CN109265754A - A kind of edible composite film and its preparation method for ham processing - Google Patents

A kind of edible composite film and its preparation method for ham processing Download PDF

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Publication number
CN109265754A
CN109265754A CN201710597499.2A CN201710597499A CN109265754A CN 109265754 A CN109265754 A CN 109265754A CN 201710597499 A CN201710597499 A CN 201710597499A CN 109265754 A CN109265754 A CN 109265754A
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CN
China
Prior art keywords
ham
composite film
edible composite
preparation
edible
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710597499.2A
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Chinese (zh)
Inventor
王伟强
陈有亮
朱伟政
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Jinhua Golden Ham Co Ltd
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Jinhua Golden Ham Co Ltd
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Priority to CN201710597499.2A priority Critical patent/CN109265754A/en
Publication of CN109265754A publication Critical patent/CN109265754A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L5/00Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2305/00Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2301/00 or C08J2303/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2405/00Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2401/00 or C08J2403/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/14Gas barrier composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Meat, Egg Or Seafood Products (AREA)

Abstract

The invention discloses a kind of edible composite films and its preparation method for ham processing, two parts are prepared including edible composite film formula and edible composite film liquid, the edible composite film, using gellan gum and pulullan polysaccharide as film forming agent, dimethyl silicone polymer be barrier, glycerol is plasticizer, and addition mould inhibitor, antioxidant are combined;Using rust steel jacketed pan as heating vessel, heating stirring forms the edible composite film liquid.The edibility ham maturation composite membrane prepared using above-mentioned formula and technique, can effectively facilitate ham fermenting, maturation, prevent mouldy, the green mould of growth occurred in ham process, and can greatly improve the color, fragrance and quality of ham.

