CN109231409A - It is a kind of for removing the upward flow Zero-valent Iron filtration reactor and filtration system of underwater trace concentration heavy metal - Google Patents
It is a kind of for removing the upward flow Zero-valent Iron filtration reactor and filtration system of underwater trace concentration heavy metal Download PDFInfo
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- CN109231409A CN109231409A CN201811353886.2A CN201811353886A CN109231409A CN 109231409 A CN109231409 A CN 109231409A CN 201811353886 A CN201811353886 A CN 201811353886A CN 109231409 A CN109231409 A CN 109231409A
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- Prior art keywords
- zero
- valent iron
- reactor
- supporting layer
- heavy metal
- Prior art date
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Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 302
- 238000001914 filtration Methods 0.000 title claims abstract description 104
- 229910001385 heavy metal Inorganic materials 0.000 title claims abstract description 102
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 213
- 239000000706 filtrate Substances 0.000 claims abstract description 89
- 239000000463 material Substances 0.000 claims abstract description 84
- 238000010926 purge Methods 0.000 claims abstract description 54
- 230000001105 regulatory effect Effects 0.000 claims abstract description 49
- 238000011001 backwashing Methods 0.000 claims abstract description 26
- 239000002253 acid Substances 0.000 claims abstract description 23
- 239000003814 drug Substances 0.000 claims description 80
- 238000005406 washing Methods 0.000 claims description 41
- 239000004744 fabric Substances 0.000 claims description 36
- 229910052742 iron Inorganic materials 0.000 claims description 33
- 238000005554 pickling Methods 0.000 claims description 33
- 239000000843 powder Substances 0.000 claims description 22
- 238000006243 chemical reaction Methods 0.000 claims description 19
- 229940079593 drug Drugs 0.000 claims description 17
- 238000003756 stirring Methods 0.000 claims description 17
- 239000006004 Quartz sand Substances 0.000 claims description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 16
- 239000002002 slurry Substances 0.000 claims description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 12
- 238000011068 loading method Methods 0.000 claims description 11
- 238000012377 drug delivery Methods 0.000 claims description 10
- 238000004073 vulcanization Methods 0.000 claims description 10
- 238000003860 storage Methods 0.000 claims description 7
- 238000009826 distribution Methods 0.000 claims description 5
- 150000004763 sulfides Chemical class 0.000 claims description 5
- JGIATAMCQXIDNZ-UHFFFAOYSA-N calcium sulfide Chemical group [Ca]=S JGIATAMCQXIDNZ-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 41
- 239000003344 environmental pollutant Substances 0.000 abstract description 36
- 231100000719 pollutant Toxicity 0.000 abstract description 36
- 230000008569 process Effects 0.000 abstract description 34
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract description 30
- 238000012545 processing Methods 0.000 abstract description 23
- 238000002161 passivation Methods 0.000 abstract description 17
- 230000001603 reducing effect Effects 0.000 abstract description 9
- 238000005987 sulfurization reaction Methods 0.000 abstract description 8
- 239000010865 sewage Substances 0.000 description 37
- 238000010586 diagram Methods 0.000 description 14
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 13
- 230000000694 effects Effects 0.000 description 13
- 239000002245 particle Substances 0.000 description 9
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 229910052793 cadmium Inorganic materials 0.000 description 8
- 238000013461 design Methods 0.000 description 8
- 238000001514 detection method Methods 0.000 description 8
- 230000003647 oxidation Effects 0.000 description 8
- 238000007254 oxidation reaction Methods 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 7
- 229910052753 mercury Inorganic materials 0.000 description 7
- 230000001376 precipitating effect Effects 0.000 description 7
- 230000009467 reduction Effects 0.000 description 7
- 238000001179 sorption measurement Methods 0.000 description 7
- 239000002699 waste material Substances 0.000 description 7
- 229910052785 arsenic Inorganic materials 0.000 description 6
- 239000003651 drinking water Substances 0.000 description 6
- 235000020188 drinking water Nutrition 0.000 description 6
- 230000006870 function Effects 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000003973 paint Substances 0.000 description 6
- 239000013049 sediment Substances 0.000 description 6
- 239000011651 chromium Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000000356 contaminant Substances 0.000 description 5
- 229910052745 lead Inorganic materials 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229910000838 Al alloy Inorganic materials 0.000 description 4
- 229910000975 Carbon steel Inorganic materials 0.000 description 4
- 229910001018 Cast iron Inorganic materials 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 238000004220 aggregation Methods 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 4
- 239000010962 carbon steel Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 238000000975 co-precipitation Methods 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 230000005484 gravity Effects 0.000 description 4
- 239000003673 groundwater Substances 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 3
- 125000001309 chloro group Chemical group Cl* 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 230000003628 erosive effect Effects 0.000 description 3
- 239000011152 fibreglass Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 235000014413 iron hydroxide Nutrition 0.000 description 3
- 238000002386 leaching Methods 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 239000002957 persistent organic pollutant Substances 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- 238000003911 water pollution Methods 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- DXRKLUVKXMAMOV-UHFFFAOYSA-N 3-heptadecylcatechol Chemical compound CCCCCCCCCCCCCCCCCC1=CC=CC(O)=C1O DXRKLUVKXMAMOV-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 239000004801 Chlorinated PVC Substances 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 240000002853 Nelumbo nucifera Species 0.000 description 2
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 2
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 229940059082 douche Drugs 0.000 description 2
- 229920006334 epoxy coating Polymers 0.000 description 2
- 229940056319 ferrosoferric oxide Drugs 0.000 description 2
- 238000005189 flocculation Methods 0.000 description 2
- 230000016615 flocculation Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- 239000013618 particulate matter Substances 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 150000003071 polychlorinated biphenyls Chemical class 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 230000009711 regulatory function Effects 0.000 description 2
- 239000002910 solid waste Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000005486 sulfidation Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000002604 ultrasonography Methods 0.000 description 2
- 239000003403 water pollutant Substances 0.000 description 2
- 244000226021 Anacardium occidentale Species 0.000 description 1
- DJHGAFSJWGLOIV-UHFFFAOYSA-K Arsenate3- Chemical compound [O-][As]([O-])([O-])=O DJHGAFSJWGLOIV-UHFFFAOYSA-K 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- DQMUQFUTDWISTM-UHFFFAOYSA-N O.[O-2].[Fe+2].[Fe+2].[O-2] Chemical compound O.[O-2].[Fe+2].[Fe+2].[O-2] DQMUQFUTDWISTM-UHFFFAOYSA-N 0.000 description 1
- 244000131316 Panax pseudoginseng Species 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- -1 alkyl mercury Chemical compound 0.000 description 1
- 229940000489 arsenate Drugs 0.000 description 1
- AQLMHYSWFMLWBS-UHFFFAOYSA-N arsenite(1-) Chemical compound O[As](O)[O-] AQLMHYSWFMLWBS-UHFFFAOYSA-N 0.000 description 1
- 231100000693 bioaccumulation Toxicity 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000020226 cashew nut Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 239000002384 drinking water standard Substances 0.000 description 1
- 230000008641 drought stress Effects 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000002920 hazardous waste Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000004698 iron complex Chemical class 0.000 description 1
- KAEAMHPPLLJBKF-UHFFFAOYSA-N iron(3+) sulfide Chemical compound [S-2].[S-2].[S-2].[Fe+3].[Fe+3] KAEAMHPPLLJBKF-UHFFFAOYSA-N 0.000 description 1
- 229910021506 iron(II) hydroxide Inorganic materials 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000013327 media filtration Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 238000011020 pilot scale process Methods 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/70—Treatment of water, waste water, or sewage by reduction
- C02F1/705—Reduction by metals
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/103—Arsenic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
- C02F2101/22—Chromium or chromium compounds, e.g. chromates
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/36—Organic compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/06—Controlling or monitoring parameters in water treatment pH
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Removal Of Specific Substances (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
It is a kind of for removing the upward flow Zero-valent Iron filtration reactor and filtration system of underwater trace concentration heavy metal, and in particular to a kind of filtration reactor and filtration system.Purpose is to solve the problems, such as that ZVI easily occurs hardened filtrate, short stream and is lost.Reactor is made of reactor body, regulating system and back-purge system;The bottom of reactor body is provided with water inlet pipe, and top is provided with drainpipe, and inside is from top to bottom provided with Zero-valent Iron filter material layer, the first supporting layer, the second supporting layer, third supporting layer and the 4th supporting layer.Filtration system is the series-parallel system that train, parallel system and the parallel system that reactor body is constituted are constituted.To avoid filtrate hardened, short stream and loss can occur for the present invention;Multiple pollutant can be handled simultaneously, and processing cost is low, and sulfurization can prevent from forming iron oxide passivation layer, and the pollutant and iron oxygen passivation layer of filter material surface are cleaned by way of backwashing and weak acid is washed, restores filtrate reducing property.The present invention is suitable for water process.
Description
Technical field
The invention belongs to technical field of water treatment equipment, and in particular to a kind of filtration reactor and filtration system.
