CN109258672A - A kind of high efficiency composition benomyl Biocidal algae-killing agent and preparation method thereof - Google Patents
A kind of high efficiency composition benomyl Biocidal algae-killing agent and preparation method thereof Download PDFInfo
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- CN109258672A CN109258672A CN201811282950.2A CN201811282950A CN109258672A CN 109258672 A CN109258672 A CN 109258672A CN 201811282950 A CN201811282950 A CN 201811282950A CN 109258672 A CN109258672 A CN 109258672A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
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- Pest Control & Pesticides (AREA)
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Abstract
The present invention relates to a kind of high efficiency composition benomyl Biocidal algae-killing agents, including benomyl, 3 methyl 4 isopropyl phenol, quaternary ammonium salt, polyethylene glycol, polyvinyl alcohol, polycarboxylic acid scale-inhibition dispersant, pH adjusting agent and deionized water.The Biocidal algae-killing agent broad spectrum activity is high, the antibacterial duration is long, is adapted to biggish temperature range, has good sterilization algae removal effect at low concentrations, and has the function of being sustained scale inhibition.
Description
Technical field
The present invention relates to a kind of Biocidal algae-killing agent more particularly to a kind of high efficiency composition benomyl Biocidal algae-killing agent and its preparations
Method.
Background technique
The growth of microorganism can cause increasing for dirt and glutinous mud in cooling water system, generate underdeposit corrosion, cause to exchange heat
The reduction of device cooling efficiency, meanwhile, hidden danger is brought to safety in production.Therefore, it is necessary to Biocidal algae-killing agent be added, to control cooling water
The growth of middle microorganism.According to the sterilization mechanism of fungicide, common circulating cooling water germicide divides oxidized form and Non-oxidized,
Wherein oxidized form mainly uses chlorine.With the extensive use of alkaline Cycle Cool Water Treatment, chlorine fungicide has been unable to satisfy
Increasingly developed water treatment technology requirement.Water after chlorine treatment generates chloroform, has a carcinogenicity, and half-life period compared with
It is long, very big harm is caused to environment, therefore develop efficiently, wide spectrum, environmental protection fungicide be instantly urgent need to resolve the problem of.
Oxidative bactericide has stronger oxidisability, the intracorporal biological oxydasis of microorganism can be made its metabolic process
It is restricted, there is very strong microorganism to kill livestock effect, broad spectrum activity height, processing cost are low；But the deficiency of oxidative bactericide
Place is that the effect of killing livestock is affected by Organic substance in water and reducing substances, and the pharmacy effect time is short, by the pH shadow in water
Sound is larger, while it is poor to disperse infiltration and peeling effect.Non-oxidative bactericide does not kill microorganism with oxidation, with
Intoxicating acts on the privileged sites of microorganism, because without being influenced by reducing substances in water.The work of killing livestock of non-oxidative bactericide
With there is certain duration, have infiltration, release effect to deposit or glutinous mud, by the reducing substances such as hydrogen sulfide, ammonia influenced compared with
It is small, influenced by pH in water smaller, but processing cost is higher with respect to oxidative bactericide.
Currently, domestic existing non-oxydizing sterilization algicide kind is few, and for a long time using same in water system
Biocide is easy to produce drug resistance, to influence water treatment efficiency and increase water process expense, so needing to develop novel kill
Bacterium algicide.
Chinese patent CN105191980A discloses a kind of composite sterilization algicide for recirculated cooling water and its preparation
Method is made of the raw material of following weight percentage: isothiazolinone 10%~30%, 2,2- bis- bromo- 3- nitrilo-s third
Amide 3%~15%, polyethylene glycol 5%~20%, alpha-bromo-cinnamaldehyde 5%~15%, glutaraldehyde 15%~25%, copper sulphate
0.5%~2%, tannin 3%~10%, surplus is deionized water.
Chinese patent CN106386807A discloses a kind of sewage treatment Biocidal algae-killing agent, is made of following raw materials: 2,
2 '-dihydroxy -5,5 '-dichloro phenylmethane, the bromo- 3- nitrilo propionamide of 2,2- bis-, zinc dialkyl dithiophosphate, di-2-ethylhexylphosphine oxide
Stearmide, 3,7- dimethyl -2,6- octadiene nitrile, boric acid diacylglycerol monostearate sodium salt, fatty alkyl dimethyl benzyl chlorine
Change ammonium, methyl ethyl ketone peroxide, 1-3 parts of dimethylethanolamine, 1,3 butylene glycol, polyvinyl alcohol, deionized water.
