CN109265807A - The feed particles formula and production method of PE film - Google Patents

The feed particles formula and production method of PE film Download PDF

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Publication number
CN109265807A
CN109265807A CN201811400729.2A CN201811400729A CN109265807A CN 109265807 A CN109265807 A CN 109265807A CN 201811400729 A CN201811400729 A CN 201811400729A CN 109265807 A CN109265807 A CN 109265807A
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Prior art keywords
parts
feed particles
film
raw material
particles
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Granted
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CN201811400729.2A
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CN109265807B (en
Inventor
曹玉
毛潞
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Guangdong Tengcong Environmental Protection New Materials Co.,Ltd.
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Chongqing Ruiting Plastic Co Ltd
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Priority to CN201811400729.2A priority Critical patent/CN109265807B/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B13/00Conditioning or physical treatment of the material to be shaped
    • B29B13/10Conditioning or physical treatment of the material to be shaped by grinding, e.g. by triturating; by sieving; by filtering
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • B29B9/02Making granules by dividing preformed material
    • B29B9/06Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D7/00Producing flat articles, e.g. films or sheets
    • B29D7/01Films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/05Alcohols; Metal alcoholates
    • C08K5/053Polyhydroxylic alcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/07Aldehydes; Ketones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

The present invention relates to technical field of polymer materials, disclose the feed particles formula of PE film, it is characterised in that: including following raw material: PE, antioxidant, ceramic particle, ceramic particle, calcium carbonate, rutile particles, glycerol, glutaraldehyde;And a kind of production method of the feed particles of PE film, comprising the following steps: need using feed particles process units, raw material enters cabinet from feed inlet, and raw material is cut into raw strip by vertical block;Raw strip can be carried out by the cycle refrigeration system in vertical block to continue cooling treatment;Interval cutting process is carried out to raw strip using cutter, obtains feed particles;Feed particles are put into plastic film blowing machine to produce, obtain PE film.This programme mainly solves the problem of bad heat resistance of current PE film, tensile strength and PE film production low efficiency.