Background technique
Micro and trace concentration inorganic pollution includes fluoride, selenate, arsenate, arsenite, chromate, again
Chromate, lead, cadmium, copper, zinc, mercury etc., micro and trace concentration organic pollutant includes nitrobenzene, chlorinatedorganic, chloro
Organic agricultural chemicals etc.;Micro and trace concentration inorganic pollution and organic pollutant often appear in all kinds of water pollution areas, dirty
Contaminate drinking water source, underground water source and natural water.These pollutant main sources be mining industry, machining manufacturing industry,
The heavy metal-containing waste water being discharged in the industrial processes such as chemical company, steel and non-ferrous metal metallurgy and agricultural irrigation, change
The organic pollutant given off in the industrial processes such as work synthesis tires out since this kind of micro and trace concentration pollutant has
It the features such as product property and persistence, is not easy to be degraded in the environment, easily be bioaccumulation.Contaminants drinking water source enters drink
Water system will seriously threaten human health and ecological environment security.On the other hand, contaminating enterprises need to locate to the sewage of discharge
Manage it is up to standard after can just be discharged into water body, the raising of the requirement with country to discharge standard, the dirt of micro and trace concentration
The removal of dye object is increasingly becoming the technical bottleneck that disposal of pollutants person promotes discharge standard.For example, urban wastewater treatment firm pollutant
Characterizing portion a class of pollutant highest allows concentration of emission limit value that need to reach in discharge standard (standard No. GB18918-2002)
Less than 1mg/L, it is even less than the rank of 1 μ g/L or the water outlet requirement that must not detect, such as total mercury need to be lower than 1 μ g/L, alkyl mercury
It must not detect, total cadmium need to be lower than 0.01mg/L, and total chromium need to be lower than 0.1mg/L, and Cr VI need to be lower than 0.05mg/L, and total arsenic need to be lower than
0.1mg/L, total lead need to be lower than 0.1mg/L;In selection item controlled, the concentration of emission of chloroform need to be lower than 0.3mg/L, and four
The concentration of emission of chlorination carbon need to be lower than 0.03mg/L.For blowdown enterprise, higher emission request need to be reached, i.e., need to meet receiving
Classification standard of the water body in water environment quality standard (standard No. GB3838-2002), wherein total mercury need to be lower than 0.05 μ
G/L (I/II class water) need to be lower than 0.1 μ g/L (III/IV class water), and total cadmium need to be lower than 0.001mg/L (I class water) or need to be lower than
0.005mg/L (II/III/IV class water), Cr VI need to be lower than 0.01mg/L (I class water) or need to be lower than 0.05mg/L (II/III/
IV class water), total arsenic need to be lower than 0.05mg/L (I/II/III class water) or need to be lower than 0.1mg/L (IV/V class water), and total lead need to be lower than
0.01mg/L (I/II class water) need to be lower than 0.05mg/L (III/IV class water).With country to blowdown enterprise to different receiving water
The emission request of body improves, so, the removal for being able to satisfy micro and trace concentration pollutant again for finding a kind of low cost is wanted
The technology asked, it has also become sewage treatment facility proposes the technical bottleneck of mark transformation.Conventional heavy metal pollution water treatment technology for
Advantageously, such as electric flocculation technique, coagulation-settlement process etc. have many successful stories for the removal of high density pollution object,
But electric flocculation technique, coagulation-settlement process etc. are needed when handling micro and trace concentration by increasing energy consumption and increasing medicine
The mode of agent dosage increases reaction power, and cost of sewage disposal is caused to increase at series.Entering water heavy metal concentration 102~
103When in the range of mg/L, the removal rate for reaching 99.9% that can be stable by the processing of traditional handicraft makes pollutant concentration
Reach 100~101Mg/L magnitude, and keep lower operating cost.However when pollutant concentration continues from 100~101mg/L
It is reduced to 10-2~10-3Mg/L is even lower, as mercury water outlet need to be lower than 0.05 μ g/L (5x10-5Mg/L), then need persistently to add
Excessive medicament increases current strength, or improves hydraulic detention time, therefore cause increasing substantially for processing cost.
Micro or trace concentration water outlet can effectively be reached using ion exchange and biosorption technology, but in reality
In the operation of border, since there is very strong selectivity often can guarantee when handling Single Pollution object for absorption resin and biological adsorption
Higher removal effect, but when being coexisted in water there are many heavy metal contaminants the case where, such as when zwitterion coexists, from
Son exchange and biosorption technology it is difficult to ensure that handle the heavy metal ion coexisted simultaneously.In addition, ion exchange and biological adsorption
In the process of running, redox or complex reaction do not occur for technology, and generated waste residue is needed according at danger wastes
Requirement disposition is set, whole operating cost is improved.
Zero-valent Iron (ZVI) has many advantages, such as that hypotoxicity, environmental-friendly, cheap, easy to operate, green is without secondary pollution,
One of the important technology for having become polluted water body reparation, it is dirty in processing nitrogen dye wastewater, chlorinatedorganic sewage, nitrate
It is standby in terms of the waste water controls such as water, perchlorate, herbicide, heavy metal containing sewage to have wide application prospect.ZVI comes from manufacture craft
Classification mainly includes common grinding iron powder, nanometer iron powder, iron sponge powder and water mist iron powder.ZVI particle can restore, adsorb and
The harmful substances such as precipitating removal multi-metal.The mechanism of Zero-valent Iron removal pollutant is divided into: (1) reduction of iron: iron is living
Metal is sprinkled, has stronger reproducibility to heavy metal contaminants, various heavy can be reduced into the valence of zero-valent state or hypotoxicity
State reaches processing intent.(2) light electrolysis acts on: Zero-valent Iron has electrochemical properties, generate in electrode reaction nascent state [H] and
Fe2+Redox can occur with many components in sewage to restore many contaminant degradations.(3) coagulation-co-precipitation is made
With: iron can generate unformed iron hydroxide, cotton-shaped Fe (OH) in corrosion process2With Fe (OH)3Isoreactivity ferrous components, they
With it is very strong adsorb, flocculate, cohere, surface complexing, chelating, build bridge, volume is swept, interface oxidation and co-precipitation ability, whereby may be used
Heavy metal Gu liquid circle Mian gan is controlled to move.(4) absorption-enrichment-co-precipitation: using at iron powder, nanometer iron powder and iron sponge powder
It, can be by micro and trace since iron powder surface has the strong characterization of adsorption of bigger serface when managing heavy metal contaminants in water
Concentration enriching pollutants form co-precipitate in the surface void of iron powder, then through reduction.
ZVI goes heavy metal research in water removal to have certain basis, but there is also problems for practical application.From application
Mode is classified, and adding of agent mode and media filtration mode are broadly divided into.Directly using nanometer ZVI or micron-sized ZVI as medicine
Agent is added in sewage, and the pollutant in water can be effectively treated, however during adding, ZVI easily with the oxygen in air
Dissolved oxygen in molecule and water reacts, the iron oxygen passivation layer of one layer of 1~4nm densification of Surface Creation, leads to corrosion slowly, instead
Answer active reduction.ZVI kernel is wrapped up by ferriferous oxide and separates further corrosion and the contact with pollutant, leads to whole work
Property it is low, efficiency decline.In order to overcome ZVI surface passivation, academia and engineering circles have carried out many trials, including preparation nanometer zero
Valence iron (nZVI), bimetallic system oxide, additional low-intensity magnetic field, ultrasonic wave synergistic reaction, loaded nano Zero-valent Iron, a hydridization huge sum of money
It is molten etc. to belong to ion (palladium, nickel), acid.Above-mentioned improvement can improve ZVI activity and enhancing removal efficiency of heavy metals to a certain extent, but all
In the presence of such as cost is excessively high, engineering construction is difficult, brings secondary pollution problems, such as patent CN106477689A,
CN203256019, CN103332823, CN104326595, CN105776491, CN102807272, CN102583689,
CN103112918 and CN103342410.Use ZVI that can prevent contact of the ZVI with air as filtrate, prevents it direct
Oxidation, while reducing the investment of medicine system and cooperative system.However, general filter type be it is lower to flow through filter, due to
ZVI grain diameter very little (partial size is usually between nm~um), lower to when flowing through filter running, filtrate frequent occurrence
The problem of hardened, short stream and loss, influence outlet effect.The either application of ZVI adding of agent formula or lower filter to stream ZVI is answered
With, in known application case, the first use of ZVI is only accounted for, it will by way of spoil disposal and replacement filtrate after use
ZVI is abandoned, therefore only the ZVI of surface portion is contaminated object oxidation or forms the oxide of iron, and is still had inside ZVI a large amount of excellent
The Zero-valent Iron for having neither part nor lot in reaction of matter is not used, and is resulted in waste of resources.
Summary of the invention
The present invention occurs hardened filtrate, short stream easily in order to solve the problems, such as in existing sewage disposal process ZVI and is lost, and mentions
It is a kind of for removing the upward flow Zero-valent Iron filtration reactor and filtration system of underwater trace concentration heavy metal out.