Chinese patent CN106219778A discloses a kind of non-phosphorus scale and corrosion inhibitor and its system with sterilization algae removal function
Preparation Method is made of the raw material of following weight percent: 30~50% polycarboxylic acids, 10~30% ethylene oxide, 1
~5% boric acid, 1~3% zinc sulfate, 1~2% benzotriazole and 24~46% deionized water.
Above-mentioned antisepsis algicide in the prior art to a certain extent can actually be good to having to individual bacteria
Antibacterial effect, but broad spectrum activity is general, and the duration is shorter, and algae and bacterium can largely breed repeatedly.This kind of antibacterial algae removal
Agent competence exertion bactericidal effect only under big concentration, results in the need for largely using, and pollutes environment.
Summary of the invention
For the defects in the prior art, the present invention provides a kind of high efficiency composition benomyl Biocidal algae-killing agent, which goes out
Algae agent broad spectrum activity is high, the antibacterial duration is long, is adapted to biggish temperature range, and there is good sterilization to go out at low concentrations
Algae effect, and have the function of being sustained scale inhibition.
The first purpose of the invention is to provide a kind of high efficiency composition benomyl Biocidal algae-killing agents, which is characterized in that including
Benomyl, 3 methyl 4 isopropyl phenol, quaternary ammonium salt, polyethylene glycol, polyvinyl alcohol, polycarboxylic acid scale-inhibition dispersant, pH adjusting agent
And deionized water.
Further, the parts by weight of the high efficiency composition benomyl Biocidal algae-killing agent each component be benomyl 1-10 parts,
1-10 parts of 3 methyl 4 isopropyl phenol, 5-15 parts of quaternary ammonium salt, 5-10 parts of polyethylene glycol, 5-10 parts of polyvinyl alcohol, polycarboxylic acids resistance
Dirty dispersing agent 1-5 parts, 1-5 parts of pH adjusting agent and 50-100 parts of deionized water.
Further, the parts by weight of the high efficiency composition benomyl Biocidal algae-killing agent each component are benomyl 1-5 parts, 3-
1-5 parts of methyl -4- isopropyl-phenol, 5-10 parts of quaternary ammonium salt, 5-8 parts of polyethylene glycol, 5-8 parts of polyvinyl alcohol, polycarboxylic acids scale inhibition point
3-5 parts of powder, 3-5 parts of pH adjusting agent and 60-80 parts of deionized water.
Further, the mass ratio of benomyl and 3 methyl 4 isopropyl phenol is 1:0.5-1:8, preferably 1:1-1:
5, more preferably 1:1-1:3.
Further, the quaternary ammonium salt be selected from dodecyl trimethyl ammonium chloride, dodecyl benzyl dimethyl ammonium chloride,
Dodecyl dimethyl benzyl ammonium bromide, styrene phenol polyoxyethylene ether ammonium sulfate, in polydimethyl diallyl ammonium chloride
One or more.
Further, the polycarboxylic acid scale-inhibition dispersant is selected from polyacrylic acid, poly-aspartate, polymaleic anhydride, Malaysia
One or more of acid anhydrides acrylic acid copolymer acid.
Further, the pH adjusting agent be selected from one of sodium carbonate, sodium bicarbonate, sodium hydroxide, ammonium hydrogen carbonate or
It is several.
A second object of the present invention is to provide a kind of preparation method of high efficiency composition benomyl Biocidal algae-killing agent, features
It is to include the following steps: to be added deionized water in benomyl, 3 methyl 4 isopropyl phenol, stirring is warming up to 30-40
DEG C, sequentially add quaternary ammonium salt, polyethylene glycol, polyvinyl alcohol, polycarboxylic acid scale-inhibition dispersant, and reaction system is warming up to 60-80
DEG C, pH adjusting agent is added, continues to stir 2-4h, solution is cooled to room temperature, obtains high efficiency composition benomyl Biocidal algae-killing agent.
