CN109251772A - A kind of new energy environment Friendly fuel oil and preparation method thereof - Google Patents

A kind of new energy environment Friendly fuel oil and preparation method thereof Download PDF

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Publication number
CN109251772A
CN109251772A CN201811362311.7A CN201811362311A CN109251772A CN 109251772 A CN109251772 A CN 109251772A CN 201811362311 A CN201811362311 A CN 201811362311A CN 109251772 A CN109251772 A CN 109251772A
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parts
stirring
added
component raw
new energy
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苏兴州
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
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    • C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
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    • C10L1/1983—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyesters
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Abstract

The present invention relates to environmentally friendly field of new energy technologies, specifically disclose a kind of new energy environment Friendly fuel oil, it is mainly prepared by the component raw material of following parts by weight by certain production method steps: 5-45 parts of diesel oil, 5-25 parts of methanol, 5-30 parts of water, 0.1-0.5 parts of ricinoleic acid, 0.1-0.5 parts of castor oil, 1-3 parts of ethyl alcohol, 1-3 parts of isobutanol, 0.1-1 parts of n-butanol, 0.1-1 parts of butanone, 0.1-1 parts of acetone, 0.1-1 parts of n-hexane, 1-5 parts of petroleum ether, 1-5 parts of polymethoxy dimethyl ether, .1-2 parts of hydrogen peroxidase 10, 1-3 parts of butyl epoxy stearate, double alkyl phosphoric acid 1-3 parts, 0.1-1 parts of antioxidant BHT, 0.1-1 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, sorbester p17 0.05-5 Part, 0.03-3 parts of tween, 0.1-2 parts of fatty acid methyl ester, 0.1-5 parts of detergent, 0.1-5 parts of combustion adjuvant.This fuel oil has calorific value high, easily lights a fire, firepower is powerful, and pollutant emission is few, and small to air pollution, environment protecting is good.

Description

A kind of new energy environment Friendly fuel oil and preparation method thereof
Technical field
The present invention relates to environmentally friendly field of new energy technologies, in particular to a kind of new energy environment Friendly fuel oil and its preparation sides Method.
Background technique
Diesel oil is as a kind of important fuel, due to the advantages such as itself has power big, and price is low, it has also become large size is set Standby major impetus fuel.The diesel oil applied at present is mainly the petroleum diesel refined from petroleum, and petroleum diesel was being applied Relative to other fuel, that there is combustibilities is low in journey, when burning in vehicle internal combustion engine, quickly due to piston motion, burning Time is very short, atomization badness, and for hypoxgia, anoxycausis causes to burn insufficient, and fuel does not allow easy firing complete, titanium dioxide Carbon emission amount is bigger；Because of incomplete combustion, pollutant load in burning waste gas is caused to increase, harmful components increase, dust-laden Grain object increases, and forms Vehicular exhaust discharge beyond standards；Because of incomplete combustion, contain heavy metallic oxide, more after burning in flue gas The poisonous and harmful elements such as cyclophane hydrocarbon oxide, polychlorinated biphenyl, dioxa glutinous rehmannia, these poisonous and harmful elements are all to life Object and human health are harmful；Because of incomplete combustion, it is easy to produce smoke particle, energy of oxidation at a lower temperature generates organic Acid, sediment, peroxide and hydroperoxides, these sediments can generate low temperature greasy filth together with water, oil, smoke particle, have Machine acid can corrode rapidly the metal in engine, especially bearing metal under the collective effect of hydroperoxides；So necessary The road of clean burn is walked, because these poisonous and harmful elements compare difficult to burn, it is quite tired for reaching clean burn Difficult, only to the modified upgrading of fuel oil, makes combustible component full combustion by increasing the oxygen content in fuel oil, adjust burning Performance can be only achieved clean burn, and Vehicular exhaust qualified discharge reduces pollutant emission, improves air quality, improve ecology Environment.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the above technological deficiency, provide a kind of new energy environment Friendly fuel oil and its Preparation method can effectively increase the contact surface of fuel oil and air, make fuel oil full combustion, reduce pollutant emission.
