CN109233560A - A kind of molybdenum disulfide anticorrosive paint and preparation method thereof - Google Patents
A kind of molybdenum disulfide anticorrosive paint and preparation method thereof Download PDFInfo
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- CN109233560A CN109233560A CN201810896499.7A CN201810896499A CN109233560A CN 109233560 A CN109233560 A CN 109233560A CN 201810896499 A CN201810896499 A CN 201810896499A CN 109233560 A CN109233560 A CN 109233560A
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- molybdenum disulfide
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- anticorrosive paint
- agent
- epoxy resin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3009—Sulfides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
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- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of molybdenum disulfide anticorrosive paint and preparation method thereof, molybdenum disulfide is added in acrylic resin/epoxy resin composition after carrying out ultrasonic disperse, is added after various auxiliary agents, mixed fillers to be put into stirring and be sanded in dispersion multiple purpose aeroplane thereto and carries out being mixed with anticorrosive paint.Wherein, by the way that silane coupling agent is added, effectively change dispersibility of the molybdenum disulfide in resin, so that preparation is compared with polymolecularity molybdenum disulfide/acrylic resin/anti-corrosive paint of epoxy resin；By the way that molybdenum disulfide is added, the good antiseptic property and mechanical property of coating are assigned.
Description
Technical field
The present invention relates to anticorrosive paint technology fields, more particularly, to a kind of molybdenum disulfide anticorrosive paint and its preparation side
Method.
Background technique
Since graphene is found, it has started a burst of research boom, and people also increasingly pay attention to class graphene
The research of the two-dimensional material of structure, molybdenum disulfide is because its lamellar structure and unique property have become two-dimensional material field
In emerging research hotspot.
Molybdenum disulfide is in black powder, and have metallic luster as class grapheme material, be molybdenite it is main at
Point.One molybdenum atom is enclosed in the intermediate layer structure for foring hexagonal crystal figure by its structure, six sulphur atoms.Single layer two
Molybdenum sulfide contains there are three atomic layer, and upper layer and lower layer S atom layer one layer of Mo atomic layer of sandwich constitutes the synusia of " S-Mo-S "
Shape structure.By being covalently keyed in layer, then combined by faint Van der Waals force between layer and layer.Due to layer of molybdenum-disulfide and layer it
Between Van der Waals force be it is very weak, can slide easily, make it have good lubricity, anti-pressure and abrasion-proof is often used as solid
Body lubricant, suitable for high speed, heavy load, high temperature, high vacuum and the equipment for having the operating conditions such as chemical attack.In molybdenum disulfide
The attachment of sulphur atom and metal surface, binding force are quite strong, and can generate one layer of firm film, are resistant to high contact pressure and height
Friction velocity.It also has preferable chemical stability, in addition to that can be corroded by chloroazotic acid, the concentrated sulfuric acid, boiling concentrated hydrochloric acid, nitric acid
Outside, the corrosion of most of acid, alkali drug can be resisted.Molybdenum disulfide is under stable general condition to ambiance, not with metal
It reacts, does not also corrode rubber material, radiation resistance is also preferable.It is covered on the surface of friction material, can protect it
Its material can be effectively prevented them and be oxidized.
Currently, research of the graphene in anticorrosive paint has had very much, graphene can be used as filler and coating be added
Middle increase coating mechanical property and antiseptic property, still, molybdenum disulfide is equally used as two-dimensional slice layer structure, applies for anti-corrosion
Research in material field is very few.
Summary of the invention
It is an object of the invention to: a kind of molybdenum disulfide anticorrosive paint and preparation method thereof is provided, how is solved by two sulphur
Change molybdenum for the problems in anticorrosive paint field.
The purpose of the present invention is achieved through the following technical solutions:
A kind of molybdenum disulfide anticorrosive paint, the component of the coating and the parts by weight of each component are as follows: molybdenum disulfide 0.5~3
Part, 100 parts of epoxy resin, 10~20 parts of acrylic resin.
Preferably, which further includes 10 parts of coalescing agent, 35 parts of mixed fillers.
Preferably, which further includes 60 parts of curing agent.
Preferably, which further includes 5 parts of defoaming agent.