Description

A kind of edible composite film and its preparation method for ham processing
Technical field
The present invention relates to a kind of production method of edible composite film for meat product processing, especially a kind of fire The edible composite film and its preparation method of leg processing, belong to food processing technology field.
Technical background
Jinhua ham is the representative of Chinese ham, it is bright in colour with it, give off a strong fragrance, flavour is delicious, good appearance, preservation The characteristics such as phase length are well-known at home and abroad.Traditional Jinhua ham production all carries out under field conditions (factors), this traditional Jinhua fire It is corrupt, rotten to be not only easy to appear das Beinfleisch generation because of the restriction by natural climate in the process of production and processing for leg production technology And that there are salt contents is higher, cannot annual balanced production etc. limitation.Thus, most of Jinhua ham adds in recent years Work manufacturing enterprise introduces external dry-cured ham production equipment successively, processes Jinhua using the wet new process of whole temperature control, control Ham.Although this new equipment, new process solve the Mechanized Processing of Jinhua ham, realize the equilibrium of Jinhua ham whole year Production, solves the problems, such as that das Beinfleisch occurs putrid and deteriorated in Processing of Jinhua Ham, reduces the salt content of ham.So And Jinhua ham is processed using this whole temperature control, the wet new process of control, equipment investment is not only considerably increased, production is improved Cost, and critical issue is fermented, in maturation at it, still as traditional handicraft, its table in ham process Face equally can also grow the mould of a large amount of greens, and these green moulds have not only seriously affected the presentation quality of product and eaten When utilization rate, and these green moulds are also possible to folder and deposit the other moulds for influencing product edible safety.By in recent years It is coming many studies have shown that, these green moulds are not that ham fermenting, mature institute are required, therefore, if can produce in Jinhua ham In the process, it effectively prevent ham mouldy in fermentation, maturation, grows green mould, will not only be conducive to improve ham quality, But also its edible safety will be greatly improved;In addition, ham fat excessive oxidation of the ham in fermentation, maturation is asked Topic can also be effectively controlled, so as to greatly improve the color, fragrance and deliciousness of Jinhua ham.
Summary of the invention
In view of above-mentioned problem, it is an object of the present invention to provide one kind to process for ham, and can effectively improve Jinhua The edible composite film and its preparation method for ham processing of ham quality.
To achieve the goals above, the invention adopts the following technical scheme:
A kind of edible composite film and its preparation method for ham processing of the present invention, including edibility are compound Film formulation and edible composite film liquid prepare two parts, it is characterized in that: the edible composite film, with gellan gum and Pu Lu Blue polysaccharide is film forming agent, dimethyl silicone polymer is barrier, glycerol is plasticizer, and addition mould inhibitor, antioxidant are answered It closes, specific formula is following (%):
The mould inhibitor is using natamycin or dehydroactic acid sodium or sodium Diacetate.
The antioxidant are as follows: butylated hydroxy anisole (BHA) or dibutyl hydroxy toluene (BHT) or tertiary butyl are to benzene Diphenol (TBHQ).
The antioxidant and mould inhibitor can respectively select its single to use, and can also respectively select its a variety of compound use.
It is of the present invention it is a kind of for ham processing edible composite film, select gellan gum and pulullan polysaccharide at Film, dimethyl silicone polymer are barrier, and glycerol is that plasticizer system carries out compound, manufactured composite membrane, are relatively suitble to fire Leg maturation and preservation.Because the film forming of pulullan polysaccharide, gas barrier property, plasticity, viscosity are relatively strong, but resistance is moist weaker, Under high humidity environment be easy the moisture absorption and it is tacky, gel cannot be formed.And dimethyl silicone polymer resistance is wet very competent, gellan gum is solidifying Colloidality is fabulous, can just make up the deficiency of pulullan polysaccharide.Antioxidant, mould inhibitor are added in above-mentioned film liquid again, can be made At the edible composite film with wet resistance, choke, mould proof, anti-oxidant etc. and good mechanical, oxygen transmission coefficient is 6.088mmol/ (kgmdMPa), water vapor transmission are 3.892 × 10-10g/(m·s·Pa)。
A kind of edible composite film liquid making method for ham processing of the present invention:
Using stainless steel jacketed pan as heating vessel, in stainless steel jacketed pan, by formula rate, at normal temperature, first Water and glycerol is added to stir evenly;While agitating, it is slowly added into gellan gum and pulullan polysaccharide, and heat temperature raising under stiring It to 85-95 DEG C, stirs 2~3 minutes, is completely dissolved gellan gum and pulullan polysaccharide, be eventually adding dimethyl silicone polymer, resist Oxidant and mould inhibitor, then it is agitated uniform, make 80 DEG C or so of its temperature, and place it in cool-bag, the temperature of storage 80 DEG C must not be lower than;In this way, having prepared a kind of edible composite film liquid for ham processing.
By the prepared edible composite film liquid for being used for ham processing 80 DEG C or so at a temperature of be coated with or leaching is multiple etc. Technique can form one layer of edibility ham maturation composite membrane after cooling in by handling surface of ham to be processed.It is this can Feeding habits ham maturation composite membrane can effectively facilitate ham fermenting, maturation, prevent in ham process it is mouldy, growth green it is mould Bacterium, and the color, fragrance and quality of ham can be greatly improved.
A kind of preparation method of edible composite film liquid for ham processing of the present invention, simple process are easy to Operation, key points for operation are the conditions that strictly grasp the temperature and time and storage of heating.
Specific embodiment
Combined with specific embodiments below, the present invention is described further, but protection scope of the present invention and not only limits In this:
Embodiment 1
1, the composition (%) for the edible composite film of ham processing:
2. the preparation of the edible composite film liquid for ham processing
Using stainless steel jacketed pan as heating vessel.In stainless steel jacketed pan, by formula rate, first add at normal temperature Water and glycerol stir evenly;While agitating, it is slowly added into gellan gum and pulullan polysaccharide, and is heated under stiring It 85-95 DEG C, stirs 2~3 minutes, is completely dissolved gellan gum and pulullan polysaccharide, is eventually adding dimethyl silicone polymer, antioxygen Agent and mould inhibitor, then it is agitated uniform, make 80 DEG C or so of its temperature, and place it in cool-bag, the temperature of storage is not It obtains and is lower than 80 DEG C;In this way, being configured to composite membrane liquid.
By prepared edible composite film liquid 80 DEG C or so at a temperature of, using techniques, the coating such as coating or leaching be multiple In surface treated surface of ham, one layer of ham maturation film can be formed after cooling.This edibility ham maturation is compound Film can effectively facilitate ham fermenting, maturation, prevent mouldy, the green mould of growth in ham process, and can greatly improve fire Color, fragrance and the quality of leg.
Embodiment 2
1, the composition (%) for the edible composite film of ham processing:
2. the preparation of the edible composite film liquid for ham processing
Using stainless steel jacketed pan as heating vessel.In stainless steel jacketed pan, by formula rate, at normal temperature, first Water and glycerol is added to stir evenly;While agitating, it is slowly added into gellan gum and pulullan polysaccharide, and heat temperature raising under stiring It to 85-95 DEG C, stirs 2~3 minutes, is completely dissolved gellan gum and pulullan polysaccharide, be eventually adding dimethyl silicone polymer, resist Oxidant and mould inhibitor, then it is agitated uniform, make 80 DEG C or so of its temperature, and place it in cool-bag, the temperature of storage 80 DEG C must not be lower than;In this way, being configured to composite membrane liquid.
By prepared edible composite film liquid 80 DEG C or so at a temperature of, using techniques, the coating such as coating or leaching be multiple In surface treated surface of ham, one layer of ham maturation film can be formed after cooling.This edibility ham maturation is compound Film can effectively facilitate ham fermenting, maturation, prevent mouldy, the green mould of growth in ham process, and can greatly improve fire Color, fragrance and the quality of leg.