In order to achieve the above object of the invention, the technical solution adopted by the present invention are as follows: a kind of new energy environment Friendly fuel oil, mainly By the component raw material of following parts by weight, it is prepared by certain production method steps: 5-45 parts of diesel oil, 5-25 parts of methanol, water 5-30 parts, 0.1-0.5 parts of ricinoleic acid, 0.1-0.5 parts of castor oil, 1-3 parts of ethyl alcohol, 1-3 parts of isobutanol, 0.1-1 parts of n-butanol, 0.1-1 parts of butanone, 0.1-1 parts of acetone, 0.1-1 parts of n-hexane, 1-5 parts of petroleum ether, 1-5 parts of polymethoxy dimethyl ether, peroxidating 0.1-2 parts of hydrogen, 1-3 parts of butyl epoxy stearate, double alkyl phosphoric acid 1-3 parts, 0.1-1 parts of antioxidant BHT, fatty alcohol polyoxy second 0.1-1 parts of alkene ether sodium sulfate, 0.05-5 parts of sorbester p17,0.03-3 parts of tween, 0.1-2 parts of fatty acid methyl ester, detergent 0.1-5 Part, 0.1-5 parts of combustion adjuvant, the detergent is made of barium mahogany sulfonate, ethylene glycol alkyl phenylate, and the combustion adjuvant is by more Ethylene polyamine hydramine, Di Iso Propyl Ether, mixing light aromatic hydrocarbons composition.
Further, a kind of new energy environment Friendly fuel oil mainly presses certain production by the component raw material of following parts by weight Method and step is prepared: 40 parts of diesel oil, 20 parts of methanol, and 20 parts of water, 0.2 part of ricinoleic acid, 0.3 part of castor oil, 2 parts of ethyl alcohol, 1.5 parts of isobutanol, 0.5 part of n-butanol, 0.5 part of butanone, 0.5 part of acetone, 0.5 part of n-hexane, 2 parts of petroleum ether, polymethoxy two 2 parts of methyl ether, 1 part of hydrogen peroxide, 1.5 parts of butyl epoxy stearate, 1.5 parts of double alkyl phosphoric acids, 0.5 part of antioxidant BHT, fat 0.5 part of alcohol polyethenoxy ether sodium sulfate, 1 part of sorbester p17,1 part of tween, 1 part of fatty acid methyl ester, 1 part of detergent, 1 part of combustion adjuvant.
Further, the combustion adjuvant is by polyethylene polyamine hydramine: Di Iso Propyl Ether: mixing light aromatic hydrocarbons=2:3:5 matter Amount proportion composition.
Further, the detergent is by barium mahogany sulfonate: ethylene glycol alkyl phenylate=1:1 quality proportioning forms.
Further, a kind of preparation method of new energy environment Friendly fuel oil the following steps are included:
(1) it is spare that various component raw materials are measured respectively according to the above ratio；
(2) first diesel oil is preheated, heating and temperature control is pumped into normal temperature and pressure agitator tank between 50 DEG C to 90 DEG C；
(3) component raw material is added in turn on agitator while stirring, is sequentially added into water, butyl epoxy stearate, double alkyl Phosphoric acid, fatty acid methyl ester, methanol continue stirring 10 minutes after adding；
(4) blender continues in stirring, and component raw material is added while stirring, then be sequentially added into castor oil, ricinoleic acid, Ethyl alcohol, isobutanol, n-butanol, sorbester p17 continue stirring 10 minutes after adding；
(5) blender continues in stirring, and component raw material is added while stirring, then be sequentially added into polymethoxy dimethyl ether, Petroleum ether, butanone, acetone continue stirring 10 minutes after adding；
(6) blender continues in stirring, and component raw material is added while stirring, then is sequentially added into n-hexane, detergent, spits Temperature continues stirring 10 minutes after adding；
(7) blender continues in stirring, and component raw material is added while stirring, then is sequentially added into hydrogen peroxide, antioxidant BHT continues stirring 10 minutes after adding；
(8) with static mixer circulation mixing 30 minutes, sodium sulfate of polyethenoxy ether of fatty alcohol is added, is uniformly mixed After be added combustion adjuvant, stand 30 minutes, be a kind of new energy environment Friendly fuel oil after filtering.
The invention has the benefit that this fuel oil has calorific value high, easily light a fire, firepower is powerful；Sulfur-bearing is low, not easily generated to have Machine acid, greasy filth, it is small to internal combustion engine corrosion, internal combustion engine service life can be extended；Oxydant is high, easily formation oxygen-enriched combusting, improves Efficiency of combustion；Viscosity is low, good fluidity, is easily atomized, and atomizing particle is tiny, and atomization is good, and burning sufficiently, is not easy coking, dust stratification It is few, carbon deposit and abrasion are reduced, burner is not easy to plug；Burning completely, easily forms clean burn, the heavy metal oxidation in flue gas Object, polycyclic aromatic hydrocarbon oxide, polychlorinated biphenyl, dioxa glutinous rehmannia poisonous and harmful element are substantially reduced, and pollutant emission is few, Small to air pollution, environment protecting is good.
