CN109252238A - A kind of preparation method of nylon hair - Google Patents
A kind of preparation method of nylon hair Download PDFInfo
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- CN109252238A CN109252238A CN201710571516.5A CN201710571516A CN109252238A CN 109252238 A CN109252238 A CN 109252238A CN 201710571516 A CN201710571516 A CN 201710571516A CN 109252238 A CN109252238 A CN 109252238A
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- Prior art keywords
- nylon hair
- preparation
- acid
- calcium carbonate
- hair
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic System
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Abstract
The present invention provides a kind of preparation method of nylon hair, comprising the following steps: (1) by weight percentage, weighs the polyester of 85-95% and the nanometer calcium carbonate of 5-15%, mix；(2) polyester and nano-calcium carbonate calcium compound are subjected to wire drawing；(3) silk pulled out by step (2) is subjected to sour processing, obtains the nylon hair；Additionally provide the preparation method of cosmetic brush bristles, one end of above-mentioned nylon hair is immersed in cellulose oxidation agent, oxidization time is controlled according to hair peak length, carry out sharpening, washing, drying, obtain cosmetic brush bristles, nylon hair toughness of the invention is big, it is strong to dip in powder power, and it is uniform to dip in powder, can save with powder amount.
Description
Technical field
The invention belongs to technical field of polymer materials, more particularly to a kind of preparation method of nylon hair.
Background technique
Cosmetic brush is mainly used for the fields such as color make-up, can be generally divided into sweet painting, blush brush, brow brush, eye-lash, informer
Brush, lash curler etc., but the structure of different cosmetic brush is mostly similar.Cosmetic brush is mainly made of two parts, as pommel and brush
Hair.The manufacture material of traditional cosmetic brush, pommel mainly use wooden or organic synthesis material；Bristle mainly uses natural animal
The synthetic materials such as chaeta or artificial nylon hair.The material of bristle determines the quality and price of cosmetic brush.In general, animal wool ratio
Synthetic nylon hair sense of touch is good, and makeup effect is also more docile, but animal wool often higher cost, has peculiar smell, color is single, is cultivated
The limitation of family natural production, while being related to the content in terms of the ethics such as animal protection.And current synthesis Buddhist nun on the market
Imperial hair is insufficient in upper powder aspect of performance, such as to dip in powder power poor, and it is uneven to glue powder, the docile degree deficiency of makeup, while portion
The phenomenon that dividing user to will appear easy allergy.
In recent years, highly ordered porous materials research field obtains development at full speed, and porous material has the specific surface of superelevation
Long-pending, uniform hole shape, aperture and uniform ordered arrangement makes it have good selection to the size and shape of molecule processed
Property, catalysis, separation, optics, nano material, micro element and in terms of show huge application potential.It will be orderly
The producing principle of porous material applies to the production of nylon hair above, by being modified to conventional polyester nylon hair surface, mentions
Its high superficial attractive forces, so that dramatically increasing it dips in powder effect.Adding nanometer calcium carbonate is a kind of preferred method, nano-calcium carbonate
Calcium is Current production maximum, and cheapest nano material adds polyester made of nanometer calcium carbonate, and toughness greatly increases,
Simultaneously after peracid treatment, surface property is also improved, and significantly increases the powder ability of dipping in of nylon hair.
Porous material can be rapidly completed absorption and desorption process, have not yet to see as efficient absorption and separation material
Porous material is used for the relevant report of cosmetic brush bristles.
Summary of the invention
In view of the defects existing in the prior art, it is an object of the present invention to provide a kind of preparation methods of nylon hair.This
Invention another object is that nylon hair of the invention is prepared into cosmetic brush bristles.
To achieve the goals above, the invention adopts the following technical scheme:
A kind of preparation method of nylon hair, comprising the following steps:
(1) by weight percentage, the polyester of 85-95% and the inorganic salts of 5-15% are weighed, is uniformly mixed；
(2) polyester and inorganic salt mixt are subjected to wire drawing；
(3) silk pulled out by step (2) is subjected to sour processing, obtains the nylon hair.
Preferably, the preparation method of the nylon hair, comprising the following steps:
(1) by weight percentage, 90% polyester and 10% inorganic salts are weighed, is uniformly mixed；
(2) polyester and inorganic salt mixt are subjected to wire drawing by wire drawing machine；
(3) sour processing will be carried out, the nylon hair is obtained after the silk shearing that step (2) pull out.
It is further preferred that the length of filament shearing is 40-100mm.
Preferably, the polyester is polyethylene terephthalate (PET), the poly terephthalic acid the third two that BASF produces
Alcohol ester (PTT or PPT) or polybutylene terephthalate (PBT) (PBT), the polyester can also be other kinds of polyester.