The present invention be used to remove the upward flow Zero-valent Iron filtration reactor of underwater trace concentration heavy metal by reactor body,
Regulating system and back-purge system are constituted;
The reactor body be containment cylinder tank or closed cuboid pond, the bottom of reactor body be provided with into
Water pipe, the top of reactor body are provided with drainpipe, are provided with intake pump on water inlet pipe;Inside reactor body from top to bottom
It is disposed with Zero-valent Iron filter material layer, the first supporting layer, the second supporting layer, third supporting layer and the 4th supporting layer;
4th supporting layer bottom is provided with big resistance cloth water assembly;Zero-valent Iron filter material layer lower part is provided with slight drag water distribution group
Part;The water inlet end of big resistance cloth water assembly is connected to water inlet pipe water outlet;The water inlet pipe of slight drag cloth water assembly is leant out to reaction
Device bottom part body is provided with valve on the water inlet pipe of the slight drag cloth water assembly outside reactor body;
Wherein, the water inlet end of big resistance cloth water assembly is connected to water inlet pipe intakes for reactor body;Slight drag water distribution
The water inlet pipe of component is connected to the backwash for answering device main body with the backwash tube that back-purge system bottom is arranged;
The Zero-valent Iron filter material layer is made of zeroth order iron powder;The effective grain size d10 of zeroth order iron powder in Zero-valent Iron filter material layer
It is 250 μm, nonuniformity coefficient k80 is less than 1.5, iron content >=96%;Zero-valent Iron filter material layer with a thickness of 0.5~1.5m;It is described
Supporting layer filtrate is filled in first supporting layer, the second supporting layer, third supporting layer and the 4th supporting layer;First supporting layer
In supporting layer filtrate be close with zeroth order iron powder identical in Zero-valent Iron filter material layer or with the zeroth order iron powder in Zero-valent Iron filter material layer
Spend identical quartz sand;The partial size of supporting layer filtrate is 0.8~2mm, 40~100mm of thickness in first supporting layer;Described second
Supporting layer filtrate in supporting layer be with zeroth order iron powder identical in Zero-valent Iron filter material layer or with the zeroth order in Zero-valent Iron filter material layer
The identical quartz sand of iron powder density;The partial size of supporting layer filtrate is 2~4mm, 40~100mm of thickness in second supporting layer;It is described
Supporting layer filtrate in third supporting layer be with zeroth order iron powder identical in Zero-valent Iron filter material layer or in Zero-valent Iron filter material layer
The identical quartz sand of Zero-valent Iron powder density;The partial size of supporting layer filtrate is 4~8mm, 40~100mm of thickness in third supporting layer;
Supporting layer filtrate in 4th supporting layer be with zeroth order iron powder identical in Zero-valent Iron filter material layer or with Zero-valent Iron filter material layer
In the identical quartz sand of Zero-valent Iron powder density;In 4th supporting layer the partial size of supporting layer filtrate be 8~16mm, thickness 40~
100mm;
The back-purge system is added by reverse washing tank, the first pH transmitter, blender, stirring slurry, the first pH electrode, first
Teat pipette and the first medicine storing pot are constituted;First pH transmitter, blender, stirring slurry and the first pH electrode are arranged in reverse washing tank
Portion, the first medicine storing pot are arranged outside reverse washing tank;Reverse washing tank bottom is provided with drain pipe and backwash tube, on backwash tube
It is provided with valve and delivery pump;First medicine storing pot is connected to reverse washing tank by pipeline, and the first dosing pump is arranged in the first drug storage
Pipeline between tank and reverse washing tank connects;The signal output end of first pH electrode and the control signal of the first pH transmitter input
End is connected to by signal wire, and the control signal output of the first pH transmitter and the control signal input of the first dosing pump pass through
Signal wire connection;The backwash tube of back-purge system bottom setting is connected to the water inlet pipe of slight drag cloth water assembly;Backwash system
Reverse washing tank top in system is connected to the drainpipe that the top of reactor body is arranged;
The regulating system is by adjusting tank, the 2nd pH transmitter, blender, stirring slurry, the 2nd pH electrode, the second dosing
Pump, the second medicine storing pot and third medicine storing pot are constituted;2nd pH transmitter, blender, stirring slurry and the setting of the 2nd pH electrode are being adjusted
It saves inside tank, the second medicine storing pot and the setting of third medicine storing pot are being adjusted outside tank, on the second medicine storing pot and third medicine storing pot respectively
It is provided with drug output branch pipe, is provided with valve, the second storage on the drug output branch pipe on the second medicine storing pot and third medicine storing pot
Drug output branch pipe on medicinal cupping and third medicine storing pot is connected to drug delivery trunk respectively, and drug delivery trunk and adjusting tank connect
It is logical, the second dosing pump is provided on drug delivery trunk;It adjusts tank top and is provided with water inlet pipe, adjust pot bottom and be provided with draining
It manages, is provided with valve on drainpipe;The signal output end of 2nd pH electrode and the control signal input of the 2nd pH transmitter are logical
Signal wire connection is crossed, the control signal output of the 2nd pH transmitter and the control signal input of the second dosing pump pass through signal
Line connection;
The water inlet of the drainpipe of pot bottom setting and the water inlet pipe of reactor body bottom setting is adjusted in regulating system
Connection;
The big resistance cloth water assembly is strainer head;The slight drag cloth water assembly is perforated pipe;
The reactor body material is glass reinforced plastic, aluminium alloy, cast iron, carbon steel, stainless steel, plastics or armored concrete;
The aluminium alloy, cast iron, carbon steel, stainless steel material reactor body the inner surface and the outer surface be coated with erosion resistant coating;Anti-corrosion
The material of layer material is raw lacquer, cashew resin, phenolic resin coating, epoxy-phenolic paint, epoxy coating, chlorinated polyvinyl chloride paints, drip
Blueness, furane resins, polyurethanes, inorganic zinc rich paint etc.;
Waterpower is negative when the upward flow Zero-valent Iron filtration reactor for removing underwater trace concentration heavy metal is run
Lotus is 4~30m3/h/m2;Air-land combat is 4~30min;
Wherein, regulating system has the function of that vulcanization and pH value regulatory function, the second medicine storing pot and third medicine storing pot are used respectively
In the dissolvable sulfide and acid solution of storage high concentration;It is the pH value most preferably reacted that pH value, which is 4~6, by the 2nd pH transmitter
It is set as 4~6, when the pH of the 2nd pH electrode detection sewage into adjusting tank is not in 4~6 ranges, the 2nd pH transmitter control
It is 4~6 that the second dosing pump, which is made, to adjusting tank to input acid solution pH of sewage into section tank;
Dissolvable sulfide is used to adjust the S of sewage in tank2-Dissolvable sulfide is added into adjusting tank in the adjusting of concentration
Make the S in sewage2-Concentration be 0.02~20mg/L;By the way that dissolvable sulfide is added in the pending water into regulating system
After acid, reactor body is entered by the drain pipe that regulating system bottom is arranged by regulating system treated pending water,
Vulcanized using regulating system, make filtrate that sulfurization occur, can prevent filtrate and oxygen or water effect from oxygen occurs in filtrate
It comes to the surface and forms iron oxide passivation layer, instead form ferrous sulfide or vulcanization iron layer, ferrous sulfide or iron sulfide
In S2-Reduction can be equally provided, and remove the heavy metal in water removal by way of precipitating;
The residence time of the regulating system is 15~45min;The dissolvable sulfide is dissolvable sulfide salt;It can
Dissolubility sulphide salt is calcium sulfide or vulcanized sodium;The acid solution is hydrochloric acid of the pH value between 1~5;
Wherein, back-purge system has the function of backwashing function and pickling;First medicine storing pot is for storing acid solution;When with
In removal underwater trace concentration heavy metal upward flow Zero-valent Iron filtration reactor in Zero-valent Iron filtrate due to oxidation and by
When gradually losing processing reducing power, the first pH transmitter controls the first dosing pump and is input to the acid solution in the first medicine storing pot instead
It is 4~6 that backwashing water pH is adjusted in can,douche;Back-purge system is to the upward flow zero for removing underwater trace concentration heavy metal
The backwashing water that input pH is 4~6 in valence iron filtration reactor carries out pickling, and the first pH transmitter setting value is in acid cleaning process
4~6;Pickling is the di-iron trioxide that the attachment of Zero-valent Iron filter material surface is dissolved in by chemical action, ferroso-ferric oxide, hydroxide
Ferrous and iron hydroxide, Zero-valent Iron is exposed again, achievees the purpose that recovery and reduction adsorption ability.Backwash is to pass through
The physical action of water flow scrubs filter material surface, and the iron oxide that the hydroxide, particulate matter, pickling of the iron of attachment are fallen off is passivated
Layer, pollutant are co-precipitated the sediments such as residue and heavy metal-iron complex and remove from filter material surface, reduce for removing trace in water removal
Measure the head resistance of the upward flow Zero-valent Iron filtration reactor of concentration heavy metal;
The period using back-purge system pickling was 1~4 week, and the pickling time of each pickling cycle is 5~30
Minute;
Hydraulic loading when being backwashed using back-purge system is 30~40m3/h/m2;Backwashing period is 24~72
Hour, the backwashing time of each backwashing period is 5~30 minutes.
The upward flow Zero-valent Iron filtration reactor that the present invention is used to remove underwater trace concentration heavy metal has following beneficial
Effect:
1, apparatus of the present invention treatment process, which does not need other ancillary equipments such as electromagnetism or ultrasound, to occur to avoid filtrate
Hardened, short stream and loss;The present invention is used to remove in the upward flow Zero-valent Iron filtration reactor of underwater trace concentration heavy metal, and zero
Valence iron powder filtering material particle is in the suspended state of gravity and buoyant equilibrium, and sewage, which is filled between zeroth order iron powder filtering material particle, makes zero
The phenomenon that valence iron filter material layer is in expansion suspended form, has prevented hardened filtrate and short stream;Sewage is entered anti-by reactor lower part
It answers in device, reactor is discharged by reactor top, zeroth order iron powder filtering material particle is suspended in sewage, therefore in zeroth order iron powder filtrate
Particle will not sink to be leaked into inlet pipeline, will not be overflowed from discharge pipe line;
2, in upward flow Zero-valent Iron filtration reactor operational process of the present invention for removing underwater trace concentration heavy metal,
Filter process only needs two parameters of expansion rate and hydraulic detention time that filtrate entirety is realized by control intake pressure, i.e., adjustable
Concentration for the treatment of up to standard required for drought stress process is horizontal, therefore easy to operate;
3, in upward flow Zero-valent Iron filtration reactor operational process of the present invention for removing underwater trace concentration heavy metal,
Make filtrate that sulfurization (Sulfidation) occur by adding dissolvable sulfide into water.Sulfurization can prevent from filtering
Material occurs to aoxidize and forms iron oxide passivation layer with oxygen or water effect, replaces to form ferrous sulfide or vulcanization iron layer;Simultaneously
The ferrous sulfide or iron sulfide of nascent state can equally provide reduction, and the huge sum of money in water removal can be removed by way of precipitating
Belong to;
4. in longtime running of the present invention, the pollutant such as iron network of filter material surface is cleaned by way of backwashing and weak acid is washed
The precipitating such as object is closed, while removing iron oxygen passivation layer, restores filtrate reducing property;Therefore filtrate has obtained the recasting of pickling repeatedly, mentions
The service life of high ZVI filtrate achievees the purpose that sufficiently to adsorb and use to greatest extent;
5, compared with conventional processing technique, the present invention utilizes the strong reducing property of Zero-valent Iron, can handle a variety of pollutions simultaneously
Object, processing cost is low, and water pollutant reaches trace concentration or less out;The pollutant that the present invention can be handled simultaneously includes a huge sum of money
Category, fluoride and chlorinated organics;Heavy metal is to compare in the metal activity series table such as Pb, As, Cd, Cr (sexavalence), Ni, Cu, Hg
The more stable metal of iron;Chlorinated organics are Polychlorinated biphenyls, containing chloro pesticide etc.;
6, in the present invention, after Zero-valent Iron filtrate is by exhaustive oxidation or adsorption saturation, backwash or pickling can not be passed through again
When restoring processing capacity again, these filtrates become discarded filtrate;The waste material and residue that apparatus of the present invention generate can pass through poison
Property leaching test, is not belonging to danger wastes.
