CN109225026B - High-salinity mine water treatment device - Google Patents
High-salinity mine water treatment device Download PDFInfo
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- CN109225026B CN109225026B CN201811172717.9A CN201811172717A CN109225026B CN 109225026 B CN109225026 B CN 109225026B CN 201811172717 A CN201811172717 A CN 201811172717A CN 109225026 B CN109225026 B CN 109225026B
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 238000002156 mixing Methods 0.000 claims abstract description 108
- 239000007788 liquid Substances 0.000 claims abstract description 70
- 238000004062 sedimentation Methods 0.000 claims abstract description 27
- 238000003756 stirring Methods 0.000 claims abstract description 26
- 239000000110 cooling liquid Substances 0.000 claims abstract description 22
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 21
- 239000010959 steel Substances 0.000 claims abstract description 21
- 230000007246 mechanism Effects 0.000 claims abstract description 20
- 238000007667 floating Methods 0.000 claims abstract description 8
- 238000001816 cooling Methods 0.000 claims abstract description 5
- 238000007789 sealing Methods 0.000 claims description 16
- 238000001514 detection method Methods 0.000 claims description 11
- 239000006185 dispersion Substances 0.000 claims description 10
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- 239000003638 chemical reducing agent Substances 0.000 claims description 7
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- 239000010865 sewage Substances 0.000 description 10
- RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical class OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 description 9
- JXHJNEJVUNHLKO-UHFFFAOYSA-N sulprofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(SC)C=C1 JXHJNEJVUNHLKO-UHFFFAOYSA-N 0.000 description 9
- 239000003431 cross linking reagent Substances 0.000 description 8
- 238000007599 discharging Methods 0.000 description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 7
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 229910052725 zinc Inorganic materials 0.000 description 7
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- 239000012498 ultrapure water Substances 0.000 description 5
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- RIJDNATVAMLZRB-UHFFFAOYSA-M sodium;oxido-propan-2-yloxy-propan-2-ylsulfanyl-sulfanylidene-$l^{5}-phosphane Chemical compound [Na+].CC(C)OP([O-])(=S)SC(C)C RIJDNATVAMLZRB-UHFFFAOYSA-M 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
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- 239000000126 substance Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- WMYJOZQKDZZHAC-UHFFFAOYSA-H trizinc;dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S WMYJOZQKDZZHAC-UHFFFAOYSA-H 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
- B01F33/80—Mixing plants; Combinations of mixers
- B01F33/82—Combinations of dissimilar mixers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/051—Stirrers characterised by their elements, materials or mechanical properties
- B01F27/053—Stirrers characterised by their elements, materials or mechanical properties characterised by their materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/40—Mounting or supporting mixing devices or receptacles; Clamping or holding arrangements therefor
- B01F35/43—Supporting receptacles on frames or stands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/45—Closures or doors specially adapted for mixing receptacles; Operating mechanisms therefor
- B01F35/453—Closures or doors specially adapted for mixing receptacles; Operating mechanisms therefor by moving them perpendicular to the plane of the opening
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/71—Feed mechanisms
- B01F35/712—Feed mechanisms for feeding fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/71—Feed mechanisms
- B01F35/717—Feed mechanisms characterised by the means for feeding the components to the mixer
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5281—Installations for water purification using chemical agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F2001/007—Processes including a sedimentation step
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
Abstract
A high salinity mine water treatment device is characterized in that a mixing tank is supported by a plurality of supporting steel frames, the bottom of the mixing tank is connected with a sedimentation treatment tank through a liquid discharge pipeline, a slow descending mechanism is arranged in the sedimentation treatment tank to prolong the reaction time, and a floating object fishing device is arranged in the sedimentation treatment tank; the support steel frame is driven by a motor to realize the lifting adjustment of the mixing tank; a jacket of a homogeneous mixing cabin body of the mixing tank is filled with heat transfer medium; an opening is formed in the side wall of a separating screen funnel in the homogenizing and mixing bin body, and the center of a bottom plate of the separating screen funnel is rotationally connected with a funnel rotating shaft; the funnel rotating shaft is driven by a driving mechanism, and a funnel stirring blade is connected to the funnel rotating shaft in the separating filter screen funnel; the liquid inlet end of the liquid feeding pipeline is connected with an external liquid feeding source; the bearing bottom support is provided with a cooling cavity and a cooling liquid supply pipeline; the homogenizing system comprises a pair of homogenizing wave wheel sets sleeved on a pair of homogenizing middle shafts, and the pair of homogenizing middle shafts are driven by a pair of homogenizing driving mechanisms. The device has simple structure, high mixing efficiency and good effect.