Description

The feed particles formula and production method of PE film
Technical field
The present invention relates to technical field of polymer materials.
Background technique
The yield of Chinese Plastics film accounts for about the 20% of plastic products total output, is that increase of production is faster in plastic products One of classification.In terms of the application field of Chinese plastic film, dosage is maximum, kind is most, it is most widely used be packaging industry, Consumption accounts for about 2/3, and followed by agricultural accounts for about 30%, then having is exactly functional membrane, such as microporous barrier, screened film, geomembrane.
Plastic film it is most-often used be polyethylene film, i.e. PE film;PE film has moisture resistance, small excellent of penetrability Gesture;PE film can produce low-density, middle density, high density different performance according to the difference of manufacturing method and control means Product.Currently, the heat resistance of PE film, tensile strength are bad, have to be optimized;In addition, the production of PE film need by Water cooling, air-dry, processes, each process such as pelletizing require to be handled using corresponding equipment, i.e., a upper process is to next A process needs replacing equipment, has elongated the production procedure of PE film, thereby reduces the production efficiency of PE film.
Summary of the invention
The invention is intended to provide a kind of feed particles formula of PE film, to solve the heat resistance of current PE film, stretch The bad problem of intensity.
In order to achieve the above object, base case of the invention is as follows: the feed particles formula of PE film, including following heavy The raw material of amount part: PE60-85 parts, 10-30 parts of antioxidant, 10-30 parts of ceramic particle, 15-50 parts of ceramic particle, calcium carbonate 10-15 parts, 30-65 parts of rutile particles, 10-30 parts of glycerol, 4-10 parts of glutaraldehyde.
The advantages of base case: the thin film strength of PE, fine heat-resisting performance in this programme, safety and environmental protection;Also, we Raw materials used price is excellent honest and clean in case, so that production cost is low.
Further, it is made by the raw material of following parts by weight: PE70 parts, 20 parts of antioxidant, 25 parts of ceramic particle, ceramics 35 parts of grain, 10 parts of calcium carbonate, 45 parts of rutile particles, 20 parts of glycerol, 8 parts of glutaraldehyde.
The invention is intended to also provide a kind of production method of the feed particles of PE film, to solve current PE film because of production Long flow path and the problem for causing production efficiency low.
In order to achieve the above object, base case of the invention is as follows: a kind of production method of the feed particles of PE film, The following steps are included:
(1) it needs to weigh each component by weight ratio using feed particles process units and put into reaction kettle, in nitrogen Reaction is heated in gas atmosphere, is re-fed into extruder and is squeezed out raw material;
(2) raw material enters cabinet from feed inlet, and raw material is cut into raw strip by vertical block;
(3) raw strip is carried out by the cycle refrigeration system in vertical block continuing cooling treatment;
(4) interval cutting process is carried out to raw strip using cutter, obtains feed particles;
(5) feed particles are put into plastic film blowing machine to produce, obtain PE film.
The advantages of base case:
1, this programme has the function of slitting, refrigeration, three kinds of pelletizing simultaneously, compared to the production method of current PE film, leads to It crosses a device and has haved the function that three equipment, shorten in three processes from a upper process to the process of next process Time effectively increases the production efficiency of PE film.
2, raw material can be cut into raw strip by vertical block in this programme, moreover it is possible to pass through the cycle refrigeration system in vertical block It realizes the cooling treatment to raw strip, realizes dual-use material, it is practical.
3, the simple process in this programme, easy to operate, industrializing implementation are easy, can be given birth to common plastics inflation film manufacturing machine It produces.
Further, when cycle refrigeration system continue cooling to raw strip in step (3), cycle refrigeration system can interval Hit vertical block.By above-mentioned setting, hit by the interval to vertical block so that vertical block generation vibration, avoids raw strip viscous It is connected on vertical block.
Further, feed particles obtained in step (4) are sieved by the sieve of horizontal reciprocating movement.By above-mentioned Setting, had not only been avoided that feed particles were adhered on sieve, but also be avoided that feed particles are packed together the blocking for leading to sieve.
Detailed description of the invention
Fig. 1 is the schematic diagram of feed particles process units embodiment of the present invention;
Fig. 2 is the structure sectional view of vertical block;
Fig. 3 is the partial sectional view of water pipe.
Specific embodiment
It is further described below by specific embodiment:
Appended drawing reference in Figure of description includes: cabinet 1, demarcation plate 2, through-hole 3, shutter 4, feed inlet 5, feed pipe Road 6, vertical block 7, corner block 8, chamber 9, push rod 10, spring 11, reflux road 12, sucking pump 13, refrigerator 14, upper opening 15, under Opening 16, water pipe 17, support rod 18, swing arm 19, asessory shaft 20, impeller 21, cam 22, motor 23, the first support shaft 24, fan tooth Take turns 25, driven gear 26, cutter 27, rack gear 28, the second support shaft 29, belt 30, disk 31, transmission arm 32, sliding slot 33, sieve 34, discharge port 35, sealing cover 36.
Embodiment
Substantially as shown in attached drawing 1, attached drawing 2 and attached drawing 3: feed particles process units, including base are equipped with case on base Body 1;Middle part is welded with demarcation plate 2 in cabinet 1, and several through-holes 3 are laterally equidistantly offered on demarcation plate 2;On the side wall of cabinet 1 Shutter 4 is slidably connected, shutter 4 is located at the top of demarcation plate 2, also, shutter 4 can seal through-hole 3.
The top of cabinet 1 offers feed inlet 5, and feed inlet 5 is rectangular;The charging of cone cell is welded on feed inlet 5 The width of pipeline 6, i.e. feed pipe 6 is gradually reduced from top to bottom.Several vertical blocks 7 are equidistantly provided on the side wall of cabinet 1, and Vertical block 7 is located at 2 top of demarcation plate;Through-hole 3 is between two neighboring vertical block 7;The top of each vertical block 7 is welded with The width of corner block 8, corner block 8 is gradually increased from top to bottom.
Chamber 9 is offered inside vertical block 7, the top of corner block 8 slides vertically the push rod for being connected with and protruding into chamber 9 10, and spring 11 is connected between push rod 10 and the top of chamber 9;Reflux road 12 is offered inside push rod 10, and the road 12 that flows back It is inside sequentially installed with sucking pump 13 and refrigerator 14 from top to bottom;The two sides of push rod 10 offer with reflux road 12 communicate on open Mouth 15 and under shed 16, and two upper openings 15 are located at the top of two under sheds 16.It is mounted on the two sides inner wall of chamber 9 The water pipe 17 of the steel material to offset with 9 inner wall of chamber, and the built-in Qing Dynasty's water of water pipe 17;The both ends of water pipe 17 offset with push rod 10 Setting, the both ends of water pipe 17 are respectively positioned on the motion profile of upper opening 15 and under shed 16.
Several support rods 18 are equidistantly vertically welded on the inner wall of water pipe 17, the top of each support rod 18 is hinged with swing arm 19, and the spacing at 18 top of 19 left end of swing arm and support rod is greater than the spacing at 18 top of 19 right end of swing arm and support rod, so that pendulum The original state of arm 19 are as follows: inclination upwards from left to right;Several asessory shafts are vertically equidistantly rotatably connected on the inside of water pipe 17 20, and asessory shaft 20 is between two neighboring support rod 18;Impeller 21 and cam 22 are respectively connected on each asessory shaft 20, and Cam 22 and swing arm 19 offset setting;When the convex portion of cam 22 squeezes the left end of swing arm 19, the right end of swing arm 19 can be hit It strikes waters the tube wall of pipe 17.
