CN109231339A - A kind of water quality cleansing agent and preparation method thereof for aquaculture - Google Patents

A kind of water quality cleansing agent and preparation method thereof for aquaculture Download PDF

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Publication number
CN109231339A
CN109231339A CN201811217171.4A CN201811217171A CN109231339A CN 109231339 A CN109231339 A CN 109231339A CN 201811217171 A CN201811217171 A CN 201811217171A CN 109231339 A CN109231339 A CN 109231339A
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CN
China
Prior art keywords
water quality
aquaculture
powder
cleansing agent
dry powder
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Pending
Application number
CN201811217171.4A
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Chinese (zh)
Inventor
李想
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Pingxiang Lele Humic Acid Plant
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Pingxiang Lele Humic Acid Plant
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Priority to CN201811217171.4A priority Critical patent/CN109231339A/en
Publication of CN109231339A publication Critical patent/CN109231339A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/286Treatment of water, waste water, or sewage by sorption using natural organic sorbents or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Farming Of Fish And Shellfish (AREA)

Abstract

The present invention provides a kind of water quality cleansing agents for aquaculture, as mass fraction, humic acid potassium including 30%-50%, the bentonite of 20%-30%, the charcoal powder of 10%-20%, the calcium oxide of 5%-10%, the clay of 3%-10%, the aluminium polychloride of 1%-20%, the food grade polyacrylamide of 1%-20%;Water quality cleansing agent of the invention solves the problems, such as purification of water quality in aquaculture, can effectively improve the water quality of breeding environment deterioration, reduces the secondary pollution for causing water body environment in breeding process, built the breeding environment for being conducive to water body animal growth.