Description
Technical Field
The invention belongs to the field of environment-friendly equipment, and particularly relates to a high-salinity mine water treatment device.
Background
Coal mining inevitably causes pollution and damage to underground water-containing systems, the reuse rate of high-salinity mine water is low at present, and the phenomenon of water resource waste is serious. The underground water is drained beyond the limit in mining activities, so that the natural balance of underground and surface water of some energy bases is seriously damaged, a large amount of high-salinity mine water is discharged to the ground, the ground surface and the underground water in a mining area are seriously polluted, the environment is degraded, and the large-area decline of the underground water level causes environmental geological disasters such as ground surface collapse, ground settlement and the like. Therefore, the development and utilization of mine inlet water are accelerated, and the reliable technology and process for treating high-salinity mine water as domestic water are found to have great significance. The traditional high-salinity mine water inlet treatment equipment has the advantages of unsatisfactory stirring effect after additives are added, low stirring efficiency and unsatisfactory precipitation and filtration effects, and cannot meet the requirement of treating high-salinity mine water because a novel high-salinity mine water treatment device needs to be invented.
Disclosure of Invention
Aiming at the problems in the prior art, the invention provides the high-salinity mine water treatment device which is simple in structure, convenient to operate, high in stirring efficiency, ideal in stirring effect, ideal in precipitation effect and convenient for discharging the treated clear liquid.
In order to achieve the purpose, the invention provides a high-salinity mine water treatment device which comprises a mixing tank, a plurality of supporting steel frames fixedly connected to the outer side of the lower part of the mixing tank, an upper connecting crank arm, an upper telescopic oil cylinder and a sedimentation treatment tank, wherein the upper connecting crank arm is fixedly connected with the lower part of the mixing tank;
the supporting steel frame comprises a support, a pair of vertical beams which are parallel and fixedly connected to the support, an L-shaped support arranged on one side of the pair of vertical beams and a support driving motor arranged on one side of the pair of vertical beams; the vertical beams are respectively provided with a longitudinally extending continuous rack and a longitudinally extending sliding rail on the same side; the upper part and the lower part of the vertical section of the L-shaped bracket corresponding to the position of the continuous rack are respectively provided with a bracket gear, and the bracket gear is rotatably connected to the vertical section of the L-shaped bracket through a gear rotating shaft at the center of the bracket gear; a sliding groove is formed in the position, corresponding to the sliding rail, of the vertical section of the L-shaped support, the sliding groove is sleeved outside the sliding rail in a sliding mode, and the end of the support on the horizontal section of the L-shaped support is fixedly connected with the outer side wall of the mixing tank; the support driving motor is fixedly connected to one side of the L-shaped support, which is far away from the support gear, an output shaft of the support driving motor is connected with an input end of a transmission case fixedly connected to one side of the L-shaped support, and an output end of the transmission case is connected with gear shafts of the two support gears;
the upper opening end of the mixing tank is provided with an upper pressure sealing cover for sealing the mixing tank, and the bottom end of the mixing tank is fixedly connected with a liquid discharge pipeline communicated with the inner cavity of the mixing tank; one end of the upper connecting crank arm is fixedly connected with the upper end face of the upper pressure sealing cover, and the other end of the upper connecting crank arm is hinged with a hinge seat fixedly connected to the outer side of the upper end of the mixing tank; one end of the upper telescopic oil cylinder is hinged with the outer side of the hinged end of the upper connecting crank arm, and the other end of the upper telescopic oil cylinder is hinged with the middle part of the tank body of the mixing tank, so that the upper pressure sealing cover is controlled to be closed or opened through telescopic action;