Preferably, which further includes 2.7% silane coupling agent for accounting for entire fine paint powders quality.
Preferably, the coalescing agent is butyl glycol ether.
Preferably, the mixed fillers are mixed by barium sulfate, talcum powder and calcium carbonate, and composition mass ratio is 4:
5:5。
Preferably, the defoaming agent is polyethylene glycol.
Preferably, the model KH-792 of the silane coupling agent.
A kind of preparation method of molybdenum disulfide anticorrosive paint, the preparation method include:
(1) to weigh raw material according to parts by weight as follows: 0.5-3 parts of molybdenum disulfide, 100 parts of epoxy resin, acrylic resin
10-20 parts, 10 parts of coalescing agent, 35 parts of mixed fillers, 5 parts of defoaming agent, 2.7% silane coupling agent of powder quality, solidification
60 parts of agent.
(2) ultrasonic disperse: first molybdenum disulfide is added in the mixture of acrylic resin and epoxy resin, uses ultrasonic wave
Washer carries out ultrasonic disperse 2h；
(3) it stirs: film forming is added to molybdenum disulfide/acrylic resin after ultrasonic disperse/epoxy resin composition kind and helps
Agent, mixed fillers, defoaming agent and silane coupling agent after stirring 2h with electric mixer, are added into stirring and are sanded and disperse to be mostly used
It is further dispersed with stirring in machine；
(4) curing agent is added in the coating prepared to step (3), it is anti-obtains molybdenum disulfide/acrylic resin/epoxy resin
Rotten coating.
Compared with prior art, the present invention is added mixing and fills out using molybdenum disulfide, acrylic resin, epoxy resin as major ingredient
Material, coalescing agent, defoaming agent and silane coupling agent are prepared by ultrasonic disperse, stirring and three big steps of grinding, prepare
Structure is relatively simple, and configuration is convenient, and cost is relatively low, and environmental pollution is small, favorable anti-corrosion effect, more beneficial new of mechanical property
Type anticorrosive paint.
Specific embodiment
With specific embodiment, the present invention is described in detail below.
Embodiment 1
The present embodiment provides a kind of molybdenum disulfide anticorrosive paint, the component of the coating and the parts by weight of each component are as follows: two
0.5~3 part of molybdenum sulfide, 100 parts of epoxy resin, 10~20 parts of acrylic resin.
More specifically, molybdenum disulfide content be respectively epoxy resin quality 0.5%, 1.0%, 1.5%, 2.0%,
2.5% and 3.0%.
Embodiment 2
The present embodiment provides a kind of molybdenum disulfide anticorrosive paint, the component of the coating and the parts by weight of each component are as follows: two
0.5~3 part of molybdenum sulfide, 100 parts of epoxy resin, 10~20 parts of acrylic resin.
More specifically, molybdenum disulfide content be respectively epoxy resin quality 0.5%, 1.0%, 1.5%, 2.0%,
2.5% and 3.0%.
The coating further includes 10 parts of coalescing agent, 35 parts of mixed fillers.Coalescing agent is butyl glycol ether.Mixed fillers by
Barium sulfate, talcum powder and calcium carbonate mix, and composition mass ratio is 4:5:5.
Embodiment 3
The present embodiment provides a kind of molybdenum disulfide anticorrosive paint, the component of the coating and the parts by weight of each component are as follows: two
0.5~3 part of molybdenum sulfide, 100 parts of epoxy resin, 10~20 parts of acrylic resin.
More specifically, molybdenum disulfide content be respectively epoxy resin quality 0.5%, 1.0%, 1.5%, 2.0%,
2.5% and 3.0%.
The coating further includes 10 parts of coalescing agent, 35 parts of mixed fillers.Coalescing agent is butyl glycol ether.Mixed fillers by
Barium sulfate, talcum powder and calcium carbonate mix, and composition mass ratio is 4:5:5.
The coating further includes 60 parts of curing agent.
Embodiment 4
The present embodiment provides a kind of molybdenum disulfide anticorrosive paint, the component of the coating and the parts by weight of each component are as follows: two
0.5~3 part of molybdenum sulfide, 100 parts of epoxy resin, 10~20 parts of acrylic resin.
