate 6-20%.
Further, each component including following parts by weight: agent for carbon hydrogen detergent 50-70%;Oleic acid 10-20%;Three isopropanols
Amine 10-15%;Aliphatic alcohol polyoxyvinethene phosphate 10-15%.
Further, the agent for carbon hydrogen detergent is de- aromatic solvent.
Further, the de- aromatic solvent is selected from D30, D40, D60 (S), D80, one of D110 or D130 or several
The composition of kind.
Further, the agent for carbon hydrogen detergent is low aromatic hydrocarbon solvent.
Further, the low aromatic hydrocarbon solvent of institute is selected from DSP80, DSP100 or combinations thereof object.
Further, the agent for carbon hydrogen detergent is the alkane that carbon atom number is 10-13.
The beneficial effects of the present invention are:
In order to solve the above-mentioned technical problems, the present invention provides a kind of agent for carbon hydrogen detergent with surface-active, by
Triisopropanolamine and oleic acid are added in hydrocarbon solvent, the hydroxyl in oleic acid molecular is by triisopropanolamine molecule under certain condition
Amino replace and generate acid amide type surfactant, and by aliphatic alcohol polyoxyvinethene phosphate solubilising in hydrocarbon solvent
So that agent for carbon hydrogen detergent has surface-active, to not only enhance agent for carbon hydrogen detergent to the solvability of polar substances, but also can be with
Emulsified solution is formed with water well, and can simply be washed with water and just get rid of agent for carbon hydrogen detergent, reduces the negative of later process
Load.
Specific embodiment
Embodiment 1:
A kind of agent for carbon hydrogen detergent with surface-active, each component including following parts by weight: agent for carbon hydrogen detergent 48%;Oil
Acid 40%;Triisopropanolamine 6%;Aliphatic alcohol polyoxyvinethene phosphate 6%.The agent for carbon hydrogen detergent is D40.
Embodiment 2:
A kind of agent for carbon hydrogen detergent with surface-active, each component including following parts by weight: agent for carbon hydrogen detergent 80%;Oil
Acid 8%;Triisopropanolamine 6%;Aliphatic alcohol polyoxyvinethene phosphate 6%.The agent for carbon hydrogen detergent is D65.
Embodiment 3:
A kind of agent for carbon hydrogen detergent with surface-active, each component including following parts by weight: agent for carbon hydrogen detergent 50%;Oil
Acid 20%;Triisopropanolamine 15%;Aliphatic alcohol polyoxyvinethene phosphate 15%.The agent for carbon hydrogen detergent is D60.
Embodiment 4:
A kind of agent for carbon hydrogen detergent with surface-active, each component including following parts by weight: agent for carbon hydrogen detergent 60%;Oil
Acid 20%;Triisopropanolamine 14%;Aliphatic alcohol polyoxyvinethene phosphate 6-%.The agent for carbon hydrogen detergent is C10.
Working method:
Step 1: workpiece to be cleaned being put into the first rinse bath, ultrasonic cleaning 3 minutes, 40 DEG C of cleaning temperature, ultrasound
Wave is 220V, 40Khz.
Step 2: workpiece is put into the second rinse bath after cleaning in step 1, and ultrasonic rinsing 3 minutes, cleaning temperature 40
DEG C, ultrasonic wave 220V, 40Khz.
Step 3: the workpiece after step 2 cleaning being subjected to drip liquid, heated-air drying completes cleaning.
Finally, it should be noted that the above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations;To the greatest extent
Pipe present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that: its according to
So be possible to modify the technical solutions described in the foregoing embodiments, or to some or all of the technical features into
Row equivalent replacement;And these are modified or replaceed, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution
The range of scheme.
Claims (7)
1. a kind of environment protection multifunctional agent for carbon hydrogen detergent, which is characterized in that each component including following parts by weight: agent for carbon hydrogen detergent
48-80%;Oleic acid 8-40%;Triisopropanolamine 6-25%;Aliphatic alcohol polyoxyvinethene phosphate 6-20%.
