CN109229298A - A kind of anti-corrosion apparatus for preventing marine organisms for ship - Google Patents

A kind of anti-corrosion apparatus for preventing marine organisms for ship Download PDF

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Publication number
CN109229298A
CN109229298A CN201811055045.3A CN201811055045A CN109229298A CN 109229298 A CN109229298 A CN 109229298A CN 201811055045 A CN201811055045 A CN 201811055045A CN 109229298 A CN109229298 A CN 109229298A
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CN
China
Prior art keywords
conductive
insulation
rotary shaft
storehouse
electrode
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Granted
Application number
CN201811055045.3A
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Chinese (zh)
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CN109229298B (en
Inventor
潘宇星
庄肖波
李垣江
姜丽
丁立
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Zhenjiang Qilin Shipping Equipment Co Ltd
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Zhenjiang Qilin Shipping Equipment Co Ltd
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Priority to CN201811055045.3A priority Critical patent/CN109229298B/en
Publication of CN109229298A publication Critical patent/CN109229298A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63BSHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B59/00Hull protection specially adapted for vessels; Cleaning devices specially adapted for vessels
    • B63B59/04Preventing hull fouling
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F13/00Inhibiting corrosion of metals by anodic or cathodic protection
    • C23F13/02Inhibiting corrosion of metals by anodic or cathodic protection cathodic; Selection of conditions, parameters or procedures for cathodic protection, e.g. of electrical conditions
    • C23F13/06Constructional parts, or assemblies of cathodic-protection apparatus

Abstract

The invention discloses a kind of anti-corrosion apparatus for preventing marine organisms for ship, a rotary shaft is provided in Sea Chest on central axis, first positive electrode, it is made of several electrode bars, several electrode bars are alternatively arranged one circular array of composition, rotary shaft periphery is coaxially arranged with several circular array, is electrolysed the outlet of storehouse first end and Sea Chest;Second positive electrode is rotatably arranged in electrolysis storehouse, second positive electrode includes a conductive shell, conductive shell is cylindrical empty cavity configuration, conductive shell central axis respectively with electrolysis storehouse and Sea Chest center overlapping of axles, several electrode plates are drawn into cavity on self-conductive shell radially inner side wall in the cavity of conductive shell, electrode plate is successively arranged at intervals in conductive shell cavity, forms a bending half-duplex channel;The outer periphery of conductive shell is axially provided with helical blade, and helical blade is connect with conductive housing conductive;The present invention efficiently solves the technical problem low to the anti-marine growth treatment effeciency of seawater corrosion prevention.

Description

A kind of anti-corrosion apparatus for preventing marine organisms for ship
Technical field
The present invention relates to ships anticorrosion technical fields, it is more particularly related to which a kind of anti-corrosion for ship is anti- Marine growth device.
Background technique
Hull, steel construction and seawaterline and salt water cooling system in marine environment are subjected to seawater corrosion and sea The dual harm of biodeterioration.There are serious electrochemical corrosion in Seawater, need that certain corrosion protection is taken to arrange It applies.Coating protecting technology is formed a film using coating by protection component surface, and corrosion protection is played the role of, and is having for corrosion protection Efficacious prescriptions method is widely used.But due to being influenced by the integrality of film forming coatings itself, for example, painting defect, impact failure, always Change, coating pore infiltration etc., however it remains certain corrosion impact, jeopardize hull, the safety of steel construction etc., and influence Subsequent maintenance cost.Therefore, it is necessary to take further additional protection.
Marine growth adheres to and grows in seawater pipeline and cooling system, can reduce seawater cooling pipe and heat exchanger is cold The effective diameter of solidifying pipeline, reduces seawater flow, reduces cooling efficiency;Aufwuch in pipeline once falls off, and can also block The nozzle of valve and cooler, pipeline is blocked completely when serious, is caused to shut down and be stopped production, causes huge economic loss.Separately Outside, sea marine organism pollution is also possible to increase ship resistance;Promote corrosion and leads to crevice corrosion;Make the instrument and device in seawater Tool failure;Absorption sound energy, makes acoustic instrument reduction or failure;Increase the sectional area of marine building pile, column, increases wave and sea The impact force of stream;Change the depthkeeping of floating body in the water such as submarine mine;Block mesh;Attachment base and bait are fought for shellfish, the algae of cultivation. Therefore, the mankind have been stained problem caused by sea organism attachment always and have perplexed since developing and using marine resources.
Marine biofouling is mainly prevented and kill off by physical method at present.Specifically, physical method is usually to use impressed current Method, i.e. electrolysis heavy metal such as copper, aluminium, electrolytic seawater etc., principle is to be killed, pressed down by ion caused by electrochemical method Marine growth or chemical ion processed recombine to form certain gluey protective layer, slow down corrosion rate.But current this method Antifouling capacity and processing capacity it is all limited, while can not carry out quick water process with reach use standard.
Summary of the invention
It is an object of the invention to solve at least the above problems, and provide the advantages of at least will be described later.
It is a still further object of the present invention to provide a kind of anti-corrosion apparatus for preventing marine organisms for ship, configured with synchronous rotation Aluminium electrode and copper electrode so that seawater comes into full contact with aluminium electrode and copper electrode generate more cuprous ions and aluminium ion, The processing capacity to seawater is improved, meanwhile, with the rotation of aluminium electrode and copper electrode, play to aluminium electrode and copper electrode surface Automatic pollution removing effect, prevent aluminium electrode and copper electrode surface under static state be capped and reduce electrolysis activity, the present invention Efficiently solve the technical problem low to the anti-marine growth treatment effeciency of seawater corrosion prevention.
