CN109250949A - A kind of permeable concrete terrace coloring agent and preparation method thereof - Google Patents
A kind of permeable concrete terrace coloring agent and preparation method thereof Download PDFInfo
- Publication number
- CN109250949A CN109250949A CN201810808492.5A CN201810808492A CN109250949A CN 109250949 A CN109250949 A CN 109250949A CN 201810808492 A CN201810808492 A CN 201810808492A CN 109250949 A CN109250949 A CN 109250949A
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- China
- Prior art keywords
- agent
- sodium
- coloring agent
- permeable concrete
- concrete terrace
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/54—Pigments; Dyes
Abstract
The invention belongs to building material technical fields, disclose a kind of permeable concrete terrace coloring agent, be made of the raw material of following parts by weight: organic pigment 20-40%, defoaming agent 0.01~0.05%, dispersing agent 0.2-0.6%, stabilizer 0.4-0.8%, guar hydroxypropyltrimonium ammonium chloride 0.1-0.3%, bleeding agent 3-5%, sodium sulfosuccinate dioctyl ester 0.1-1%, potassium tripolyphosphate 1-2%, pH value adjustment agent 0.5-0.8%, surplus are water.Dosage of the present invention is 8-12 m2/kg, and dyeing effect is secured, and the color concrete terrace after use is alkaline-resisting, water-fast, temperature difference resistance is good.
Description
Technical field
The invention belongs to building material technical fields, are related to a kind of concrete floor coloring agent, specially a kind of osmosis type
Concrete floor coloring agent and preparation method thereof.
Background technique
Concrete hardening terrace be with a kind of concrete sealing, dust-proof, wear-resistant hardener fundamentally solve cement flooring,
The short problem of terrazzo floor, diamond dust terrace, the flaking, hollowing, fragmentation, fall off of epoxide terrace, dusting, service life.It is mixed
Solidifying soil coloring agent is a novel product, and non-toxic and tasteless, harmless, uvioresistant and weathering, tone are stablized, and coagulation is utilized
Soil, the progress such as terrazzo is artificially colored, both the products such as concrete can be made more rich and varied, can penetrate into concrete surface layer and mix
Solidifying soil fusion does not fade permanently, is again avoidable because epoxy resin falls off caused by problem unsightly.The dividend of concrete coloring agent,
The basic colors such as green, yellow, grey, blue and dedicated toner voluntarily prepare required other colors.It is easy to use, to concrete system
The mechanical property of product does not influence.Advantage: permeability is superpower, super abrasive, permanently do not fade, do not fade, uvioresistant and weathering,
It is good weatherability, rich in color；Non-toxic and tasteless, harmless, environment-friendly products surmount epoxide terrace, avoid showing for peeling shelling
As, construction is simple.Osmosis type coloring agent has stronger permeability, can effectively penetrate into inside concrete, forms coloured silk beautiful in colour
Color surface layer concrete.Easy to use, color is uniform, rich in color, and having more than ten of conventional color kind, (common color is tangerine
It is yellow, bright red, emerald green, gorgeous indigo plant, grey, just black etc.), user is also using the golden yellow, bright red, gorgeous blue of conventional color kind and just
It is black, voluntarily mix other required any colors.Currently, there is also product homogeneity to ask for terrace concrete coloring agent
Topic, the ability for penetrating into concrete topping have much room for improvement, and there are also coloring agents in concrete topping with atmospheric temperature (or season)
Variation colour stability problem.
Summary of the invention
In order to improve the homogeneity problem of coloring agent, the ability that coloring agent penetrates into concrete topping is improved, the present invention mentions
A kind of permeable concrete terrace coloring agent has been supplied, the product homogeneity is good, not stratified, concrete topping can be penetrated into, and
Coloring agent is stablized for a long time in concrete topping, will not lead to the problem of color color difference with the variation of atmospheric temperature (or season).
In order to achieve the above objectives, the invention adopts the following technical scheme: a kind of permeable concrete terrace coloring agent, by following parts by weight
Several raw material compositions: organic pigment 20-40%, defoaming agent 0.01~0.05%, dispersing agent 0.2-0.6%, stabilizer 0.4-0.8%,
Guar hydroxypropyltrimonium ammonium chloride 0.1-0.3%, bleeding agent 3-5%, sodium sulfosuccinate dioctyl ester 0.1-1%, tripolyphosphate
Potassium 1-2%, pH value adjustment agent 0.5-0.8%, surplus are water.