the mixing tank comprises a homogeneous mixing cabin body with a jacket structure, a heat transfer medium is filled in a jacket of the homogeneous mixing cabin body, a heat medium pipeline communicated with the jacket space of the homogeneous mixing cabin body is connected to the outside of the homogeneous mixing cabin body, and the other end of the heat medium pipeline is connected with a heat medium supply source;
the device comprises a homogenizing mixing bin body, a liquid feeding pipeline, a separating screen funnel and a homogenizing system, wherein the liquid feeding pipeline is obliquely arranged in the homogenizing mixing bin body from top to bottom, the separating screen funnel is horizontally placed and can rotate relative to the homogenizing mixing bin body, a plurality of side wall openings are formed in the side wall of the separating screen funnel in a spreading mode, a plurality of small holes are formed in the surface of the bottom plate of the separating screen funnel in a spreading mode, the rotating center of the bottom plate is connected with a funnel rotating shaft through a bearing base fixedly connected with the bottom plate, and the lower end, inside the separating screen funnel, of the funnel rotating shaft is connected with a funnel stirring blade in; the funnel rotating shaft is sleeved with an outer gear ring at the upper end of the outer part of the separating filter screen funnel, and the outer gear ring is fixedly connected with the funnel rotating shaft through a radial connecting beam; a waterproof motor is fixedly connected to the inner side wall of the homogeneous mixing cabin body corresponding to the outer gear ring, a funnel gear is assembled on an output shaft of the waterproof motor, and the funnel gear is meshed with the outer gear ring; the liquid outlet end of the liquid feeding pipeline is positioned above the separating filter screen funnel, and the liquid inlet end of the liquid feeding pipeline penetrates through the side wall of the homogenizing and mixing bin body and then is connected with a liquid feeding source;
a bearing accommodating groove which is sunken downwards is formed in the center of the bearing bottom support, and an annular cavity is formed in the bearing bottom support in a mode of surrounding the bearing accommodating groove; a backstop bearing is fixedly assembled in the bearing accommodating groove, and an inner ring of the backstop bearing is fixedly connected with the funnel rotating shaft; the annular cavity is respectively connected with a cooling liquid inlet pipeline and a cooling liquid outlet pipeline which are communicated with the inner cavity of the annular cavity, and the cooling liquid inlet pipeline and the cooling liquid outlet pipeline are respectively connected with a cooling source and a cooling liquid recovery box after radially penetrating through the separating filter screen funnel and the homogeneous mixing bin body;
the homogenizing system comprises a pair of homogenizing middle shafts which are arranged side by side, a pair of homogenizing middle shafts are respectively sleeved with a pair of corresponding homogenizing impeller sets in a rotatable mode in the middle, each homogenizing impeller set is composed of a plurality of high-speed homogenizing impellers, and high-speed homogenizing impellers in the pair of homogenizing impeller sets are meshed with each other; two opposite ends of the pair of homogenizing middle shafts respectively penetrate out of the homogenizing mixing cabin body in a rotatable mode and then are respectively connected with output parts of homogenizing driving mechanisms fixedly connected to two sides of the outside of the homogenizing mixing cabin body; the other end of the homogenizing middle shaft, which is far away from the driving mechanism, is rotationally connected with the inner side wall of the homogenizing mixing bin body through a closed thrust bearing.