It is filtered using the upward flow Zero-valent Iron for removing underwater trace concentration heavy metal that above-mentioned reactor body is constituted
Reactor train is made of multiple reactor bodies, regulating system and back-purge system;
The water inlet pipe that the drainpipe and first reactor body bottom that pot bottom setting is adjusted in regulating system are arranged
Water inlet connection;The water inlet of the drainpipe of previous reactor body and the latter reactor body in adjacent reactor body
The drainpipe of pipe connection, the setting of the last one reactor body top is connected to the reverse washing tank top in back-purge system;Instead
The backwash tube of rinse-system bottom setting is connected to the water inlet end of the slight drag cloth water assembly in reactor body respectively;
The upward flow Zero-valent Iron filtration reactor train that the present invention is used to remove underwater trace concentration heavy metal can be with
Longer air-land combat is provided, pollutant passes through the process filtered step by step, and pollutant concentration reduces step by step in sewage;Series connection
Each the pollutant process rate of the upward flow Zero-valent Iron filtration reactor for removing underwater trace concentration heavy metal is in system
80~99%;
It is filtered using the upward flow Zero-valent Iron for removing underwater trace concentration heavy metal that above-mentioned reactor body is constituted
Reactor parallel system is by multiple reactor bodies, regulating system, back-purge system, water inlet supervisor, drain header and backwash
Supervisor is constituted;Multiple reactor bodies are set side by side, and the drainpipe and water inlet supervisor that pot bottom setting is adjusted in regulating system connect
Logical, the water inlet pipe of each reactor body is connected to water inlet supervisor respectively, the drainpipe of each reactor body respectively with draining
Supervisor's connection, drain header are connected to the reverse washing tank top in back-purge system;The backwash of back-purge system bottom setting
Pipe is connected to backwash supervisor, and the water inlet end of the slight drag cloth water assembly in reactor body is connected to backwash supervisor respectively;
Using above-mentioned for removing the upward flow Zero-valent Iron filtration reactor parallel system structure of underwater trace concentration heavy metal
At for removing the upward flow Zero-valent Iron filtration reactor series-parallel system of underwater trace concentration heavy metal by multiple reactions singly
Member is constituted;The reaction member is the upward flow Zero-valent Iron filtration reactor taken in conjunction for removing underwater trace concentration heavy metal
System;It is adjusted in the drain pipe and the latter reaction member of the reverse washing tank bottom setting of back-purge system in previous reaction member
The water inlet pipe of the adjusting tank top setting of system is connected to by unit connecting tube;
The upward flow Zero-valent Iron filtration reactor series-parallel system that the present invention is used to remove underwater trace concentration heavy metal is suitable
When larger for sewage quantity, and in sewage pollutant concentration fluctuation it is larger when, longer air-land combat, pollutant are provided
By the process filtered step by step, pollutant concentration reduces step by step in sewage;Extend the processing time, and can provide additional standby
Use system.
Detailed description of the invention
Fig. 1 is the upward flow Zero-valent Iron filtration reactor structural schematic diagram for removing underwater trace concentration heavy metal;
Fig. 2 is the schematic diagram that hardened phenomenon occurs for the existing lower ZVI into stream filter process;Arrow direction is water in Fig. 2
Flow direction;
Fig. 3 is filtrate occupied state in the upward flow Zero-valent Iron filtration reactor for removing underwater trace concentration heavy metal
Schematic diagram;
Fig. 4 is filtrate suspended state in the upward flow Zero-valent Iron filtration reactor for removing underwater trace concentration heavy metal
Schematic diagram;
Fig. 5 is weight in the upward flow Zero-valent Iron filtration reactor backwash process for removing underwater trace concentration heavy metal
The sediment removal process schematic diagram such as metal-iron complex;
Fig. 6 is iron oxide passivation layer in the upward flow Zero-valent Iron filtration reactor for removing underwater trace concentration heavy metal
Removal process schematic diagram;
Fig. 7 be in upward flow Zero-valent Iron filtration reactor for removing underwater trace concentration heavy metal FeS layer or
Vulcanize the forming process schematic diagram of iron layer;
Fig. 8 is to illustrate for removing the upward flow Zero-valent Iron filtration reactor train of underwater trace concentration heavy metal
Figure;
Fig. 9 is to illustrate for removing the upward flow Zero-valent Iron filtration reactor parallel system of underwater trace concentration heavy metal
Figure;
Figure 10 is to show for removing the upward flow Zero-valent Iron filtration reactor series-parallel system of underwater trace concentration heavy metal
It is intended to.
Specific embodiment:
The technical solution of the present invention is not limited to the following list, further includes between each specific embodiment
Any reasonable combination.
Specific embodiment 1: illustrating that present embodiment, present embodiment are dense for removing underwater trace in conjunction with Fig. 1~8
The upward flow Zero-valent Iron filtration reactor of degree heavy metal is made of reactor body 1, regulating system 3 and back-purge system 4;
The reactor body 1 is that containment cylinder tank or closed cuboid pond, the bottom of reactor body 1 are provided with
Water inlet pipe 11, the top of reactor body 1 are provided with drainpipe 13, intake pump 12 are provided on water inlet pipe 11;Reactor body 1
Inside is from top to bottom disposed with Zero-valent Iron filter material layer 18, the first supporting layer 14, the second supporting layer 15,16 and of third supporting layer
4th supporting layer 17;
4th supporting layer, 17 bottom is provided with big resistance cloth water assembly 22;18 lower part of Zero-valent Iron filter material layer is provided with slight drag
Cloth water assembly 23;The water inlet end of big resistance cloth water assembly 22 is connected to 11 water outlet of water inlet pipe;Slight drag cloth water assembly 23 into
Water pipe is leant out to 1 bottom of reactor body, is provided with valve on the water inlet pipe of the slight drag cloth water assembly 23 outside reactor body 1
Door;The Zero-valent Iron filter material layer 18 is made of zeroth order iron powder;The effective grain size d10 of zeroth order iron powder in Zero-valent Iron filter material layer 18 is
250 μm, nonuniformity coefficient k80 is less than 1.5, iron content >=96%;Zero-valent Iron filter material layer 18 with a thickness of 0.5~1.5m;
Support is filled in first supporting layer 14, the second supporting layer 15, third supporting layer 16 and the 4th supporting layer 17
Layer filtrate;Supporting layer filtrate in first supporting layer 14 is with zeroth order iron powder identical in Zero-valent Iron filter material layer 18 or with zero
The identical quartz sand of Zero-valent Iron powder density in valence iron filter material layer 18;The partial size of supporting layer filtrate is 0.8 in first supporting layer 14
~2mm, 40~100mm of thickness;Supporting layer filtrate in second supporting layer 15 is identical with Zero-valent Iron filter material layer 18
Zeroth order iron powder or quartz sand identical with the Zero-valent Iron powder density in Zero-valent Iron filter material layer 18;Supporting layer is filtered in second supporting layer 15
The partial size of material is 2~4mm, 40~100mm of thickness;Supporting layer filtrate in the third supporting layer 16 is and Zero-valent Iron filter material layer
Identical zeroth order iron powder or quartz sand identical with the Zero-valent Iron powder density in Zero-valent Iron filter material layer 18 in 18;Third supporting layer 16
The partial size of middle supporting layer filtrate is 4~8mm, 40~100mm of thickness;Supporting layer filtrate in 4th supporting layer 17 is and zero
Identical zeroth order iron powder or quartz sand identical with the Zero-valent Iron powder density in Zero-valent Iron filter material layer 18 in valence iron filter material layer 18;The
The partial size of supporting layer filtrate is 8~16mm, 40~100mm of thickness in four supporting layers 17.
Fig. 1 is the upward flow Zero-valent Iron filtration reactor structural schematic diagram for removing underwater trace concentration heavy metal;Fig. 2
The schematic diagram of hardened phenomenon occurs for the existing lower ZVI into stream filter process;Arrow direction is water (flow) direction in Fig. 2;Due to
The lower gravity to the waterpower squeezing action of stream and filtrate itself, causes filtrate to generate aggregation during the filtration process.After aggregation
Filter material layer sufficient time of filtration can not be provided, therefore water flow can only be flowed by the gap between hardened piece, generate short stream,
Sewage can not come into full contact with filtrate, influence filter effect and reaction effect;
Fig. 3 is filtrate occupied state in the upward flow Zero-valent Iron filtration reactor for removing underwater trace concentration heavy metal
Schematic diagram;Hardened phenomenon easily occurs for filtrate during upward flow filtration in the prior art, the reason is that the gradation due to filtrate does not conform to
Reason, density is bigger than normal, and the relatively low factor of hydraulic loading of filtering, causes filtrate during the filtration process without forming ideal suspend
State, since the effect of gravity generates aggregation.Filter material layer after aggregation can not provide sufficient time of filtration, therefore water flow can only
By the gap flowing between hardened piece, short stream is generated, can not be come into full contact with filtrate, influence filter effect and reaction effect.
The effective grain size d10 of zeroth order iron powder is 250 μm in Fig. 3, and nonuniformity coefficient k80 is less than 1.5, the ferrous powder granules of small particle after filling
It is interspersed between large-sized ferrous powder granules, forms uniform gap.Fig. 4 is for removing underwater trace concentration heavy metal
The filtrate suspended state schematic diagram into stream Zero-valent Iron filtration reactor;Fig. 4 can be seen that the uniform of big resistance water distribution system generation
Upward flow, filtrate entirety under hydraulic loading expansion rate be 5~10% between, formed suspended state, uniform fluid flow distribution
Between the uniform gap that bulky grain and short grained Zero-valent Iron filtrate generate.Fig. 5 is for removing a underwater trace concentration huge sum of money
The sediment removal process schematic diagram such as heavy metal-iron complex in the upward flow Zero-valent Iron filtration reactor backwash process of category;
Fig. 5 it is found that the sediments such as a large amount of heavy metal-iron complex can be generated after filtering after a period of time, between ferrous powder granules,
Gap between obstruction filtrate;By the backwash of high water-base fluid, water flow can remove the sediment of these obstructions, discharge filtrate
Gap reduces head resistance when conventional upward flow filtration;Fig. 6 is the upward flow zero for removing underwater trace concentration heavy metal
Iron oxide passivation layer removal process schematic diagram in valence iron filtration reactor;After filtering after a period of time, ferrous powder granules surface
One layer is formed by Fe2O3、Fe4O3Or Fe (OH)3The iron oxide passivation layer that the oxide of equal iron is formed.Due to depositing for the passivation layer
The active Zero-valent Iron of filter material surface can not come into full contact with filtered water stream, lose reducing power.Present embodiment passes through weak
Acid backwash removes iron oxide passivation layer, and weak acid backwash uses the weak acid of pH=4~6, and it is blunt can effectively to dissolve iron oxide
Change layer, while again will not be by zeroth order dissolved ferric iron;Fig. 7 is to filter for removing the upward flow Zero-valent Iron of underwater trace concentration heavy metal
The forming process schematic diagram of FeS layer or vulcanization iron layer in reactor;When there are a certain amount of S in water flow2-When ion, Fe
And the Fe that Fe is formed in oxidation-reduction process2+And Fe3+Ion meeting and S2-Sulfurization occurs, forms FeS and Fe2S3, take
Generation iron oxide passivation layer, due to S in the ferrous sulfide or iron sulfide of these nascent states2-Presence can equally provide and go back original work
With.