In order to realize these purposes and other advantages according to the present invention, a kind of anti-Hai Sheng of the anti-corrosion for ship is provided Object device, comprising:
Sea Chest is provided with a rotary shaft on interior central axis, and the rotary shaft is conductive metal, and the Sea Chest enters A filter plate is installed at mouthful, the first end of the rotary shaft is rotatably installed in the filter plate center, and the rotary shaft with it is described Filter plate insulation connection;
First positive electrode is made of several electrode bars, and several electrode bars are alternatively arranged one circular array of composition, The rotary shaft periphery is coaxially arranged with several circular array, and conducting interval connects between each circular array, The innermost circular array insulation is connected in the rotary shaft;
It is electrolysed storehouse, the outlet for conductive cylindrical empty cavity configuration, the electrolysis storehouse first end and the Sea Chest connects It is logical;
Second positive electrode is rotatably arranged in the electrolysis storehouse, and second positive electrode includes a conductive shell, described Conductive shell be cylindrical empty cavity configuration, the conductive shell central axis respectively with it is described electrolysis storehouse and Sea Chest central axis weight It closes, draws several electrode plates, the electrode into cavity on self-conductive shell radially inner side wall in the cavity of the conductive shell Plate is successively arranged at intervals in the conductive shell cavity, forms a bending half-duplex channel;The outer periphery of the conductive shell Axially be provided with helical blade, the helical blade to the electrolysis storehouse axial direction second end precession, the helical blade with it is described Conductive housing conductive connection;And
Galvanostat, there are three cathode output ends for configuration, wherein the first cathode output end and first positive electrode connect It connects, the second cathode output end is connect with second positive electrode, third cathode output end and the rotation axis connection, the permanent electricity Flow instrument cathode output end respectively with the Sea Chest and be electrolysed storehouse cage connection;
Wherein, the second positive electrode axial ends is rotatably arranged on the axial ends inner sidewall of the electrolysis storehouse, described A motor is provided on the outside of electrolysis storehouse second end, and the rotation axis of the motor is through electrolysis storehouse second end side wall and described the The connection of two positive electrode second end centers;The outlet in space and the Sea Chest on the outside of the conductive shell between electrolysis storehouse connects It is logical, run through in the conductive shell second end radial sidewalls and offers first through hole, the conductive shell first end side wall center Offer the second through-hole, second through-hole extends outwardly a circle interface, and the of a hollow out is provided in the circle interface One insulation connection seat, the circle interface periphery are arranged with an output channel, the output channel first end and the circle interface Between rotatory sealing connection, the output channel first end passes through hollow out on first insulation connection seat and the conductive shell Internal portion's connection, the output channel second end are drawn outward in the channel between the Sea Chest and electrolysis storehouse, and described A water-delivery pump is provided in output channel second end, the rotary shaft second end is connected to described first through the output channel On insulation connection seat.
Preferably, the filter plate inner sidewall is provided centrally with first bearing, and the first bearing is set with filter plate insulation It sets, the rotary shaft first end is rotatably connected on the filter plate center by the first bearing, and the rotary shaft is by Titanium base And it is covered on the ceramic metal oxide coating composition of titanium-based external surface.
Preferably, the specific structure of first positive electrode includes:
Connecting seats comprising conductive ferrule and the conductive connection conduction described in each adjacent two of several concentric arrangements Supporting element between ring body is equidistantly provided with several conductive connections buttons, the outermost conductive ferrule on the conductive ferrule Periphery concentric spacing is provided with a conductive contact ring, and the conductive contact ring and the connecting seats are conductively connected;
Insulate connection buckle, is arranged concentrically on the center of the connecting seats, the insulation connection buckle with it is innermost The conductive ferrule connection, the insulation connection buckle are fixed on the periphery of the rotary shaft, at least described rotating shaft terminal difference The connecting seats are provided with, the conductive connection button on each connecting seats corresponds;And
Electrode bar, both ends pass through the conductive connection for being conductively connected button and being connected to the rotating shaft terminal respectively On seat, the conductive ferrule of two sides and its between one circular array of the electrode bar construction for connecting.
Preferably, the electrode bar and supporting element are made of aluminum, and the length of the electrode bar is less than the length of the rotary shaft Degree, first positive electrode and is arranged with Sea Chest inner wall interval, one of them described connecting seats is corresponding described Be provided through one first conductive contact head on Sea Chest side wall, the conductive contact ring by the first conductive contact head with The first cathode output end connection;
The first conductive contact head includes conducting rod and conductive boots, and the conducting rod extends vertically through the Sea Chest side Wall, and the conducting rod is connect with the Sea Chest lateral wall insulation, first cathode output end and the conducting rod outboard end Connection, the conduction boots are arranged on the conducting rod inner end, are provided with one and the conductive contact ring on the conduction boots The guide groove being slidably matched, is provided with an electrically conducting contact in the guide groove, the electrically conducting contact by an elastic component with it is described The connection of guide groove bottom conductive.
Preferably, the Sea Chest inlet is provided with a fan blade, and the fan blade is located at the filter plate and the first sun Between electrode, and the diameter of the fan blade is not less than the diameter of the connecting seats, and the rotary shaft first end insulation is set It is equipped with second bearing, the fan blade center is rotatably arranged in the rotary shaft by the second bearing.
Preferably, it is provided with a metal plate between the Sea Chest outlet and the first positive electrode, metal plate center connection In the rotary shaft, and the material of the metal plate is consistent with the material of the rotary shaft, and the diameter of the metal plate is not small Several third through-holes are offered in running through on the diameter of the connecting seats, the metal plate.
Preferably, pass through a pipeline connection, and the Sea Chest, pipeline and electricity between the Sea Chest and the electrolysis storehouse Solving storehouse cage connection becomes equipotentiality body, and the pipeline is connect with the cathode output end of the galvanostat;
The rotary shaft second end is connect through the pipeline with the first insulation connection seat on second positive electrode, institute It states and is provided through one second conductive contact head on pipeline side wall, the rotary shaft in the pipeline, which protrudes above, to be provided with One ring body protrusion, the ring body protrusion and the second conductive contact head conduction sliding contact, the rotary shaft pass through described the Two conductive contact heads are connect with the third cathode output end, the second conductive contact head and the first conductive contact head Structure is consistent.
Preferably, the conductive shell inner sidewall opposite sides draws several electrode plates respectively, and each electrode plate is flat Row setting, the electrode plate of two sides is interlaced, and the conductive shell inner sidewall interval of the electrode plate and opposite side Certain distance;The electrode plate is tilted to the electrolysis storehouse first end, and tilt angle is between 30 °~70 °.