Motor 23 and the first support shaft 24 are installed on base, are connected with elevating arc 25 on the output shaft of motor 23;First The driven gear 26 engaged with elevating arc 25 is rotatably connected in support shaft 24, and between driven gear 26 and the first support shaft 24 It is connected with torsional spring;Cutter 27 is slidably connected on the right side wall of cabinet 1, and the right end of cutter 27 is connected with and nibbles with driven gear 26 The rack gear 28 of conjunction.
It is rotatably connected to the second support shaft 29 on base, and is socketed between the second support shaft 29 and the output shaft of motor 23 Belt 30;Disk 31 is connected in second support shaft 29, the eccentric part of disk 31 is hinged with transmission arm 32;In the left side of cabinet 1 Sliding slot 33 is laterally offered on wall, and sieve 34 is slidably connected in sliding slot 33;The right end of sieve 34 passes through the right side wall of cabinet 1, The right end and transmission arm 32 of sieve 34 are hinged.
The bottom of cabinet 1 offers discharge port 35, and sealing cover 36 is threaded on discharge port 35.
The production method of the feed particles of PE film is needed using above-mentioned raw materials particle production apparatus.
The feed particles formula of PE film, is made by the raw material of following parts by weight: PE70 parts, 20 parts of antioxidant, and ceramics 25 parts of particle, 35 parts of ceramic particle, 10 parts of calcium carbonate, 45 parts of rutile particles, 20 parts of glycerol, 8 parts of glutaraldehyde.
A kind of production method of the feed particles of PE film, comprising the following steps:
(1) each component is weighed by weight ratio and is put into reaction kettle, and reaction is heated in nitrogen atmosphere, is re-fed into crowded Machine and squeeze out raw material out;
(2) raw material enters cabinet 1 from feed inlet 5, and raw material is cut into raw strip by vertical block 7;
(3) raw strip can be carried out by the cycle refrigeration system in vertical block 7 continuing cooling treatment, simultaneously, moreover it is possible to It has a rest and hits vertical block 7 vertical block 7 is made to generate vibration, raw strip is avoided to stick on vertical block 7;
(4) interval cutting process is carried out to raw strip using cutter 27, obtains feed particles;Feed particles pass through horizontal past The sieve 34 moved again is sieved, and has not only been avoided that feed particles are adhered on sieve 34, but also be avoided that feed particles are deposited in Lead to the blocking of sieve 34 together;
(5) feed particles are put into plastic film blowing machine to produce, obtain PE film.
Step (1) to the concrete operating principle that step (5) is handled is carried out to raw material using feed particles process units to be:
Each component is weighed by weight ratio, is put into reaction kettle, reaction is heated in nitrogen atmosphere, is then fed into double Screw extruder, the raw material of extrusion are fallen in feed pipe 6.
Raw material is concentrated under the action of feed pipe 6 to the movement of the direction of feed inlet 5, and raw material is under the action of feed inlet 5 In plate-like;Raw material carries out cutting process under the action of corner block 8 to get raw strip is arrived, and passes through the clear water in water pipe 17 Cooling processing is carried out to raw strip, so that clear water temperature rises, obtains warm water.
When raw material is through 8 cutting process of corner block, the weight pressure-ram 10 of raw material is moved down, so that upper on push rod 10 Opening 15 is communicated with the upper end of water pipe 17, and the under shed 16 on push rod 10 is communicated with the lower end of water pipe 17;Start sucking pump 13 and system Cooler 14, by the suction of sucking pump 13 by the warm water sucking reflux road 12 in water pipe 17, warm water is obtained through the cooling of refrigerator 14 Cold water;Cold water is moved in water pipe 17 through reflux road 12, recycles cold water to carry out cooling processing to raw material, with this circulation continuous pair Raw strip carries out cooling processing to get dry raw strip is arrived.
The process that water flow recycles in water pipe 17 and return pipe will drive the rotation of impeller 21, and impeller 21 passes through 20 band of asessory shaft Moving cam 22 rotates;The left end of swing arm 19 is squeezed by the convex portion of cam 22, so that swing arm 19 rotates, the right end of swing arm 19 The tube wall of water pipe 17 is hit, so that the tube wall of water pipe 17 generates vibration, and then drives vertical block 7 to generate vibration by water pipe 17; Water flow recycles in water pipe 17 and return pipe, so that the convex portion Intermittent pneumatic compression swing arm 19 of cam 22 is realized to 17 tube wall of water pipe Shock, i.e., water pipe 17 generate intermittent control shaking;Since water pipe 17 and vertical block 7 are affixed, and then drive vertical block 7 to generate interval and shake It is dynamic, that is, it can avoid raw strip and be sticked together during cooling with vertical block 7.
After raw strip completes cooling processing, shutter 4 is taken out from the side wall of cabinet 1, i.e., shutter 4 is to through-hole 3 Sealing function disappears, so that through-hole 3 and raw strip are vertically opposite.Start motor 23, the output shaft of motor 23 drives elevating arc 25 Rotation, so that 25 interval of elevating arc is engaged with driven gear 26;When elevating arc 25 is engaged with driven gear 26,25 band of elevating arc Dynamic driven gear 26 rotates, and driven gear 26 moves from right to left with carry-over bar 28 and cutter 27, i.e., using cutter 27 to raw material Item carries out cutting process, obtains feed particles;When elevating arc 25 is not engaged with driven gear 26, driven gear 26 is in torsional spring Effect is lower to be resetted, i.e., driven gear 26 is resetted with carry-over bar 28 and cutter 27;Pass through 26 interval of elevating arc 25 and driven gear Engagement obtains feed particles, it can be achieved that cutter 27 intermittently cuts raw strip.
Feed particles after cutting are fallen on sieve 34, and the output shaft of motor 23 can also drive second by belt 30 It supports axis 29 to rotate, the second support shaft 29 drives disk 31 to rotate;The disk 31 of rotation drives sieve 34 along cunning by transmission arm 32 The path horizontal direction of slot 33 moves back and forth, and has both been avoided that feed particles were adhered to by the reciprocating motion of 34 horizontal direction of sieve On sieve 34, and it is avoided that feed particles are packed together the blocking for leading to sieve 34, and original can also be sieved by sieve 34 Expect particle, out-of-size feed particles are blocked on sieve 34, the feed particles of size qualification is enabled to pass through sieve 34 collect to the bottom of cabinet 1.
When needing using feed particles, after sealing cover 36 is removed from discharge port 35, can be obtained;Again by feed particles It is put into plastic film blowing machine to be produced, obtains PE film.
What has been described above is only an embodiment of the present invention, and the common sense such as well known specific structure and/or characteristic are herein in scheme It does not describe excessively.It should be pointed out that for those skilled in the art, without departing from the structure of the invention, also Several modifications and improvements can be made, these also should be considered as protection scope of the present invention, these all will not influence of the invention real The effect and patent practicability applied.The scope of protection required by this application should be based on the content of the claims, specification In the records such as specific embodiment can be used for explaining the content of claim.