2. a kind of agent for carbon hydrogen detergent with surface-active as described in claim 1, which is characterized in that including following parts by weight
Each component: agent for carbon hydrogen detergent 50-70%;Oleic acid 10-20%;Triisopropanolamine 10-15%;Fatty alcohol polyoxyethylene ether phosphoric acid
Ester 10-15%.
3. a kind of environment protection multifunctional agent for carbon hydrogen detergent as described in claim 1, it is characterised in that: it is characterized in that, the carbon
Hydrogen cleaning agent is de- aromatic solvent.
4. a kind of environment protection multifunctional agent for carbon hydrogen detergent as described in claim 1, it is characterised in that: the de- aromatic solvent choosing
From D30, D40, D60 (S), the composition of one or more of D80, D110 or D130.
5. a kind of environment protection multifunctional agent for carbon hydrogen detergent as described in claim 1, it is characterised in that: the agent for carbon hydrogen detergent is low
Aromatic hydrocarbon solvent.
6. a kind of environment protection multifunctional agent for carbon hydrogen detergent as described in claim 1, it is characterised in that: the low aromatic hydrocarbon solvent of institute is selected from
DSP80, DSP100 or combinations thereof object.
7. a kind of environment protection multifunctional agent for carbon hydrogen detergent as described in claim 1, it is characterised in that: the agent for carbon hydrogen detergent is carbon
Atomicity is the alkane of 10-13.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810878655.7A CN109266456A (en) | 2018-08-03 | 2018-08-03 | A kind of environment protection multifunctional agent for carbon hydrogen detergent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810878655.7A CN109266456A (en) | 2018-08-03 | 2018-08-03 | A kind of environment protection multifunctional agent for carbon hydrogen detergent |
Publications (1)
Publication Number | Publication Date |
---|---|
CN109266456A true CN109266456A (en) | 2019-01-25 |
Family
ID=65153095
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810878655.7A Pending CN109266456A (en) | 2018-08-03 | 2018-08-03 | A kind of environment protection multifunctional agent for carbon hydrogen detergent |
Country Status (1)
Country | Link |
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CN (1) | CN109266456A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114277382A (en) * | 2021-12-29 | 2022-04-05 | 泰伦特生物工程股份有限公司 | Water-cutting cleaning agent replacing rinsing and drying process and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102191141A (en) * | 2010-03-17 | 2011-09-21 | 东莞市新球防锈有限公司 | Modified hydrocarbon cleaning agent |
CN102703252A (en) * | 2012-04-20 | 2012-10-03 | 东莞市新球清洗科技有限公司 | Hydrocarbon cleaning agent with surface activity |
CN106635553A (en) * | 2015-11-04 | 2017-05-10 | 江阴市五洋化工有限公司 | Methyl monoethanolamine modified composite hydrocarbon cleaner |
-
2018
- 2018-08-03 CN CN201810878655.7A patent/CN109266456A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102191141A (en) * | 2010-03-17 | 2011-09-21 | 东莞市新球防锈有限公司 | Modified hydrocarbon cleaning agent |
CN102191141B (en) * | 2010-03-17 | 2013-01-30 | 东莞市新球清洗科技有限公司 | Modified hydrocarbon cleaning agent |
CN102703252A (en) * | 2012-04-20 | 2012-10-03 | 东莞市新球清洗科技有限公司 | Hydrocarbon cleaning agent with surface activity |
CN106635553A (en) * | 2015-11-04 | 2017-05-10 | 江阴市五洋化工有限公司 | Methyl monoethanolamine modified composite hydrocarbon cleaner |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114277382A (en) * | 2021-12-29 | 2022-04-05 | 泰伦特生物工程股份有限公司 | Water-cutting cleaning agent replacing rinsing and drying process and preparation method thereof |
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PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
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RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190125 |
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RJ01 | Rejection of invention patent application after publication |