Third object of the present invention is to provide a kind of high efficiency composition benomyl Biocidal algae-killing agents, it is characterised in that according to this
A kind of preparation method of high efficiency composition benomyl Biocidal algae-killing agent of second purpose of invention is prepared.
Fourth object of the present invention is to provide a kind of application of high efficiency composition benomyl Biocidal algae-killing agent, and feature exists
In: suitable for circulation, cooling water system, refinery water system, textile process water system, dyeing and printing process water system
System, oil field flood pattern, metalworking fluid systems, paper mill process water system.
Further, the use concentration of the Biocidal algae-killing agent be 1mg/L-50mg/L, preferably 1mg/L-20mg/L, more
Preferably 2mg/L-10mg/L.
Further, the use temperature of the Biocidal algae-killing agent is 10-80 DEG C, preferably 20-75 DEG C, more preferably 25-
60℃。
Benomyl, chemical name 1- n-butyl amine base formyl-methyl 2-benzimidazolecarbamate are systemic fungicide,
Plant intracellular metabolite is that carbendazim and another kind have volatility butyl isocyanate, is its major antibacterial substance.Sterling is white knot
Crystalline substance, slightly stink.To low toxicities such as people, animal, fish, honeybees.It is applied to industry for agricultural bacteriocide benomyl as main component
With water process, this has a very important significance to application of the pesticide in non-agricultural field is developed.
Quaternary ammonium salt bactericide is mainly that cation passes through electrostatic force, hydrogen bond force and surfactant molecule and protein point
The effects of hydrophobic binding between son, electronegative bacterial body is adsorbed, is gathered on cell wall, generating chamber's inhibition effect leads to bacterium
It grows suppressed and dead；Its hydrophobic alkyl can also be acted on the hydrophilic group of bacterium simultaneously, changed the permeability of film, then occurred molten
Born of the same parents' effect, destroys eucaryotic cell structure, causes the dissolution and death of cell.This kind of fungicide has efficient, low toxicity, not vulnerable to pH value change
The influence of change, it is easy to use, have stronger release effect, stable chemical performance, dispersion and corrosion inhibition to rete malpighii preferably etc.
Feature.Quaternary ammonium salt fungicide has wide spectrum, efficient sterilization algae removal ability, can efficiently control bacterium algae breeding and foundry loam in water
Growth, and there is good sludge stripping effect and certain dispersion, osmosis, it can effectively cut out algae reproduction and foundry loam
Increase, there is good sterilization in different pH value ranges；Have simultaneously it is certain deoil, deodorizing capability and corrosion inhibition.
Polycarboxylic acid dirt dispersion agent has good scale effect to lime scale.It is mainly used for the water cooling of every profession and trade
The anti-corrosion and resistance of the equipment such as device, oil cooler, condenser, air cooler, evaporator, radiator, reaction kettle, absorption tower, basin, pipeline
Dirt.Polycarboxylic acids of the invention exists since electrostatic repulsion, solubilising and distortion of lattice act on, thus to a variety of inorganic scales and colloid dirt
With preferable dispersing and dissolving ability.There is polycarboxylic acids dispersion and scale effect, one end can be adsorbed on calcium carbonate etc. into dirt
On the crystal grain of the factor, rest part is then surrounded around crystal grain, be increased it can not and is become round and smooth, and indissoluble is reduced or control
Salt is gathered into dirt, is mainly used for preventing calcium carbonate, silicate, sulfate and phosphatic scale deposition.
If the content of phosphorus is more than certain standard (such as 20mg/L) in water body, water body serious eutrophication will lead to,
The mortality of the biology such as fish is eventually led to, the ecological balance in water is destroyed.Biocidal algae-killing agent of the invention is not phosphorous, effectively subtracts
Few water pollution.
Biocidal algae-killing agent of the invention has at low concentrations compared to the Biocidal algae-killing agent more highly effective in existing market
There is good sterilization algae removal effect.The use concentration of Biocidal algae-killing agent of the present invention is 1mg/L-50mg/L, preferably 1mg/L-
20mg/L, more preferably 2mg/L-10mg/L.
Compared with prior art, beneficial effects of the present invention are as follows:
1, using agricultural bacteriocide benomyl as main component applied to industrial water processing, this is to exploitation pesticide non-agricultural
The application in field has a very important significance.
