CN109251501A - A kind of high heat resistance thin-walled flame retardant polycarbonate composition - Google Patents
A kind of high heat resistance thin-walled flame retardant polycarbonate composition Download PDFInfo
- Publication number
- CN109251501A CN109251501A CN201810828647.1A CN201810828647A CN109251501A CN 109251501 A CN109251501 A CN 109251501A CN 201810828647 A CN201810828647 A CN 201810828647A CN 109251501 A CN109251501 A CN 109251501A
- Authority
- CN
- China
- Prior art keywords
- flame retardant
- heat resistance
- high heat
- resistance thin
- fire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention provides a kind of high heat resistance thin-walled flame retardant polycarbonate compositions, the composition is by including that the raw material of following parts by weight is made: 96.0-99.8 parts of polycarbonate resin, 0.1-5.0 parts of toughener, 0.01-3.0 parts of fire retardant, 0.1-8.0 parts of fire retarding synergist, 0.01-2.0 parts of antioxidant, 0.01-0.8 parts of auxiliary agent；The polycarbonate resin is at least one of the aromatic copolycarbonate of viscosity average molecular weigh 10000-40000.High heat resistance thin-walled flame retardant polycarbonate composition of the present invention selects the fire retardant for not influencing polycarbonate heat resisting temperature, the addition of fire retarding synergist, promote flame retardant property greatly, addition toughener can not only supplement composition toughness and reduce influence to flame retardant property to the greatest extent.
Description
Technical field
The invention belongs to engineering plastics technical fields, combine more particularly, to a kind of high heat resistance thin-walled fire-retardant polycarbonate
Object.
Background technique
Polycarbonate resin (PC) is a kind of general engineering plastic, has the transparency, impact resistance, heat resistance, size steady
The advantages of various aspects such as qualitative, and due to its above-mentioned excellent characteristic, industrially it is widely used as automotive field, printer
Electrical, electronic field the material such as equal office equipment field, mobile phone.For current production is minimized, lightweight, height
The characteristics of purpose of functionalization etc., above-mentioned product are thinning year by year, this just proposes high fluidity to material, even if
Be thinning in light-weighted formed body, people also or seeking to have the mechanical properties such as sufficient impact resistance good and
The resin material of good appearance.
In addition many application fields, fire block articles, it is heat-resisting be the market demand developing direction, PC often uses organic phosphate flame-retardant
Agent have many advantages, such as environmental protection, it is fire-retardant efficient, but its addition usually to PC generate plasticization, influence the toughness of PC resin
And heat resistance.Therefore, the application of aromatic phosphate acid ester flame retardant is greatly limited.
PC is often used in fire retardant, diphenyl sulfone metal organic sulfonate (KSS) and potassium perfluorobutane sulfonate (PPFBS)
It is the fire retardant of mainstream.The fire retardant of metal organic sulfonate class can be good compared with thick product (thickness >=3.2mm) acquirement
Flame retardant effect, but when being applied to compared with thin article (1.6mm≤thickness < 3.2mm), since metal organic sulfonate fire retardant adds
Dosage is usually smaller (≤1), it is more difficult to which the factors such as uniformly mixed influence, and the meeting of metal organic sulfonate fire retardant is it is difficult to ensure that compare
Stable flame retardant effect.Both fire retardants can satisfy heat-resisting requirement, but not be able to satisfy the fire-retardant demand of thin-walled.Cause
This, the application of above two fire retardant is greatly limited.
Summary of the invention
In view of this, the present invention is directed to propose a kind of high heat resistance thin-walled flame retardant polycarbonate composition, has preferable resistance
Fire performance and toughness.
In order to achieve the above objectives, the technical scheme of the present invention is realized as follows:
A kind of high heat resistance thin-walled flame retardant polycarbonate composition, it is characterised in that: the composition is by including following parts by weight
Raw material be made:
The polycarbonate resin is at least one in the aromatic copolycarbonate of viscosity average molecular weigh 10000-40000
Kind.
Preferably, the composition is by including that the raw material of following parts by weight is made:
The polycarbonate resin is at least one in the aromatic copolycarbonate of viscosity average molecular weigh 10000-40000
Kind.