Preferably, second positive electrode is made of copper, in the conductive shell first end and electrolysis storehouse first end By insulation ring pads connection between side wall, the periphery of the electrolysis storehouse entrance, the insulation ring pads are arranged in the insulation ring pads A first annular guide rail is offered on second end side wall, and the first rolling member, institute are provided on the conductive shell first end side wall The first rolling member limitation activity is stated in the first annular guide rail;
Second through-hole is located at the insulation ring pads center, and the insulation ring pads extend radially through several fourth holes, The fourth hole is connected to the outer space of the pipeline and the conductive shell;
The output channel outer diameter is less than the tubing internal diameter, and the output channel first end inner sidewall connects with the circle At least provided with one of rotating seal ring between mouthful lateral wall, the output channel is fixed on the pipeline, and from the pipe It is drawn outward in road.
Preferably, one first insulation dottle pin, the conductive shell second are provided on the second end inner sidewall of the electrolysis storehouse It is provided with a ring shaped conductive sliding rail between end and the first insulation dottle pin, the is provided on the conductive shell second end side wall Two rolling members, the second rolling member activity is in the ring shaped conductive sliding rail, and the conductive shell and the ring shaped conductive Sliding rail conductive contact;
The motor is arranged on the second end lateral wall of the electrolysis storehouse by one second insulation dottle pin, and the conductive shell Body second end lateral wall is provided centrally with one second insulation connection seat, and the rotation axis of the motor sequentially passes through second insulation Dottle pin, electrolysis storehouse second end side wall, the first insulation dottle pin are fixed with second insulation connection seat, the rotation axis and the electricity It solves between storehouse second end lateral wall through insulation slip ring connection;
An electric conductor is provided through on the second end side wall of the electrolysis storehouse, the electric conductor first end is led with the annular Electric sliding rail conductive contact, the electric conductor second end are drawn and defeated with the second of the galvanostat the anode from the electrolysis storehouse Outlet connection, it is in sealing contact by insulating part between the electric conductor and electrolysis storehouse second end lateral wall.
The present invention is include at least the following beneficial effects:
1, the present invention is configured with the aluminium electrode and copper electrode rotated synchronously, so that seawater sufficiently connects with aluminium electrode and copper electrode Touching generates more cuprous ions and aluminium ion, improves to the anti-marine growth treatment effeciency of the anti-corrosion of seawater, realizes quickly water intaking;
2, aluminium electrode and copper electrode simultaneously and rapidly rotate, and improve the automatic pollution removing energy to aluminium electrode and copper electrode own face Power prevents aluminium electrode and copper electrode surface to be capped under static state and reduces electrolysis activity, further improves to seawater Treatment effeciency;
3, optimize field distribution, be provided with positively charged rotary shaft, Sea Chest and electrolysis storehouse shell simultaneously in Sea Chest Negative electricity is connect, is played to Sea Chest and electrolysis storehouse cathodic protection effect, effectively prevent seawater to Sea Chest and is electrolysed the corrosion in storehouse;
4, aluminium electrode and copper electrode are equivalent to the additional of building relative to the shell of negatively charged gesture respectively as positive electrode Current cathodic protection system, the anti-corrosion ability for further increasing Sea Chest and being electrolysed storehouse.
Further advantage, target and feature of the invention will be partially reflected by the following instructions, and part will also be by this The research and practice of invention and be understood by the person skilled in the art.
Detailed description of the invention
Fig. 1 is the overall structure diagram of apparatus of the present invention;
Fig. 2 is the structural schematic diagram of part A in Fig. 1;
Fig. 3 is the first positive electrode side view;
Fig. 4 is the structural schematic diagram of the first conductive contact head;
Fig. 5 is the structural schematic diagram of the second positive electrode;
Fig. 6 is the radial cross-section of the second positive electrode;
Fig. 7 is the radial side view of the second positive electrode;
Fig. 8 is the structural schematic diagram of part B in Fig. 1.
Specific embodiment
Present invention will be described in further detail below with reference to the accompanying drawings, to enable those skilled in the art referring to specification text Word can be implemented accordingly.
It should be appreciated that such as " having ", "comprising" and " comprising " term used herein do not allot one or more The presence or addition of a other elements or combinations thereof.
First embodiment
As shown in figures 1-8, the present invention provides a kind of anti-corrosion apparatus for preventing marine organisms for ship, comprising: Sea Chest 10 And its internal component, electrolysis storehouse 50 and its internal component, motor 90 and galvanostat.Galvanostat uses seawater corrosion prevention field In common model, no particular/special requirement.
Wherein, the axial first end of Sea Chest 10 is arranged in the entrance of Sea Chest 10, and the axis of Sea Chest 10 is arranged in outlet To second end, Sea Chest 10 is arranged to the axial length for having certain, so that seawater flows through abundant distance in Sea Chest 10, protects Card seawater comes into full contact in Sea Chest 10 with the first positive electrode, improves the treatment effeciency to seawater.
A rotary shaft 40 is provided in Sea Chest 10 on central axis, the rotary shaft 40 is conductive metal, the Sea Chest 10 inlet is equipped with a filter plate 11, carries out primary filtration to seawater, the first end of the rotary shaft 40 is rotatably installed in institute 11 center of filter plate is stated, and the rotary shaft 40 and the filter plate 11 insulation connect.Specifically, the 11 inner sidewall center of filter plate is set It is equipped with first bearing 111, the first bearing 111 and 11 insulation set of filter plate, 40 first end of rotary shaft pass through institute It states first bearing 111 and is rotatably connected on 11 center of filter plate.
In the present embodiment, the rotary shaft 40 is simultaneously as the impressed current anode in cathodic protection system, to Sea Chest 10 Shell carries out cathodic protection, therefore rotary shaft 40 by Titanium base and is covered on the ceramic metal oxide coating of titanium-based external surface Constitute, ceramic metal oxide coating can by one of ruthenium-oxide, yttrium oxide, palladium oxide platinum metal oxides or it is a variety of and One of titanium oxide, tin oxide, tantalum oxide non-noble metal oxide a variety of mix.