Specific embodiment
Embodiment 1
A kind of new energy environment Friendly fuel oil mainly presses certain production method steps system by the component raw material of following parts by weight It is standby to form: 40 parts of diesel oil, 20 parts of methanol, 20 parts of water, 0.2 part of ricinoleic acid, 0.3 part of castor oil, 2 parts of ethyl alcohol, isobutanol 1.5 Part, 0.5 part of n-butanol, 0.5 part of butanone, 0.5 part of acetone, 0.5 part of n-hexane, 2 parts of petroleum ether, 2 parts of polymethoxy dimethyl ether, mistake 1 part of hydrogen oxide, 1.5 parts of butyl epoxy stearate, 1.5 parts of double alkyl phosphoric acids, 0.5 part of antioxidant BHT, aliphatic alcohol polyethenoxy 0.5 part of ether sodium sulfate, 1 part of sorbester p17,1 part of tween, 1 part of fatty acid methyl ester, 1 part of detergent, 1 part of combustion adjuvant, described is combustion-supporting Agent is by polyethylene polyamine hydramine: Di Iso Propyl Ether: mixing light aromatic hydrocarbons=2:3:5 quality proportioning forms, and the detergent is by stone Oily barium sulfonate: ethylene glycol alkyl phenylate=1:1 quality proportioning composition.
Preparation method the following steps are included:
(1) it is spare that various component raw materials are measured respectively according to the above ratio；
(2) first diesel oil is preheated, heating and temperature control is pumped into normal temperature and pressure agitator tank between 50 DEG C to 90 DEG C；
(3) component raw material is added in turn on agitator while stirring, is sequentially added into water, butyl epoxy stearate, double alkyl Phosphoric acid, fatty acid methyl ester, methanol continue stirring 10 minutes after adding；
(4) blender continues in stirring, and component raw material is added while stirring, then be sequentially added into castor oil, ricinoleic acid, Ethyl alcohol, isobutanol, n-butanol, sorbester p17 continue stirring 10 minutes after adding；
(5) blender continues in stirring, and component raw material is added while stirring, then be sequentially added into polymethoxy dimethyl ether, Petroleum ether, butanone, acetone continue stirring 10 minutes after adding；
(6) blender continues in stirring, and component raw material is added while stirring, then is sequentially added into n-hexane, detergent, spits Temperature continues stirring 10 minutes after adding；
(7) blender continues in stirring, and component raw material is added while stirring, then is sequentially added into hydrogen peroxide, antioxidant BHT continues stirring 10 minutes after adding；
(8) with static mixer circulation mixing 30 minutes, sodium sulfate of polyethenoxy ether of fatty alcohol is added, is uniformly mixed After be added combustion adjuvant, stand 30 minutes, be a kind of new energy environment Friendly fuel oil after filtering.
Embodiment 2
A kind of new energy environment Friendly fuel oil mainly presses certain production method steps system by the component raw material of following parts by weight It is standby to form: 37 parts of diesel oil, 25 parts of methanol, 30 parts of water, 0.2 part of ricinoleic acid, 0.2 part of castor oil, 1 part of ethyl alcohol, 1 part of isobutanol, 0.2 part of n-butanol, 0.1 part of butanone, 0.1 part of acetone, 0.1 part of n-hexane, 1 part of petroleum ether, 1 part of polymethoxy dimethyl ether, peroxide 0.1 part of hydrogen of change, 1 part of butyl epoxy stearate, 1 part of double alkyl phosphoric acids, 0.2 part of antioxidant BHT, fatty alcohol polyoxyethylene ether sulphur 0.2 part of sour sodium, it is 0.1 part of sorbester p17,0.1 part of tween, 0.2 part of fatty acid methyl ester, 0.1 part of detergent, 0.1 part of combustion adjuvant, described Combustion adjuvant by polyethylene polyamine hydramine: Di Iso Propyl Ether: mixing light aromatic hydrocarbons=2:3:5 quality proportioning form, the cleaning Agent is by barium mahogany sulfonate: ethylene glycol alkyl phenylate=1:1 quality proportioning forms.
