CN109231891A - A kind of chromatic cementing agent mixing preparation method for material - Google Patents

A kind of chromatic cementing agent mixing preparation method for material Download PDF

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Publication number
CN109231891A
CN109231891A CN201811173587.0A CN201811173587A CN109231891A CN 109231891 A CN109231891 A CN 109231891A CN 201811173587 A CN201811173587 A CN 201811173587A CN 109231891 A CN109231891 A CN 109231891A
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CN
China
Prior art keywords
mineral aggregate
stirred tank
cementitious matter
chromatic
basalt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811173587.0A
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Chinese (zh)
Inventor
黄艳芳
刘双
许宏
骆新平
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China Petroleum and Chemical Corp
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China Petroleum and Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Petroleum and Chemical Corp filed Critical China Petroleum and Chemical Corp
Priority to CN201811173587.0A priority Critical patent/CN109231891A/en
Publication of CN109231891A publication Critical patent/CN109231891A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/26Bituminous materials, e.g. tar, pitch
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20Mortars, concrete or artificial stone characterised by specific physical values for the density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Road Paving Structures (AREA)

Abstract

A kind of chromatic cementing agent mixing preparation method for material, the composition of chromatic bitumen mixture include: cementitious matter, antistripping agent, big mineral aggregate, Mineral Material, small mineral aggregate, middle sand, miberal powder and inorganic toner;Wherein cementitious matter includes: aromatic naphtha, Petropols and SBS.Preparation step includes: to pour into after the heating of big mineral aggregate, Mineral Material, small mineral aggregate and middle sand in stirred tank in proportion.It will be poured into stirred tank after toner and miberal powder heating in proportion.After cementitious matter is heated to 155-180 DEG C of thawing, additive is added and reconciles uniformly, is subsequently poured into stirred tank.It is stirred 40-60 seconds being maintained the temperature in stirred tank between 165-185 DEG C, until mixture uniformity, mineral aggregate particle all wraps cementitious matter, no flower material, no conglomeration or block or serious coarse fodder fines segregation phenomenon, obtains finished product.Product made of the present invention has good high-temperature stability, low-temperature cracking-resistance, ageing resistance.