First positive electrode 30 is made of several electrode bars 35, and the specific structure of first positive electrode 30 includes:
Connecting seats comprising the conductive ferrule 34 of several concentric arrangements and being conductively connected described in each adjacent two is led Supporting element 32 between electric ring body 34, so that being mutually conductively connected between each conductive ferrule 34, and each conductive ferrule 34 and rotation Shaft 40 is coaxially disposed;Several conductive connections button 31 is equidistantly provided on the conductive ferrule 34, being conductively connected button 31 can be with It is conductive anchor ear or conductive hasp, buckle etc., the outermost 34 periphery concentric spacing of conductive ferrule is provided with a conduction Ring 341 is contacted, the conductive contact ring 341 is conductively connected with the connecting seats, plays between connecting seats and power supply The effect of connection;
Insulate connection buckle 33, the center of the connecting seats is arranged concentrically on, specifically, the insulation connection buckle 33 It is connect with the innermost conductive ferrule 34, the insulation connection buckle 33 is fixed on the periphery of the rotary shaft 40, so that leading Electric connection socket and the insulation of rotary shaft 40 connect, in the present embodiment, be respectively arranged with one at 40 both ends of rotary shaft described in lead Electric connection socket can also be also provided with a connecting seats in 40 center of rotary shaft, on each connecting seats Button 31 is conductively connected to correspond;
Electrode bar 35, both ends are connected to the described of 40 both ends of rotary shaft by the conductive connection button 31 respectively and lead On electric connection socket, so that electrode bar 35 and connecting seats are integrally formed the conductive structure of formula, that is to say, that the conducting ring of two sides Be alternatively arranged several electrode bars 35 on body 34, the conductive ferrule 34 of two sides and its between 35 structure of the electrode bar that connects At a circular array, 40 periphery of rotary shaft is coaxially arranged with several circular array, specifically can be according to Sea Chest 10 inside dimension adjusts the quantity of circular array.
In the present embodiment, the common heart is provided with 4 circular array, and conducting interval is arranged between each circular array, each Setting is spaced between electrode bar 35 on circular array, the center of each circular array is existed by 33 insulation set of connection buckle that insulate 40 periphery of rotary shaft, to form anode construction three-dimensional, with circulation gap.First positive electrode 30 is axially arranged on sea Inside bottom door 10, the setting of 10 entrance of Sea Chest is arranged in 30 first end of the first positive electrode, the outlet of Sea Chest 10 in the first positive electrode 30 second ends, therefore, seawater is during flowing through Sea Chest 10, it is necessary to flow through axis from the axial first end of the first positive electrode 30 To second end, to increase seawater and the first positive electrode 30 effectively contact distance, the first positive electrode 30 is improved to the electricity of seawater Solve efficiency.
In the present embodiment, the electrode bar 35 and supporting element 32 are made of aluminum, so that the first positive electrode 30 constitutes one A aluminium electrode with stereochemical structure, the length of the electrode bar 35 are less than the length of the rotary shaft 40, first positive electricity Pole 30 and it is arranged with the 10 inner wall interval of Sea Chest, the connecting seats at the second end position of rotary shaft are corresponding described One first conductive contact head 12 is provided through on 10 side wall of Sea Chest, the conductive contact ring 341 is conductive by described first Contact head 12 is connect with the first cathode output end of galvanostat so that the current potential on the first positive electrode 30 0.5V~8V it Between.
By applying positive voltage to aluminium electrode, cell reaction is carried out to seawater, produces aluminium ion floccule in the seawater, it is attached In container, equipment, pipe surface, to play anti-corrosion protection effect.Seawater in Sea Chest 10 with the aluminium electrode of stereochemical structure It comes into full contact with, improves aluminium electrode to the electrolysis treatment effeciency of seawater, effectively increase the anti-corrosion protection ability to equipment.
In the present embodiment, the first conductive contact head 12 includes conducting rod 121 and conductive boots 122, the conducting rod 121 10 side wall of Sea Chest is extended vertically through, and the conducting rod 121 is connect with 10 lateral wall insulation of Sea Chest, galvanostat First cathode output end is connect with 121 outboard end of conducting rod, and conduction boots 122 setting is in 121 inside of conducting rod On end, that is, it is located in Sea Chest, is provided with one on the conduction boots 122 and is slidably matched with the conductive contact ring 341 Guide groove 126, is provided with an electrically conducting contact 125 in the guide groove 126, the electrically conducting contact 125 by an elastic component 127 with 126 bottom conductive of the guide groove connection, in the rotary course of the first positive electrode 30, the first positive electrode 30 passes through conductive contact ring 341 and first conductive contact head 12 connect with the first cathode output end of galvanostat, conductive contact ring 341 passes through conductive contact Portion 125 and elastic component 127 are connect with conducting rod 121, and elastic component 127 absorbs the vibration in the rotary course of the first positive electrode 30 Dynamic or radial displacement improves the first positive electrode 30 so that the first positive electrode 30 is contacted with 12 sliding conduction of the first conductive contact head Rotate the stability of operation.
In the present embodiment, electrolysis storehouse 50 is conductive cylindrical empty cavity configuration, the entrance in electrolysis 50 first end of storehouse It is identical as electrolysis 50 entrance opening dimension of storehouse as the outlet of the outlet of the Sea Chest 10, Sea Chest 10.Specifically, the seabed It is connected between door 10 and the electrolysis storehouse 50 by a pipeline 20, and the Sea Chest 10, pipeline 20 and electrolysis 50 shell of storehouse connect It is connected into as equipotentiality body, the pipeline 20 is connect with the cathode output end of the galvanostat, collectively forms cathode, galvanostat Cathode output end output electric current between 15A~40A, the current potential on cathode is between -0.5V~-1.2V.