The organic pigment is one of azo pigments, phthalocyanine color, Aniline black pigment.
Preferably, the organic pigment is azo pigments (red or yellow), phthalocyanine (blue or green) pigment, Aniline black pigment
One of.
The defoaming agent is one or both of organic silicon defoamer and polyether antifoam agent.
The dispersing agent is melamine resin series high-efficiency water-reducing agent or polycarboxylate water-reducer.
The stabilizer is made of sodium lignin sulfonate (the wooden sodium) and cellulose ether.
Preferably, the cellulose ether is methylcellulose or CMC cellulose ether.
The bleeding agent is by sodium alkyl sulfonate, sodium alkyl benzene sulfonate, alkyl sulfate sodium, sodium secondary alkyl sulfonate, secondary alkyl
Sodium sulfovinate, Negel, succinic acid alkyl ester sulfonate sodium, sulfamic acid sodium, fatty alcohol polyoxyethylene ether, alkyl phenol are poly-
Two kinds of compositions in ethylene oxide ether.
Preferably, the bleeding agent is made of sulfamic acid sodium and fatty alcohol polyoxyethylene ether.
The PH regulator is one of oxalic acid, sulfamic acid, glacial acetic acid.
Preferably, the pH adjusting agent is oxalic acid.
The preparation method of above-mentioned permeable concrete terrace coloring agent, comprising the following steps: (1) aqueous solvent is poured into stirring
In machine, organic pigment is then added and is stirred 5~10 min；(2) defoaming agent, dispersing agent, stabilizer, infiltration are separately added into
Agent, sodium sulfosuccinate dioctyl ester, potassium tripolyphosphate continue 20~40 min of stirring；(3) guar hydroxypropyltrimonium is added
Ammonium chloride continues 2 ~ 3 min of stirring, can be prepared by permeability concrete coloring agent of the invention.
The present invention also provides the application methods of above-mentioned permeable concrete terrace coloring agent, comprising the following steps: (1) will
Mattess removes dust, cement mortar screeding hardening；(2) it is ground with the grinding of 50 mesh steel, 150 mesh resin abrasive discs, 300 mesh resins
Piece distinguishes grinding process；(3) gunning concrete sealing and curing handles reinforcing agent, and dosage is generally in 0.5-2.0 kg/m2Between,
It is polished after drying with 500 mesh resin abrasive discs；(4) spraying coloring agent first time, after dry, with 1000 mesh resin abrasive discs polishing one
Time, it then sprays 2-3 times again, after spontaneously drying 24 h of maintenance, can normally invade concrete topping 3-7mm after coloring agent is dry；(5)
Polishing grinding is handled after spraying glazing agent drying.
In the present invention, stabilizer can improve coloring agent to the sensibility of temperature change, solve coloring agent in concrete topping
In with atmospheric temperature (or season) variation colour stability problem.Guar hydroxypropyltrimonium ammonium chloride can make to dye
Agent stable system does not generate layering, precipitating, solves the problems, such as its homogeneity.Sodium sulfosuccinate dioctyl ester can reduce surface tension,
Interfacial tension enables coloring agent rapid deployment on concrete surface, improves the penetrating power of coloring agent.Potassium tripolyphosphate is not only
Interfacial tension can be reduced, wetting and dispersing is played the role of, moreover it is possible to which it is insoluble that complex reaction generation occurs with the metal ion in concrete
Property crystalline solid, the pore in filling blocking concrete, the compactness for increasing inside concrete improves the intensity of concrete and resistance to
Mill property, potassium tripolyphosphate and melamine water reducing agent or PCE polycarboxylate water-reducer have good synergistic effect, while adding dye
Toner system dispersion performance is good, can rapidly, be uniformly diffused into concrete surface, significantly improve the penetrating power of coloring agent.Oxalic acid
Not only adjustable pH value can also generate calcium oxalate with the calcium ion of inside concrete, keep concrete structure finer and close.
Beneficial effects of the present invention:
Permeable concrete terrace coloring agent dosage 8-12 m of the present invention2/kg.The dyeing effect of the coloring agent is secured, concrete
Terrace color alkali stability is good, wearability is good.
Specific embodiment
It explains in conjunction with the embodiments below.
Raw material used in embodiment are as follows:
Azo pigments (red or yellow), powder, the production of Jiangsu moral color painting Chemical Co., Ltd.