The polycarbonate resin refers to that aromatic hydroxy compound reacts or aromatic series with phosgene or carbonic diester
The Thermoplastic aromatic with branch that hydroxy compounds and a small amount of polyol are reacted with phosgene or carbonic diester
Adoption carbonate polymer or copolymer.The manufacturing method of above-mentioned aromatic polycarbonate resin is not particularly limited, and can be used
Currently known technical method, such as phosgenation (interfacial polymerization), fusion method (ester-interchange method).
Further, the toughener is Methyl Methacrylate-Butadiene-Styrene Copolymer, methyl methacrylate
Ester-acrylic copolymer, ethylene-methyl acrylate copolymer, ethylene-butyl acrylate copolymer, ethylene-acrylate-first
Base glycidyl acrylate terpolymer, the ethylene-vinyl acetate copolymer of maleic anhydride functional, acrylic compounds increase
At least one of tough dose or organic silicon rubber graft toughener；Preferably, the toughener is organic silicon rubber grafting
Object toughener, the volume average particle size of the rubber constituent in the organic silicon rubber graft toughener are 400-800nm.
The toughener refers to containing polysiloxane and ethene polymers rubber and grafting vinyl monomer
Copolymer, wherein in the toughener rubber constituent volume average particle size be 200-2000nm, preferably 220-1500nm, more
Preferably 280-1000nm, further preferably 350-800nm.By making the volume average particle size of rubber constituent in 350-
Within the scope of 800nm, preferable impact resistance can be obtained and influence small resin combination to fire-retardant.The volume of rubber constituent is flat
If equal partial size is in 350nm or more, it is preferred that the impact resistance of resin combination, which becomes well,；And the volume of rubber constituent
If average grain diameter is in 600nm hereinafter, the influence to resin combination flame retardant property is smaller.
Further, the fire retardant is halogen based flame retardant, phosphorus flame retardant, type siloxane fire retardant, metallic salt
One of fire retardant or boryl fire retardant；Preferably, the fire retardant is metallic salt fire retardant；Preferably, described
Metallic salt fire retardant is metal organic sulfonate；Preferably, the metal organic sulfonate is organic metal potassium sulfonate
Salt；Preferably, the metal in the metallic salt fire retardant is one of alkali or alkaline earth metal；The alkali gold
Belong to for one kind of caesium, lithium, sodium, potassium or middle rubidium；Preferably, the alkali metal is one of sodium, potassium or caesium；The alkali
Earth metal is one of barium, magnesium or calcium.
From the aspect of anti-flammability and hydrolytic resistance, preferred potassium.
This kind of fire retardant is applied to can not to affect the mechanical properties while providing fire-retardant in resin and heat resisting temperature.
The fire retardant is preferably metal organic sulfonate fire retardant；The metal organic sulfonate fire retardant
The formation that can promote polycarbonate resin carburization zone during burning is introduced, thus the fire-retardant of polycarbonate can be improved well
Property, it can be with the excellent horizontal property for maintaining polycarbonate to possess, such as electrical properties, heat resistance, impact resistance.
Metal in metal organic sulfonate is not particularly limited, preferably metal such as sodium, lithium, potassium or caesium or alkaline earth gold
Belong to such as beryllium, magnesium, calcium, strontium or barium.But from the aspect of anti-flammability and hydrolytic resistance, preferred potassium.
The metal organic sulfonate is the metal of the metal salt of fluorine-containing aliphatic sulfonic, fluorine-containing aromatic sulphonimides
One of salt, the metal salt of aromatic sulfonic acid or metal salt of aromatic sulfonamides；Preferably, the metal organic sulfonate
For the metal salt of fluorine-containing aliphatic sulfonic or metal salt (such as the diphenyl sulfone metal organic sulfonate, full phenyl fourth of aromatic sulfonic acid
One of alkyl sulfonic acid potassium)；Preferably, the metal organic sulfonate is the metal salt of fluorine-containing aliphatic sulfonic.