2, broad spectrum antibacterial: antibacterial agent of the invention has good antibacterial effect to various bacteria, and antibacterial type is more, extensively
Spectrum, to such as heterotrophic bacteria, ammonifiers, sulfur bacteria, iron bacteria, foundry loam cenobium, football shirt bacterium, sulfate reducing bacteria, nitrococcus, anti-
Nitrifier and fungi etc. have extraordinary effect.
3, Biocidal algae-killing agent of the invention is compared to the Biocidal algae-killing agent more highly effective in existing market, at low concentrations
With good sterilization algae removal effect.Biocidal algae-killing agent of the present invention in the case where 10mg/L is using concentration also there is extraordinary sterilization to go out
Algae effect, reduces the usage amount of fungicide.
4, chemicals used in the present invention is the environment protection chemical product of easily biological-degradable, belongs to low toxicity level industrial products, not dirty
Water environment is contaminated, is a kind of Phosphateless environmentally friendly water treatment agent efficiently, economic.
5, compared with existing product, Biocidal algae-killing agent of the present invention can inhibit and interfere the normal growth of glutinous mud, prevent
It generates the multilayer composite containing various organisms and sticks mud, improve heat transfer and the cooling effect of recirculated cooling water pipeline, reduce pipe
Wall erosion rate.Above-mentioned each component plays synergistic effect, compared with existing product, sterilization algae removal effect of the present invention have persistently,
Efficiently, stable feature.
Specific embodiment
Embodiment
Preparation method: being added deionized water in benomyl, 3 methyl 4 isopropyl phenol, and stirring is warming up to 30-40
DEG C, sequentially add quaternary ammonium salt, polyethylene glycol, polyvinyl alcohol, polycarboxylic acid scale-inhibition dispersant, and reaction system is warming up to 60-80
DEG C, pH adjusting agent is added, continues to stir 2-4h, solution is cooled to room temperature, obtains high efficiency composition benomyl Biocidal algae-killing agent.
In order to prove sterilization algae removal of the invention, scale-inhibiting properties, the performance of the resulting Biocidal algae-killing agent of above-described embodiment is commented
It is as follows to determine method:
Bactericidal property measurement
(DL/T 1116-2009) is evaluated with bactericidal property using recirculated cooling water to be measured, and uses embodiment 1-6's
Biocidal algae-killing agent to a variety of bacterium determination bactericidal properties, reference examples be market products geramine (comparative example 1) and
The Biocidal algae-killing agent (comparative example 2) of CN105191980A embodiment 1.Wherein, embodiment 1-6 and comparative example 1-2 using dense
Degree is 10mg/L, and temperature is 35 DEG C.Test result is shown in Table 1.
1 sterilizing rate of table (%)
From the point of view of 1 result of table, the Biocidal algae-killing agent of 1-6 of the embodiment of the present invention has very strong antibacterial to imitate various strains
Fruit has 99.5% or more antibiotic rate, and very wide spectrum to the strain of test at low concentrations under 10mg/L, to various thin
The sterilizing rate of bacterium is all very high.The antibiotic rate of comparative example 1-2 is poor with the effect of the embodiment of the present invention 1-6 only 72% or more
Away from larger.
(DL/T 1116-2009) is evaluated with bactericidal property using recirculated cooling water to be measured, and uses embodiment 1 and right
Ratio 1-2 measurement measures bactericidal property to heterotrophic bacteria at different temperatures, wherein the use of concentration being 10mg/L.Test result is shown in
Table 2.
Table 2
| Temperature/DEG C | Embodiment 1 | Comparative example 1 | Comparative example 2 |
| 10 | 97.6 | 52.6 | 33.5 |
| 20 | 98.9 | 66.3 | 69.0 |
| 25 | 99.9 | 82.3 | 78.3 |
| 30 | 99.9 | 90.4 | 83.2 |
| 35 | 99.9 | 86.4 | 75.6 |
| 40 | 99.9 | 92.3 | 73.5 |
| 50 | 99.9 | 77.5 | 48.2 |
| 60 | 98.7 | 52.7 | 40.2 |
| 70 | 95.6 | 40.3 | 20.4 |
| 80 | 94.0 | 33.8 | 19.7 |
From the point of view of 2 result of table, the Biocidal algae-killing agent of the embodiment of the present invention 1 has in the range of 10-80 DEG C of temperature range
There is higher sterilizing rate, applicable temperature range is very wide.Due to circulation, cooling water system, refinery water system, spin
Knit processing water system, dyeing and printing process water system, oil field flood pattern, metalworking fluid systems, paper mill process water system
Coolant-temperature gage in system is different, therefore Biocidal algae-killing agent of the invention can be applicable in the water under different situations.Comparative example 1-2's
Biocidal algae-killing agent bactericidal effect under higher and lower temperature is very undesirable, has biggish gap with the embodiment of the present invention.
