CN109265833A - It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port - Google Patents

It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port Download PDF

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Publication number
CN109265833A
CN109265833A CN201811151085.8A CN201811151085A CN109265833A CN 109265833 A CN109265833 A CN 109265833A CN 201811151085 A CN201811151085 A CN 201811151085A CN 109265833 A CN109265833 A CN 109265833A
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CN
China
Prior art keywords
parts
outer cover
composite membrane
plastic containers
injected intravenously
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811151085.8A
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Chinese (zh)
Inventor
戴王强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongcheng Strong Peak Packing Co Ltd
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Tongcheng Strong Peak Packing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority to CN201811151085.8A priority Critical patent/CN109265833A/en
Publication of CN109265833A publication Critical patent/CN109265833A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10Homopolymers or copolymers of propene
    • C08J2323/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2401/00Characterised by the use of cellulose, modified cellulose or cellulose derivatives
    • C08J2401/08Cellulose derivatives
    • C08J2401/10Esters of organic acids
    • C08J2401/12Cellulose acetate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2433/06Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2433/10Homopolymers or copolymers of methacrylic acid esters
    • C08J2433/12Homopolymers or copolymers of methyl methacrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2489/00Characterised by the use of proteins; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04Ingredients characterised by their shape and organic or inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0856Iron
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/06Elements

Abstract

The invention discloses a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, its is composed of the following components by weight: 100-150 parts of polypropylene, 50-60 parts of polymethyl methacrylate, 10-15 parts of toluene sulfonyl semicarbazide, 1-1.5 parts of butanone, 13-15 parts of carbon fiber, 8-15 parts of cellulose acetate, 2-5 parts of acetone, 1-1.5 parts of dioxane, 2-6 parts of magnesium perchlorate, 8-15 parts of clay, 2-3 parts of gelatin, 15-20 parts of hydroxypropul starch, 14-20 parts of iron powder.Composite membrane outer cover of the invention is able to maintain complete in retort sterilization, avoids the occurrence of delamination and damaged situation, and when by stretching to remove outer cover, can be avoided release surface and generating impurity.