The metal salt of the fluorine-containing aliphatic sulfonic includes: the fluorine-containing aliphatic sulfonic in molecule comprising at least one C-F key
Alkali metal salt；The metal salt of the fluorine-containing aliphatic sulfonic is potassium perfluorobutane sulfonate, lithium perfluorobutane, perfluor
Butane conversion caesium, trifluoromethayl sulfonic acid lithium, trifluoromethayl sulfonic acid sodium, trifluoromethayl sulfonic acid potassium, pentafluoroethane potassium sulfonate, seven fluorine
One of propane sulfonic acid potassium or ten fluoro- 4- (pentafluoroethyl group) cyclohexanesulfonic potassium；Preferably, the fluorine-containing aliphatic sulphur
The metal salt of acid is potassium perfluorobutane sulfonate.
Further, the fire retarding synergist is one of calcium carbonate, talcum powder, mica or wollastonite；Preferably,
The fire retarding synergist is wollastonite；The partial size of the wollastonite is 100-500nm.
The wollastonite while fire-retardant synergistic is provided can the minimal mechanical property etc. to polycarbonate cause shadow
It rings.
Further, the polycarbonate resin is in the aromatic copolycarbonate of viscosity average molecular weigh 12000-30000
It is at least one.
Preferably, the polycarbonate resin is in the aromatic copolycarbonate of viscosity average molecular weigh 12000-25000
It is at least one.
By the way that viscosity average molecular weigh is set as in aforementioned range, it is ensured that poly carbonate resin composition of the invention
Mechanical strength, in the purposes high for requirement of mechanical strength be it is furthermore preferred that in addition certifiable shaping thin wall when high stream
Dynamic property.
Further, the antioxidant is made of quality proportioning for the primary antioxidant and auxiliary anti-oxidant of 1:(0.5-1).
The primary antioxidant and auxiliary anti-oxidant includes the antioxidant of following types: acrylic ester kind antioxidant may include
But it is not limited to octadecyl -3- (3,5- di-t-butyl -4- hydroxy phenyl) propionic ester；Phosphite ester antioxidant can wrap
Include but be not limited to three (nonyl phenyl) phosphite esters, bis- (2,4- di-tert-butyl-phenyl) pentaerythritol diphosphites, distearyl
Base pentaerythritol diphosphites；The alkylated reaction product of alkylated monophenols or polyphenols, polyphenol and diene, such as four is [sub-
Methyl (3,5- di-t-butyl -4- hydroxy hydrocinnamate)] methane, paracresol or bicyclopentadiene butylated reaction
Product；Alkylated hydroquinone；Hydroxylated thiodiphenyl ethers；Alkylidenebisphenols；Benzyl compounds；β-(bis--uncle of 3,5-
Butyl -4- hydroxy phenyl)-propionic acid and unitary or polyalcohol ester；β-(5- tertiary butyl-4-hydroxy -3- aminomethyl phenyl)-propionic acid
With the ester of unitary or polyalcohol；The ester of alkylthio or thioaryl compounds, such as distearyl thiopropionate, two laurels
Base thiopropionate, tricosyl thiodipropionate, [3- (the 3,5- di-t-butyl 4- hydroxy benzenes of pentaerythrite base-four
Base) propionic ester；The amide of β-(3,5- di-t-butyl -4- hydroxy phenyl)-propionic acid, or including at least one in above-mentioned antioxidant
The combination of kind.
It further, include lubricant in the auxiliary agent.
The auxiliary agent, which can according to need, to be properly added, such as may include lubricant, anti-dripping agent, is made in the present invention
Lubricant selects tristerin, and anti-dripping agent selects the PTFE of AS cladding lid.
Preferably, the composition is by including that the raw material of following parts by weight is made:
Wherein the quality proportioning of primary antioxidant Chinox1076 and auxiliary anti-oxidant THANOX 168 are 1.0:(0.5-1.0).
The preparation method of the high heat resistance thin-walled flame retardant polycarbonate composition, includes the following steps:
It (1), will be upper after weighing polycarbonate resin, toughener, fire retardant, fire retarding synergist, antioxidant and auxiliary agent respectively
State raw material successively put into mixing machine be blended into uniformly, obtain pre-composition；
(2) it will be prepared in step (1) in resulting pre-composition investment double screw extruder, the double screw extruder
Screw slenderness ratio is 40-45:1, and barrel temperature is 250-280 DEG C, and screw speed 400-500rpm, the pre-composition is at this
Melting mixing and extruding pelletization, are made the high heat resistance thin-walled flame retardant polycarbonate composition in double screw extruder.