Second positive electrode 60 is rotatably arranged in the electrolysis storehouse 50, and second positive electrode 60 includes a conductive shell 69, the conductive shell 69 be cylindrical empty cavity configuration, 69 central axis of conductive shell respectively with the electrolysis storehouse 50 and sea The axis center in electrolysis storehouse 50 is arranged in the center overlapping of axles of bottom door 10, in other words, conductive shell 69, the conductive shell 69 Draw several electrode plates 62 in cavity on 69 radially inner side wall of self-conductive shell into cavity, the electrode plate 62 is successively spaced and sets It sets in 69 cavity of conductive shell, forms a bending half-duplex channel;Seawater flows through after the bending half-duplex channel from conduction Outflow in shell 69, what bending half-duplex channel increased seawater flows through path, so that seawater and conductive shell 69 and electrode plate 62 It comes into full contact with, improves electrolytic efficiency.
Specifically, the 69 inner sidewall opposite sides of conductive shell draws several electrode plates 62, each electrode respectively The setting of 62 parallel interval of plate, the electrode plate 62 of two sides is interlaced, and the conduction of the electrode plate 62 and opposite side 69 inner sidewall of shell is spaced apart, provides the circulation bore of certain size for seawater;The electrode plate 62 is to the electrolysis The inclination of 50 first end of storehouse, tilt angle is at 45 °.
The outer periphery of the conductive shell 69 is axially provided with helical blade 63, and the helical blade is to electrolysis storehouse axis To second end precession, the helical blade 63 is conductively connected with the conductive shell 69, so that helical blade 63, conductive shell Body 69 and electrode plate 62 also constitute the anode bodies of a specific stereochemical structure, and electrolysis storehouse 50 is similarly arranged to the axis for having certain To length, the second positive electrode 60 is axially mounted in electrolysis storehouse 50, is effectively contacted to increase seawater with the second positive electrode 60 Distance improves the second positive electrode 60 to the electrolytic efficiency of seawater.
In the present embodiment, the outlet in space and the Sea Chest 10 between 69 outside of conductive shell and electrolysis storehouse 50 Connection enters 69 outside of conductive shell and electrolysis storehouse 50 by pipeline 20 by the first positive electrode 30 electrolysis treated seawater Between space, through offering first through hole 611, the conductive shell in the 69 second end radial sidewalls of conductive shell 69 first end side wall centers offer the second through-hole 612, and second through-hole 612 extends outwardly a circle interface 64, and circle connects The outer diameter of mouth 64 is less than the internal diameter of pipeline 20, and the first insulation connection seat 65 of a hollow out, tool are provided in the circle interface 64 Body, 65 periphery of the first insulation connection seat is connected to 64 inner circumferential of circle interface, each insulating component by several insulating components 68 Setting is spaced between 68, so that the perforation inside and outside circle interface 64 will not be hindered.
64 periphery of circle interface is arranged with an output channel 70,70 first end of output channel and the circle interface Rotatory sealing connects between 64, specifically, 70 outer diameter of the output channel is less than 20 internal diameter of pipeline, the output channel 70 At least provided with rotating seal ring 642 together between 64 lateral wall of first end inner sidewall and the circle interface, to guarantee defeated Rotatory sealing connects between 70 first end of pipeline and the circle interface 64 out, as shown in figure 5,64 periphery of circle interface is spaced apart Equipped with the annular groove 641 for installing rotating seal ring 642.
The output channel 70 is fixed on the pipeline 20, and is drawn outward from the pipeline 20.Output channel 70 After being tightly connected with circle interface 64,70 first end of output channel by hollow out on first insulation connection seat 65 and It is connected to inside the conductive shell 69, pipeline of 70 second end of output channel between the Sea Chest 10 and electrolysis storehouse 50 It is drawn outward in 20, and is provided with a water-delivery pump 80 in 70 second end of the output channel, for the seawater after the completion of handling Extraction outward is sent into in water treatment facilities.
Second through-hole 612 is located at 52 center of insulation ring pads, and the insulation ring pads 52 extend radially through several Four through-holes 521, the fourth hole 521 are connected to the outer space of the pipeline 20 and the conductive shell 69, so that through It crosses the first positive electrode 30 electrolysis treated seawater and enters 69 outside of conductive shell and electricity by pipeline 20, fourth hole 521 Solve the space between storehouse 50.
40 second end of rotary shaft is connected on first insulation connection seat 65 through the output channel 70.Specifically , 40 second end of rotary shaft connects through the pipeline 20 with the first insulation connection seat 65 on second positive electrode 60 It connects, is provided through one second conductive contact head 43 on 20 side wall of pipeline, the rotary shaft in the pipeline 20 40 protrude above and are provided with a ring body protrusion 13, the ring body protrusion 13 and the conductive sliding contact of the second conductive contact head 43, So that rotary shaft 40 and the second conductive contact head 43 are conductively connected.The second conductive contact head 43 and first conduction The structure of contact head 12 is consistent.
It is provided with a metal plate 42 between the Sea Chest 10 outlet and the first positive electrode 30 simultaneously, in the metal plate 42 The heart is connected in the rotary shaft 40, so that metal plate 42 and rotary shaft 40 form the conductive structure of integral type, and the metal The material of plate 42 is consistent with the material of the rotary shaft 40, and the diameter of the metal plate 42 is straight not less than the connecting seats Diameter for providing circulation passage for seawater, while also optimizing sea through several third through-holes are offered on the metal plate 42 Circulation path of the water in Sea Chest, balanced seawater velocity especially increase the flow velocity of seawater near Sea Chest inner wall, avoid Seawater deposits near Sea Chest inner wall and marine growth is enriched with, and causes attachment and corrosion to Sea Chest.The rotary shaft 40 are connect by the second conductive contact head 43 with the third cathode output end, so that the current potential in rotary shaft 40 is in 0.8V Between~2V.Sea Chest 10 is cathode, so as to form the cathodic protection system of impressed current, optimizes field distribution, plays To 10 cathodic protection effect of Sea Chest, it effectively prevent corrosion of the seawater to Sea Chest 10.
