CN109266456A - A kind of environment protection multifunctional agent for carbon hydrogen detergent - Google Patents

A kind of environment protection multifunctional agent for carbon hydrogen detergent Download PDF

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Publication number
CN109266456A
CN109266456A CN201810878655.7A CN201810878655A CN109266456A CN 109266456 A CN109266456 A CN 109266456A CN 201810878655 A CN201810878655 A CN 201810878655A CN 109266456 A CN109266456 A CN 109266456A
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CN
China
Prior art keywords
agent
carbon hydrogen
hydrogen detergent
environment protection
detergent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810878655.7A
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Chinese (zh)
Inventor
朱国梅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin New Materials Co Ltd
Original Assignee
Tianjin New Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin New Materials Co Ltd filed Critical Tianjin New Materials Co Ltd
Priority to CN201810878655.7A priority Critical patent/CN109266456A/en
Publication of CN109266456A publication Critical patent/CN109266456A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/18Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43Solvents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/78Neutral esters of acids of phosphorus
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/40Specific cleaning or washing processes
    • C11D2111/44Multi-step processes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/40Specific cleaning or washing processes
    • C11D2111/46Specific cleaning or washing processes applying energy, e.g. irradiation

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

A kind of environment protection multifunctional agent for carbon hydrogen detergent, which is characterized in that each component including following parts by weight: agent for carbon hydrogen detergent 48-80%;Oleic acid 8-40%;Triisopropanolamine 6-25%;Aliphatic alcohol polyoxyvinethene phosphate 6-20%.The present invention provides a kind of agent for carbon hydrogen detergent with surface-active, by adding triisopropanolamine and oleic acid in hydrocarbon solvent, the hydroxyl in oleic acid molecular is replaced by the amino in triisopropanolamine molecule and generates acid amide type surfactant under certain condition, and make agent for carbon hydrogen detergent that there is surface-active in hydrocarbon solvent by aliphatic alcohol polyoxyvinethene phosphate solubilising, to both enhance agent for carbon hydrogen detergent to the solvability of polar substances, again emulsified solution can be formed with water well, and it can simply be washed with water and just get rid of agent for carbon hydrogen detergent, reduce the burden of later process.

Description

A kind of environment protection multifunctional agent for carbon hydrogen detergent
Technical field
The present invention relates to a kind of cleaning agents, and in particular to a kind of environment protection multifunctional agent for carbon hydrogen detergent.
Background technique
In industrial cleaning agent field, halogenated hydrocarbons cleaning agent such as trichloroethanes, chloroform methyl bromofom etc. can consume ozone Layer substance, has biggish toxicity and corrosivity, thus causes biggish destruction to environment and human health.For this purpose, with people Environmental consciousness enhancing, also have developed the carbon hydrocarbon cleaning agent of alternative halogenated hydrocarbons cleaning agent.However, the application actually makes Being constituted with middle discovery agent for carbon hydrogen detergent ingredient is mainly alkane derivative, this cleaning agent belongs to non-polar compound, to mineral The apolar substances such as matter oil have good dissolubility, are usually used in the cleaning of process of metal working greasy dirt.But have smell larger, Volatilization not exclusively has the shortcomings that a small amount of residual.After having cleaned, need to reach by drying or aqueous cleaning agent cleaning The purpose for removing agent for carbon hydrogen detergent, there is energy consumption height, waste big disadvantage.
Summary of the invention
The present invention solves the technical problem of: a kind of environment protection multifunctional agent for carbon hydrogen detergent is provided.
In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is that: a kind of environment protection multifunctional hydrocarbon cleaning Agent, which is characterized in that each component including following parts by weight: agent for carbon hydrogen detergent 48-80%;Oleic acid 8-40%;Triisopropanolamine 6-25%;Aliphatic alcohol polyoxyvinethene phosphate 6-20%.
Further, each component including following parts by weight: agent for carbon hydrogen detergent 50-70%;Oleic acid 10-20%;Three isopropanols Amine 10-15%;Aliphatic alcohol polyoxyvinethene phosphate 10-15%.
Further, the agent for carbon hydrogen detergent is de- aromatic solvent.
Further, the de- aromatic solvent is selected from D30, D40, D60 (S), D80, one of D110 or D130 or several The composition of kind.
Further, the agent for carbon hydrogen detergent is low aromatic hydrocarbon solvent.
Further, the low aromatic hydrocarbon solvent of institute is selected from DSP80, DSP100 or combinations thereof object.
Further, the agent for carbon hydrogen detergent is the alkane that carbon atom number is 10-13.
The beneficial effects of the present invention are:
In order to solve the above-mentioned technical problems, the present invention provides a kind of agent for carbon hydrogen detergent with surface-active, by Triisopropanolamine and oleic acid are added in hydrocarbon solvent, the hydroxyl in oleic acid molecular is by triisopropanolamine molecule under certain condition Amino replace and generate acid amide type surfactant, and by aliphatic alcohol polyoxyvinethene phosphate solubilising in hydrocarbon solvent So that agent for carbon hydrogen detergent has surface-active, to not only enhance agent for carbon hydrogen detergent to the solvability of polar substances, but also can be with Emulsified solution is formed with water well, and can simply be washed with water and just get rid of agent for carbon hydrogen detergent, reduces the negative of later process Load.
Specific embodiment
Embodiment 1:
A kind of agent for carbon hydrogen detergent with surface-active, each component including following parts by weight: agent for carbon hydrogen detergent 48%;Oil Acid 40%;Triisopropanolamine 6%;Aliphatic alcohol polyoxyvinethene phosphate 6%.The agent for carbon hydrogen detergent is D40.
Embodiment 2:
A kind of agent for carbon hydrogen detergent with surface-active, each component including following parts by weight: agent for carbon hydrogen detergent 80%;Oil Acid 8%;Triisopropanolamine 6%;Aliphatic alcohol polyoxyvinethene phosphate 6%.The agent for carbon hydrogen detergent is D65.
Embodiment 3:
A kind of agent for carbon hydrogen detergent with surface-active, each component including following parts by weight: agent for carbon hydrogen detergent 50%;Oil Acid 20%;Triisopropanolamine 15%;Aliphatic alcohol polyoxyvinethene phosphate 15%.The agent for carbon hydrogen detergent is D60.
Embodiment 4:
A kind of agent for carbon hydrogen detergent with surface-active, each component including following parts by weight: agent for carbon hydrogen detergent 60%;Oil Acid 20%;Triisopropanolamine 14%;Aliphatic alcohol polyoxyvinethene phosphate 6-%.The agent for carbon hydrogen detergent is C10.
Working method:
Step 1: workpiece to be cleaned being put into the first rinse bath, ultrasonic cleaning 3 minutes, 40 DEG C of cleaning temperature, ultrasound Wave is 220V, 40Khz.
Step 2: workpiece is put into the second rinse bath after cleaning in step 1, and ultrasonic rinsing 3 minutes, cleaning temperature 40 DEG C, ultrasonic wave 220V, 40Khz.
Step 3: the workpiece after step 2 cleaning being subjected to drip liquid, heated-air drying completes cleaning.
Finally, it should be noted that the above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations;To the greatest extent Pipe present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that: its according to So be possible to modify the technical solutions described in the foregoing embodiments, or to some or all of the technical features into Row equivalent replacement;And these are modified or replaceed, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution The range of scheme.