Description

A kind of chromatic cementing agent mixing preparation method for material
Technical field
The present invention relates to oil product manufacture fields, and in particular to a kind of weather-proof particulate formula coloured glue for road pavement Ramming material mixing preparation method for material.
Background technique
Chromatic bitumen mixture is that one kind is formed by cementitious matter, mineral material, colorant and modifying agent blending and modifying, is had The pavement of road paver for the features such as performance is stable, bright in colour, pavement performance is good, can be made different face as needed Color.
Government road department is worked well in highway construction process using chromatic bitumen mixture laying road at present.Such as On road in black spot, or by middle and primary schools school district, making red or orange-yellow asphalt are improved Driver's is vigilant, drives a vehicle with caution;Or the asphalt of different colours was used to distinguish difference on the road surface of multilane Lane.
The existing Colorful Asphalt Pavement bad phenomenon that there are weatherabilities is poor, the service life is shorter, color is thin out at present.Especially It is in pavement diseases, the resistance such as the southern area that temperature is high, relative humidity is big, rainfall is big there is also track, deformation, film fall off The popularization and use of chromatic bitumen mixture are hindered.
Summary of the invention
The object of the present invention is to provide a kind of chromatic bitumen mixture preparation method, the present invention has simple, easy to operate, steady Fixed advantage.The resistance to environmental change of prepared product color, good high-temperature stability, low-temperature cracking-resistance, ageing resistance spy Point.
The object of the invention can be realized by technical solution below:
A kind of chromatic cementing agent mixing preparation method for material, chromatic bitumen mixture component by mass percentage by below at It is grouped as:
Wherein cementitious matter consists of the following compositions by mass percentage:
Aromatic naphtha 30-70%
Petropols 20-60%
SBS 3-20%
The basalt and/or limestone that big mineral aggregate I is partial size 10-15mm;
Mineral Material II is the basalt and/or limestone of partial size 5-10mm;
Small mineral aggregate III is the basalt and/or limestone of partial size 0.5-5mm;
Middle sand is basalt and/or the Machine-made Sand that partial size is 0.35-0.5mm is made in limestone;
Miberal powder is the miberal powder that partial size < 0.35mm is made in basalt and/or limestone;
Toner is inorganic toner.
The SBS is the block copolymer of s-B-S, and the aromatic naphtha using subtracting four, take out by line furfural Fuel-displaced, the Petropols use C9 hydrogenated petroleum resin.
Its step are as follows:
1. pouring into stirring after big mineral aggregate, Mineral Material, small mineral aggregate and middle sand are heated and maintained at 175-185 DEG C in proportion In kettle;
2. toner and miberal powder are poured into stirred tank in proportion;
3. after cementitious matter is heated to 155-180 DEG C of thawing, antistripping agent being added and reconciles uniformly, is subsequently poured into stirred tank It is interior;
4. 40-60s is stirred between 165-185 DEG C maintaining the temperature in stirred tank, until mixture uniformity, mineral aggregate Particle all wraps cementitious matter, no flower material, no conglomeration or block or serious coarse fodder fines segregation phenomenon, obtains finished product.
Flower material refers to pitch and building stones in stirring, and the uneven a part package pitch that generates of stirring is especially more, a part of There are no package to the problem of.
It includes that pitch is especially more that conglomeration or block, which refer to that pitch and building stones have part in stirring, forms biggish group or block.
Serious coarse fodder fines isolation refers to that in stirring, coarse fodder part and fine fraction separation are serious, is not uniformly mixed.
The present invention can be done to be improved further below:
The inorganic toner is preferably iron oxide red, iron oxide yellow, iron oxide green or chromium oxide.
The antistripping agent is preferably amino amine derivative liquid antistripping agent, and the effect of antistripping agent is to prevent cementitious matter It is separated with mineral aggregate, it is more preferable using its effect of amino amine derivative liquid antistripping agent that inventor studies discovery.
Compared with prior art, the invention has the following advantages:
1) production equipment used by this preparation method is similar to the production production equipment of asphalt concrete, does not need Increase additional equipment, to increase cost.
2) product made of the present invention is more preferable than plain asphalt in high-temperature stability, low-temperature cracking-resistance, ageing resistance, with SBS modified asphalt mixture, which is compared, has better crack resistance at low-temperature;Meet the requirement of domestic communication standard.
3) product made of the present invention adjusts its additional amount, can spread out different colours by adding different inorganic toners Road surface.
4) the road surface good weatherability that product made of the present invention is laid with is less prone to track, the road surfaces disease such as deformation, film fall off Evil.
Detailed description of the invention
Fig. 1 is chromatic bitumen mixture experimental conditions one of the present invention;
Fig. 2 is chromatic bitumen mixture experimental conditions two of the present invention.
Specific embodiment
The invention will be further described for specific embodiment below, so that those skilled in the art can better understand this It invents and can be practiced, but illustrated embodiment is not as a limitation of the invention.
Raw material is screened according to the performance indicator of table 1, table 2, table 3, table 4, table 5.
1 cementitious matter physicochemical property table of table
Project Actual measurement Product technology C-70 Test method
Needle penetration, 1/10mm 70 61-80 GB/T4509
Ductility (15 DEG C), cm 126 >100 GB/T4508
Softening point, DEG C 62.5 ≮50 GB/T4507
2 coarse aggregate technical indicator of table
3 fine aggregate technical indicator of table
4 miberal powder technical requirement of table
5 inorganic pigment S, H series performance of table
Wherein, the coarse aggregate of table 2, which refers to, is greater than 2.36mm or more mineral aggregate by partial size (including big mineral aggregate, Mineral Material and part is small Mineral aggregate), the fine aggregate of table 3 refers to that partial size is less than the mineral aggregate (including the small mineral aggregate in part and middle sand) of 2.36mm.
Chromatic bitumen mixture is made by proportion shown in table 6, it is calculated in weight percent
6 chromatic cementing agent mix material proportioning of table
Additive described in table 6 is amino amine derivative liquid antistripping agent, wherein the aromatic naphtha in cementitious matter, petroleum Resin, SBS are formed with the ratio (mass ratio) of 30-70:20-60:3-20.Wherein the mineral aggregate of embodiment one is basalt, real The mineral aggregate for applying example two is limestone, and embodiment three-five is that basalt and limestone use simultaneously, three basalt of embodiment and stone The ratio of limestone is 1:9 (mass ratio), example IV 1:1;Example IV is 1:4.
Its preparation step is as follows:
1. pouring into stirring after big mineral aggregate, Mineral Material, small mineral aggregate and middle sand are heated and maintained at 175-185 DEG C in proportion In kettle.
2. toner and miberal powder are poured into stirred tank in proportion.
3. reconciling uniformly, being subsequently poured into stirred tank into additive after cementitious matter is heated to 155-180 DEG C of thawing.
4. being stirred between 165-185 DEG C 40-60 seconds in newspaper temperature in stirred tank, until mixture uniformity, mine Material particle all wraps cementitious matter, no flower material, no conglomeration or block or serious coarse fodder fines segregation phenomenon, obtains finished product.
Wherein, step 1 heating temperature of embodiment one is 175 DEG C, and step 2 heating temperature is 175 DEG C, step 3 heating For temperature at 155-180 DEG C, standard is cementitious matter, and the temperature of step 4 is 165-185 DEG C, and keeping cementitious matter is to melt shape State, mixing time are 50 seconds.
Step 1 heating temperature of embodiment two is 180 DEG C, and step 2 heating temperature is 180 DEG C, and step 3 heating temperature exists 155-180 DEG C, standard is cementitious matter, and the temperature of step 4 is 165-185 DEG C, and holding cementitious matter is melting state, is stirred Mixing the time is 50 seconds.
Step 1 heating temperature of embodiment three is 182 DEG C, and step 2 heating temperature is 182 DEG C, and step 3 heating temperature exists 155-180 DEG C, standard is cementitious matter, and the temperature of step 4 is 165-185 DEG C, and holding cementitious matter is melting state, is stirred Mixing the time is 55 seconds.
Step 1 heating temperature of example IV and embodiment five is 185 DEG C, and step 2 heating temperature is 185 DEG C, step 3 For heating temperature at 155-180 DEG C, standard is cementitious matter, and the temperature of step 4 is 165-185 DEG C, and keeping cementitious matter is to melt Change state, mixing time are 60 seconds.
Marshall experiment is carried out to manufactured finished product, as a result such as table 7;Low-temperature bending test is carried out to finished product, as a result Such as table 8.
7 Marshall Test result of table
8 low-temperature bending test result of table
Wherein, one to five cementitious matter of embodiment is 5 grades to the adhesiveness of mineral aggregate.
High-temperature behavior (at 60 DEG C): the dynamic stability of embodiment one is 3556 (secondary/mm), and embodiment two is 3830, implements Example three is 3120, example IV 2903, and embodiment five is 3022, is above the standard 1105 of asphalt for high grade road mixture (secondary/mm).
Construction and application
It is constructed according to condition shown in table 9, table 10 is actual use local climate condition.
9 mixture construction temperature controlling range (DEG C) of table
10 local climate condition of table
After using a period of time (4 years) according to the conditions shown in Table 9, road conditions are as shown in Figure 1 and Figure 2, and Surface of Trial Pavement does not go out Existing track, deformation, film such as fall off at the pavement diseases.And color keeps good under the conditions of local climate.
The above embodiment of the present invention is not limiting the scope of the present invention, and embodiments of the present invention are not limited to This, all this kind above content according to the present invention is not departing from this according to the ordinary technical knowledge and customary means of this field Modification, replacement or change under the premise of inventing above-mentioned basic fundamental thought, to other diversified forms that above structure of the present invention is made More, it should all fall within the scope and spirit of the invention.