More specifically, molybdenum disulfide content be respectively epoxy resin quality 0.5%, 1.0%, 1.5%, 2.0%,
2.5% and 3.0%.
The coating further includes 10 parts of coalescing agent, 35 parts of mixed fillers.Coalescing agent is butyl glycol ether.Mixed fillers by
Barium sulfate, talcum powder and calcium carbonate mix, and composition mass ratio is 4:5:5.
The coating further includes 60 parts of curing agent.
The coating further includes 5 parts of defoaming agent.Defoaming agent is polyethylene glycol.
Embodiment 5
The present embodiment provides a kind of molybdenum disulfide anticorrosive paint, the component of the coating and the parts by weight of each component are as follows: two
0.5~3 part of molybdenum sulfide, 100 parts of epoxy resin, 10~20 parts of acrylic resin.
More specifically, molybdenum disulfide content be respectively epoxy resin quality 0.5%, 1.0%, 1.5%, 2.0%,
2.5% and 3.0%.
The coating further includes 10 parts of coalescing agent, 35 parts of mixed fillers.Coalescing agent is butyl glycol ether.Mixed fillers by
Barium sulfate, talcum powder and calcium carbonate mix, and composition mass ratio is 4:5:5.
The coating further includes 60 parts of curing agent.
The coating further includes 5 parts of defoaming agent.Defoaming agent is polyethylene glycol.
The coating further includes 2.7% silane coupling agent for accounting for entire fine paint powders quality.The model of silane coupling agent
KH-792。
Embodiment 6
The present embodiment provides a kind of preparation method of molybdenum disulfide anticorrosive paint, which includes:
(1) to weigh raw material according to weight as follows:
(2) ultrasonic disperse: first molybdenum disulfide being added in acrylic resin/epoxy resin mixture, clear with ultrasonic wave
It washes device and carries out ultrasonic disperse 2h, it is therefore an objective to increase dispersibility of the molybdenum disulfide in resin.The molybdenum disulfide content of addition can be with
It is 0.5%, 1.0%, 1.5%, 2.0%, 2.5% or the 3.0% of epoxy resin quality.
(3) it stirs: film forming is added to molybdenum disulfide/acrylic resin after ultrasonic disperse/epoxy resin composition kind and helps
After stirring 2h with electric precise blender, it is more to be added into stirring sand milling dispersion for agent, mixed fillers, defoaming agent, silane coupling agent
With being further dispersed with stirring in machine, so that each component dispersion is more uniform.By the way that silane coupling agent is added, it was made both
Physical entanglement occurs while chemical reaction with molybdenum disulfide with polymer again, effectively changes molybdenum disulfide in resin
Dispersibility, so that preparation is compared with polymolecularity molybdenum disulfide/acrylic resin/anti-corrosive paint of epoxy resin.
(4) curing agent is added in the coating prepared to step (3), it is anti-obtains molybdenum disulfide/acrylic resin/epoxy resin
Rotten coating.
Coalescing agent is butyl glycol ether.Mixed fillers are mixed with barium sulfate, talcum powder and calcium carbonate,
The mass ratio correspondence respectively formed is 4:5:5.Defoaming agent is polyethylene glycol.The model KH-792 of silane coupling agent.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, it is noted that all
Made any modifications, equivalent replacements, and improvements etc. within the spirit and principles in the present invention should be included in guarantor of the invention
Within the scope of shield.
Claims (10)
1. a kind of molybdenum disulfide anticorrosive paint, which is characterized in that the component of the coating and the parts by weight of each component are as follows: curing
0.5~3 part of molybdenum, 100 parts of epoxy resin, 10~20 parts of acrylic resin.
2. a kind of molybdenum disulfide anticorrosive paint according to claim 1, which is characterized in that the coating further includes coalescing agent
10 parts, 35 parts of mixed fillers.
3. a kind of molybdenum disulfide anticorrosive paint according to claim 2, which is characterized in that the coating further includes curing agent 60
Part.
4. a kind of molybdenum disulfide anticorrosive paint according to claim 3, which is characterized in that the coating further includes defoaming agent 5
Part.