The upward flow Zero-valent Iron filtration reactor that present embodiment is used to remove underwater trace concentration heavy metal has following
The utility model has the advantages that
1, present embodiment device treatment process do not need other ancillary equipments such as electromagnetism or ultrasound can be to avoid filtrate
Hardened, short stream and loss occurs;The upward flow Zero-valent Iron filtering that present embodiment is used to remove underwater trace concentration heavy metal is anti-
It answers in device, zeroth order iron powder filtering material particle is in the suspended state of gravity and buoyant equilibrium, and sewage is filled in zeroth order iron powder filtrate
The phenomenon that making Zero-valent Iron filter material layer 18 be in expansion suspended form between grain, having prevented hardened filtrate and short stream;Sewage is by reacting
Device lower part enters in reactor, and reactor is discharged by reactor top, and zeroth order iron powder filtering material particle is suspended in sewage, therefore
Zeroth order iron powder filtering material particle will not sink to be leaked into inlet pipeline, will not be overflowed from discharge pipe line;
2, the upward flow Zero-valent Iron filtration reactor that present embodiment is used to remove underwater trace concentration heavy metal was run
Cheng Zhong, filter process only need two parameters of expansion rate and hydraulic detention time that filtrate entirety is realized by control intake pressure,
Concentration for the treatment of up to standard required for i.e. controllable water treatment procedure is horizontal, therefore easy to operate;
3, the upward flow Zero-valent Iron filtration reactor that present embodiment is used to remove underwater trace concentration heavy metal was run
Cheng Zhong makes filtrate that sulfurization (Sulfidation) occur by adding dissolvable sulfide into water.Sulfurization can be to prevent
Only filtrate and the effect of oxygen or water occur to aoxidize and form iron oxide passivation layer, replace to form ferrous sulfide or vulcanization iron layer;
The ferrous sulfide or iron sulfide of synkaingenesis state can equally provide reduction, can be gone by way of precipitating in water removal
Heavy metal;
4. in present embodiment longtime running, cleaning the pollutant of filter material surface such as by way of backwashing and weak acid is washed
The precipitating such as iron complex, while iron oxygen passivation layer is removed, restore filtrate reducing property;Therefore filtrate has obtained pickling weight repeatedly
System improves the service life of ZVI filtrate, achievees the purpose that sufficiently to adsorb and use to greatest extent;
5, compared with conventional processing technique, present embodiment utilizes the strong reducing property of Zero-valent Iron, can handle simultaneously a variety of
Pollutant, processing cost is low, and water pollutant reaches trace concentration or less out;The pollutant that present embodiment can be handled simultaneously
Including heavy metal, fluoride and chlorinated organics;Heavy metal is that the movable metallics such as Pb, As, Cd, Cr (sexavalence), Ni, Cu, Hg are suitable
The metal more more stable than iron in sequence table;Chlorinated organics are Polychlorinated biphenyls, containing chloro pesticide etc.;
6, in present embodiment, after Zero-valent Iron filtrate is by exhaustive oxidation or adsorption saturation, can not again by backwash or
When pickling restores processing capacity again, these filtrates become discarded filtrate;The waste material and residue energy that present embodiment device generates
Enough by toxic leaching test, it is not belonging to danger wastes.
Specific embodiment 2: the present embodiment is different from the first embodiment in that: the big resistance cloth water assembly
22 be strainer head;The slight drag cloth water assembly 23 is perforated pipe.Other steps and parameter are same as the specific embodiment one.
Specific embodiment 3: the present embodiment is different from the first and the second embodiment in that: the reactor body 1
Material is glass reinforced plastic, aluminium alloy, cast iron, carbon steel, stainless steel, plastics or armored concrete;The aluminium alloy, cast iron, carbon steel, no
The inner surface and the outer surface of the reactor body 1 for steel material of becoming rusty is coated with erosion resistant coating;The material of erosion resistant coating material is raw lacquer, laccol
Resin, phenolic resin coating, epoxy-phenolic paint, epoxy coating, chlorinated polyvinyl chloride paints, pitch, furane resins, polyurethane
Ester or inorganic zinc rich paint.Other steps and parameter are the same as one or two specific embodiments.
Specific embodiment 4: unlike one of present embodiment and specific embodiment one to three: described is used for
Hydraulic loading is 4~30m when removing the upward flow Zero-valent Iron filtration reactor operation of underwater trace concentration heavy metal3/h/m2;It is empty
Bed time of contact is 4~30min.Other steps and parameter are identical as one of specific embodiment one to three.
Specific embodiment 5: unlike one of present embodiment and specific embodiment one to four: the adjusting is
The residence time of system 3 is 15~45min;The dissolvable sulfide is dissolvable sulfide salt;Dissolvable sulfide salt is sulphur
Change calcium or vulcanized sodium;The acid solution is the hydrochloric acid that pH value is 1~5.Other steps and parameter and specific embodiment one to four
One of it is identical.
Specific embodiment 6: unlike one of present embodiment and specific embodiment one to five: described using anti-
The period of 4 pickling of rinse-system was 1~4 week, and the pickling time of each pickling cycle is 5~30 minutes.Other steps and ginseng
Number is identical as one of specific embodiment one to five.
Specific embodiment 7: unlike one of present embodiment and specific embodiment one to six: described using anti-
Hydraulic loading when rinse-system 4 backwashes is 30~40m3/h/m2;Backwashing period is 24~72 hours, each backwash week
The backwashing time of phase is 5~30 minutes.Other steps and parameter are identical as one of specific embodiment one to six.
Specific embodiment 8: embodiment is described with reference to Fig.8, present embodiment utilizes the composition of reactor body 1
For remove the upward flow Zero-valent Iron filtration reactor train of underwater trace concentration heavy metal by multiple reactor bodies 1,
Regulating system 3 and back-purge system 4 are constituted;
The drainpipe of pot bottom setting and the water inlet pipe of first 1 bottom of reactor body setting are adjusted in regulating system 3
11 water inlet connection;The drainpipe 13 of previous reactor body 1 and the latter reactor master in adjacent reactor body 1
The water inlet pipe 11 of body 1 is connected to, the drainpipe 13 of the last one 1 top of reactor body setting and the recoil in back-purge system 4
The connection of cleaning of evaporator top;4 bottom of back-purge system setting backwash tube respectively with the slight drag cloth water assembly in reactor body 1
23 water inlet end connection.
Present embodiment is used to remove the upward flow Zero-valent Iron filtration reactor train of underwater trace concentration heavy metal
Longer air-land combat can be provided, pollutant passes through the process filtered step by step, and pollutant concentration reduces step by step in sewage;
Each for removing the pollutant process of the upward flow Zero-valent Iron filtration reactor of underwater trace concentration heavy metal in train
Rate is 80~99%.
Specific embodiment 9: embodiment is described with reference to Fig.9, present embodiment utilizes the composition of reactor body 1
For remove the upward flow Zero-valent Iron filtration reactor parallel system of underwater trace concentration heavy metal by multiple reactor bodies 1,
Regulating system 3, back-purge system 4, water inlet supervisor 19, drain header 20 and backwash supervisor 21 are constituted;Multiple reactor bodies 1
It is set side by side, the drainpipe that pot bottom setting is adjusted in regulating system 3 is connected to water inlet supervisor 19, each reactor body 1
Water inlet pipe 11 is connected to water inlet supervisor 19 respectively, and the drainpipe 13 of each reactor body 1 is connected to drain header 20 respectively, row
Water supervisor 20 is connected to the reverse washing tank top in back-purge system 4;The backwash tube of 4 bottom of back-purge system setting and recoil
21 connection of supervisor is washed, the water inlet end of the slight drag cloth water assembly 23 in reactor body 1 is connected to backwash supervisor 21 respectively.
Present embodiment is used to remove the upward flow Zero-valent Iron filtration reactor parallel system of underwater trace concentration heavy metal
Additional back-up system can be provided, be suitable for water and fluctuate biggish sewage treatment requirement.
Specific embodiment 10: embodiment is described with reference to Fig.10, present embodiment is utilized for removing underwater trace
What the upward flow Zero-valent Iron filtration reactor parallel system of concentration heavy metal was constituted is used to remove underwater trace concentration heavy metal
Upward flow Zero-valent Iron filtration reactor series-parallel system is made of multiple reaction members;The reaction member is for going in water removal
The upward flow Zero-valent Iron filtration reactor parallel system of trace concentration heavy metal;Back-purge system 4 in previous reaction member
The water inlet pipe for adjusting the setting of tank top of regulating system 3 is logical in the drain pipe and the latter reaction member of the setting of reverse washing tank bottom
Cross the connection of unit connecting tube 24.
Present embodiment is used to remove the upward flow Zero-valent Iron filtration reactor of underwater trace concentration heavy metal
System be suitable for sewage quantity it is larger when, and when pollutant concentration fluctuation is larger in sewage, provide longer air-land combat, it is dirty
Dye object passes through the process filtered step by step, and pollutant concentration reduces step by step in sewage;Extend the processing time, and can provide additional
Back-up system.