Claims (7)

1. a kind of environment protection multifunctional agent for carbon hydrogen detergent, which is characterized in that each component including following parts by weight: agent for carbon hydrogen detergent 48-80%;Oleic acid 8-40%;Triisopropanolamine 6-25%;Aliphatic alcohol polyoxyvinethene phosphate 6-20%.
2. a kind of agent for carbon hydrogen detergent with surface-active as described in claim 1, which is characterized in that including following parts by weight Each component: agent for carbon hydrogen detergent 50-70%;Oleic acid 10-20%;Triisopropanolamine 10-15%;Fatty alcohol polyoxyethylene ether phosphoric acid Ester 10-15%.
3. a kind of environment protection multifunctional agent for carbon hydrogen detergent as described in claim 1, it is characterised in that: it is characterized in that, the carbon Hydrogen cleaning agent is de- aromatic solvent.
4. a kind of environment protection multifunctional agent for carbon hydrogen detergent as described in claim 1, it is characterised in that: the de- aromatic solvent choosing From D30, D40, D60 (S), the composition of one or more of D80, D110 or D130.
5. a kind of environment protection multifunctional agent for carbon hydrogen detergent as described in claim 1, it is characterised in that: the agent for carbon hydrogen detergent is low Aromatic hydrocarbon solvent.
6. a kind of environment protection multifunctional agent for carbon hydrogen detergent as described in claim 1, it is characterised in that: the low aromatic hydrocarbon solvent of institute is selected from DSP80, DSP100 or combinations thereof object.
7. a kind of environment protection multifunctional agent for carbon hydrogen detergent as described in claim 1, it is characterised in that: the agent for carbon hydrogen detergent is carbon Atomicity is the alkane of 10-13.
CN201810878655.7A 2018-08-03 2018-08-03 A kind of environment protection multifunctional agent for carbon hydrogen detergent Pending CN109266456A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810878655.7A CN109266456A (en) 2018-08-03 2018-08-03 A kind of environment protection multifunctional agent for carbon hydrogen detergent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810878655.7A CN109266456A (en) 2018-08-03 2018-08-03 A kind of environment protection multifunctional agent for carbon hydrogen detergent

Publications (1)

Publication Number Publication Date
CN109266456A true CN109266456A (en) 2019-01-25

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Country Status (1)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114277382A (en) * 2021-12-29 2022-04-05 泰伦特生物工程股份有限公司 Water-cutting cleaning agent replacing rinsing and drying process and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102191141A (en) * 2010-03-17 2011-09-21 东莞市新球防锈有限公司 Modified hydrocarbon cleaning agent
CN102703252A (en) * 2012-04-20 2012-10-03 东莞市新球清洗科技有限公司 Hydrocarbon cleaning agent with surface activity
CN106635553A (en) * 2015-11-04 2017-05-10 江阴市五洋化工有限公司 Methyl monoethanolamine modified composite hydrocarbon cleaner

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102191141A (en) * 2010-03-17 2011-09-21 东莞市新球防锈有限公司 Modified hydrocarbon cleaning agent
CN102191141B (en) * 2010-03-17 2013-01-30 东莞市新球清洗科技有限公司 Modified hydrocarbon cleaning agent
CN102703252A (en) * 2012-04-20 2012-10-03 东莞市新球清洗科技有限公司 Hydrocarbon cleaning agent with surface activity
CN106635553A (en) * 2015-11-04 2017-05-10 江阴市五洋化工有限公司 Methyl monoethanolamine modified composite hydrocarbon cleaner

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114277382A (en) * 2021-12-29 2022-04-05 泰伦特生物工程股份有限公司 Water-cutting cleaning agent replacing rinsing and drying process and preparation method thereof

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Application publication date: 20190125

RJ01 Rejection of invention patent application after publication