Description

A kind of water quality cleansing agent and preparation method thereof for aquaculture
Technical field
The present invention relates to a kind of water quality cleansing agent, specifically a kind of water quality cleansing agent and its preparation side for aquaculture Method.
Background technique
China is global first aquaculture big country, and status holds the balance in agriculture field, because of aquaculture face Product is big, and breeding water body pollution is also to have mesh to block up altogether, although water body has certain self-purification capacity, pursues high yield high density and supports It grows, the organic matters such as residual bait and excrement constantly accumulate, and often result in water body ammonia nitrogen, sulfide surges, and water hypoxia and richness occur Nutrient laden, this consequence are directly dead in addition to may cause cultivated animals, it is also possible to keep the phytoplankton being exponentially increased fast in short term Speed outburst, forms fierce ecologic competition, and leads to aquaculture organism severe depletion of oxygen indirectly and batch is dead, causes one to aquaculture Setting loss is lost.In order to improve cultivation water environment quality, ensures that breeding production is gone on smoothly, guarantee cultivation using Water body cleansing agent Water quality just seems especially necessary.
For the purified treatment of cultivation water, at present still without satisfactory medicament, traditional water in terms of chemicals treatment Body cleanser main component is adsorbent, is directly adsorbed to the impurity of water body, but cleaning effect is not thorough, clean-up effect compared with Difference;Water body is increased since chemical agent will affect water ecology using the usually used Water Treatment agent of sewage disposal system Other pollutional loads, it is larger to the negative effect after water body purification, and time consumption and energy consumption, hold time short;Using biological cleaning Preparation is often slow in the presence of decontamination speed, the bad defect of scavenging effect.
Summary of the invention
The present invention is in order to solve the problems, such as to provide a kind of water prepared with humic acid potassium and a variety of chelating agents in above-mentioned technology Matter cleanser solves the problems, such as purification of water quality in aquaculture, can effectively improve the water quality of breeding environment deterioration, builds one Be conducive to the breeding environment of water body animal growth.
The present invention provides a kind of water quality cleansing agents for aquaculture, as mass fraction, including 30%-50%'s Humic acid potassium, the bentonite of 20%-30%, the charcoal powder of 10%-20%, the calcium oxide of 5%-10%, the clay of 3%-10%, The aluminium polychloride of 1%-20%, the food grade polyacrylamide of 1%-20%.
The present invention also provides a kind of water quality cleansing agent preparation methods for aquaculture, comprising the following steps:
1) it takes weathered coal to be put into pulverizer, is crushed to the weathered coal powder that fineness is 100-120 mesh, food-grade hydrogen-oxygen is added It is put into reaction kettle extracting after changing potassium solution, takes supernatant to be pumped into centrifuge and is centrifuged, residue use is filtered out after slag-liquid separation In fertilizers for potted flowers and Nutrition Soil, the liquid filtered out is condensed into humic acid potassium stoste by thickener, and it is stand-by to be pumped into mixed preparing tank;
2) bentonite, charcoal powder, calcium oxide, clay are compounded in proportion and is put into pulverizer crushing, fineness after mixing evenly Reach 100-200 mesh, the preparing tank being sent into step 1) is stirred with humic acid potassium stoste, and mixed liquor is made;
3) mixture pump feeding spray dryer is dried to dry powder, dry powder is sent into dry powder blender by conveyer belt;
4) food grade polyacrylamide and aluminium polychloride is added toward dry powder blender in proportion, after being sufficiently mixed, passes through Conveyer belt is sent into pelleter, and powder piece is made;
5) powder piece is packed and stored by examining, sorting into packing machine.
Further, the dry powder moisture control in step 3) is in 10%-15%.
Compared with prior art, the present invention provides a kind of water quality cleansing agent prepared with humic acid potassium and a variety of chelating agents, It solves the problems, such as purification of water quality in aquaculture, can effectively improve the water quality of breeding environment deterioration, reduce in breeding process The breeding environment for being conducive to water body animal growth has been built in the secondary pollution for causing water body environment.
In addition, the potassium humate, bentonite, charcoal powder, polyacrylamide and aluminium polychloride in the present invention are net in water quality Play considerable effect in agent:
Humic acid potassium is a kind of complicated chelate, has stronger suction-operated to ammonia nitrogen, has organic point of flocculation Effect of son, can decompose the excreta of bottom cultivated animals, residual bait, organic floc sedimentation etc. in breeding water body, both reduce It is metabolized the stink of excrement, and increases the fertilizer efficiency of bottom grass algae because absorbing ammonia;It can also be by activating Pituitary Adrenal System promotes cortin and can simultaneously slow down the increase of capillary permeability caused by amine.In addition, humic acid potassium is macromolecule network Conjunction object is simultaneously containing alkaloids, has stronger adsorption capacity to enteric microorganism and noxious material, while viscous to cultivated animals enteron aisle Film has astriction and prevention enterogastritis effect;Humic acid potassium is compared with the antibiotic that the prior art uses, not only without toxicity And there are also detoxications, have detoxication to heavy metal, strychnia etc., and can reduce fertilizer urea toxicity in water body.
Several kinds of mineral elements contained in bentonite is that various metabolic processes and bone build institute not in animal body It can lack, adjusting can be played the role of, supplement microelement in aquaculture, fish and shrimp organism metabolism can be effectively facilitated, Disease resistance improves survival rate;And there is excellent absorption property, sulphion, the ammonium ion, heavy metal ion in water body can be made Deng concentration decline rapidly, can effectively stop the corruption of aquaculture pond bottom organic matter, so that the growing environment of aquaculture organism is always In good state, the yield of cultivation is improved.
Charcoal powder has very strong suction-operated, and has apparent deodorization functions, from a wealth of sources, quality-high and inexpensive, reduces The production cost of finished product.
Polyacrylamide and aluminium polychloride are gold partner in aquaculture, and the two collocation is a kind of efficient water Treatment agent, can make suspended matter, colloidal substance form wadding body, achieve the purpose that water purification by precipitating, to solve cultivation Production waste water cannot be discharged into municipal sewage plant, can not discharge in violation of regulations problem.
Specific embodiment
For a further understanding of the present invention, the preferred embodiment of the invention is described below with reference to embodiment, still It should be appreciated that these descriptions are only further explanation the features and advantages of the present invention, rather than to the claims in the present invention Limitation.
Embodiment one
A kind of water quality cleansing agent for aquaculture, as mass fraction, including 35% humic acid potassium, 20% it is swollen Profit soil, 20% charcoal powder, 4% calcium oxide, 5% clay, 3% aluminium polychloride, 3% food grade polyacrylamide With 10% water.
The present invention also provides a kind of water quality cleansing agent preparation methods for aquaculture, comprising the following steps:
1) it takes weathered coal to be put into pulverizer, is crushed to the weathered coal powder that fineness is 150 mesh, food grade potassium hydroxide is added It is put into reaction kettle extracting after solution, takes supernatant to be pumped into centrifuge and is centrifuged, residue is filtered out after slag-liquid separation for spending Fertilizer and Nutrition Soil, the liquid filtered out are condensed into humic acid potassium stoste by thickener, it is stand-by to be pumped into mixed preparing tank;
2) bentonite, charcoal powder, calcium oxide, clay are compounded in proportion and is put into pulverizer crushing, fineness after mixing evenly Reach 150 mesh, the preparing tank being sent into step 1) is stirred with humic acid potassium stoste, and mixed liquor is made;
3) mixture pump feeding spray dryer is dried to the dry powder containing 15% moisture content, dry powder is sent by conveyer belt Enter dry powder blender;
4) food grade polyacrylamide and aluminium polychloride is added toward dry powder blender in proportion, after being sufficiently mixed, passes through Conveyer belt is sent into pelleter, and powder piece is made;
5) powder piece is packed and stored into packing machine by examining, sorting, obtains producing for the water quality cleansing agent of aquaculture Product.
The present embodiment also tests water quality cleansing agent obtained, and test method is as follows:
The water sample of 4 bottles of reservoir cultivation water the same areas is taken, water quality cleansing agent is added and is tested by coagulation test parameter, takes Unfiltered water detection after sedimentation.Wherein, in coagulation test, 4 bottles of water samples are successively tested by following process: 500rpm revolving speed Stir stirring 40s, 200rpm revolving speed stirring 1min, 80rpm revolving speed stirring 2min, 40rpm revolving speed stirring of 30s, 300rpm revolving speed 1min, 10min is finally stood.Testing result such as table 1.
As shown in Table 1,
For reservoir cultivation water, aquaculture water purifying agent is added as flocculation aid, turbidity, coloration are reduced obviously, helped Solidifying significant effect, in addition, a large amount of algae can also be killed and precipitate to aquaculture water purifying agent.
The water quality cleansing agent coagulation test result of 1 aquaculture of table
Note: the water temperature of former reservoir water is 17 DEG C, pH value 7.