Phthalocyanine (blue or green) pigment, powder, the production of Nantong Zhen Xin pigment Co., Ltd；
Aniline black pigment, powder, the production of Dezhou Hongqiao dye chemical industry Co., Ltd；
Organic silicon defoamer, powder, Changzhou is along magnificent Chemical Co., Ltd.'s production；
Polyether antifoam agent, liquid, content 96.5%, the production of Weifang Sai Yang Trade Co., Ltd.；
The wooden sodium, powder, the production of Jilin Morning Ring Paper Indusrty Co., Ltd；
MC methyl cellulose ether, powder, the production of Zhejiang Hai Shen new material Co., Ltd；
CMC cellulose ether, powder, the municipal day Chemical Co., Ltd. production of Hebei Renqiu；
Guar hydroxypropyltrimonium ammonium chloride, powder, the production of one hundred Hongxin Materials Co., Ltd of Shandong；
Bleeding agent: sulfamic acid sodium, powder, the bright big chemical Science and Technology Co., Ltd.'s production in Shandong；Fatty alcohol polyoxyethylene ether,
Liquid, the production of Jiangsu Hai'an petrochemical plant.
Sodium sulfosuccinate dioctyl ester, powder, Guangzhou Li Yan trade Co., Ltd；
Potassium tripolyphosphate, powder, Zhejiang Wu Wangnong Biotechnology Co., Ltd；
Melamine resin series high-efficiency water-reducing agent, powder, Jiangxi Jin Yuan chemical color Co., Ltd；
Polycarboxylate water-reducer (powder) PCE, powder, Liaoning Fine Chemical Industry Co., Ltd.'s production.
CH3COOH, glacial acetic acid, technical grade, the production of gloomy space chemical industry sale Co., Ltd of Shijiazhuang Gaocheng area.
Oxalic acid, sulfamic acid: commercially available analysis is pure.
1 embodiment of table and comparative formulation table
Note: bleeding agent used in embodiment 5 is made of sulfamic acid sodium and fatty alcohol polyoxyethylene ether by weight 1-3:1, used
PH regulator is oxalic acid, and PH regulator used in comparative example 4 is sulfamic acid.
The preparation method of permeable concrete terrace coloring agent described in embodiment 1-6, comprising the following steps: (1) will be molten
Agent water pours into blender, and organic pigment is then added and is stirred 5~10 min；(2) be separately added into defoaming agent, dispersing agent,
Stabilizer, bleeding agent, sodium sulfosuccinate dioctyl ester, potassium tripolyphosphate continue 20~40 min of stirring；(3) guar gum hydroxyl is added
Hydroxypropyltrimonium chloride continues 2 ~ 3 min of stirring, can be prepared by permeability concrete coloring agent of the invention.
Performance test
Embodiment 1-6, comparative example 1-4 and commercial product are applied to C30 concrete surface, are tested for the property, as a result such as following table
2。
Performance of 2 embodiment of table in terrace concrete topping
From the above data, performance of the terrace concrete coloring agent in concrete topping of the formula preparation in the application compared with
Good, concrete floor color is alkaline-resisting, water-fast and temperature difference resistance is good.
The above, only presently preferred embodiments of the present invention, are not intended to limit the invention, it is all in spirit of the invention and
Within principle, any modification, equivalent substitution, improvement and etc. done be should all be included in the protection scope of the present invention.
Claims (9)
1. a kind of permeable concrete terrace coloring agent, which is characterized in that be made of the raw material of following parts by weight: organic pigment
20-40%, defoaming agent 0.01~0.05%, dispersing agent 0.2-0.6%, stabilizer 0.4-0.8%, guar hydroxypropyltrimonium chlorination
Ammonium 0.1-0.3%, bleeding agent 3-5%, sodium sulfosuccinate dioctyl ester 0.1-1%, potassium tripolyphosphate 1-2%, pH value adjustment agent 0.5-
0.8%, surplus is water.
2. permeable concrete terrace coloring agent according to claim 1, which is characterized in that the organic pigment is azo
One of pigment, phthalocyanine color, Aniline black pigment.
3. permeable concrete terrace coloring agent according to claim 1, which is characterized in that the defoaming agent is organosilicon
One or both of defoaming agent and polyether antifoam agent.
4. permeable concrete terrace coloring agent according to claim 1, which is characterized in that the dispersing agent is melamine
Amine-formaldehyde resins series high-efficiency water-reducing agent or polycarboxylate water-reducer.