In the present embodiment, pass through insulation between 69 first end of conductive shell and the 50 first end inner sidewall of electrolysis storehouse Ring pads 52 connect, and connect so that insulating between 69 first end of conductive shell and electrolysis storehouse 50, the insulation ring pads 52 are arranged in institute On the 50 first end inner sidewall of electrolysis storehouse for stating electrolysis 50 entrance periphery of storehouse, one is offered on the 52 second end side wall of insulation ring pads First annular guide rail, it is corresponding, one second ring-shaped guide rail 67 is offered on 69 first end lateral wall of conductive shell, it is first annular to lead The first rolling member 54 is provided between rail and the second ring-shaped guide rail 67, the first rolling member 54 is ball, so that, the conduction 69 first end side wall of shell is rotatably arranged on the axial first end inner sidewall in electrolysis storehouse 50 by the first rolling member 54.
Be provided on the 50 second end inner sidewall of electrolysis storehouse one first insulation dottle pin 51 so that electrolysis 50 second end of storehouse with Second positive electrode, 60 insulation set is provided with an annular between 69 second end of conductive shell and the first insulation dottle pin 51 Conductiving slide rail 55, it is corresponding, a third ring-shaped guide rail 66, ring shaped conductive sliding rail are offered on 69 second end lateral wall of conductive shell The second rolling member 53 is provided between 55 and third ring-shaped guide rail 66, the second rolling member 53 is ball, so that, the conduction 69 second end side wall of shell is rotatably arranged on the axial second end inner sidewall in electrolysis storehouse 50 by the second rolling member 53, and described is led Electric shell 69 and 55 conductive contact of ring shaped conductive sliding rail.
Meanwhile an electric conductor 56,56 first end of electric conductor are provided through on the 50 second end side wall of electrolysis storehouse With 55 conductive contact of ring shaped conductive sliding rail, 56 second end of electric conductor drawn from the electrolysis storehouse 50 and with the perseverance Second cathode output end of electric current instrument connects, and passes through insulation between the electric conductor 56 and the 50 second end lateral wall of electrolysis storehouse Part 57 is in sealing contact.
Second positive electrode 60 is made of copper, that is to say, that the second positive electrode 60 constitutes the copper with stereochemical structure Electrode, the second cathode output end connection of entire second positive electrode, 60 galvanostat, so that the current potential on the second positive electrode 60 exists Between 0.5V~8V.By applying positive voltage to copper electrode, cell reaction is carried out to seawater, in the seawater production pressure copper ion, The strains such as marine growth are effectively killed, avoid sea organism attachment in container, equipment, pipe surface, prevent marine growth generation to rise Effect.
Conductive shell is entered by pipeline 20, fourth hole 521 by the first positive electrode 30 electrolysis treated seawater Space between 69 outsides and electrolysis storehouse 50, seawater flows in this space, from electrolysis storehouse first end to second end, in this process In, seawater is threadingly advanced by the effect of helical blade 63 of 69 periphery of conductive shell, so that seawater and helical blade 63 It comes into full contact with, a part of 69 outer surface of conductive shell and helical blade 63 as copper electrode plays the work of preelectrolysis to seawater With generation cuprous ion then enters 69 internal second end of conductive shell, out of conductive shell 69 from first through hole 611 Portion's second end flows to 69 inner first end of conductive shell, and in the process, seawater passes through the 69 internal electrode plate of conductive shell The 62 bending half-duplex channels constituted, seawater are flowed out out of conductive shell 69 after flowing through the bending half-duplex channel, bending half-duplex channel Increase seawater flows through path, and seawater after preelectrolysis comes into full contact with 69 inner sidewall of conductive shell and electrode plate 62, makes Electrolytic efficiency must be further increased, the biological bacteria in seawater is sufficiently killed, improved to the anti-sea of seawater by the cuprous ion of generation The ability that biology generates.
After seawater is electrolysed by preelectrolysis and again, copper electrode is effectively increased to the electrolytic sterilizing efficiency of seawater.
In the present embodiment, the motor 90 is arranged on the outside of 50 second end of electrolysis storehouse by one second insulation dottle pin 91 On wall, and 69 second end lateral wall of the conductive shell is provided centrally with one second insulation connection seat 93, and the motor 90 turns Moving axis 92 sequentially passes through the second insulation dottle pin 91, electrolysis 50 second end side wall of storehouse, the first insulation dottle pin 51 and described second Insulation connection seat 93 is fixed, so that motor and the second positive electrode are drivingly connected, the rotation axis and the electrolysis storehouse 50 the It is connected between two end lateral walls by insulation slip ring 94.
When ship takes seawater, the rotation of the second positive electrode of motor driven, meanwhile, the second positive electrode and the first positive electrode it Between by rotary shaft synchronized links so that aluminium electrode, copper electrode and rotary shaft rotate synchronously so that seawater and aluminium electrode and Copper electrode comes into full contact with, and generates more cuprous ions and aluminium ion, improves to the anti-marine growth treatment effeciency of the anti-corrosion of seawater, real Now quickly water intaking.And in the prior art, it needs for seawater to be placed in advance in Sea Chest by prolonged processing, can just take With time-consuming and laborious, the present invention realizes quick water intaking, and existing enchashment is used.
Meanwhile as aluminium electrode and copper electrode simultaneously and rapidly rotate, improve to oneself of aluminium electrode and copper electrode own face Dynamic dirty removal capacities adhere to unstable because the impurity such as marine growth are not easy to be enriched in the aluminium electrode and copper electrode quickly moved Marine growth can be also detached under high-speed rotation, realized self-cleaning function, prevented aluminium electrode and copper electrode surface under static state It is capped and reduces electrolysis activity, further improve the treatment effeciency to seawater.
Further, in the present invention, field distribution is optimized, specifically, being provided with simultaneously in Sea Chest 10 positively charged Rotary shaft 40, Sea Chest 10 and electrolysis 50 shell of storehouse connect negative electricity, play to Sea Chest 10 and electrolysis 50 cathodic protection of storehouse effect Fruit effectively prevent seawater to Sea Chest 10 and is electrolysed the corrosion in storehouse 50.Also, aluminium electrode and copper electrode be respectively as positive electrode, Relative to the shell of negatively charged gesture, also correspond to the impressed current cathodic protection system of building, further increase Sea Chest 10 and It is electrolysed the anti-corrosion ability in storehouse 50.