Compared with the existing technology, high heat resistance thin-walled flame retardant polycarbonate composition of the present invention has the advantage that
(1) high heat resistance thin-walled flame retardant polycarbonate composition selection of the present invention does not influence the heat-resisting temperature of polycarbonate
The fire retardant of degree, the addition of fire retarding synergist, promotes flame retardant property greatly, and addition toughener can not only supplement composition
Toughness and reduce influence to flame retardant property to the greatest extent.
(2) high heat resistance thin-walled flame retardant polycarbonate composition of the present invention has preferable flame retardant property and toughness,
And heat resisting temperature is higher than 120 DEG C, and relatively high occasion is required especially suitable for use environment.
Specific embodiment
In addition to being defined, technical term used in following embodiment has general with those skilled in the art of the invention
All over the identical meanings understood.Test reagent used in following embodiment is unless otherwise specified conventional biochemical reagent；Institute
Experimental method is stated, is conventional method unless otherwise specified.
Polycarbonate resin in the embodiment of the present invention: viscosity average molecular weigh 20000, trade mark S-3000F, producer: Japan
Mitsubishi；
Toughener in the embodiment of the present invention: SX-005, producer: the beautiful sun of Mitsubishi；
Other toughener in the embodiment of the present invention: S-2001: producer: Mitsubishi；
Fire retardant in the embodiment of the present invention: EF-42, producer: Mitsubishi；
Synergistic flame retardant in the embodiment of the present invention: WFB15, producer: Hubei Feng Jiashan silicon is fine；
Primary antioxidant in the embodiment of the present invention: Chinox1076；Producer: TaiWan, China double bond chemical industry；
Auxiliary antioxidant in the embodiment of the present invention: THANOX 168；Producer: Tianjin Li Anlong；
Lubricant in the embodiment of the present invention: UNISTER-M9676, producer: Japan Oil Co；
Anti-dripping agent in the embodiment of the present invention: A3800, producer: Mitsubishi；
Below with reference to embodiment, the present invention will be described in detail.
Embodiment 1
A kind of high heat resistance thin-walled flame retardant polycarbonate composition, the composition is by including that the raw material of following parts by weight is made:
97.19 parts of polycarbonate resin S-3000F, 1.0 parts of toughener SX-005,0.06 part of fire retardant EF42, fire retarding synergist
1.0 parts of WFB15,0.1 part of primary antioxidant, 0.05 part of auxiliary anti-oxidant, 0.2 part of lubricant, 0.4 part of anti-dripping agent.
The preparation method of the high heat resistance thin-walled flame retardant polycarbonate composition, includes the following steps:
It (1), will be upper after weighing polycarbonate resin, toughener, fire retardant, fire retarding synergist, antioxidant and auxiliary agent respectively
State raw material successively put into mixing machine be blended into uniformly, obtain pre-composition；
(2) it will be prepared in step (1) in resulting pre-composition investment double screw extruder, the double screw extruder
Screw slenderness ratio is 40:1, and barrel temperature is 260-280 DEG C, and screw speed 400-500rpm, the pre-composition is in double spiral shells
Melting mixing and extruding pelletization, are made the high heat resistance thin-walled flame retardant polycarbonate composition in bar extruder.
Embodiment 2
A kind of high heat resistance thin-walled flame retardant polycarbonate composition, the composition is by including that the raw material of following parts by weight is made:
97.59 parts of polycarbonate resin S-3000F, 0.6 part of toughener SX-005,0.06 part of fire retardant EF42, fire retarding synergist
1.0 parts of WFB15,0.1 part of primary antioxidant, 0.05 part of auxiliary anti-oxidant, 0.2 part of lubricant, 0.4 part of anti-dripping agent.
The preparation method is the same as that of Example 1 for the high heat resistance thin-walled flame retardant polycarbonate composition.
Embodiment 3
A kind of high heat resistance thin-walled flame retardant polycarbonate composition, the composition is by including that the raw material of following parts by weight is made:
97.15 parts of polycarbonate resin S-3000F, 1.0 parts of toughener SX-005,0.1 part of fire retardant EF42, fire retarding synergist
1.0 parts of WFB15,0.1 part of primary antioxidant, 0.05 part of auxiliary anti-oxidant, 0.2 part of lubricant, 0.4 part of anti-dripping agent.