Specific embodiment 11: the present embodiment is different from the first embodiment in that: the back-purge system 4 by
Reverse washing tank, the first pH transmitter 41, blender, stirring slurry, the first pH electrode 42, the first dosing pump 43 and the first medicine storing pot 44
It constitutes;First pH transmitter 41, blender, stirring slurry and the first pH electrode 42 are arranged inside reverse washing tank, the first medicine storing pot
44 are arranged outside reverse washing tank;Reverse washing tank bottom is provided with drain pipe and backwash tube, is provided with valve on backwash tube
And delivery pump;First medicine storing pot 44 is connected to reverse washing tank by pipeline, the setting of the first dosing pump 43 the first medicine storing pot 44 with
Pipeline between reverse washing tank connects;The signal output end of first pH electrode 42 and the control signal of the first pH transmitter 41 input
End is connected to by signal wire, the control signal input of the control signal output of the first pH transmitter 41 and the first dosing pump 43
It is connected to by signal wire;
The backwash tube of 4 bottom of back-purge system setting is connected to the water inlet pipe of slight drag cloth water assembly 23;Backwash system
Reverse washing tank top in system 4 is connected to the drainpipe 13 that the top of reactor body 1 is arranged.Other steps and parameter and specific
Embodiment one is identical.
Present embodiment back-purge system 4 has the function of backwashing function and pickling;First medicine storing pot 44 is for storing acid
Solution;When in the upward flow Zero-valent Iron filtration reactor for removing underwater trace concentration heavy metal Zero-valent Iron filtrate due to oxidation
When acting on and gradually losing processing reducing power, the first pH transmitter 41 controls the first dosing pump 43 will be in the first medicine storing pot 44
It is 4~6 that acid solution, which is input in reverse washing tank and adjusts backwashing water pH,;Back-purge system 4 is to for removing underwater trace concentration
PH is inputted in the upward flow Zero-valent Iron filtration reactor of heavy metal for 4~6 backwashing water progress pickling, first in acid cleaning process
41 setting value of pH transmitter is 4~6;Pickling is that three oxidations two of Zero-valent Iron filter material surface attachment are dissolved in by chemical action
Zero-valent Iron is exposed again, reaches recovery and reduction adsorption energy by iron, ferroso-ferric oxide, ferrous hydroxide and iron hydroxide
The purpose of power.Backwash is to scrub filter material surface by the physical action of water flow, by the hydroxide of the iron of attachment, particulate matter,
Iron oxide passivation layer that pickling falls off, the pollutant co-precipitation sediments such as residue and heavy metal-iron complex are gone from filter material surface
It removes, reduces the head resistance for removing the upward flow Zero-valent Iron filtration reactor of underwater trace concentration heavy metal;
Specific embodiment 12: the present embodiment is different from the first embodiment in that: the regulating system 3 is by adjusting
Save tank, the 2nd pH transmitter 31, blender, stirring slurry, the 2nd pH electrode 32, the second dosing pump 33, the second medicine storing pot 34 and the
Three medicine storing pots 35 are constituted;2nd pH transmitter 31, blender, stirring slurry and the setting of the 2nd pH electrode 32 are being adjusted inside tank, the
Two medicine storing pots 34 and the setting of third medicine storing pot 35 are being adjusted outside tank, are respectively set on the second medicine storing pot 34 and third medicine storing pot 35
There is drug to export branch pipe, is provided with valve, the second storage on the drug output branch pipe on the second medicine storing pot 34 and third medicine storing pot 35
Drug output branch pipe on medicinal cupping 34 and third medicine storing pot 35 is connected to drug delivery trunk respectively, drug delivery trunk and adjusting
Tank is connected to, and is provided with the second dosing pump 33 on drug delivery trunk;It adjusts tank top and is provided with water inlet pipe, adjust pot bottom setting
There is drainpipe, is provided with valve on drainpipe;The control of the signal output end and the 2nd pH transmitter 31 of 2nd pH electrode 32 is believed
Number input terminal passes through signal wire and is connected to, the control signal of the control signal output of the 2nd pH transmitter 31 and the second dosing pump 33
Input terminal is connected to by signal wire;
In regulating system 3 adjust pot bottom setting drainpipe and 1 bottom of reactor body setting water inlet pipe 11 into
Mouth of a river connection.Other steps and parameter are identical with embodiment two.
Present embodiment regulating system 3 has the function of vulcanization and pH value regulatory function, the second medicine storing pot 34 and third drug storage
Tank 35 is respectively used to the dissolvable sulfide and acid solution of storage high concentration;It is the pH value most preferably reacted that pH value, which is 4~6, by
Two pH transmitters 31 are set as 4~6, when the 2nd pH electrode 32 detects the pH for adjusting sewage in tank not in 4~6 ranges,
It is 4~6 that 2nd pH transmitter 31, which controls the second dosing pump 33 to adjusting tank to input acid solution pH of sewage into section tank,;
Dissolvable sulfide is used to adjust the S of sewage in tank2-Dissolvable sulfide is added into adjusting tank in the adjusting of concentration
Make the S in sewage2-Concentration be 0.02~20mg/L;By the way that soluble vulcanization is added in the pending water into regulating system 3
After object and acid, reactor master is entered by the drain pipe that 3 bottom of regulating system is arranged by treated the pending water of regulating system 3
Body 1 is vulcanized using regulating system 3, makes filtrate that sulfurization occur, and can be prevented filtrate and oxygen or water effect from oxygen occurs and be existed
Filter material surface simultaneously forms iron oxide passivation layer, instead forms ferrous sulfide or vulcanization iron layer, ferrous sulfide or sulphur
Change the S in iron2-Reduction can be equally provided, and remove the heavy metal in water removal by way of precipitating.
Beneficial effects of the present invention are verified using following embodiment:
Embodiment 1:
The present embodiment is used to remove the upward flow Zero-valent Iron filtration reactor of underwater trace concentration heavy metal by reactor master
Body 1, regulating system 3 and back-purge system 4 are constituted;
The reactor body 1 is that containment cylinder tank or closed cuboid pond, the bottom of reactor body 1 are provided with
Water inlet pipe 11, the top of reactor body 1 are provided with drainpipe 13, intake pump 12 are provided on water inlet pipe 11;Reactor body 1
Inside is from top to bottom disposed with Zero-valent Iron filter material layer 18, the first supporting layer 14, the second supporting layer 15,16 and of third supporting layer
4th supporting layer 17;
The regulating system 3 is by adjusting tank, the 2nd pH transmitter 31, blender, stirring slurry, the 2nd pH electrode 32, second
Dosing pump 33, the second medicine storing pot 34 and third medicine storing pot 35 are constituted;2nd pH transmitter 31, blender, stirring slurry and the 2nd pH
The setting of electrode 32 is being adjusted inside tank, and the second medicine storing pot 34 and the setting of third medicine storing pot 35 are being adjusted outside tank, the second medicine storing pot
34 and third medicine storing pot 35 on be respectively arranged with drug output branch pipe, the drug on the second medicine storing pot 34 and third medicine storing pot 35 is defeated
Valve is provided on branch pipe out, the drug output branch pipe on the second medicine storing pot 34 and third medicine storing pot 35 is total with drug output respectively
Pipe connection, drug delivery trunk are connected to tank is adjusted, and the second dosing pump 33 is provided on drug delivery trunk;Tank top is adjusted to set
It is equipped with water inlet pipe, pot bottom is adjusted and is provided with drainpipe, be provided with valve on drainpipe;The signal output end of 2nd pH electrode 32
It is connected to the control signal input of the 2nd pH transmitter 31 by signal wire, the control signal output of the 2nd pH transmitter 31
It is connected to the control signal input of the second dosing pump 33 by signal wire;
The back-purge system 4 by reverse washing tank, the first pH transmitter 41, blender, stirring slurry, the first pH electrode 42,
First dosing pump 43 and the first medicine storing pot 44 are constituted;First pH transmitter 41, blender, stirring slurry and the setting of the first pH electrode 42
Inside reverse washing tank, the first medicine storing pot 44 is arranged outside reverse washing tank;Reverse washing tank bottom is provided with drain pipe and recoil
Pipe is washed, is provided with valve and delivery pump on backwash tube;First medicine storing pot 44 is connected to reverse washing tank by pipeline, the first dosing
The pipeline that pump 43 is arranged between the first medicine storing pot 44 and reverse washing tank connects;The signal output end and first of first pH electrode 42
The control signal input of pH transmitter 41 is connected to by signal wire, the control signal output and first of the first pH transmitter 41
The control signal input of dosing pump 43 is connected to by signal wire;
4th supporting layer, 17 bottom is provided with big resistance cloth water assembly 22;18 lower part of Zero-valent Iron filter material layer is provided with slight drag
Cloth water assembly 23;The water inlet end of big resistance cloth water assembly 22 is connected to 11 water outlet of water inlet pipe;Slight drag cloth water assembly 23 into
Water pipe leans out to 1 bottom of reactor body and is connected to the backwash tube of 4 bottom of back-purge system setting, reactor body 1
Valve is provided on the water inlet pipe of external slight drag cloth water assembly 23;The drainpipe of pot bottom setting is adjusted in regulating system 3
It is connected to the water inlet of the water inlet pipe 11 of 1 bottom of reactor body setting;Reactor body 1 top setting drainpipe 13 with
Reverse washing tank top connection in back-purge system 4;
The Zero-valent Iron filter material layer 18 is made of zeroth order iron powder;The effective grain size of zeroth order iron powder in Zero-valent Iron filter material layer 18
D10 is 250 μm, and nonuniformity coefficient k80 is less than 1.5, iron content >=96%;Zero-valent Iron filter material layer 18 with a thickness of 1m;
Support is filled in first supporting layer 14, the second supporting layer 15, third supporting layer 16 and the 4th supporting layer 17
Layer filtrate;Supporting layer filtrate in first supporting layer 14 is with zeroth order iron powder identical in Zero-valent Iron filter material layer 18 or with zero
The identical quartz sand of Zero-valent Iron powder density in valence iron filter material layer 18;The partial size of supporting layer filtrate is 1mm in first supporting layer 14,
Thickness 40mm;Supporting layer filtrate in second supporting layer 15 be with zeroth order iron powder identical in Zero-valent Iron filter material layer 18 or with
The identical quartz sand of Zero-valent Iron powder density in Zero-valent Iron filter material layer 18;The partial size of supporting layer filtrate is in second supporting layer 15
3mm, thickness 40mm;Supporting layer filtrate in the third supporting layer 16 is and zeroth order iron powder identical in Zero-valent Iron filter material layer 18
Or quartz sand identical with the Zero-valent Iron powder density in Zero-valent Iron filter material layer 18;The partial size of supporting layer filtrate in third supporting layer 16
For 6mm, thickness 40mm;Supporting layer filtrate in 4th supporting layer 17 is and identical Zero-valent Iron in Zero-valent Iron filter material layer 18
Powder or quartz sand identical with the Zero-valent Iron powder density in Zero-valent Iron filter material layer 18;The grain of supporting layer filtrate in 4th supporting layer 17
Diameter is 10mm, thickness 40mm.The big resistance cloth water assembly 22 is strainer head;The slight drag cloth water assembly 23 is perforation
Pipe;1 material of reactor body is glass reinforced plastic;
For removing the design discharge of the upward flow Zero-valent Iron filtration reactor of underwater trace concentration heavy metal in embodiment 1
1.2 ton/hours, 24 hours continuous operations design air-land combat 10min, design hydraulic loading 10m3/h/m2;Regulating system
The pH that sewage in tank is adjusted in 3 is adjusted to 5.5;PH adjust use pH value for 2 hydrochloric acid;S in sewage in adjusting tank2-Concentration be
0.05mg/L, S2-Concentration, which is adjusted, uses calcium sulfide;The residence time of the regulating system 3 is 30min;Back-purge system 4 goes out
The concentration of As, Cd and Pb are respectively 0.01482,<0.0005 and<0.0005PPM in water, and removal rate is respectively 90%,>99% and
> 99%;The period of 4 pickling of back-purge system was 1 week, and the pickling time of each pickling cycle is 10 minutes, and when pickling is anti-
PH is 5 in can,douche;The hydraulic loading when backwash using back-purge system 4 is 30m3/h/m2;Backwashing period is 24
Hour, the backwashing time of each backwashing period is 10 minutes;
The process object of embodiment 1 is the underground water in certain underground water pollution amelioration project, after underground water takes pump-and-treat system
Discharge, treating capacity are 25 ton per days, and emission request reaches GB3838-2002IV class water quality standard.