Claims (3)

1. a kind of water quality cleansing agent for aquaculture, which is characterized in that as mass fraction, the corruption including 30%-50% POTASSIUM PHYTATE, the bentonite of 20%-30%, the charcoal powder of 10%-20%, the calcium oxide of 5%-10%, the clay of 3%-10%, The aluminium polychloride of 1%-20%, the food grade polyacrylamide of 1%-20%.
2. a kind of water quality cleansing agent preparation method for aquaculture, which comprises the following steps:
1) it takes weathered coal to be put into pulverizer, is crushed to the weathered coal powder that fineness is 100-120 mesh, food grade potassium hydroxide is added It is put into reaction kettle extracting after solution, takes supernatant to be pumped into centrifuge and is centrifuged, residue is filtered out after slag-liquid separation for spending Fertilizer and Nutrition Soil, the liquid filtered out are condensed into humic acid potassium stoste by thickener, it is stand-by to be pumped into mixed preparing tank;
2) bentonite, charcoal powder, calcium oxide, clay are compounded in proportion and is put into pulverizer crushing after mixing evenly, fineness reaches 100-200 mesh, the preparing tank being sent into step 1) are stirred with humic acid potassium stoste, and mixed liquor is made;
3) mixture pump feeding spray dryer is dried to dry powder, dry powder is sent into dry powder blender by conveyer belt;
4) food grade polyacrylamide and aluminium polychloride is added toward dry powder blender in proportion, after being sufficiently mixed, by transmission Band is sent into pelleter, and powder piece is made;
5) powder piece is packed and stored by examining, sorting into packing machine.
3. a kind of water quality cleansing agent preparation method for aquaculture according to claim 2, it is characterised in that: the dry powder Moisture control in 10%-15%.
CN201811217171.4A 2018-10-18 2018-10-18 A kind of water quality cleansing agent and preparation method thereof for aquaculture Pending CN109231339A (en)

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109796056A (en) * 2019-03-07 2019-05-24 内蒙古艾顿腐植酸科技有限公司 A kind of dedicated sheet sodium humate of aquaculture and its preparation process
CN109879353A (en) * 2019-03-26 2019-06-14 长沙如洋环保科技有限公司 A kind of aquiculture waste water treatment process
CN112850966A (en) * 2021-01-28 2021-05-28 清远海贝生物技术有限公司 Economical aquaculture water body modifier and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101024590A (en) * 2007-02-01 2007-08-29 陕西鼎天济农腐殖酸制品有限公司 Method for preparing water solutable fertilizer containing humic acid
CN103880139A (en) * 2014-04-05 2014-06-25 青岛大学 Natural high polymer flocculant and preparation method thereof
CN107473396A (en) * 2017-07-26 2017-12-15 明光市永言水产食品有限公司 A kind of water body organic improving preparation
CN107555612A (en) * 2017-10-17 2018-01-09 唐宏泉 A kind of culture environment of aquatic products special purification agent and its preparation technology

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101024590A (en) * 2007-02-01 2007-08-29 陕西鼎天济农腐殖酸制品有限公司 Method for preparing water solutable fertilizer containing humic acid
CN103880139A (en) * 2014-04-05 2014-06-25 青岛大学 Natural high polymer flocculant and preparation method thereof
CN107473396A (en) * 2017-07-26 2017-12-15 明光市永言水产食品有限公司 A kind of water body organic improving preparation
CN107555612A (en) * 2017-10-17 2018-01-09 唐宏泉 A kind of culture environment of aquatic products special purification agent and its preparation technology

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109796056A (en) * 2019-03-07 2019-05-24 内蒙古艾顿腐植酸科技有限公司 A kind of dedicated sheet sodium humate of aquaculture and its preparation process
CN109879353A (en) * 2019-03-26 2019-06-14 长沙如洋环保科技有限公司 A kind of aquiculture waste water treatment process
CN112850966A (en) * 2021-01-28 2021-05-28 清远海贝生物技术有限公司 Economical aquaculture water body modifier and application thereof

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Application publication date: 20190118

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