The preparation method is the same as that of Example 1 for the polycarbonate compositions.
Comparative example 1
A kind of polycarbonate compositions, the composition is by including that the raw material of following parts by weight is made: polycarbonate resin S-
It is 98.09 parts of 3000F, 0.6 part of toughener SX-005,0.06 part of fire retardant EF42,0.5 part of fire retarding synergist WFB15, main
0.1 part of antioxidant, 0.05 part of auxiliary anti-oxidant, 0.2 part of lubricant, 0.4 part of anti-dripping agent.
The preparation method is the same as that of Example 1 for the polycarbonate compositions.
Comparative example 2
A kind of polycarbonate compositions, the composition is by including that the raw material of following parts by weight is made: polycarbonate resin S-
It is 95.59 parts of 3000F, 0.6 part of toughener SX-005,0.06 part of fire retardant EF42,3.0 parts of fire retarding synergist WFB15, main
0.1 part of antioxidant, 0.05 part of auxiliary anti-oxidant, 0.2 part of lubricant, 0.4 part of anti-dripping agent.
The preparation method is the same as that of Example 1 for the polycarbonate compositions.
Comparative example 3
A kind of polycarbonate compositions, the composition is by including that the raw material of following parts by weight is made: polycarbonate resin S-
98.59 parts of 3000F, 0.6 part of toughener SX-005,0.06 part of fire retardant EF42,0.1 part of primary antioxidant, auxiliary anti-oxidant
0.05 part, 0.2 part of lubricant, 0.4 part of anti-dripping agent.
The preparation method is the same as that of Example 1 for the polycarbonate compositions.
Comparative example 4
A kind of polycarbonate compositions, the composition is by including that the raw material of following parts by weight is made: polycarbonate resin S-
It is 97.59 parts of 3000F, 0.6 part of toughener S-2001,0.06 part of fire retardant EF42,1.0 parts of fire retarding synergist WFB15, main
0.1 part of antioxidant, 0.05 part of auxiliary anti-oxidant, 0.2 part of lubricant, 0.4 part of anti-dripping agent.
The preparation method is the same as that of Example 1 for the polycarbonate compositions.
Comparative example 5
A kind of polycarbonate compositions, the composition is by including that the raw material of following parts by weight is made: polycarbonate resin S-
96.19 parts of 3000F, 2.0 parts of toughener SX-005,0.06 part of fire retardant EF42,0.1 part of primary antioxidant, auxiliary anti-oxidant
0.05 part, 0.2 part of lubricant, 0.4 part of anti-dripping agent.
The preparation method is the same as that of Example 1 for the polycarbonate compositions.
To preparing the scorching hot of resulting high heat resistance thin-walled flame retardant polycarbonate composition in embodiment 1-3 and comparative example 1-5
Silk initiation temperature and notched Chalpy impact intensity are tested, and test institute's reference standard or method is as described below:
(1) measuring method of melt flow rate (MFR) (MFR).Allow plastic pellet within certain time (10 minutes), certain temperature
And (a variety of materials standard is different) are melted into plastic liquid under pressure, then measurement is flowed out by a diameter by 2.1mm round tube
Grams.The grams value of outflow is bigger, indicates that the processing fluidity of the plastic material is better, on the contrary then poorer；It is used herein
Testing standard is ISO 1133, unit: g/10min.Using test condition are as follows: the melt flows under 300 DEG C, 1.2kg load
Rate (MFR).
(2) it the measuring method of cantilever beam impact strength: is measured and is lacked using the molding notched Chalpy impact stick of 4.0mm thickness
Mouth cantilever beam impact strength.Notched Chalpy impact intensity is measured according to ISO 180, is recorded with kJ/m2 as a result, testing in room
It is carried out under warm (23 DEG C).