Embodiment 1 is used to remove backwash and the acid of the upward flow Zero-valent Iron filtration reactor of underwater trace concentration heavy metal
The concentration for washing As, Cd and Pb in the water outlet that journey generates is respectively 0.00558,0.001 and 0.0007PPM, also corresponds to discharge
Standard, therefore can also be with direct emission.The application of the technology effectively removes the heavy metal ion in underground water, after processing in water
As meet emission request, Cd and Pb reach the processing target of no detection.And process is it is experimentally confirmed that the present embodiment generation is given up
It abandons in solid waste leachate of the filtrate by HJ/T299 preparation, any one endangers component content and is less than GB5085.3-
The concentration of 2007 tables 1 limits, and determines that the solid waste is not belonging to the hazardous waste with Leaching feature.In embodiment 1
The total quantity control on emission and processing result being lauched are as shown in table 1;0.0005L is represented in table 1 pollutes in treated underground water
Detection limit 0.0005PPM or less of the concentration of the detection of object in detection method;
Table 1
Pollutant | Total As | Total Cd | Total Pb |
Unit | PPM | PPM | PPM |
It is up to standard to require GB3838-2002IV | <0.1 | <0.005 | <0.05 |
Before groundwater treatment | 0.1439 | 0.0063 | 0.0739 |
After groundwater treatment | 0.01482 | 0.0005L | 0.0005L |
Backwash water outlet | 0.00558 | 0.001 | 0.0007 |
Embodiment 2:
Embodiment 2 is to be constituted using reactor body 1 described in embodiment 1 for removing underwater trace concentration heavy metal
Upward flow Zero-valent Iron filtration reactor train, this is used to remove the upward flow Zero-valent Iron mistake of underwater trace concentration heavy metal
Filter reactor train is made of multiple reactor bodies 1, regulating system 3 and back-purge system 4;It is adjusted in regulating system 3
The drainpipe of pot bottom setting is connected to the water inlet for the water inlet pipe 11 that first 1 bottom of reactor body is arranged;Adjacent is anti-
The drainpipe 13 of previous reactor body 1 in device main body 1 is answered to be connected to the water inlet pipe 11 of the latter reactor body 1, finally
The drainpipe 13 of one 1 top of reactor body setting is connected to the reverse washing tank top in back-purge system 4;Back-purge system
The backwash tube of 4 bottoms setting is connected to the water inlet end of the slight drag cloth water assembly 23 in reactor body 1 respectively.
It is used to remove the upward flow Zero-valent Iron filtration reactor train of underwater trace concentration heavy metal in embodiment 2
1.2 ton/hours of design discharge, 24 hours continuous operations design total air-land combat 30min, each for removing trace in water removal
The air-land combat for measuring the upward flow Zero-valent Iron filtration reactor of concentration heavy metal is 10min, each for removing trace in water removal
Measure the hydraulic loading 10m of the upward flow Zero-valent Iron filtration reactor of concentration heavy metal3/h/m2;It is adjusted in regulating system 3 dirty in tank
The pH of water is adjusted to 5.5;PH adjust use pH value for 2 hydrochloric acid;S in sewage in adjusting tank2-Concentration be 0.1mg/L;S2-It is dense
Degree, which is adjusted, uses calcium sulfide;The residence time of the regulating system 3 is 30min;The period of 4 pickling of back-purge system is 1 star
Phase, the pickling time of each pickling cycle are 10 minutes, and pH is 5 in reverse washing tank when pickling;It is described anti-using back-purge system 4
Hydraulic loading during rinsing is 30m3/h/m2;Backwashing period is 24 hours, and the backwashing time of each backwashing period is 10
Minute;
The process object of embodiment 2 is somewhere underground water drinking water treatment pilot scale, and underground water is local drinking water source, in water
As concentration be 0.54494ppm, treating capacity requires to be 25 ton per days, and processing requirement reaches GB5749-2006 Drinking Water and defend
Raw standard.As concentration in treated underground water is lower than the concentration of GB5749-2006 standards for drinking water quality 0.01PPM
It is required that an order of magnitude, reaches drinking water standard.The total quantity control on emission of underground water and processing result such as table 2 in embodiment 2
It is shown;0.001L represents detection limit 0.001PPM or less of the concentration in detection method of detection in table 2;
Table 2
Pollutant | Total As |
Unit | PPM |
It is up to standard to require GB5749-2006 | <0.01 |
Before groundwater treatment | 0.54494 |
After coagulation | 0.03932 |
After two stage treatment | 0.01151 |
After tertiary treatment | 0.001L |
Embodiment 3:
Embodiment 3 is to be constituted using reactor body 1 described in embodiment 1 for removing underwater trace concentration heavy metal
Upward flow Zero-valent Iron filtration reactor parallel system, this is used to remove the upward flow Zero-valent Iron mistake of underwater trace concentration heavy metal
Reactor parallel system is filtered by multiple reactor bodies 1, regulating system 3, back-purge system 4, water inlet supervisor 19, drain header 20
It is constituted with backwash supervisor 21;Multiple reactor bodies 1 are set side by side, and the drainpipe of pot bottom setting is adjusted in regulating system 3
It is connected to water inlet supervisor 19, the water inlet pipe 11 of each reactor body 1 is connected to water inlet supervisor 19 respectively, each reactor body
1 drainpipe 13 is connected to drain header 20 respectively, and drain header 20 is connected to the reverse washing tank top in back-purge system 4;
The backwash tube of 4 bottom of back-purge system setting is connected to backwash supervisor 21, the slight drag cloth water assembly in reactor body 1
23 water inlet end is connected to backwash supervisor 21 respectively.
Each design discharge for removing the upward flow Zero-valent Iron filtration reactor of underwater trace concentration heavy metal is 25
Ton/day, the design discharge of two operations simultaneously is 50 ton per days.Each upward flow for being used to remove underwater trace concentration heavy metal
The air-land combat of Zero-valent Iron filtration reactor is 10min, each for removing the upward flow of underwater trace concentration heavy metal
The design hydraulic loading 10m of Zero-valent Iron filtration reactor3/h/m2.The pH that sewage in tank is adjusted in regulating system 3 is adjusted to 5.5;
PH adjust use pH value for 2 hydrochloric acid;S in sewage in adjusting tank2-Concentration be 0.15mg/L, S2-Concentration is adjusted using vulcanization
Calcium;The residence time of the regulating system 3 is 30min;The period of 4 pickling of back-purge system is 1 week, each pickling cycle
Pickling time be 10 minutes, pH is 5 in reverse washing tank when pickling;The waterpower when backwash using back-purge system 4 is negative
Lotus is 30m3/h/m2;Backwashing period is 24 hours, and the backwashing time of each backwashing period is 10 minutes;
The process object of embodiment 3 is somewhere underground water pollution rehablitation project, and underground water by rainy season due to being influenced, water
Amount changes greatly, 25 ton per day of dry season day output, 50 ton per day of rainy season day output.Pollutant concentration in underground water is shown in Table 3;
Processing requirement reaches GB3838-2002IV class water quality standard.