(DL/T 1116-2009) is evaluated with bactericidal property using recirculated cooling water to be measured, using embodiment 1-6 and
Comparative example 1-2 measurement measures bactericidal property to heterotrophic bacteria under different time, wherein the use of concentration being 10mg/L.Test result
It is shown in Table 3.
Table 3
| Time | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Comparative example 1 | Comparative example 2 |
| 1 | 81.3 | 78.9 | 80.7 | 73.6 | 85.3 | 75.9 | 42.5 | 33.2 |
| 4 | 96.5 | 97.2 | 98.3 | 94.8 | 99.4 | 95.9 | 61.2 | 56.7 |
| 8 | 99.9 | 99.9 | 99.9 | 99.9 | 99.9 | 99.9 | 73.2 | 66.9 |
| 24 | 99.9 | 99.9 | 99.9 | 99.9 | 99.9 | 99.9 | 86.4 | 75.6 |
| 48 | 99.9 | 99.9 | 99.9 | 99.9 | 99.9 | 99.9 | 80.1 | 69.1 |
| 72 | 95.3 | 94.3 | 96.7 | 93.1 | 96.8 | 93.2 | 60.3 | 55.2 |
| 96 | 85.1 | 88.2 | 90.3 | 84.5 | 92.3 | 87.6 | 40.2 | 39.0 |
From the point of view of 3 result of table, the duration of the bactericidal property of the Biocidal algae-killing agent of 1-6 of the embodiment of the present invention is longer, and 96
Also there is a preferable bactericidal effect after hour, and the Biocidal algae-killing agent of the comparative example 1-2 range of decrease under bactericidal effect over time
It spends larger, has biggish gap with the embodiment of the present invention.
Scale-inhibiting properties measurement
Scale-inhibiting properties measurement is carried out using static-state scale inhibition experiment method (GB16632-1996), test result is shown in Table 4.
Table 4
From the results shown in Table 4, the Biocidal algae-killing agent of 1-6 of the embodiment of the present invention has extraordinary scale inhibition performance,
99% or more, and the scale inhibition performance of comparative example 1-2 is general, obvious with gap of the embodiment of the present invention.
More than, embodiments of the present invention are illustrated.But the present invention is not limited to above embodiment.It is all
Within the spirit and principles in the present invention, any modification, equivalent substitution, improvement and etc. done should be included in guarantor of the invention
Within the scope of shield.
Claims (10)
1. a kind of high efficiency composition benomyl Biocidal algae-killing agent, which is characterized in that including benomyl, 3 methyl 4 isopropyl phenol,
Quaternary ammonium salt, polyethylene glycol, polyvinyl alcohol, polycarboxylic acid scale-inhibition dispersant, pH adjusting agent and deionized water.
2. a kind of high efficiency composition benomyl Biocidal algae-killing agent according to claim 1, it is characterised in that the high efficiency composition benzene bacterium
The parts by weight of clever Biocidal algae-killing agent each component are benomyl 1-10 parts, 1-10 parts of 3 methyl 4 isopropyl phenol, quaternary ammonium salt 5-
15 parts, 5-10 parts of polyethylene glycol, 5-10 parts of polyvinyl alcohol, 1-5 parts of polycarboxylic acid scale-inhibition dispersant, 1-5 parts of pH adjusting agent and go
50-100 parts of ionized water.
3. a kind of high efficiency composition benomyl Biocidal algae-killing agent according to claim 2, it is characterised in that the high efficiency composition benzene bacterium
The parts by weight of clever Biocidal algae-killing agent each component are benomyl 1-5 parts, 1-5 parts of 3 methyl 4 isopropyl phenol, quaternary ammonium salt 5-10
Part, 5-8 parts of polyethylene glycol, 5-8 parts of polyvinyl alcohol, 3-5 parts of polycarboxylic acid scale-inhibition dispersant, 3-5 parts of pH adjusting agent and deionization
60-80 parts of water.