(3) measuring method of UL94 anti-flammability:
According to " the flammable test of plastic material, the regulation of UL94 " carry out flammable test.Based on burn rate, put out
Go out the time, resist drippage ability and fall drop (drip) whether just burning, to obtain flame retardant rating.Sample for test
Product: having a size of 125mm length × 13mm width × it is not more than the stick of 13mm thickness, the thickness of present invention stick when testing
It is selected as 1.0mm.It, can be by material flame retardant rating according to the UL94 regulation, and based on the test result obtained for five samples
It is classified as (UL94-HB): V0, V1, V2,5VA and/or 5VB；But in the present invention, only the flame retardant rating of material is classified are as follows:
V0, V1 and V2, and the classification standard of each flame retardant rating are as follows:
V0: it is placing so that in the sample that its long axis is 180 degree relative to flame, after flame is lighted in removing, is burning
And/or the period smouldered is no more than 10 seconds, and the sample being disposed vertically does not generate the drop of the burning particles for the absorbent cotton that ignites
It falls.The flame out time of 5th stick is the flame out time of five sticks, is each lighted twice, wherein the first flame out time lighted
(t1) it is less than or equal to 50 seconds with the second summation (as maximum flame out time (t1+t2)) of flame out time (t2) for lighting.
V1: it is placing so that in the sample that its long axis is 180 degree relative to flame, after flame is lighted in removing, is burning
And/or the period smouldered is no more than 30 seconds, and the sample being disposed vertically does not generate the drop of the burning particles for the absorbent cotton that ignites
It falls.The flame out time of 5th stick is the flame out time of five sticks, is each lighted twice, wherein the first flame out time lighted
(t1) it is less than or equal to 250 seconds with the second summation (as maximum flame out time (t1+t2)) of flame out time (t2) for lighting.
V2: it is placing so that in the sample that its long axis is 180 degree relative to flame, after flame is lighted in removing, is burning
And/or the Average Life smouldered is no more than 30 seconds, but the sample being disposed vertically generates the drippage of the burning particles for cotton of igniting.
The flame out time of 5th stick is the flame out time of five sticks, is each lighted twice, wherein the first flame out time lighted
(t1) it is less than or equal to 250 seconds with the second summation (as maximum flame out time (t1+t2)) of flame out time (t2) for lighting.
(4) it the measuring method of heat deflection temperature (HDT): is used under 1.82MPa load according to testing standard ISO 75
The stick of 4.0mm thickness lays flat measurement HDT, with a DEG C record result.
Above-mentioned test result is referring to table 1.
The specific dosage of table 1 (unit: parts by weight) and the performance test results
As can be seen that comparative example 1-5 is made compared with specific embodiment 1-3 composite material obtained by the comparative example 1-5
The high or low variation of the ISO notch impact strength and flame retardant property of the polycarbonate compositions obtained, cannot meet height simultaneously
Toughness and the fire-retardant requirement of thin-walled.Different from comparative example 1-5, the fire-retardant poly- carbon of high heat resistance thin-walled obtained by the embodiment of the present invention
Polycarbonate greatly improved after organic metal sulfonate salt flame and nanometer wollastonite synergistic flame retardant in acid ester composite
The flame retardant property of resin can accomplish the V-0 fire-retardant rank of 1.0mm thickness, and influence on the mechanical property of resin and heat resistance
It is smaller, and since the selectivity of organic silicon rubber graft is added, the toughness of material is greatly improved, while to material
Flame retardant property also has little effect.
High heat resistance thin-walled flame retardant polycarbonate composition product obtained by the present invention can be widely applied to such as household electric
Device, switch on wall, kitchen appliance, house material, automotive material and component manufacture material of other industrial circles etc..
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (9)
1. a kind of high heat resistance thin-walled flame retardant polycarbonate composition, it is characterised in that: the composition is by including following parts by weight
Raw material is made:
The polycarbonate resin is at least one of the aromatic copolycarbonate of viscosity average molecular weigh 10000-40000.
2. high heat resistance thin-walled flame retardant polycarbonate composition according to claim 1, it is characterised in that: the composition
It is made of the raw material for including following parts by weight:
The polycarbonate resin is at least one of the aromatic copolycarbonate of viscosity average molecular weigh 10000-40000.
3. high heat resistance thin-walled flame retardant polycarbonate composition according to claim 2, it is characterised in that: the toughener
For Methyl Methacrylate-Butadiene-Styrene Copolymer, methyl methacrylate-acrylic acid copolymer, ethylene-acrylic acid
Methyl terpolymer, ethylene-butyl acrylate copolymer, ethylene-acrylate-glycidyl methacrylate ternary polymerization
Object, the ethylene-vinyl acetate copolymer of maleic anhydride functional, acrylic compounds toughener or organic silicon rubber graft toughener
At least one of；Preferably, the toughener is organic silicon rubber graft toughener, the organic silicon rubber grafting
The volume average particle size of rubber constituent in object toughener is 400-800nm.