Description

It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port
Technical field
It is specially a kind of for being injected intravenously outside the composite membrane of plastic containers insert port the present invention relates to plastic film field Lid.
Background technique
With natural or artificial synthesized macromolecule membrane, using outside energy or chemical potential difference as motive force, to bi-component or The method that multi-component solute is separated with solvent, be classified, purified and is enriched with, is referred to as membrane separation process.Synthesis film can divide For organic (polymer) film and inoranic membrane, most important one membrane material is organic matter, i.e. polymer or macromolecular.It is so far Only, it is applied in industry and laboratory most importantly cellulose esters mesentery, in addition synthetic polymeric membrane such as aliphatic and fragrance The research of polyamide film, fragrance-heterocyclic polymer film, ionic film, polyvinyl and co-polymer membrane, PS membrane etc. is close Also there is very big development over year.In recent years, with the acquirement of the introduction of technology and the successes achieved in research, the effective UF membrane of a batch Device gradually has been widely used in fields such as water process, industrial separation, wastewater treatment, laboratory separation.
Summary of the invention
The purpose of the present invention is to provide a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port.
The purpose of the present invention can be achieved through the following technical solutions:
It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, its is composed of the following components by weight: 100-150 parts of polypropylene, 50-60 parts of polymethyl methacrylate, 10-15 parts of toluene sulfonyl semicarbazide, 1-1.5 parts of butanone, carbon 13-15 parts of fiber, 8-15 parts of cellulose acetate, 2-5 parts of acetone, 1-1.5 parts of dioxane, 2-6 parts of magnesium perchlorate, clay 8-15 Part, 2-3 parts of gelatin, 15-20 parts of hydroxypropul starch, 14-20 parts of iron powder.
Described a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, it is by following components group by weight At: 100 parts of polypropylene, 50 parts of polymethyl methacrylate, 10 parts of toluene sulfonyl semicarbazide, 1 part of butanone, 13 parts of carbon fiber, vinegar 8 parts of acid cellulose, 2 parts of acetone, 1 part of dioxane, 2 parts of magnesium perchlorate, 8 parts of clay, 2 parts of gelatin, 15 parts of hydroxypropul starch, iron 14 parts of powder.
Described a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, it is by following components group by weight At: 150 parts of polypropylene, 60 parts of polymethyl methacrylate, 15 parts of toluene sulfonyl semicarbazide, 1.5 parts of butanone, 15 parts of carbon fiber, 15 parts of cellulose acetate, 5 parts of acetone, 1.5 parts of dioxane, 6 parts of magnesium perchlorate, 15 parts of clay, 3 parts of gelatin, hydroxypropul starch 20 parts, 20 parts of iron powder.
Described a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, it is by following components group by weight At: 120 parts of polypropylene, 55 parts of polymethyl methacrylate, 12 parts of toluene sulfonyl semicarbazide, 1 part of butanone, 14 parts of carbon fiber, vinegar 10 parts of acid cellulose, 3 parts of acetone, 1 part of dioxane, 3 parts of magnesium perchlorate, 10 parts of clay, 3 parts of gelatin, 18 parts of hydroxypropul starch, 16 parts of iron powder.
It is described a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, the composite membrane outer cover with a thickness of 45-70 μm, porosity 48-60%, water content 55-62%, elongation at break 8-12.8%, tensile strength 2.8- 5.0kg。
Described a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, preparation method includes the following steps:
S1, it prepares casting solution: by the mass percent weighing of above-mentioned polymer compound film raw material, the material weighed up being mixed and is matched Casting solution is made;
S2, homogenize casting solution: by casting solution, isothermal vibration to film liquid is completely dissolved to obtain uniform casting film at 15-25 DEG C Liquid;
S3, film: uniform casting solution is film-made using L-S phase inversion method, evaporates 25-40s at 18-28 DEG C;
S4, coagulating bath: it is to impregnate 6- in 20-30 DEG C of weak aqua ammonia that the film liquid layer prepared in step S3, which is immersed in temperature, 15min, secure satisfactory grades sub- composite membrane.
Beneficial effects of the present invention: composite membrane outer cover of the invention is able to maintain completely, avoids the occurrence of in retort sterilization Delamination and damaged situation, and when by stretching to remove outer cover, it can be avoided release surface and generate impurity.
Specific embodiment
The present invention is described further below with reference to embodiment.
Embodiment 1
It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, its is composed of the following components by weight: 100 parts of polypropylene, 50 parts of polymethyl methacrylate, 10 parts of toluene sulfonyl semicarbazide, 1 part of butanone, 13 parts of carbon fiber, acetic acid is fine 8 parts of dimension element, 2 parts of acetone, 1 part of dioxane, 2 parts of magnesium perchlorate, 8 parts of clay, 2 parts of gelatin, 15 parts of hydroxypropul starch, iron powder 14 Part.
Embodiment 2
It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, its is composed of the following components by weight: 150 parts of polypropylene, 60 parts of polymethyl methacrylate, 15 parts of toluene sulfonyl semicarbazide, 1.5 parts of butanone, 15 parts of carbon fiber, acetic acid 15 parts of cellulose, 5 parts of acetone, 1.5 parts of dioxane, 6 parts of magnesium perchlorate, 15 parts of clay, 3 parts of gelatin, 20 parts of hydroxypropul starch, 20 parts of iron powder.
Embodiment 3
It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, its is composed of the following components by weight: 120 parts of polypropylene, 55 parts of polymethyl methacrylate, 12 parts of toluene sulfonyl semicarbazide, 1 part of butanone, 14 parts of carbon fiber, acetic acid is fine 10 parts of dimension element, 3 parts of acetone, 1 part of dioxane, 3 parts of magnesium perchlorate, 10 parts of clay, 3 parts of gelatin, 18 parts of hydroxypropul starch, iron powder 16 parts.
Above content is only to structure of the invention example and explanation, affiliated those skilled in the art couple Described specific example does various modifications or additions or is substituted in a similar manner, as long as wanting not past this right Range defined in book is sought, should belong to the protection scope of invention.