Claims (5)

1. a kind of chromatic cementing agent mixing preparation method for material, which is characterized in that the chromatic bitumen mixture is by mass percentage It consists of the following compositions:
Wherein cementitious matter consists of the following compositions by mass percentage:
Aromatic naphtha 30-70%
Petropols 20-60%
SBS 3-20%
The big mineral aggregate is the basalt and/or limestone of partial size 10-15mm;The Mineral Material is the basalt of partial size 5-10mm And/or limestone;The small mineral aggregate is the basalt and/or limestone of partial size 0.5-5mm;The middle sand be by basalt and/ Or the Machine-made Sand that partial size is 0.35-0.5mm is made in limestone;The miberal powder is that partial size < is made in basalt and/or limestone The miberal powder of 0.35mm;
Its step are as follows:
1) it after big mineral aggregate, Mineral Material, small mineral aggregate and middle sand being heated and maintained at 175-185 DEG C in proportion, pours into stirred tank;
2) miberal powder and toner are poured into stirred tank in proportion;
3) after cementitious matter being heated to thawing, antistripping agent is added and reconciles uniformly, is subsequently poured into stirred tank;
4) it stirs being maintained the temperature in stirred tank between 165-185 DEG C, until mixture uniformity, mineral aggregate particle is all wrapped up in Cementitious matter is covered, no flower expects and without conglomeration, obtains finished product.
2. chromatic cementing agent mixing preparation method for material according to claim 1, it is characterised in that: the inorganic toner includes Iron oxide red, iron oxide yellow, iron oxide green, chromium oxide.
3. chromatic cementing agent mixing preparation method for material according to claim 1 or 2, it is characterised in that: the antistripping agent For amino amine derivative liquid antistripping agent.
4. chromatic cementing agent mixing preparation method for material according to claim 3, it is characterised in that: the heating of the step 3) Temperature is 155-180 DEG C.
5. chromatic cementing agent mixing preparation method for material according to claim 4, it is characterised in that: the mixing time of stirred tank It is 40-60 seconds.
CN201811173587.0A 2018-10-09 2018-10-09 A kind of chromatic cementing agent mixing preparation method for material Pending CN109231891A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115505275A (en) * 2021-06-28 2022-12-23 黑玄土集团有限公司 Low-temperature anti-cracking colored asphalt and preparation method thereof

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US20070062416A1 (en) * 2005-09-22 2007-03-22 Brzuskiewicz John E Patching composition having tailorable appearance properties
CN102329101A (en) * 2010-07-13 2012-01-25 上海彤路道路工程有限公司 Colored asphalt mixture and preparation method thereof
CN106866035A (en) * 2017-02-23 2017-06-20 山东交通学院 A kind of Modified coloured asphalt concrete and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070062416A1 (en) * 2005-09-22 2007-03-22 Brzuskiewicz John E Patching composition having tailorable appearance properties
CN102329101A (en) * 2010-07-13 2012-01-25 上海彤路道路工程有限公司 Colored asphalt mixture and preparation method thereof
CN106866035A (en) * 2017-02-23 2017-06-20 山东交通学院 A kind of Modified coloured asphalt concrete and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115505275A (en) * 2021-06-28 2022-12-23 黑玄土集团有限公司 Low-temperature anti-cracking colored asphalt and preparation method thereof

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Application publication date: 20190118

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