4. high heat resistance thin-walled flame retardant polycarbonate composition according to claim 2, it is characterised in that: the fire retardant
For one of halogen based flame retardant, phosphorus flame retardant, type siloxane fire retardant, metallic salt fire retardant or boryl fire retardant；
Preferably, the fire retardant is metallic salt fire retardant；Preferably, the metallic salt fire retardant is organic sulfonic acid metal
Salt；Preferably, the metal in the metallic salt fire retardant is one of alkali or alkaline earth metal；The alkali metal
For one kind of caesium, lithium, sodium, potassium or middle rubidium；Preferably, the alkali metal is one of sodium, potassium or caesium；The alkaline earth gold
Belong to is one of barium, magnesium or calcium.
5. high heat resistance thin-walled flame retardant polycarbonate composition according to claim 2, it is characterised in that: the fire-retardant association
Effect agent is one of calcium carbonate, talcum powder, mica or wollastonite；Preferably, the fire retarding synergist is wollastonite；It is described
Wollastonite partial size be 100-500nm.
6. high heat resistance thin-walled flame retardant polycarbonate composition according to claim 2, it is characterised in that: the poly- carbonic acid
Ester resin is at least one of the aromatic copolycarbonate of viscosity average molecular weigh 12000-30000.
7. high heat resistance thin-walled flame retardant polycarbonate composition according to claim 2, it is characterised in that: the antioxidant
It is made of quality proportioning for the primary antioxidant and auxiliary anti-oxidant of 1:(0.5-1).
8. high heat resistance thin-walled flame retardant polycarbonate composition according to claim 2, it is characterised in that: in the auxiliary agent
Including lubricant.
9. the preparation method of high heat resistance thin-walled flame retardant polycarbonate composition of any of claims 1-8, feature
It is: includes the following steps:
(1) after weighing polycarbonate resin, toughener, fire retardant, fire retarding synergist, antioxidant and auxiliary agent respectively, by above-mentioned original
Material successively puts into mixing machine and is blended into uniformly, obtains pre-composition；
(2) it will be prepared in step (1) in resulting pre-composition investment double screw extruder, the screw rod of the double screw extruder is long
Diameter ratio is 40-45:1, and barrel temperature is 250-280 DEG C, screw speed 400-500rpm, and the pre-composition is squeezed in the twin-screw
Melting mixing and extruding pelletization in machine out, are made the high heat resistance thin-walled flame retardant polycarbonate composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810828647.1A CN109251501A (en) | 2018-07-25 | 2018-07-25 | A kind of high heat resistance thin-walled flame retardant polycarbonate composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810828647.1A CN109251501A (en) | 2018-07-25 | 2018-07-25 | A kind of high heat resistance thin-walled flame retardant polycarbonate composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109251501A true CN109251501A (en) | 2019-01-22 |
Family
ID=65049793
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810828647.1A Pending CN109251501A (en) | 2018-07-25 | 2018-07-25 | A kind of high heat resistance thin-walled flame retardant polycarbonate composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109251501A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110283442A (en) * | 2019-06-22 | 2019-09-27 | 宁波浙铁大风化工有限公司 | A kind of low white fire retardation PC of VOC toughening porcelain and preparation method thereof |
| CN112111138A (en) * | 2020-08-25 | 2020-12-22 | 天津金发新材料有限公司 | Flame-retardant polycarbonate composition and preparation method thereof |
| CN112143197A (en) * | 2020-08-25 | 2020-12-29 | 天津金发新材料有限公司 | Novel flame-retardant polycarbonate composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150337131A1 (en) * | 2014-05-20 | 2015-11-26 | Konica Minolta, Inc. | Method for producing thermoplastic resin composition |
| CN106916429A (en) * | 2017-03-09 | 2017-07-04 | 江苏金发科技新材料有限公司 | White high tenacity high glowing filament ignition temperature polycarbonate compositions and preparation method thereof |