5. a kind of molybdenum disulfide anticorrosive paint according to claim 4, which is characterized in that the coating further includes accounting for entire painting
2.7% silane coupling agent of feed powder weight.
6. a kind of molybdenum disulfide anticorrosive paint according to claim 2, which is characterized in that the coalescing agent is second two
Alcohol butyl ether.
7. a kind of molybdenum disulfide anticorrosive paint according to claim 2, which is characterized in that the mixed fillers are by sulfuric acid
Barium, talcum powder and calcium carbonate mix, and composition mass ratio is 4:5:5.
8. a kind of molybdenum disulfide anticorrosive paint according to claim 4, which is characterized in that the defoaming agent is poly- second two
Alcohol.
9. a kind of molybdenum disulfide anticorrosive paint according to claim 5, which is characterized in that the type of the silane coupling agent
Number be KH-792.
10. a kind of preparation method of molybdenum disulfide anticorrosive paint, which is characterized in that the preparation method includes:
(1) to weigh raw material according to parts by weight as follows: 0.5-3 parts of molybdenum disulfide, 100 parts of epoxy resin, acrylic resin 10~
20 parts, 10 parts of coalescing agent, 35 parts of mixed fillers, 5 parts of defoaming agent, 2.7% silane coupling agent of powder quality, curing agent 60
Part.
(2) ultrasonic disperse: first molybdenum disulfide is added in the mixture of acrylic resin and epoxy resin, uses ultrasonic cleaning
Device carries out ultrasonic disperse 2h；
(3) it stirs: coalescing agent is added to molybdenum disulfide/acrylic resin after ultrasonic disperse/epoxy resin composition kind, mixes
Close filler, defoaming agent and silane coupling agent, after stirring 2h with electric mixer, be added into stirring be sanded in dispersion multiple purpose aeroplane into
Row is further dispersed with stirring；
(4) curing agent is added in the coating prepared to step (3), obtains molybdenum disulfide/acrylic resin/epoxy resin anti-corrosion and applies
Material.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810896499.7A CN109233560A (en) | 2018-08-08 | 2018-08-08 | A kind of molybdenum disulfide anticorrosive paint and preparation method thereof |
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| CN201810896499.7A CN109233560A (en) | 2018-08-08 | 2018-08-08 | A kind of molybdenum disulfide anticorrosive paint and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110093088A (en) * | 2019-04-24 | 2019-08-06 | 中国海洋大学 | One type graphene self-dispersing coating and preparation method thereof |
| CN112898872A (en) * | 2021-01-28 | 2021-06-04 | 深圳市捷路安科技发展有限公司 | Polyamide modified MoS2Modified epoxy resin anticorrosive floor paint and preparation method thereof |
| CN114085572A (en) * | 2021-12-06 | 2022-02-25 | 长春蓝天密封技术开发有限公司 | Metal gasket surface treating agent with good sealing property |
| CN115637091A (en) * | 2022-09-21 | 2023-01-24 | 北京睿汲能源技术有限公司 | Two-dimensional nano composite, preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110093088A (en) * | 2019-04-24 | 2019-08-06 | 中国海洋大学 | One type graphene self-dispersing coating and preparation method thereof |
| CN112898872A (en) * | 2021-01-28 | 2021-06-04 | 深圳市捷路安科技发展有限公司 | Polyamide modified MoS2Modified epoxy resin anticorrosive floor paint and preparation method thereof |
| CN112898872B (en) * | 2021-01-28 | 2021-08-24 | 深圳市捷路安科技发展有限公司 | Polyamide modified MoS2Modified epoxy resin anticorrosive floor paint and preparation method thereof |
| CN114085572A (en) * | 2021-12-06 | 2022-02-25 | 长春蓝天密封技术开发有限公司 | Metal gasket surface treating agent with good sealing property |
| CN115637091A (en) * | 2022-09-21 | 2023-01-24 | 北京睿汲能源技术有限公司 | Two-dimensional nano composite, preparation method and application thereof |
| CN115637091B (en) * | 2022-09-21 | 2024-02-23 | 北京睿汲能源技术有限公司 | Two-dimensional nano-composite, preparation method and application thereof |
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Application publication date: 20190118 |