CN109225230A - It is a kind of to prepare high-performance Ni/Al2O3The method of aerogel catalyst - Google Patents
It is a kind of to prepare high-performance Ni/Al2O3The method of aerogel catalyst Download PDFInfo
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- CN109225230A CN109225230A CN201811219658.6A CN201811219658A CN109225230A CN 109225230 A CN109225230 A CN 109225230A CN 201811219658 A CN201811219658 A CN 201811219658A CN 109225230 A CN109225230 A CN 109225230A
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- catalyst
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- aerogel catalyst
- aeroge
- aerogel
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- 239000003054 catalyst Substances 0.000 title claims abstract description 47
- 239000004964 aerogel Substances 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 claims abstract description 17
- 239000011240 wet gel Substances 0.000 claims abstract description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 29
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 24
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 229910052593 corundum Inorganic materials 0.000 claims description 9
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 7
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 6
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 6
- 239000012298 atmosphere Substances 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 4
- 230000008901 benefit Effects 0.000 abstract description 6
- 238000006555 catalytic reaction Methods 0.000 abstract description 6
- 230000008569 process Effects 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 239000000499 gel Substances 0.000 description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- 230000003197 catalytic effect Effects 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 229960000935 dehydrated alcohol Drugs 0.000 description 6
- 239000012153 distilled water Substances 0.000 description 6
- 239000012299 nitrogen atmosphere Substances 0.000 description 6
- 239000003755 preservative agent Substances 0.000 description 6
- 230000002335 preservative effect Effects 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 238000003421 catalytic decomposition reaction Methods 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910017709 Ni Co Inorganic materials 0.000 description 1
- 229910003267 Ni-Co Inorganic materials 0.000 description 1
- 229910003262 Ni‐Co Inorganic materials 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
Abstract
High-performance Ni/Al is prepared the invention discloses a kind of2O3The method of aerogel catalyst.It comprises the concrete steps that using improved sol-gal process and prepares wet gel, restore to obtain aerogel catalyst further across drying and roasting.With it is traditional prepare the method for catalyst compared with, this method economical and efficient and reproducible is suitable for large-scale industrial production.The aerogel catalyst of preparation compared to traditional catalyst there is large specific surface area, the load capacity of metal, utilization rate and catalysis performance to have many advantages, such as being substantially improved.The aerogel catalyst of this method preparation has important practical value and good application prospect.
Description
Technical field
The present invention relates to aerogel catalyst preparation field, specifically a kind of economical and efficient prepares large specific surface area, hole
The method for the aerogel catalyst that rate is high and catalytic performance is good.
Background technique
Hydrogen is ideal clean energy resource.Catalytic decomposition methane hydrogen manufacturing is simple with process, low energy consumption, separating step
Less and no coupling product COXThe advantages that generation and cause people and greatly pay close attention to.Catalyst is the key that the reaction.Applied to work
Catalyst in industry production should have the features such as large specific surface area, activity is high, and stability is good.But using conventional method preparation
That there are specific surface areas in terms of methane hydrogen manufacturing is catalytically decomposed is small for catalyst, and actual metal load capacity is small, stability is poor, high temperature is easily burnt
The serious problems such as knot, carbon distribution inactivation.Various countries researcher is in the performance for making great efforts raising traditional catalyst all the time.Aeroge
(Aerogels) it is many unique to have the advantages that large specific surface area, thermal stability are good, hole is flourishing etc., fireclay insulating refractory,
Catalyst carrier, gas and cleanser of water etc. have broad application prospects.Chinese patent CN102443154B is related to
One kind contains TiO2And ZrO2Aerogel particle, the aerogel particle diameter be 10-200nm, density 30-600mg/
cm3, have important application value in terms of as catalyst carrier and absorption.Publication number CN103285920B discloses one kind three
Fiber base aerogel catalyst carrier and preparation method thereof is tieed up, the present invention is simple, raw material limitation is few, aeroge catalysis
Agent carrier product has good flexibility, connectivity and catalyst load capacity, has in catalytic applications and potentially answers
With value.Aerogel catalyst prepared by these publications respectively has advantage and disadvantage and optimal using field, but for some
Catalysis is reacted but and is not suitable for, such as catalytic methane decomposing hydrogen-production and the reaction for synthesizing ammonia, because of both aerogel catalysts
Catalysis performance and stability it is poor.It also needs to develop requirement of a variety of aerogel catalysts to adapt to different catalysis reactions thus.