Claims (6)

1. a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, which is characterized in that it is by following by weight Group is grouped as: 100-150 parts of polypropylene, 50-60 parts of polymethyl methacrylate, and 10-15 parts of toluene sulfonyl semicarbazide, butanone 1- 1.5 parts, 13-15 parts of carbon fiber, 8-15 parts of cellulose acetate, 2-5 parts of acetone, 1-1.5 parts of dioxane, 2-6 parts of magnesium perchlorate, 8-15 parts of clay, 2-3 parts of gelatin, 15-20 parts of hydroxypropul starch, 14-20 parts of iron powder.
2. a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port according to claim 1, which is characterized in that Its is composed of the following components by weight: 100 parts of polypropylene, 50 parts of polymethyl methacrylate, and 10 parts of toluene sulfonyl semicarbazide, 1 part of butanone, 13 parts of carbon fiber, 8 parts of cellulose acetate, 2 parts of acetone, 1 part of dioxane, 2 parts of magnesium perchlorate, 8 parts of clay, gelatin 2 parts, 15 parts of hydroxypropul starch, 14 parts of iron powder.
3. a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port according to claim 1, which is characterized in that Its is composed of the following components by weight: 150 parts of polypropylene, 60 parts of polymethyl methacrylate, and 15 parts of toluene sulfonyl semicarbazide, 1.5 parts of butanone, 15 parts of carbon fiber, 15 parts of cellulose acetate, 5 parts of acetone, 1.5 parts of dioxane, 6 parts of magnesium perchlorate, clay 15 Part, 3 parts of gelatin, 20 parts of hydroxypropul starch, 20 parts of iron powder.
4. a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port according to claim 1, which is characterized in that Its is composed of the following components by weight: 120 parts of polypropylene, 55 parts of polymethyl methacrylate, and 12 parts of toluene sulfonyl semicarbazide, It is 1 part of butanone, 14 parts of carbon fiber, 10 parts of cellulose acetate, 3 parts of acetone, 1 part of dioxane, 3 parts of magnesium perchlorate, 10 parts of clay, bright 3 parts of glue, 18 parts of hydroxypropul starch, 16 parts of iron powder.
5. a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port according to claim 1, which is characterized in that The composite membrane outer cover is with a thickness of 45-70 μm, porosity 48-60%, water content 55-62%, elongation at break 8- 12.8%, tensile strength 2.8-5.0kg.
6. a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port according to claim 1, which is characterized in that Preparation method includes the following steps:
S1, it prepares casting solution: by the mass percent weighing of above-mentioned polymer compound film raw material, the material weighed up being hybridly prepared into Casting solution;
S2, homogenize casting solution: by casting solution, isothermal vibration to film liquid is completely dissolved to obtain uniform casting solution at 15-25 DEG C;
S3, film: uniform casting solution is film-made using L-S phase inversion method, evaporates 25-40s at 18-28 DEG C;
S4, coagulating bath: it is to impregnate 6-15min in 20-30 DEG C of weak aqua ammonia that the film liquid layer prepared in step S3, which is immersed in temperature, is obtained Polymer compound film.
CN201811151085.8A 2018-09-29 2018-09-29 It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port Pending CN109265833A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811151085.8A CN109265833A (en) 2018-09-29 2018-09-29 It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port

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Application Number Priority Date Filing Date Title
CN201811151085.8A CN109265833A (en) 2018-09-29 2018-09-29 It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105232326A (en) * 2015-10-10 2016-01-13 江苏中金玛泰医药包装有限公司 Outer composite film cover for insertion openings of plastic containers for intravenous injection and manufacturing method
CN108236846A (en) * 2016-12-27 2018-07-03 中国科学院宁波城市环境观测研究站 A kind of polymer compound film and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105232326A (en) * 2015-10-10 2016-01-13 江苏中金玛泰医药包装有限公司 Outer composite film cover for insertion openings of plastic containers for intravenous injection and manufacturing method
CN108236846A (en) * 2016-12-27 2018-07-03 中国科学院宁波城市环境观测研究站 A kind of polymer compound film and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
杨中文: "《塑料用树脂及助剂》", 31 December 2009, 印刷工业出版社 *

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Application publication date: 20190125

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