Claims (5)

  1. The feed particles formula of 1.PE film, it is characterised in that: the raw material including following parts by weight: PE60-85 parts, antioxidant 10-30 parts, 10-30 parts of ceramic particle, 15-50 parts of ceramic particle, 10-15 parts of calcium carbonate, 30-65 parts of rutile particles, glycerol 10-30 parts, 4-10 parts of glutaraldehyde.
  2. 2. the feed particles formula of PE film according to claim 1, it is characterised in that: by the raw material system of following parts by weight : it is PE70 parts, 20 parts of antioxidant, 25 parts of ceramic particle, 35 parts of ceramic particle, 10 parts of calcium carbonate, 45 parts of rutile particles, sweet 20 parts, 8 parts of glutaraldehyde of oil.
  3. 3. the production method of the feed particles of PE film according to claim 1, it is characterised in that: the following steps are included:
    (1) it needs to weigh each component by weight ratio using feed particles process units and put into reaction kettle, in nitrogen gas Reaction is heated in atmosphere, is re-fed into extruder and is squeezed out raw material;
    (2) raw material enters cabinet from feed inlet, and raw material is cut into raw strip by vertical block;
    (3) raw strip is carried out by the cycle refrigeration system in vertical block continuing cooling treatment;
    (4) interval cutting process is carried out to raw strip using cutter, obtains feed particles;
    (5) feed particles are put into plastic film blowing machine to produce, obtain PE film.
  4. 4. the production method of the feed particles of PE film according to claim 3, it is characterised in that: circulation in step (3) When refrigeration system continue cooling to raw strip, cycle refrigeration system can intermittently hit vertical block.
  5. 5. the production method of the feed particles of PE film according to claim 4, it is characterised in that: step obtains in (4) Feed particles sieved by the sieve of horizontal reciprocating movement.
CN201811400729.2A 2018-11-22 2018-11-22 Raw material particle formula of PE film and production method Active CN109265807B (en)

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CN109265807B CN109265807B (en) 2021-04-16

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