Summary of the invention
In view of the above shortcomings of the prior art, the object of the present invention is to provide a kind of economical and efficient preparation large specific surface area,
The Ni/Al that porosity height and catalytic performance are excellent in2O3The preparation method of aerogel catalyst, to achieve the above object, this hair
It is bright to use following technical scheme:
It is a kind of to prepare high-performance Ni/Al2O3The method of aerogel catalyst, includes the following steps:
Step 1: preparing the mixed liquor of aluminium chloride and nickel chloride；
Step 2: propylene oxide is added into the mixed liquor that above-mentioned steps prepare, by the mixing after addition propylene oxide
Liquid heated sealed, then cools to room temperature to be put into stand in baking oven and obtains wet gel；
Step 3: obtaining aeroge after the wet gel that above-mentioned steps are prepared is dried, and obtained aeroge is existed
Muffle kiln roasting；
Step 4: the aeroge of above-mentioned steps preparation is first purged under inert gas atmosphere, hydrogen reducing is then used again
Obtain aerogel catalyst；
In step 1, the mass percentage concentration for preparing aluminium chloride and nickel chloride in aluminium chloride and nickel chloride mixed liquor
Range is respectively as follows: 1wt%-90wt%, 1wt%-90wt%.
In step 2, the volume of propylene oxide is added into the mixed liquor that above-mentioned steps prepare are as follows: 1mL-90mL.
In step 3, the temperature of aeroge that above-mentioned steps are prepared in Muffle kiln roasting are as follows: 50 DEG C -2500
℃.In step 4, aeroge prepared by above-mentioned steps is purged under inert gas atmosphere, then uses the temperature of hydrogen reducing again
Are as follows: 50 ° -2500 DEG C, time 0-60h.
The beneficial effects of the present invention are:
Method of the invention is to be prepared for height using sol-gel method in the preparation method by improving traditional catalyst
Performance Ni/Al2O3Aerogel catalyst.This method has the advantages that simple step, economical and efficient, reaction condition are mild；Preparation
Ni/Al2O3Aerogel catalyst has the characteristics that large specific surface area, porosity are high and catalytic performance is good.Therefore, the present invention provides
Aerogel catalyst have important practical value and good application prospect.
Detailed description of the invention
Fig. 1 is that the invention prepares Ni/Al2O3The process flow chart of aerogel catalyst；
Fig. 2 is the Ni/Al of the embodiment of the present invention preparation2O3The catalysis expression effect figure of aerogel catalyst.
Specific embodiment
Below with reference to example, the invention will be further described, and following embodiment is intended to illustrate invention rather than to this
Invention further limits.
Embodiment 1
Weigh 4.74g AlCl3·6H2O and 4.95g Ni (NO3)2·6H2O is put into beaker, be added 10mL distilled water and
15.5mL dehydrated alcohol, stirring 35min are mixed them thoroughly uniformly, and beaker is then enclosed in 80 DEG C of water-bath with three layers of preservative film
15.5mL propylene oxide (PO) is added after being cooled to room temperature in lower heating 1h, then by mixed liquor rest in 50 DEG C of baking ovens 2 days to
Its gel, is further dried to obtain aeroge for wet gel.By gained aeroge first in Muffle kiln roasting 8h, temperature 550
DEG C, 35min is then purged in nitrogen atmosphere at 120 DEG C, finally obtains Ni/Al after hydrogen reducing 2.5h at 450 DEG C2O3Gas
Gel catalyst.
Embodiment 2
Weigh 4.74g AlCl3·6H2O and 3.89g Ni (NO3)2·6H2O is put into beaker, be added 10mL distilled water and
15.5mL dehydrated alcohol, stirring 35min are mixed them thoroughly uniformly, and beaker is then sealed 80 DEG C of rear water-bath with three layers of preservative film
15.5mL propylene oxide (PO) is added after being cooled to room temperature in lower heating 1h, then by mixed liquor rest in 50 DEG C of baking ovens 2 days to
Its gel, is further dried to obtain aeroge for wet gel.By gained aeroge first in Muffle kiln roasting 8h, temperature 550
DEG C, 35min is then purged in nitrogen atmosphere at 120 DEG C, finally obtains Ni/Al after hydrogen reducing 2.5h at 450 DEG C2O3Gas
Gel catalyst.