Preparation method the following steps are included:
(1) it is spare that various component raw materials are measured respectively according to the above ratio；
(2) first diesel oil is preheated, heating and temperature control is pumped into normal temperature and pressure agitator tank between 50 DEG C to 90 DEG C；
(3) component raw material is added in turn on agitator while stirring, is sequentially added into water, butyl epoxy stearate, double alkyl Phosphoric acid, fatty acid methyl ester, methanol continue stirring 10 minutes after adding；
(4) blender continues in stirring, and component raw material is added while stirring, then be sequentially added into castor oil, ricinoleic acid, Ethyl alcohol, isobutanol, n-butanol, sorbester p17 continue stirring 10 minutes after adding；
(5) blender continues in stirring, and component raw material is added while stirring, then be sequentially added into polymethoxy dimethyl ether, Petroleum ether, butanone, acetone continue stirring 10 minutes after adding；
(6) blender continues in stirring, and component raw material is added while stirring, then is sequentially added into n-hexane, detergent, spits Temperature continues stirring 10 minutes after adding；
(7) blender continues in stirring, and component raw material is added while stirring, then is sequentially added into hydrogen peroxide, antioxidant BHT continues stirring 10 minutes after adding；
(8) with static mixer circulation mixing 30 minutes, sodium sulfate of polyethenoxy ether of fatty alcohol is added, is uniformly mixed After be added combustion adjuvant, stand 30 minutes, be a kind of new energy environment Friendly fuel oil after filtering.
Embodiment 3
A kind of new energy environment Friendly fuel oil, mainly by the component raw material of following parts by weight, by certain production method steps It is prepared: 33 parts of diesel oil, 20 parts of methanol, 10 parts of water, 0.5 part of ricinoleic acid, 0.5 part of castor oil, 3 parts of ethyl alcohol, isobutanol 3 Part, 1 part of n-butanol, 1 part of butanone, 1 part of acetone, 1 part of n-hexane, 2 parts of petroleum ether, 2 parts of polymethoxy dimethyl ether, hydrogen peroxide 2 Part, 3 parts of butyl epoxy stearate, 3 parts of double alkyl phosphoric acids, 1 part of antioxidant BHT, 1 part of sodium sulfate of polyethenoxy ether of fatty alcohol, department 80 2 parts of disk, 2 parts of tween, 2 parts of fatty acid methyl ester, 3 parts of detergent, 3 parts of combustion adjuvant, the combustion adjuvant is by polyethylene polyamine alcohol Amine: Di Iso Propyl Ether: mixing light aromatic hydrocarbons=2:3:5 quality proportioning composition, the detergent is by barium mahogany sulfonate: ethylene glycol alkane Base phenylate=1:1 quality proportioning composition.
Preparation method the following steps are included:
(1) it is spare that various component raw materials are measured respectively according to the above ratio；
(2) first diesel oil is preheated, heating and temperature control is pumped into normal temperature and pressure agitator tank between 50 DEG C to 90 DEG C；
(3) component raw material is added in turn on agitator while stirring, is sequentially added into water, butyl epoxy stearate, double alkyl Phosphoric acid, fatty acid methyl ester, methanol continue stirring 10 minutes after adding；
(4) blender continues in stirring, and component raw material is added while stirring, then be sequentially added into castor oil, ricinoleic acid, Ethyl alcohol, isobutanol, n-butanol, sorbester p17 continue stirring 10 minutes after adding；
(5) blender continues in stirring, and component raw material is added while stirring, then be sequentially added into polymethoxy dimethyl ether, Petroleum ether, butanone, acetone continue stirring 10 minutes after adding；
(6) blender continues in stirring, and component raw material is added while stirring, then is sequentially added into n-hexane, detergent, spits Temperature continues stirring 10 minutes after adding；
(7) blender continues in stirring, and component raw material is added while stirring, then is sequentially added into hydrogen peroxide, antioxidant BHT continues stirring 10 minutes after adding；
(8) with static mixer circulation mixing 30 minutes, sodium sulfate of polyethenoxy ether of fatty alcohol is added, is uniformly mixed After be added combustion adjuvant, stand 30 minutes, be a kind of new energy environment Friendly fuel oil after filtering.
The present invention and its embodiments have been described above, this description is not restricted.All in all if originally The those of ordinary skill in field is enlightened by it, without departing from the spirit of the invention, is not inventively designed Embodiment similar with the technical solution, is within the scope of protection of the invention.