Preferably, the inorganic salts are one of calcium carbonate, magnesium carbonate and sodium carbonate or a variety of.
It is further preferred that the inorganic salts are calcium carbonate.
It is highly preferred that the inorganic salts are nanometer grade calcium carbonate.Preferably, the partial size of the nanometer grade calcium carbonate is
0.03um-1um.It is further preferred that the partial size of the nanometer grade calcium carbonate is 500nm.
It is further preferred that the shape of the nanometer calcium carbonate is hammer shape, cube, chain, aciculiform, spherical, silk cocoon shape.
It is highly preferred that the shape of the nanometer calcium carbonate is spherical.
Preferably, acid processing acid used is inorganic acid in step (3).
It is further preferred that the inorganic acid is one of sulfuric acid, phosphoric acid, hydrochloric acid and nitric acid or a variety of.
It is highly preferred that the sulfuric acid that the inorganic acid is 10%.
Preferably, the temperature of acid processing is 30-40 DEG C in step (3), time 8-15h.
A kind of cosmetic brush bristles are prepared by the nylon hair being prepared according to the above method.
Preferably, the cosmetic brush bristles preparation the following steps are included:
(1) nylon hair is cleaned；
(2) at 125-130 DEG C, after one end of nylon hair is carried out immersion treatment with fiber oxidation agent, when impregnating oxidation
Between according to hair peak length control, carry out sharpening, washing, drying to get.
It is further preferred that the fiber oxidation agent is industrial soda.
Beneficial effects of the present invention:
1, it is combined using inorganic salts and polyester, significantly increases the toughness of nylon hair；
2, common cosmetic brush on the market is the grip force between bristle to dip in powder, and in use, powder easily falls
It falls, causes to waste；And the cosmetic brush that surface treated nylon hair of the invention is prepared into has more advantage, cosmetic brush bristles table
EDS maps it is nanometer level microporous, to increase the adsorption capacity to powder, in use, avoid powder and fall, in turn
It saves with powder amount；
3, the micropore size on surface treated nylon hair of the invention surface is essentially identical, so that its dipped in powder is big
It is small uniformly not inhale extra powder liquid, more saving powder liquid；
4, size is dispersed on the cosmetic brush bristles surface being prepared into due to surface treated nylon hair of the invention
Uniform micropore, during dipping in powder, powder is attached on micropore, and then bristle is made uniformly to dip in powder, when embrocating skin surface,
It can be with more uniform upper powder.
Detailed description of the invention
Fig. 1 is the scanning electron microscope (SEM) photograph of commercially available nylon hair；
Fig. 2 is the scanning electron microscope (SEM) photograph of nylon hair of the present invention；
Fig. 3 is that nylon hair of the present invention dips in the flying-spot microscope figure after powder；
Fig. 4 is that commercially available nylon hair dips in the flying-spot microscope figure after powder.
Specific embodiment
Embodiment 1
A kind of preparation method of cosmetic brush bristles, comprising the following steps:
(1) to be in mass ratio that 10:1 is carried out for BASF PBT slice and spherical nanometer calcium carbonate uniformly mixed；It is described to receive
The partial size of rice calcium carbonate is 500nm；
(2) mixture of BASF PBT slice and nanometer calcium carbonate is subjected to wire drawing, wire-drawing temperature 250- by wire drawing machine
270℃；
(3) silk pulled out by step (2) is sheared according to 50mm, then under conditions of temperature is 35 DEG C,
After being impregnated 10 hours in 10% dilute sulfuric acid, cleans up, obtain nylon hair；
(4) under conditions of 125 DEG C, one end of nylon hair is immersed in 10h in cellulose oxidation agent, carries out sharpening, water
It washes, dry, obtain cosmetic brush bristles.
Embodiment 2
A kind of preparation method of cosmetic brush bristles, comprising the following steps:
(1) to be in mass ratio that 9:1 is carried out for BASF PBT slice and spherical nanometer calcium carbonate uniformly mixed；It is described to receive
The partial size of rice calcium carbonate is 500nm；
(2) mixture of BASF PBT slice and nanometer calcium carbonate is subjected to wire drawing, wire-drawing temperature 250- by wire drawing machine
270℃；
(3) silk pulled out by step (2) is sheared according to 40mm, then under conditions of temperature is 35 DEG C,
After being impregnated 10 hours in 10% dilute sulfuric acid, cleans up, obtain nylon hair；
(4) under conditions of temperature is 130 DEG C, one end of nylon hair is immersed in cellulose oxidation agent and impregnates 8h, into
Row sharpening, washing, drying, obtain cosmetic brush bristles.