Embodiment 3
Weigh 4.74g AlCl3·6H2O and 4.95g Ni (NO3)2·6H2O is put into beaker, be added 10mL distilled water and
15.5mL dehydrated alcohol, stirring 35min are mixed them thoroughly uniformly, and beaker is then sealed 80 DEG C of rear water-bath with three layers of preservative film
20mL propylene oxide (PO) is added after being cooled to room temperature in lower heating 1h, and mixed liquor is then rested in 50 DEG C of baking ovens 2 days to it
Wet gel is further dried to obtain aeroge by gel.By gained aeroge first in Muffle kiln roasting 8h, temperature is 450 DEG C,
Then 35min is purged in nitrogen atmosphere at 120 DEG C, finally obtains Ni/Al after hydrogen reducing 2.5h at 450 DEG C2O3Aeroge
Catalyst.
Embodiment 4
Weigh 4.74g AlCl3·6H2O and 4.95g Ni (NO3)2·6H2O is put into beaker, be added 10mL distilled water and
15.5mL dehydrated alcohol, stirring 35min are mixed them thoroughly uniformly, and beaker is then sealed 80 DEG C of rear water-bath with three layers of preservative film
15.5mL propylene oxide (PO) is added after being cooled to room temperature in lower heating 1h, then by mixed liquor rest in 50 DEG C of baking ovens 2 days to
Its gel, is further dried to obtain aeroge for wet gel.By gained aeroge first in Muffle kiln roasting 8h, temperature 550
DEG C, 35min is then purged in nitrogen atmosphere at 120 DEG C, finally obtains Ni/Al after hydrogen reducing 2h at 450 DEG C2O3Airsetting
Glue catalyst.
Embodiment 5
Weigh 4.74g AlCl3·6H2O and 4.95g Ni (NO3)2·6H2O is put into beaker, be added 10mL distilled water and
15.5mL dehydrated alcohol, stirring 35min are mixed them thoroughly uniformly, and beaker is then sealed 80 DEG C of rear water-bath with three layers of preservative film
35mL propylene oxide (PO) is added after being cooled to room temperature in lower heating 1h, and mixed liquor is then rested in 50 DEG C of baking ovens 2 days to it
Wet gel is further dried to obtain aeroge by gel.By gained aeroge first in Muffle kiln roasting 8h, temperature is 550 DEG C,
Then 35min is purged in nitrogen atmosphere at 120 DEG C, finally obtains Ni/Al after hydrogen reducing 2h at 430 DEG C2O3Aeroge is urged
Agent.
Embodiment 6
Weigh 3.76g AlCl3·6H2O and 4.95g Ni (NO3)2·6H2O is put into beaker, be added 10mL distilled water and
15.5mL dehydrated alcohol, stirring 35min are mixed them thoroughly uniformly, and beaker is then sealed 80 DEG C of rear water-bath with three layers of preservative film
15.5mL propylene oxide (PO) is added after being cooled to room temperature in lower heating 1h, then by mixed liquor rest in 50 DEG C of baking ovens 2 days to
Its gel, is further dried to obtain aeroge for wet gel.By gained aeroge first in Muffle kiln roasting 8h, temperature 550
DEG C, 35min is then purged in nitrogen atmosphere at 120 DEG C, finally obtains Ni/Al after hydrogen reducing 2h at 450 DEG C2O3Airsetting
Glue catalyst.
In above-described embodiment, Ni/Al2O3Aerogel catalyst is made using existing method.
Fig. 2 is the Ni/Al that above-described embodiment is prepared2O3Aerogel catalyst and traditional catalyst (Ni/Al2O3、Ni-
Fe/Al2O3、Fe/Al2O3、Ni/SiO2、Ni-Co/SiO2Deng) catalytic decomposition methane activity comparison diagram.All test conditions are all protected
It holds consistent.It can be seen that using the Ni/Al of the method preparation2O3The catalytic performance of aerogel catalyst is significantly better than conventional catalyst
Agent.This illustrates that aerogel catalyst has many advantages, such as that large specific surface area, porosity are high and catalytic performance is good.
The above is only a preferred embodiment of the present invention, it should be pointed out that: for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (5)
1. a kind of prepare high-performance Ni/Al2O3The method of aerogel catalyst, characterized by the following steps:
Step 1: preparing the mixed liquor of aluminium chloride and nickel chloride；
Step 2: propylene oxide is added into the mixed liquor that above-mentioned steps prepare, the mixed liquor after addition propylene oxide is close
Envelope heating, then cools to room temperature to be put into stand in baking oven and obtains wet gel；
Step 3: obtaining aeroge after the wet gel that above-mentioned steps are prepared is dried, and by obtained aeroge in Muffle
Kiln roasting；
Step 4: the aeroge of above-mentioned steps preparation is first purged under inert gas atmosphere, then obtained again with hydrogen reducing
Aerogel catalyst.