Claims (4)

1. a kind of edible composite film and its preparation method for ham processing, including edible composite film formula and edibility Composite membrane liquid prepares two parts, it is characterized in that: the edible composite film, is film forming with gellan gum and pulullan polysaccharide Agent, dimethyl silicone polymer are barrier, glycerol is plasticizer, and addition mould inhibitor, antioxidant are combined, specific It is formulated following (%):
2. a kind of edible composite film and its preparation method for ham processing according to claim 1, it is characterized in that: The mould inhibitor is using natamycin or dehydroactic acid sodium or sodium Diacetate.
3. a kind of edible composite film and its preparation method for ham processing according to claim 1, it is characterized in that: The antioxidant are as follows: butylated hydroxy anisole (BHA) or dibutyl hydroxy toluene (BHT) or tert-butylhydroquinone (TBHQ)。
4. a kind of edible composite film and its preparation method for ham processing according to claim 1, it is characterized in that: The preparation method of the edible composite film liquid, using stainless steel jacketed pan as heating vessel, in stainless steel jacketed pan, By formula rate, at normal temperature, first plus water and glycerol are stirred evenly;While agitating, gellan gum and Propiram are slowly added into Polysaccharide, and it is heated to 85-95 DEG C under stiring, it stirs 2~3 minutes, is completely dissolved gellan gum and pulullan polysaccharide, most Dimethyl silicone polymer, antioxidant and mould inhibitor are added afterwards, then agitated uniform, make 80 DEG C or so of its temperature, and set In in cool-bag, the temperature of storage must not be lower than 80 DEG C.
CN201710597499.2A 2017-07-17 2017-07-17 A kind of edible composite film and its preparation method for ham processing Pending CN109265754A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201710597499.2A CN109265754A (en) 2017-07-17 2017-07-17 A kind of edible composite film and its preparation method for ham processing

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110973223A (en) * 2019-12-12 2020-04-10 裘先远 Anti-oxidation and anti-ultraviolet protection method in ham aging process

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1072633A1 (en) * 1999-07-22 2001-01-31 Warner-Lambert Company Pullulan film compositions
CN102670563A (en) * 2012-06-05 2012-09-19 江南大学 Preparation method of soft capsule without gelatin
CN104448408A (en) * 2014-11-28 2015-03-25 张明 Compound edible biofilm
CN106146907A (en) * 2016-07-28 2016-11-23 马鞍山市五谷禽业专业合作社 The starch base composite mulching film that a kind of block-water performance is good

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1072633A1 (en) * 1999-07-22 2001-01-31 Warner-Lambert Company Pullulan film compositions
CN102670563A (en) * 2012-06-05 2012-09-19 江南大学 Preparation method of soft capsule without gelatin
CN104448408A (en) * 2014-11-28 2015-03-25 张明 Compound edible biofilm
CN106146907A (en) * 2016-07-28 2016-11-23 马鞍山市五谷禽业专业合作社 The starch base composite mulching film that a kind of block-water performance is good

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
BRIAN G. ZUKAS等: "Improved Water Barrier Properties of Calcium Alginate Capsules Modifed by Silicone Oil", 《GELS》 *
周然等: "可食性保鲜涂膜对冷藏黄花梨品质的影响", 《农业工程学报》 *
朱桂兰等: "普鲁兰、甘油共混对结冷胶食用膜性能的影响", 《食品工业科技》 *
高翔: "多糖可食用包装膜的制备与应用研究", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110973223A (en) * 2019-12-12 2020-04-10 裘先远 Anti-oxidation and anti-ultraviolet protection method in ham aging process

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Application publication date: 20190125