4. any one of -3 a kind of high efficiency composition benomyl Biocidal algae-killing agent according to claim 1, it is characterised in that benomyl and
The mass ratio of 3 methyl 4 isopropyl phenol is 1:0.5-1:8, preferably 1:1-1:5, more preferably 1:1-1:3.
5. any one of -4 a kind of high efficiency composition benomyl Biocidal algae-killing agent according to claim 1, it is characterised in that the quaternary ammonium
Salt be selected from dodecyl trimethyl ammonium chloride, dodecyl benzyl dimethyl ammonium chloride, dodecyl dimethyl benzyl ammonium bromide,
One or more of styrene phenol polyoxyethylene ether ammonium sulfate, polydimethyl diallyl ammonium chloride.
6. any one of -5 a kind of high efficiency composition benomyl Biocidal algae-killing agent according to claim 1, it is characterised in that the poly- carboxylic
Sour dirt dispersion agent be selected from one of polyacrylic acid, poly-aspartate, polymaleic anhydride, maleic anhydride acrylic acid copolymer acid or
It is several.
7. any one of -6 a kind of high efficiency composition benomyl Biocidal algae-killing agent according to claim 1, it is characterised in that the pH tune
It saves agent and is selected from one or more of sodium carbonate, sodium bicarbonate, sodium hydroxide, ammonium hydrogen carbonate.
8. a kind of preparation method of any one of -7 high efficiency composition benomyl Biocidal algae-killing agent, feature exist according to claim 1
In including the following steps: that deionized water is added in benomyl, 3 methyl 4 isopropyl phenol, stirring be warming up to 30-40 DEG C,
Quaternary ammonium salt, polyethylene glycol, polyvinyl alcohol, polycarboxylic acid scale-inhibition dispersant are sequentially added, and reaction system is warming up to 60-80 DEG C,
PH adjusting agent is added, continues to stir 2-4h, solution is cooled to room temperature, obtains high efficiency composition benomyl Biocidal algae-killing agent.
9. the application of any one of -7 a kind of high efficiency composition benomyl Biocidal algae-killing agent according to claim 1, it is characterised in that suitable
For circulation, cooling water system, refinery water system, textile process water system, dyeing and printing process water system, oil field
Flood pattern, metalworking fluid systems, paper mill process water system.
10. a kind of application of high efficiency composition benomyl Biocidal algae-killing agent according to claim 9, it is characterised in that the sterilization is gone out
The use concentration of algae agent is 1mg/L-50mg/L, preferably 1mg/L-20mg/L, more preferably 2mg/L-10mg/L.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114106788A (en) * | 2021-12-15 | 2022-03-01 | 湖南省希润弗高分子新材料有限公司 | Industrial circulating cooling liquid |
| CN114557346A (en) * | 2022-02-24 | 2022-05-31 | 上海康跃化工科技有限公司 | Mildew-removing and anti-blocking composition, application thereof and mildew-removing and anti-blocking sheet |
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| CN105746512A (en) * | 2016-03-08 | 2016-07-13 | 佛山市聚成生化技术研发有限公司 | Quaternary ammonium salt type water treatment bactericide |
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- 2018-10-31 CN CN201811282950.2A patent/CN109258672A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105746512A (en) * | 2016-03-08 | 2016-07-13 | 佛山市聚成生化技术研发有限公司 | Quaternary ammonium salt type water treatment bactericide |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114106788A (en) * | 2021-12-15 | 2022-03-01 | 湖南省希润弗高分子新材料有限公司 | Industrial circulating cooling liquid |
| CN114557346A (en) * | 2022-02-24 | 2022-05-31 | 上海康跃化工科技有限公司 | Mildew-removing and anti-blocking composition, application thereof and mildew-removing and anti-blocking sheet |
| CN114557346B (en) * | 2022-02-24 | 2024-01-05 | 浙江康星科技有限公司 | Mildew-removal anti-blocking composition, application thereof and mildew-removal anti-blocking sheet |
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