CN109265833A - It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port - Google Patents
It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port Download PDFInfo
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- CN109265833A CN109265833A CN201811151085.8A CN201811151085A CN109265833A CN 109265833 A CN109265833 A CN 109265833A CN 201811151085 A CN201811151085 A CN 201811151085A CN 109265833 A CN109265833 A CN 109265833A
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- Prior art keywords
- parts
- outer cover
- composite membrane
- plastic containers
- injected intravenously
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2401/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
- C08J2401/08—Cellulose derivatives
- C08J2401/10—Esters of organic acids
- C08J2401/12—Cellulose acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2433/10—Homopolymers or copolymers of methacrylic acid esters
- C08J2433/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2489/00—Characterised by the use of proteins; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0856—Iron
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
Abstract
The invention discloses a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, its is composed of the following components by weight: 100-150 parts of polypropylene, 50-60 parts of polymethyl methacrylate, 10-15 parts of toluene sulfonyl semicarbazide, 1-1.5 parts of butanone, 13-15 parts of carbon fiber, 8-15 parts of cellulose acetate, 2-5 parts of acetone, 1-1.5 parts of dioxane, 2-6 parts of magnesium perchlorate, 8-15 parts of clay, 2-3 parts of gelatin, 15-20 parts of hydroxypropul starch, 14-20 parts of iron powder.Composite membrane outer cover of the invention is able to maintain complete in retort sterilization, avoids the occurrence of delamination and damaged situation, and when by stretching to remove outer cover, can be avoided release surface and generating impurity.
Description
Technical field
It is specially a kind of for being injected intravenously outside the composite membrane of plastic containers insert port the present invention relates to plastic film field
Lid.
Background technique
With natural or artificial synthesized macromolecule membrane, using outside energy or chemical potential difference as motive force, to bi-component or
The method that multi-component solute is separated with solvent, be classified, purified and is enriched with, is referred to as membrane separation process.Synthesis film can divide
For organic (polymer) film and inoranic membrane, most important one membrane material is organic matter, i.e. polymer or macromolecular.It is so far
Only, it is applied in industry and laboratory most importantly cellulose esters mesentery, in addition synthetic polymeric membrane such as aliphatic and fragrance
The research of polyamide film, fragrance-heterocyclic polymer film, ionic film, polyvinyl and co-polymer membrane, PS membrane etc. is close
Also there is very big development over year.In recent years, with the acquirement of the introduction of technology and the successes achieved in research, the effective UF membrane of a batch
Device gradually has been widely used in fields such as water process, industrial separation, wastewater treatment, laboratory separation.
Summary of the invention
The purpose of the present invention is to provide a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port.
The purpose of the present invention can be achieved through the following technical solutions:
It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, its is composed of the following components by weight:
100-150 parts of polypropylene, 50-60 parts of polymethyl methacrylate, 10-15 parts of toluene sulfonyl semicarbazide, 1-1.5 parts of butanone, carbon
13-15 parts of fiber, 8-15 parts of cellulose acetate, 2-5 parts of acetone, 1-1.5 parts of dioxane, 2-6 parts of magnesium perchlorate, clay 8-15
Part, 2-3 parts of gelatin, 15-20 parts of hydroxypropul starch, 14-20 parts of iron powder.
Described a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, it is by following components group by weight
At: 100 parts of polypropylene, 50 parts of polymethyl methacrylate, 10 parts of toluene sulfonyl semicarbazide, 1 part of butanone, 13 parts of carbon fiber, vinegar
8 parts of acid cellulose, 2 parts of acetone, 1 part of dioxane, 2 parts of magnesium perchlorate, 8 parts of clay, 2 parts of gelatin, 15 parts of hydroxypropul starch, iron
14 parts of powder.
Described a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, it is by following components group by weight
At: 150 parts of polypropylene, 60 parts of polymethyl methacrylate, 15 parts of toluene sulfonyl semicarbazide, 1.5 parts of butanone, 15 parts of carbon fiber,
15 parts of cellulose acetate, 5 parts of acetone, 1.5 parts of dioxane, 6 parts of magnesium perchlorate, 15 parts of clay, 3 parts of gelatin, hydroxypropul starch
20 parts, 20 parts of iron powder.