2. preparation high-performance Ni/Al according to claim 12O3The method of aerogel catalyst, it is characterised in that: step
In one, the mass percentage concentration range of aluminium chloride and nickel chloride in aluminium chloride and nickel chloride mixed liquor for preparing is respectively as follows:
1wt%-90wt%, 1wt%-90wt%.
3. preparation high-performance Ni/Al according to claim 12O3The method of aerogel catalyst, it is characterised in that: step
In two, the volume of propylene oxide is added into the mixed liquor that above-mentioned steps prepare are as follows: 1mL-90mL.
4. preparation high-performance Ni/Al according to claim 12O3The method of aerogel catalyst, it is characterised in that: step
In three, the temperature of aeroge that above-mentioned steps are prepared in Muffle kiln roasting are as follows: 50 DEG C -2500 DEG C.
5. preparation high-performance Ni/Al according to claim 12O3The method of aerogel catalyst, it is characterised in that: step
In four, aeroge prepared by above-mentioned steps is purged under inert gas atmosphere, then uses the temperature of hydrogen reducing again are as follows: 50 °-
2500 DEG C, time 0-60h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811219658.6A CN109225230A (en) | 2018-10-19 | 2018-10-19 | It is a kind of to prepare high-performance Ni/Al2O3The method of aerogel catalyst |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811219658.6A CN109225230A (en) | 2018-10-19 | 2018-10-19 | It is a kind of to prepare high-performance Ni/Al2O3The method of aerogel catalyst |
Publications (1)
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| CN109225230A true CN109225230A (en) | 2019-01-18 |
Family
ID=65080544
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| CN201811219658.6A Pending CN109225230A (en) | 2018-10-19 | 2018-10-19 | It is a kind of to prepare high-performance Ni/Al2O3The method of aerogel catalyst |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113198547A (en) * | 2021-05-27 | 2021-08-03 | 淮阴工学院 | Preparation method of block metal catalyst using attapulgite-alumina aerogel as carrier |
| CN115212887A (en) * | 2022-07-05 | 2022-10-21 | 南京大学 | Preparation method of reforming catalyst with high dispersion degree of active metal components |
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| CN102145994A (en) * | 2010-02-09 | 2011-08-10 | 航天材料及工艺研究所 | Block alumina aerogel with high temperature resistance and high specific surface area and preparation method thereof |
| CN105170156A (en) * | 2015-09-10 | 2015-12-23 | 上海大学 | Preparation method of nickel-base methane dry-reforming catalyst of aerogel-like structure |
| US20160129421A1 (en) * | 2014-11-12 | 2016-05-12 | Myongji University Industry And Academia Cooperation Foundation | Aerogel for capturing carbon dioxide |
| CN106430265A (en) * | 2016-08-31 | 2017-02-22 | 贵州师范大学 | Method for preparing alumina aerogel through extracting aluminum from bauxite |
| CN107159217A (en) * | 2017-04-25 | 2017-09-15 | 江苏大学 | A kind of Cu ZnO/SiO2Aeroge bimetallic catalyst and its production and use |
-
2018
- 2018-10-19 CN CN201811219658.6A patent/CN109225230A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102145994A (en) * | 2010-02-09 | 2011-08-10 | 航天材料及工艺研究所 | Block alumina aerogel with high temperature resistance and high specific surface area and preparation method thereof |
| US20160129421A1 (en) * | 2014-11-12 | 2016-05-12 | Myongji University Industry And Academia Cooperation Foundation | Aerogel for capturing carbon dioxide |
| CN105170156A (en) * | 2015-09-10 | 2015-12-23 | 上海大学 | Preparation method of nickel-base methane dry-reforming catalyst of aerogel-like structure |
| CN106430265A (en) * | 2016-08-31 | 2017-02-22 | 贵州师范大学 | Method for preparing alumina aerogel through extracting aluminum from bauxite |
| CN107159217A (en) * | 2017-04-25 | 2017-09-15 | 江苏大学 | A kind of Cu ZnO/SiO2Aeroge bimetallic catalyst and its production and use |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113198547A (en) * | 2021-05-27 | 2021-08-03 | 淮阴工学院 | Preparation method of block metal catalyst using attapulgite-alumina aerogel as carrier |
| CN115212887A (en) * | 2022-07-05 | 2022-10-21 | 南京大学 | Preparation method of reforming catalyst with high dispersion degree of active metal components |
| CN115212887B (en) * | 2022-07-05 | 2023-06-06 | 南京大学 | Preparation method of reforming catalyst with high dispersity of active metal component |
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Application publication date: 20190118 |