Heavy metal ion in embodiment 3 in underground water effectively removes, and the As after processing in water meets emission request, rainy season
It is run simultaneously using two groups of parallel systems, treating capacity is increased to 50 ton per days by 25 ton per days.The concentration of As is in water outlet
0.03188PPM, removal rate are respectively 78.57%.The total quantity control on emission of underground water and processing result such as table 3 in embodiment 3
It is shown;
Table 3
Pollutant | Total As |
Unit | PPM |
It is up to standard to require GB3838-2002IV | <0.1 |
Before groundwater treatment | 0.14885 |
After coagulation | 0.03188 |
Claims (10)
1. a kind of for removing the upward flow Zero-valent Iron filtration reactor of underwater trace concentration heavy metal, it is characterised in that: be used for
Remove underwater trace concentration heavy metal upward flow Zero-valent Iron filtration reactor by reactor body (1), regulating system (3) and instead
Rinse-system (4) is constituted;
The reactor body (1) is containment cylinder tank or closed cuboid pond, and the bottom of reactor body (1) is provided with
Water inlet pipe (11), the top of reactor body (1) are provided with drainpipe (13), and intake pump (12) are provided on water inlet pipe (11);
Zero-valent Iron filter material layer (18), the first supporting layer (14), the second supporting layer are from top to bottom disposed with inside reactor body (1)
(15), third supporting layer (16) and the 4th supporting layer (17);
4th supporting layer (17) bottom is provided with big resistance cloth water assembly (22);Zero-valent Iron filter material layer (18) lower part is provided with small resistance
Power cloth water assembly (23);The water inlet end of big resistance cloth water assembly (22) is connected to water inlet pipe (11) water outlet;Slight drag water distribution group
The water inlet pipe of part (23) is leant out to reactor body (1) bottom, the external slight drag cloth water assembly (23) of reactor body (1)
Valve is provided on water inlet pipe;The Zero-valent Iron filter material layer (18) is made of zeroth order iron powder;Zero in Zero-valent Iron filter material layer (18)
The effective grain size d10 of valence iron powder is 250 μm, and nonuniformity coefficient k80 is less than 1.5, iron content >=96%;Zero-valent Iron filter material layer (18)
With a thickness of 0.5~1.5m;
It is filled in first supporting layer (14), the second supporting layer (15), third supporting layer (16) and the 4th supporting layer (17)
Supporting layer filtrate;Supporting layer filtrate in first supporting layer (14) is and identical Zero-valent Iron in Zero-valent Iron filter material layer (18)
Powder or quartz sand identical with the Zero-valent Iron powder density in Zero-valent Iron filter material layer (18);Supporting layer filtrate in first supporting layer (14)
Partial size be 0.8~2mm, 40~100mm of thickness;Supporting layer filtrate in second supporting layer (15) is and Zero-valent Iron filtrate
Identical zeroth order iron powder or quartz sand identical with the Zero-valent Iron powder density in Zero-valent Iron filter material layer (18) in layer (18);Second holds
The partial size for holding in the palm supporting layer filtrate in layer (15) is 2~4mm, 40~100mm of thickness;Supporting layer in the third supporting layer (16)
Filtrate be with identical zeroth order iron powder in Zero-valent Iron filter material layer (18) or with the Zero-valent Iron powder density in Zero-valent Iron filter material layer (18)
Identical quartz sand;The partial size of supporting layer filtrate is 4~8mm, 40~100mm of thickness in third supporting layer (16);Described 4th
Supporting layer filtrate in supporting layer (17) be with identical zeroth order iron powder in Zero-valent Iron filter material layer (18) or with Zero-valent Iron filter material layer
(18) the identical quartz sand of Zero-valent Iron powder density in;The partial size of supporting layer filtrate is 8~16mm in 4th supporting layer (17), thick
Spend 40~100mm.
2. it is according to claim 1 for removing the upward flow Zero-valent Iron filtration reactor of underwater trace concentration heavy metal,
It is characterized by: the back-purge system (4) is by reverse washing tank, the first pH transmitter (41), blender, stirring slurry, the first pH
Electrode (42), the first dosing pump (43) and the first medicine storing pot (44) are constituted;First pH transmitter (41), blender, stirring slurry and
First pH electrode (42) is arranged inside reverse washing tank, and the first medicine storing pot (44) is arranged outside reverse washing tank;Reverse washing tank bottom
Portion is provided with drain pipe and backwash tube, is provided with valve and delivery pump on backwash tube;First medicine storing pot (44) and backwash
Tank is connected to by pipeline, and the pipeline that the first dosing pump (43) is arranged between the first medicine storing pot (44) and reverse washing tank connects;The
The signal output end of one pH electrode (42) is connected to the control signal input of the first pH transmitter (41) by signal wire, and first
The control signal output of pH transmitter (41) is connected to the control signal input of the first dosing pump (43) by signal wire;
The backwash tube of back-purge system (4) bottom setting is connected to the water inlet pipe of slight drag cloth water assembly (23);Backwash system
Reverse washing tank top in system (4) is connected to the drainpipe (13) that the top of reactor body (1) is arranged.
3. it is according to claim 1 for removing the upward flow Zero-valent Iron filtration reactor of underwater trace concentration heavy metal,
It is characterized by: the regulating system (3) is by adjusting tank, the 2nd pH transmitter (31), blender, stirring slurry, the 2nd pH electrode
(32), the second dosing pump (33), the second medicine storing pot (34) and third medicine storing pot (35) are constituted;2nd pH transmitter (31), stirring
Machine, stirring slurry and the setting of the 2nd pH electrode (32) are being adjusted inside tank, the second medicine storing pot (34) and third medicine storing pot (35) setting
It is adjusting outside tank, drug output branch pipe, the second drug storage is respectively arranged on the second medicine storing pot (34) and third medicine storing pot (35)
Valve, the second medicine storing pot (34) and third medicine storing pot are provided on drug output branch pipe on tank (34) and third medicine storing pot (35)
(35) the drug output branch pipe on is connected to drug delivery trunk respectively, and drug delivery trunk is connected to tank is adjusted, drug output
The second dosing pump (33) are provided on general pipeline;It adjusts tank top and is provided with water inlet pipe, adjust pot bottom and be provided with drainpipe, drain
Valve is provided on pipe;The signal output end of 2nd pH electrode (32) and the control signal input of the 2nd pH transmitter (31) are logical
Cross signal wire connection, the control signal output of the 2nd pH transmitter (31) and the control signal input of the second dosing pump (33)
It is connected to by signal wire;
The water inlet pipe (11) that the drainpipe and reactor body (1) bottom that pot bottom setting is adjusted in regulating system (3) are arranged
Water inlet connection.
4. it is according to claim 1 for removing the upward flow Zero-valent Iron filtration reactor of underwater trace concentration heavy metal,
It is characterized by: waterpower when the upward flow Zero-valent Iron filtration reactor for removing underwater trace concentration heavy metal is run
Load is 4~30m3/h/m2;Air-land combat is 4~30min.
5. it is according to claim 1 for removing the upward flow Zero-valent Iron filtration reactor of underwater trace concentration heavy metal,
It is characterized by: the residence time of the regulating system (3) is 15~45min;The dissolvable sulfide is soluble vulcanization
Object salt;Dissolvable sulfide salt is calcium sulfide or vulcanized sodium;The acid solution is the hydrochloric acid that pH value is 1~5.
6. it is according to claim 1 for removing the upward flow Zero-valent Iron filtration reactor of underwater trace concentration heavy metal,
It is characterized by: the period using back-purge system (4) pickling was 1~4 week, the pickling time of each pickling cycle is
5~30 minutes.
7. it is according to claim 1 for removing the upward flow Zero-valent Iron filtration reactor of underwater trace concentration heavy metal,
It is characterized by: hydraulic loading when utilization back-purge system (4) backwashes is 30~40m3/h/m2;Backwashing period is
24~72 hours, the backwashing time of each backwashing period was 5~30 minutes.
8. utilize reactor body described in claim 1 (1) constitute for remove underwater trace concentration heavy metal on to
Flow Zero-valent Iron filtration reactor train, it is characterised in that: this is used to remove the upward flow zero of underwater trace concentration heavy metal
Valence iron filtration reactor train is made of multiple reactor bodies (1), regulating system (3) and back-purge system (4);
The drainpipe of pot bottom setting and the water inlet pipe of first reactor body (1) bottom setting are adjusted in regulating system (3)
(11) water inlet connection;The drainpipe (13) and the latter of previous reactor body (1) in adjacent reactor body (1)
The water inlet pipe (11) of reactor body (1) is connected to, the drainpipe (13) of the last one reactor body (1) top setting and recoil
Wash the connection of the reverse washing tank top in system (4);Back-purge system (4) bottom setting backwash tube respectively with reactor body
(1) water inlet end of the slight drag cloth water assembly (23) in is connected to.
9. utilize reactor body described in claim 1 (1) constitute for remove underwater trace concentration heavy metal on to
Flow Zero-valent Iron filtration reactor parallel system, it is characterised in that: this is used to remove the upward flow zero of underwater trace concentration heavy metal
Valence iron filtration reactor parallel system is responsible for by multiple reactor bodies (1), regulating system (3), back-purge system (4), water inlet
(19), drain header (20) and backwash supervisor (21) are constituted;Multiple reactor bodies (1) are set side by side, in regulating system (3)
Adjust pot bottom setting drainpipe with water inlet be responsible for (19) be connected to, the water inlet pipe (11) of each reactor body (1) respectively with
Water inlet supervisor (19) connection, the drainpipe (13) of each reactor body (1) are connected to drain header (20) respectively, drain header
(20) it is connected to the reverse washing tank top in back-purge system (4);The backwash tube of back-purge system (4) bottom setting and recoil
Supervisor (21) connection is washed, the water inlet end of the slight drag cloth water assembly (23) in reactor body (1) is responsible for backwash respectively
(21) it is connected to.
10. using as claimed in claim 9 for removing the upward flow Zero-valent Iron filtration reactor of underwater trace concentration heavy metal
The upward flow Zero-valent Iron filtration reactor series-parallel system for being used to remove underwater trace concentration heavy metal that parallel system is constituted,
Be characterized in that: this is used to remove the upward flow Zero-valent Iron filtration reactor series-parallel system of underwater trace concentration heavy metal by multiple
Reaction member is constituted;The reaction member is the upward flow Zero-valent Iron filtration reactor for removing underwater trace concentration heavy metal
Parallel system;The drain pipe of the reverse washing tank bottom setting of back-purge system (4) is reacted with the latter in previous reaction member
The water inlet pipe for adjusting the setting of tank top of regulating system (3) is connected to by unit connecting tube (24) in unit.
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