Described a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, it is by following components group by weight
At: 120 parts of polypropylene, 55 parts of polymethyl methacrylate, 12 parts of toluene sulfonyl semicarbazide, 1 part of butanone, 14 parts of carbon fiber, vinegar
10 parts of acid cellulose, 3 parts of acetone, 1 part of dioxane, 3 parts of magnesium perchlorate, 10 parts of clay, 3 parts of gelatin, 18 parts of hydroxypropul starch,
16 parts of iron powder.
It is described a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, the composite membrane outer cover with a thickness of
45-70 μm, porosity 48-60%, water content 55-62%, elongation at break 8-12.8%, tensile strength 2.8-
5.0kg。
Described a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, preparation method includes the following steps:
S1, it prepares casting solution: by the mass percent weighing of above-mentioned polymer compound film raw material, the material weighed up being mixed and is matched
Casting solution is made;
S2, homogenize casting solution: by casting solution, isothermal vibration to film liquid is completely dissolved to obtain uniform casting film at 15-25 DEG C
Liquid;
S3, film: uniform casting solution is film-made using L-S phase inversion method, evaporates 25-40s at 18-28 DEG C;
S4, coagulating bath: it is to impregnate 6- in 20-30 DEG C of weak aqua ammonia that the film liquid layer prepared in step S3, which is immersed in temperature,
15min, secure satisfactory grades sub- composite membrane.
Beneficial effects of the present invention: composite membrane outer cover of the invention is able to maintain completely, avoids the occurrence of in retort sterilization
Delamination and damaged situation, and when by stretching to remove outer cover, it can be avoided release surface and generate impurity.
Specific embodiment
The present invention is described further below with reference to embodiment.
Embodiment 1
It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, its is composed of the following components by weight:
100 parts of polypropylene, 50 parts of polymethyl methacrylate, 10 parts of toluene sulfonyl semicarbazide, 1 part of butanone, 13 parts of carbon fiber, acetic acid is fine
8 parts of dimension element, 2 parts of acetone, 1 part of dioxane, 2 parts of magnesium perchlorate, 8 parts of clay, 2 parts of gelatin, 15 parts of hydroxypropul starch, iron powder 14
Part.
Embodiment 2
It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, its is composed of the following components by weight:
150 parts of polypropylene, 60 parts of polymethyl methacrylate, 15 parts of toluene sulfonyl semicarbazide, 1.5 parts of butanone, 15 parts of carbon fiber, acetic acid
15 parts of cellulose, 5 parts of acetone, 1.5 parts of dioxane, 6 parts of magnesium perchlorate, 15 parts of clay, 3 parts of gelatin, 20 parts of hydroxypropul starch,
20 parts of iron powder.
Embodiment 3
It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, its is composed of the following components by weight:
120 parts of polypropylene, 55 parts of polymethyl methacrylate, 12 parts of toluene sulfonyl semicarbazide, 1 part of butanone, 14 parts of carbon fiber, acetic acid is fine
10 parts of dimension element, 3 parts of acetone, 1 part of dioxane, 3 parts of magnesium perchlorate, 10 parts of clay, 3 parts of gelatin, 18 parts of hydroxypropul starch, iron powder
16 parts.
Above content is only to structure of the invention example and explanation, affiliated those skilled in the art couple
Described specific example does various modifications or additions or is substituted in a similar manner, as long as wanting not past this right
Range defined in book is sought, should belong to the protection scope of invention.
Claims (6)
1. a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port, which is characterized in that it is by following by weight
Group is grouped as: 100-150 parts of polypropylene, 50-60 parts of polymethyl methacrylate, and 10-15 parts of toluene sulfonyl semicarbazide, butanone 1-
1.5 parts, 13-15 parts of carbon fiber, 8-15 parts of cellulose acetate, 2-5 parts of acetone, 1-1.5 parts of dioxane, 2-6 parts of magnesium perchlorate,
8-15 parts of clay, 2-3 parts of gelatin, 15-20 parts of hydroxypropul starch, 14-20 parts of iron powder.