Embodiment 3
A kind of preparation method of cosmetic brush bristles, comprising the following steps:
(1) to be in mass ratio that 17:3 is carried out for the BASF PBT nanometer calcium carbonate for being sliced and hammering into shape shape uniformly mixed；It is described to receive
The partial size of rice calcium carbonate is 500nm；
(2) mixture of BASF PBT slice and nanometer calcium carbonate is subjected to wire drawing, wire-drawing temperature 250- by wire drawing machine
270℃；
(3) silk pulled out by step (2) is sheared according to 55mm, then under conditions of temperature is 35 DEG C,
After being impregnated 10 hours in 10% dilute sulfuric acid, cleans up, obtain nylon hair；
(4) under conditions of temperature is 128 DEG C, one end of nylon hair is immersed in cellulose oxidation agent and impregnates 10h, into
Row sharpening, washing, drying, obtain cosmetic brush bristles.
Embodiment 4
A kind of preparation method of cosmetic brush bristles, comprising the following steps:
(1) to be in mass ratio that 9:1 is carried out for the nanometer calcium carbonate of BASF PBT slice and chain uniformly mixed；It is described to receive
The partial size of rice calcium carbonate is 500nm；
(2) mixture of BASF PBT slice and nanometer calcium carbonate is subjected to wire drawing, wire-drawing temperature 250- by wire drawing machine
270℃
(3) silk pulled out by step (2) is sheared according to 50mm, then under conditions of temperature is 35 DEG C,
After being impregnated 10 hours in 10% dilute sulfuric acid, cleans up, obtain nylon hair；
(4) under conditions of temperature is 128 DEG C, one end of nylon hair is immersed in cellulose oxidation agent and impregnates 8h, into
Row sharpening, washing, drying obtain nano-pearl cosmetic brush bristles.
Embodiment 5
A kind of preparation method of cosmetic brush bristles, comprising the following steps:
(1) to be in mass ratio that 9:1 is carried out for the nanometer calcium carbonate of BASF PBT slice and aciculiform uniformly mixed；It is described to receive
The partial size of rice calcium carbonate is 500nm；
(2) mixture of BASF PBT slice and nanometer calcium carbonate is subjected to wire drawing, wire-drawing temperature 250- by wire drawing machine
270℃；
(3) silk pulled out by step (2) is sheared according to 50mm, then under conditions of temperature is 35 DEG C,
After being impregnated 12 hours in 3.6% hydrochloric acid, cleans up, obtain nylon hair；
(4) under conditions of temperature is 128 DEG C, one end of nylon hair is immersed in cellulose oxidation agent and impregnates 8h, into
Row sharpening, washing, drying, obtain cosmetic brush bristles.
Performance test
Experimental example 1
By nylon hair made from embodiment 1 and commercially available nylon hair (hair products factory of Shenzhen Donggang City, model PBT monochrome ripple
Hair) it send to Heng Xin testing agency and is scanned Electronic Speculum detection, testing result is as depicted in figs. 1 and 2.
Nylon hair made from commercially available nylon hair and embodiment 1 is immersed in loose powder (brand PartyQueen article No. DY-
LP003 in), it is then transferred to microscope, by low power electron microscope observation, as a result as shown in Figure 3 and Figure 4.
The nylon hair of the commercially available nylon hair and embodiment 1 that take same size carries out dipping in powder aptitude tests, electronic analytical balance
Test (FA2004N, MAX=200g, d=0.1mg) its test result is for example shown in table 1,2 and 3.
Table 1 dips in powder aptitude tests result for the nylon hair of commercially available nylon hair and embodiment 1
Table 2 dips in powder aptitude tests result for the nylon hair of commercially available nylon hair and embodiment 2
Table 3 dips in powder aptitude tests result for the nylon hair of commercially available nylon hair and embodiment 1
Experimental example 2
The 1 nylon hair (0.07mm*55mm) of embodiment and common nylon hair (0.07mm*55mm) (the two of weight such as weigh
Ripple is small echo), be made into specification be overall length 11.5cm, staple length 3.5cm, the loose powder brush of the wide 4cm of hair, using subject face as
Experimental Area, carries out powder, and experimental result is shown in Table 4.
Table 4 is that loose powder made of commercially available nylon hair and the nylon hair of embodiment 1 paints powder result
Claims (10)
1. a kind of preparation method of nylon hair, which comprises the following steps:
(1) by weight percentage, the polyester of 85-95% and the inorganic salts of 5-15% are weighed, is mixed evenly；
(2) polyester and inorganic salt mixt are subjected to wire drawing；
(3) silk pulled out by step (2) is subjected to sour processing, obtains the nylon hair.