Second embodiment
On the basis of example 1,10 inlet of Sea Chest is provided with a fan blade 41, the fan blade 41 Between the filter plate 11 and the first positive electrode 30, and the diameter of the fan blade 41 is straight not less than the connecting seats Diameter, the 40 first end insulation set of rotary shaft have second bearing 411, and 41 center of fan blade passes through the second bearing 411 are rotatably arranged in the rotary shaft 40, during water intaking, as seawater flows into Sea Chest, will drive fan blade 41 rotations, the area distributions of fan blade 41 and the entire radial section of Sea Chest are essentially identical, and the seawater of entrance passes through fan blade 41 rotation drives, and seawater is uniformly brought into Sea Chest, the current balance function to seawater is played, optimizes seawater in sea Circulation path in bottom door, balanced seawater velocity especially increase the flow velocity of seawater near Sea Chest inner wall, seawater are avoided to exist Sea Chest inner wall nearby deposits and marine growth is enriched with, and causes attachment and corrosion to Sea Chest.
From the above mentioned, the present invention is configured with the aluminium electrode and copper electrode rotated synchronously, so that seawater and aluminium electrode and copper electricity Pole comes into full contact with, and generates more cuprous ions and aluminium ion, improves to the anti-marine growth treatment effeciency of the anti-corrosion of seawater, realizes fast Speed water intaking;Meanwhile aluminium electrode and copper electrode simultaneously and rapidly rotate, and improve the automatic pollution removing to aluminium electrode and copper electrode own face Ability prevents aluminium electrode and copper electrode surface to be capped under static state and reduces electrolysis activity, further improves to sea The treatment effeciency of water;Further, the present invention optimizes field distribution, is provided with positively charged rotary shaft simultaneously in Sea Chest, Sea Chest and electrolysis storehouse shell connect negative electricity, play to Sea Chest and electrolysis storehouse cathodic protection effect, effectively prevent seawater to sea Bottom door and the corrosion for being electrolysed storehouse;Also, aluminium electrode and copper electrode are respectively as positive electrode, relative to the shell of negatively charged gesture, phase When in the impressed current cathodic protection system of building, the anti-corrosion ability for further increasing Sea Chest and being electrolysed storehouse.
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited In specific details and legend shown and described herein.

Claims (10)

1. a kind of anti-corrosion apparatus for preventing marine organisms for ship characterized by comprising
Sea Chest, a rotary shaft is provided on interior central axis, and the rotary shaft is conductive metal, the inlet of the Sea Chest One filter plate is installed, the first end of the rotary shaft is rotatably installed in the filter plate center, and the rotary shaft and the filter plate Insulation connection;
First positive electrode is made of several electrode bars, and several electrode bars are alternatively arranged one circular array of composition, described Rotary shaft periphery is coaxially arranged with several circular array, and conducting interval connects between each circular array, most interior The circular array insulation of side is connected in the rotary shaft;
It is electrolysed storehouse, for conductive cylindrical empty cavity configuration, the outlet of electrolysis the storehouse first end and the Sea Chest;
Second positive electrode is rotatably arranged in the electrolysis storehouse, and second positive electrode includes a conductive shell, the conduction Shell be cylindrical empty cavity configuration, the conductive shell central axis respectively with it is described electrolysis storehouse and Sea Chest center overlapping of axles, Draw several electrode plates in the cavity of the conductive shell on self-conductive shell radially inner side wall into cavity, the electrode plate according to Minor tick is arranged in the conductive shell cavity, forms a bending half-duplex channel;The outer periphery of the conductive shell is axial It is provided with helical blade, the helical blade is to the electrolysis storehouse axial direction second end precession, the helical blade and the conduction Housing conductive connection;And
Galvanostat, there are three cathode output ends for configuration, wherein the first cathode output end is connect with first positive electrode, the Two cathode output ends are connect with second positive electrode, third cathode output end and the rotation axis connection, the galvanostat Cathode output end respectively with the Sea Chest and electrolysis storehouse cage connection;
Wherein, the second positive electrode axial ends is rotatably arranged on the axial ends inner sidewall of the electrolysis storehouse, the electrolysis A motor is provided on the outside of the second end of storehouse, the rotation axis of the motor is through electrolysis storehouse second end side wall and second sun The connection of electrode second end center;The outlet in space and the Sea Chest on the outside of the conductive shell between electrolysis storehouse, Through first through hole is offered in the conductive shell second end radial sidewalls, the conductive shell first end side wall center is opened up There is the second through-hole, second through-hole extends outwardly a circle interface, and the first of a hollow out is provided in the circle interface absolutely Edge attachment base, the circle interface periphery are arranged with an output channel, between the output channel first end and the circle interface Rotatory sealing connection, the output channel first end pass through in the hollow out and the conductive shell on first insulation connection seat Portion's connection, the output channel second end is drawn outward in the channel between the Sea Chest and electrolysis storehouse, and the output A water-delivery pump is provided in pipeline second end, the rotary shaft second end is connected to first insulation through the output channel On attachment base.
2. being used for the anti-corrosion apparatus for preventing marine organisms of ship as described in claim 1, which is characterized in that in the filter plate inner sidewall The heart is provided with first bearing, the first bearing and the filter plate insulation set, and the rotary shaft first end passes through described first Bearing is rotatably connected on the filter plate center, and the rotary shaft is by Titanium base and is covered on the ceramet oxygen of titanium-based external surface Compound coating is constituted.