2. a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port according to claim 1, which is characterized in that
Its is composed of the following components by weight: 100 parts of polypropylene, 50 parts of polymethyl methacrylate, and 10 parts of toluene sulfonyl semicarbazide,
1 part of butanone, 13 parts of carbon fiber, 8 parts of cellulose acetate, 2 parts of acetone, 1 part of dioxane, 2 parts of magnesium perchlorate, 8 parts of clay, gelatin
2 parts, 15 parts of hydroxypropul starch, 14 parts of iron powder.
3. a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port according to claim 1, which is characterized in that
Its is composed of the following components by weight: 150 parts of polypropylene, 60 parts of polymethyl methacrylate, and 15 parts of toluene sulfonyl semicarbazide,
1.5 parts of butanone, 15 parts of carbon fiber, 15 parts of cellulose acetate, 5 parts of acetone, 1.5 parts of dioxane, 6 parts of magnesium perchlorate, clay 15
Part, 3 parts of gelatin, 20 parts of hydroxypropul starch, 20 parts of iron powder.
4. a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port according to claim 1, which is characterized in that
Its is composed of the following components by weight: 120 parts of polypropylene, 55 parts of polymethyl methacrylate, and 12 parts of toluene sulfonyl semicarbazide,
It is 1 part of butanone, 14 parts of carbon fiber, 10 parts of cellulose acetate, 3 parts of acetone, 1 part of dioxane, 3 parts of magnesium perchlorate, 10 parts of clay, bright
3 parts of glue, 18 parts of hydroxypropul starch, 16 parts of iron powder.
5. a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port according to claim 1, which is characterized in that
The composite membrane outer cover is with a thickness of 45-70 μm, porosity 48-60%, water content 55-62%, elongation at break 8-
12.8%, tensile strength 2.8-5.0kg.
6. a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port according to claim 1, which is characterized in that
Preparation method includes the following steps:
S1, it prepares casting solution: by the mass percent weighing of above-mentioned polymer compound film raw material, the material weighed up being hybridly prepared into
Casting solution;
S2, homogenize casting solution: by casting solution, isothermal vibration to film liquid is completely dissolved to obtain uniform casting solution at 15-25 DEG C;
S3, film: uniform casting solution is film-made using L-S phase inversion method, evaporates 25-40s at 18-28 DEG C;
S4, coagulating bath: it is to impregnate 6-15min in 20-30 DEG C of weak aqua ammonia that the film liquid layer prepared in step S3, which is immersed in temperature, is obtained
Polymer compound film.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811151085.8A CN109265833A (en) | 2018-09-29 | 2018-09-29 | It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201811151085.8A CN109265833A (en) | 2018-09-29 | 2018-09-29 | It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port |
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CN109265833A true CN109265833A (en) | 2019-01-25 |
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CN201811151085.8A Pending CN109265833A (en) | 2018-09-29 | 2018-09-29 | It is a kind of for being injected intravenously the composite membrane outer cover of plastic containers insert port |
Country Status (1)
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105232326A (en) * | 2015-10-10 | 2016-01-13 | 江苏中金玛泰医药包装有限公司 | Outer composite film cover for insertion openings of plastic containers for intravenous injection and manufacturing method |
CN108236846A (en) * | 2016-12-27 | 2018-07-03 | 中国科学院宁波城市环境观测研究站 | A kind of polymer compound film and preparation method thereof |
-
2018
- 2018-09-29 CN CN201811151085.8A patent/CN109265833A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105232326A (en) * | 2015-10-10 | 2016-01-13 | 江苏中金玛泰医药包装有限公司 | Outer composite film cover for insertion openings of plastic containers for intravenous injection and manufacturing method |
CN108236846A (en) * | 2016-12-27 | 2018-07-03 | 中国科学院宁波城市环境观测研究站 | A kind of polymer compound film and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
杨中文: "《塑料用树脂及助剂》", 31 December 2009, 印刷工业出版社 * |
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RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190125 |
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RJ01 | Rejection of invention patent application after publication |