2. the preparation method of nylon hair according to claim 1, which is characterized in that the polyester is poly terephthalic acid second
Diol ester, polypropylene terephthalate or polybutylene terephthalate (PBT).
3. the preparation method of nylon hair according to claim 1, which is characterized in that the inorganic salts are calcium carbonate, carbonic acid
One of magnesium and sodium carbonate are a variety of.
4. the preparation method of nylon hair according to claim 3, which is characterized in that the inorganic salts are calcium carbonate, wherein
The calcium carbonate is nanometer grade calcium carbonate, partial size 0.03um-1um.
5. the preparation method of nylon hair according to claim 4, which is characterized in that the partial size of the nanometer grade calcium carbonate is
500nm。
6. the preparation method of nylon hair according to claim 1, which is characterized in that acid processing acid used in step (3)
For inorganic acid.
7. the preparation method of nylon hair according to claim 6, which is characterized in that the inorganic acid is sulfuric acid, phosphoric acid, salt
One of acid and nitric acid are a variety of.
8. the preparation method of nylon hair according to claim 1, which is characterized in that the temperature of acid processing is in step (3)
30-40 DEG C, the processing time is 8-15h.
9. a kind of cosmetic brush bristles, which is characterized in that the preparation of cosmetic brush bristles method as described according to claim 1-8
Obtained nylon hair is prepared.
10. the preparation method of cosmetic brush bristles according to claim 9, which comprises the following steps:
(1) nylon hair is cleaned；
(2) at 125-130 DEG C, after one end of nylon hair is carried out immersion treatment with fiber oxidation agent, oxidization time is according to hair
Peak length is controlled, by sharpening, washing, drying to get.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710571516.5A CN109252238A (en) | 2017-07-13 | 2017-07-13 | A kind of preparation method of nylon hair |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710571516.5A CN109252238A (en) | 2017-07-13 | 2017-07-13 | A kind of preparation method of nylon hair |
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| CN109252238A true CN109252238A (en) | 2019-01-22 |
Family
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| CN201710571516.5A Pending CN109252238A (en) | 2017-07-13 | 2017-07-13 | A kind of preparation method of nylon hair |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109837605A (en) * | 2019-01-30 | 2019-06-04 | 中国科学院长春应用化学研究所 | Compound brush filament of a kind of titania modified polyester nano of two-dimensional ultrathin and preparation method thereof |
| CN110055612A (en) * | 2019-03-22 | 2019-07-26 | 中山尚洋科技股份有限公司 | A kind of negative ion far-infrared antimicrobial nylon hair, cosmetic brush bristles and cosmetic brush |
| CN115644589A (en) * | 2022-10-10 | 2023-01-31 | 杭州伊珂包装科技有限公司 | Eraser brush head conforming to ergonomics and production process thereof |
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| JP2008136711A (en) * | 2006-12-04 | 2008-06-19 | Teijin Fibers Ltd | Polyester fiber used for brush or writing brush, and method of manufacturing the same |
| US20140331428A1 (en) * | 2011-02-16 | 2014-11-13 | Kenji Nakamura | Brush for powder cosmetics |
| CN105239201A (en) * | 2015-08-15 | 2016-01-13 | 陆思烨 | Toothbrush hair having anti-bacterial and health-caring function and preparation method thereof |
| CN105332089B (en) * | 2015-12-03 | 2017-06-13 | 苏州宝力塑胶材料有限公司 | The preparation method of moisture absorption sweat discharging functions polyester fiber |
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| CN2669689Y (en) * | 2003-12-03 | 2005-01-12 | 殷新中 | Sharp brush bristles |
| JP2008136711A (en) * | 2006-12-04 | 2008-06-19 | Teijin Fibers Ltd | Polyester fiber used for brush or writing brush, and method of manufacturing the same |
| US20140331428A1 (en) * | 2011-02-16 | 2014-11-13 | Kenji Nakamura | Brush for powder cosmetics |
| CN105239201A (en) * | 2015-08-15 | 2016-01-13 | 陆思烨 | Toothbrush hair having anti-bacterial and health-caring function and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109837605A (en) * | 2019-01-30 | 2019-06-04 | 中国科学院长春应用化学研究所 | Compound brush filament of a kind of titania modified polyester nano of two-dimensional ultrathin and preparation method thereof |
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| CN110055612A (en) * | 2019-03-22 | 2019-07-26 | 中山尚洋科技股份有限公司 | A kind of negative ion far-infrared antimicrobial nylon hair, cosmetic brush bristles and cosmetic brush |
| CN115644589A (en) * | 2022-10-10 | 2023-01-31 | 杭州伊珂包装科技有限公司 | Eraser brush head conforming to ergonomics and production process thereof |
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