5. permeable concrete terrace coloring agent according to claim 1, which is characterized in that the stabilizer is by lignin
Sodium sulfonate and cellulose ether composition.
6. permeable concrete terrace coloring agent according to claim 1, which is characterized in that the bleeding agent is by alkyl sulphur
Sour sodium, sodium alkyl benzene sulfonate, alkyl sulfate sodium, sodium secondary alkyl sulfonate, secondary alkyl sulphate sodium, Negel, amber
Acid alkyl ester sodium sulfonate, sulfamic acid sodium, fatty alcohol polyoxyethylene ether, two kinds of compositions in alkyl phenol polyoxyethylene ether.
7. permeable concrete terrace coloring agent according to claim 6, which is characterized in that the bleeding agent is by amino sulphur
Sour sodium and fatty alcohol polyoxyethylene ether composition.
8. permeable concrete terrace coloring agent according to claim 1, which is characterized in that the PH regulator is grass
One of acid, sulfamic acid, glacial acetic acid.
9. the preparation method of any permeable concrete terrace coloring agent of claim 1-8, which is characterized in that including with
Lower step: (1) pouring into aqueous solvent in blender, and organic pigment is then added and is stirred 5~10 min；(2) it is separately added into
Defoaming agent, dispersing agent, stabilizer, bleeding agent, sodium sulfosuccinate dioctyl ester, potassium tripolyphosphate continue 20~40 min of stirring；
(3) guar hydroxypropyltrimonium ammonium chloride is added and continues 2 ~ 3 min of stirring, can be prepared by permeability concrete dye of the invention
Toner.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810808492.5A CN109250949A (en) | 2018-07-23 | 2018-07-23 | A kind of permeable concrete terrace coloring agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810808492.5A CN109250949A (en) | 2018-07-23 | 2018-07-23 | A kind of permeable concrete terrace coloring agent and preparation method thereof |
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| CN109250949A true CN109250949A (en) | 2019-01-22 |
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| CN201810808492.5A Pending CN109250949A (en) | 2018-07-23 | 2018-07-23 | A kind of permeable concrete terrace coloring agent and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111978797A (en) * | 2020-08-27 | 2020-11-24 | 深圳市嘉固工业地坪有限公司 | Water-based composite nano toner and preparation method thereof |
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|---|---|---|---|---|
| CN1569982A (en) * | 2003-07-21 | 2005-01-26 | 深圳市海川实业股份有限公司 | Hydrophobic ferric oxide aqueous color paste |
| CN105038422A (en) * | 2015-07-14 | 2015-11-11 | 上海森瀚新型材料科技有限公司 | Composite functional type heat insulating coating for building wall |
| CN107903787A (en) * | 2017-12-15 | 2018-04-13 | 苏州金润新材料科技有限公司 | A kind of concrete penetrating colorants and its application |
| CN107987647A (en) * | 2017-12-15 | 2018-05-04 | 苏州赛斯德工程设备有限公司 | A kind of water-proofing anticracking coating and preparation method thereof |
| CN108314351A (en) * | 2017-12-15 | 2018-07-24 | 苏州金润新材料科技有限公司 | A kind of concrete nanometer colorant and its application |
-
2018
- 2018-07-23 CN CN201810808492.5A patent/CN109250949A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1569982A (en) * | 2003-07-21 | 2005-01-26 | 深圳市海川实业股份有限公司 | Hydrophobic ferric oxide aqueous color paste |
| CN105038422A (en) * | 2015-07-14 | 2015-11-11 | 上海森瀚新型材料科技有限公司 | Composite functional type heat insulating coating for building wall |
| CN107903787A (en) * | 2017-12-15 | 2018-04-13 | 苏州金润新材料科技有限公司 | A kind of concrete penetrating colorants and its application |
| CN107987647A (en) * | 2017-12-15 | 2018-05-04 | 苏州赛斯德工程设备有限公司 | A kind of water-proofing anticracking coating and preparation method thereof |
| CN108314351A (en) * | 2017-12-15 | 2018-07-24 | 苏州金润新材料科技有限公司 | A kind of concrete nanometer colorant and its application |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111978797A (en) * | 2020-08-27 | 2020-11-24 | 深圳市嘉固工业地坪有限公司 | Water-based composite nano toner and preparation method thereof |
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Application publication date: 20190122 |