| CN107556725A (en) * | 2017-08-16 | 2018-01-09 | 上海金发科技发展有限公司 | Halogen-free flame-retardant polycarbonate composition and preparation method thereof |
-
2018
- 2018-07-25 CN CN201810828647.1A patent/CN109251501A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150337131A1 (en) * | 2014-05-20 | 2015-11-26 | Konica Minolta, Inc. | Method for producing thermoplastic resin composition |
| CN106916429A (en) * | 2017-03-09 | 2017-07-04 | 江苏金发科技新材料有限公司 | White high tenacity high glowing filament ignition temperature polycarbonate compositions and preparation method thereof |
| CN107556725A (en) * | 2017-08-16 | 2018-01-09 | 上海金发科技发展有限公司 | Halogen-free flame-retardant polycarbonate composition and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110283442A (en) * | 2019-06-22 | 2019-09-27 | 宁波浙铁大风化工有限公司 | A kind of low white fire retardation PC of VOC toughening porcelain and preparation method thereof |
| CN110283442B (en) * | 2019-06-22 | 2022-02-15 | 宁波浙铁大风化工有限公司 | Low-VOC toughened porcelain white flame-retardant PC and preparation method thereof |
| CN112111138A (en) * | 2020-08-25 | 2020-12-22 | 天津金发新材料有限公司 | Flame-retardant polycarbonate composition and preparation method thereof |
| CN112143197A (en) * | 2020-08-25 | 2020-12-29 | 天津金发新材料有限公司 | Novel flame-retardant polycarbonate composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107383829A (en) | Ageing-resistant hydrolysis halogen-free flame-retardant polycarbonate composition and preparation method thereof | |
| KR101795132B1 (en) | Polycarbonate resin composition and molded article using the same | |
| CN109535683A (en) | Fire retardant polycarbonate compositions and preparation method thereof | |
| CN109251501A (en) | A kind of high heat resistance thin-walled flame retardant polycarbonate composition | |
| CN107556725A (en) | Halogen-free flame-retardant polycarbonate composition and preparation method thereof | |
| CN101693778A (en) | PVC/ABS blend and pipe thereof | |
| CN103304978A (en) | Highly heat-resistant and impact-resistant polycarbonate composition and preparation method thereof | |
| CN106147188B (en) | A kind of high fluidity polycarbonate alloy and preparation method thereof | |
| CN106317821A (en) | Flame-retardant PC/ABS composite material with high hydrolysis resistance and preparation method thereof | |
| CN107955368B (en) | Heat-conducting nylon with improved heat resistance and preparation method thereof | |
| CN1965055B (en) | Fire retardant formulations | |
| CN101945948A (en) | Polycarbonate resin composition with excellent flame retardancy | |
| CN105802021A (en) | Scratch-resistant flame-retardant polypropylene composition and preparation method thereof | |
| CN103333478A (en) | Halogen-free flame-retardant polycarbonate and preparation method thereof | |
| CN104725797B (en) | Method for preparing flame-retardant plastic composite material | |
| CN108129824A (en) | A kind of fire-retardant enhancing PC/ABS alloy materials of graphene and preparation method thereof | |
| CN104629327A (en) | Environmental-friendly flame-retardant reinforced wear-resistant PC/ABS blended alloy | |
| CN117343524A (en) | Low-temperature impact-resistant flame-retardant modified polycarbonate-based composite material and preparation method thereof | |
| CN113444354A (en) | high-CTI high-impact-resistance flame-retardant PC-PBT composite material and preparation method thereof | |
| CN109135235B (en) | Polycarbonate composition and preparation method and application thereof | |
| CN115584114B (en) | Polycarbonate alloy composition and preparation method and application thereof | |
| CN101058662B (en) | ABS resin composition with excellent antistatic capability and preparation method | |
| CN101824203B (en) | Solid polycondensation type phosphate ester inflaming retarding ABS/PC (Acrylonitrile Butadiene Styrene/Polycarbonate) alloy and preparation method thereof | |
| CN107383828B (en) | Good appearance halogen-free flame retardant PC/PET composite material and preparation method thereof | |
| CN101654547A (en) | Solid condensation-type organic phosphate flame-retardant PBT/ABS alloy material and preparation method thereof. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190122 |
|
| RJ01 | Rejection of invention patent application after publication |