Claims (5)

1. a kind of new energy environment Friendly fuel oil, which is characterized in that mainly press certain production by the component raw material of following parts by weight Method and step is prepared: 5-45 parts of diesel oil, 5-25 parts of methanol, and 5-30 parts of water, 0.1-0.5 parts of ricinoleic acid, castor oil 0.1- 0.5 part, 1-3 parts of ethyl alcohol, 1-3 parts of isobutanol, 0.1-1 parts of n-butanol, 0.1-1 parts of butanone, 0.1-1 parts of acetone, n-hexane 0.1-1 Part, 1-5 parts of petroleum ether, 1-5 parts of polymethoxy dimethyl ether .1-2 parts of hydrogen peroxidase 10,1-3 parts of butyl epoxy stearate, double alkyl It -3 parts of phosphatase 11,0.1-1 parts of antioxidant BHT, 0.1-1 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 0.05-5 parts of sorbester p17, spits It is 0.03-3 parts warm, 0.1-2 parts of fatty acid methyl ester, 0.1-5 parts of detergent, 0.1-5 parts of combustion adjuvant；
The detergent is made of barium mahogany sulfonate, ethylene glycol alkyl phenylate, the combustion adjuvant by polyethylene polyamine hydramine, Di Iso Propyl Ether, mixing light aromatic hydrocarbons composition.
2. a kind of new energy environment Friendly fuel oil according to claim 1, it is characterised in that: mainly by following weight percent Component raw material, be prepared by certain production method steps: 40 parts of diesel oil, 20 parts of methanol, 20 parts of water, ricinoleic acid 0.2 Part, 0.3 part of castor oil, 2 parts of ethyl alcohol, 1.5 parts of isobutanol, 0.5 part of n-butanol, 0.5 part of butanone, 0.5 part of acetone, n-hexane 0.5 Part, 2 parts of petroleum ether, 2 parts of polymethoxy dimethyl ether, 1 part of hydrogen peroxide, 1.5 parts of butyl epoxy stearate, double alkyl phosphoric acids 1.5 Part, 0.5 part of antioxidant BHT, 0.5 part of sodium sulfate of polyethenoxy ether of fatty alcohol, 1 part of sorbester p17,1 part of tween, fatty acid methyl ester 1 Part, 1 part of detergent, 1 part of combustion adjuvant.
3. a kind of new energy environment Friendly fuel oil according to claim 1, it is characterised in that: the combustion adjuvant is by more ethylene Polyamines hydramine: Di Iso Propyl Ether: mixing light aromatic hydrocarbons=2:3:5 quality proportioning composition.
4. a kind of new energy environment Friendly fuel oil according to claim 1, it is characterised in that: the detergent is by petroleum sulphur Sour barium: ethylene glycol alkyl phenylate=1:1 quality proportioning composition.
5. a kind of new energy environment Friendly fuel oil preparation method according to claim 1, it is characterised in that: including following step It is rapid:
(1) it is spare that various component raw materials are measured respectively according to the above ratio；
(2) first diesel oil is preheated, heating and temperature control is pumped into normal temperature and pressure agitator tank between 50 DEG C to 90 DEG C；
(3) component raw material is added in turn on agitator while stirring, is sequentially added into water, butyl epoxy stearate, double alkyl phosphorus Acid, fatty acid methyl ester, methanol continue stirring 10 minutes after adding；
(4) blender continues in stirring, and component raw material is added while stirring, then is sequentially added into castor oil, ricinoleic acid, second Alcohol, isobutanol, n-butanol, sorbester p17 continue stirring 10 minutes after adding；
(5) blender continues in stirring, and component raw material is added while stirring, then is sequentially added into polymethoxy dimethyl ether, petroleum Ether, butanone, acetone continue stirring 10 minutes after adding；
(6) blender continues in stirring, and component raw material is added while stirring, then is sequentially added into n-hexane, detergent, tween, Continue stirring 10 minutes after adding；
(7) blender continues in stirring, and component raw material is added while stirring, then is sequentially added into hydrogen peroxide, antioxidant BHT, Continue stirring 10 minutes after adding；
(8) with static mixer circulation mixing 30 minutes, sodium sulfate of polyethenoxy ether of fatty alcohol is added, adds after being uniformly mixed Enter combustion adjuvant, stand 30 minutes, is a kind of new energy environment Friendly fuel oil after filtering.
CN201811362311.7A 2018-11-15 2018-11-15 A kind of new energy environment Friendly fuel oil and preparation method thereof Withdrawn CN109251772A (en)

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