3. being used for the anti-corrosion apparatus for preventing marine organisms of ship as claimed in claim 2, which is characterized in that first positive electrode Specific structure includes:
Connecting seats comprising conductive ferrule and the conductive connection conductive ferrule described in each adjacent two of several concentric arrangements Between supporting element, several conductive connections buttons, the outermost conductive ferrule periphery are equidistantly provided on the conductive ferrule Concentric spacing is provided with a conductive contact ring, and the conductive contact ring and the connecting seats are conductively connected;
Insulate connection buckle, is arranged concentrically on the center of the connecting seats, the insulation connection buckle with it is innermost described Conductive ferrule connection, the insulation connection buckle are fixed on the periphery of the rotary shaft, and at least described rotating shaft terminal is respectively set There are the connecting seats, the conductive connection button on each connecting seats corresponds;And
Electrode bar, both ends pass through the connecting seats for being conductively connected button and being connected to the rotating shaft terminal respectively On, the conductive ferrule of two sides and its between one circular array of the electrode bar construction for connecting.
4. being used for the anti-corrosion apparatus for preventing marine organisms of ship as claimed in claim 3, which is characterized in that the electrode bar and support Part is made of aluminum, and the length of the electrode bar is less than the length of the rotary shaft, first positive electrode and with the Sea Chest The setting of inner wall interval is provided through one first conduction on the corresponding Sea Chest side wall of one of them described connecting seats Contact head, the conductive contact ring are connect by the first conductive contact head with first cathode output end;
The first conductive contact head includes conducting rod and conductive boots, and the conducting rod extends vertically through the Sea Chest side wall, and The conducting rod is connect with the Sea Chest lateral wall insulation, and first cathode output end is connect with the conducting rod outboard end, The conduction boots are arranged on the conducting rod inner end, and one is provided on the conduction boots and is matched with conductive contact ring sliding The guide groove of conjunction, an electrically conducting contact is provided in the guide groove, and the electrically conducting contact passes through an elastic component and the guide groove bottom Portion is conductively connected.
5. being used for the anti-corrosion apparatus for preventing marine organisms of ship as claimed in claim 4, which is characterized in that the Sea Chest inlet It is provided with a fan blade, the fan blade is between the filter plate and the first positive electrode, and the diameter of the fan blade is not small In the diameter of the connecting seats, the rotary shaft first end insulation set has second bearing, and the fan blade center passes through The second bearing is rotatably arranged in the rotary shaft.
6. being used for the anti-corrosion apparatus for preventing marine organisms of ship as claimed in claim 5, which is characterized in that Sea Chest outlet and A metal plate is provided between first positive electrode, which is connected in the rotary shaft, and the material of the metal plate Matter is consistent with the material of the rotary shaft, and the diameter of the metal plate is not less than the diameter of the connecting seats, the metal Run through on plate and offers several third through-holes.
7. as claimed in claim 6 be used for ship anti-corrosion apparatus for preventing marine organisms, which is characterized in that the Sea Chest with it is described It is electrolysed between storehouse through a pipeline connection, and the Sea Chest, pipeline and electrolysis storehouse cage connection become equipotentiality body, the pipeline It is connect with the cathode output end of the galvanostat;
The rotary shaft second end is connect through the pipeline with the first insulation connection seat on second positive electrode, the pipe One second conductive contact head is provided through on trackside wall, the rotary shaft in the pipeline, which protrudes above, is provided with a ring Body protrusion, the ring body protrusion and the second conductive contact head conduction sliding contact, the rotary shaft are led by described second Electrical contact head is connect with the third cathode output end, the structure of the second conductive contact head and the first conductive contact head Unanimously.
8. being used for the anti-corrosion apparatus for preventing marine organisms of ship as claimed in claim 7, which is characterized in that on the inside of the conductive shell Wall opposite sides draws several electrode plates respectively, and each electrode plate is arranged in parallel, and the electrode plate of two sides is interlaced, And the electrode plate and the conductive shell inner sidewall of opposite side are spaced apart;The electrode plate is to the electrolysis storehouse One end inclination, tilt angle is between 30 °~70 °.
9. as claimed in claim 8 be used for ship anti-corrosion apparatus for preventing marine organisms, which is characterized in that second positive electrode by Copper is at described exhausted by insulation ring pads connection between the conductive shell first end and electrolysis storehouse first end inner sidewall The periphery of the electrolysis storehouse entrance is arranged in edge ring pads, and one is offered on the insulation ring pads second end side wall and first annular is led Rail is provided with the first rolling member on the conductive shell first end side wall, and the first rolling member limitation activity is described first In ring-shaped guide rail;
Second through-hole is located at the insulation ring pads center, and the insulation ring pads extend radially through several fourth holes, described Fourth hole is connected to the outer space of the pipeline and the conductive shell;
The output channel outer diameter is less than the tubing internal diameter, outside the output channel first end inner sidewall and the circle interface At least provided with one of rotating seal ring between side wall, the output channel is fixed on the pipeline, and from the pipeline It draws outward.
10. being used for the anti-corrosion apparatus for preventing marine organisms of ship as claimed in claim 9, which is characterized in that the electrolysis storehouse second It is provided with one first insulation dottle pin on the inner sidewall of end, is provided between the conductive shell second end and the first insulation dottle pin One ring shaped conductive sliding rail is provided with the second rolling member on the conductive shell second end side wall, and the second rolling member activity exists In the ring shaped conductive sliding rail, and the conductive shell and the ring shaped conductive sliding rail conductive contact;
The motor is arranged on the second end lateral wall of the electrolysis storehouse by one second insulation dottle pin, and the conductive shell the Two end lateral walls are provided centrally with one second insulation connection seat, the rotation axis of the motor sequentially pass through second insulation every Pad, electrolysis storehouse second end side wall, the first insulation dottle pin are fixed with second insulation connection seat, the rotation axis and the electrolysis Pass through insulation slip ring connection between the second end lateral wall of storehouse;
An electric conductor is provided through on the second end side wall of the electrolysis storehouse, the electric conductor first end and the ring shaped conductive are sliding Rail conductive contact, the electric conductor second end is drawn from the electrolysis storehouse and the second cathode output end with the galvanostat Connection, it is in sealing contact by insulating part between the electric conductor and electrolysis storehouse second end lateral wall.
CN201811055045.3A 2018-09-11 2018-09-11 Corrosion-resistant marine organism-proof device for ship Active CN109229298B (en)

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CN113212686A (en) * 2021-05-07 2021-08-06 陆雨轩 Hull surface cleaning equipment and working method thereof
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