The sedimentation treatment tank comprises a tank body with an opening at the upper end, floating object fishing equipment arranged in the tank body, a tank body bracket fixedly supported outside the tank body, a sedimentation treatment tank water inlet pipeline fixedly connected to the upper end of the tank body, a bottom mud discharge pipeline communicated with the bottom of an inner cavity of the tank body and fixedly connected to the bottom end of the tank body, and a sedimentation treatment tank water outlet pipeline communicated with the middle of the inner cavity of the tank body and fixedly connected to one side of the tank body; a clear liquid zone is formed in the middle part in the tank body, and a sludge accumulation zone is formed at the bottom in the tank body; the liquid inlet end of the water inlet pipeline of the sedimentation treatment tank is communicated with the liquid outlet end of the liquid discharge pipeline;
the device comprises a clear liquid area, a sedimentation treatment pool, a dispersion board unit, a slow descending board unit and a slow descending net, wherein the clear liquid area is sequentially provided with the dispersion board unit, the slow descending board unit and the slow descending net from top to bottom, the dispersion board unit is composed of a plurality of wing-shaped dispersion boards which are arranged side by side, adjacent wing-shaped dispersion boards are fixedly connected through a connecting rod, the slow descending board unit is composed of a plurality of square slow descending boards which are arranged side by side, adjacent square slow descending boards are fixedly connected through a connecting rod, the water inlet end of a water outlet pipeline of the sedimentation treatment pool is positioned at the lower part of the slow descending net, the clear liquid area is provided with a detection port at the upper;
the floating object fishing equipment comprises a fishing frame fixedly connected to the upper end of the tank body, a fishing driving mechanism fixedly connected to the upper part of the fishing frame, fishing rotating shafts which are arranged in parallel and respectively rotatably connected to two opposite sides of the fishing frame, and a plurality of pairs of fishing crank arms which are arranged oppositely and respectively fixedly connected to the two fishing rotating shafts; one end of each pair of fishing crank arms, which is far away from the fishing rotating shaft, extends into the tank body and is connected with the fishing crank arms through fishing steel wires; the fishing driving mechanism comprises a fishing motor and a fishing cam assembled on an output shaft of the fishing motor, eccentric connecting points on the fishing cam are respectively hinged with the inner ends of two fishing driving rods, the two fishing driving rods are respectively hinged with the inner ends of two fishing driving arms which are arranged oppositely, and the outer ends of the two fishing driving arms are respectively fixedly connected with one ends of two fishing rotating shafts.
Preferably, the homogenizing driving mechanism is formed by connecting a homogenizing driving motor and a speed reducer.
Furthermore, in order to facilitate centralized control, the system also comprises a control box, wherein a speed sensor is arranged on the speed reducer, and the heat medium supply source and the liquid adding source are respectively a heat medium supply pump connected with the heat medium source and a liquid adding pump connected with the liquid source;
the control box is respectively connected with the bracket driving motor, the homogeneous driving motor, the rotating speed sensor, the heat medium supply pump, the liquid feeding pump, the waterproof motor and the fishing motor.
Preferably, the number of the supporting steel frames is 3, and the supporting steel frames are uniformly distributed on the outer side of the mixing tank;
the wall thickness of the homogenizing and mixing bin body is 2 mm-50 mm;
the separating filter screen funnel is positioned at the position which is 25 mm-55 mm above the waist part of the homogeneous mixing cabin body;
the included angle between the liquid feeding pipeline and the horizontal direction is 10-32 degrees;
the funnel stirring blade consists of a circular ring sleeved outside the funnel rotating shaft and a radial connecting rod for connecting the circular ring and the funnel rotating shaft;
the thickness of the pore canal is 20 mm-30 mm;
the diameter of the salvaging cam is 5 cm-10 cm;
the number of the fishing crank arms on each fishing rotating shaft is 11; the distance between adjacent fishing crank arms is 40 cm-60 cm.
Further, in order to facilitate the detection homogeneity degree, still including setting up the homogeneity degree detector in the homogeneous mixing storehouse internal portion, the homogeneity degree detector is connected with the control box.
Furthermore, in order to improve the homogenizing effect, the number of the high-speed homogenizing wave wheels is 10, the adjacent high-speed homogenizing wave wheels are arranged at equal intervals, the interval is between 5mm and 12mm, and the appearance of the high-speed homogenizing wave wheels is in a ratchet shape.
Further, in order to improve the heat dissipation effect, the quantity of fin exhibition pole and hydro-cylinder fin is 6, and the material of hydro-cylinder fin is sheet metal stainless steel.
Furthermore, the bottom of the tank body is in an inverted frustum shape, and a COD sensor connected with the control box is arranged in the clear liquid zone.
Further, the distance between the two bracket gears is 15 cm-25 cm
Further, in order to obtain a high-speed homogeneous wave wheel with good homogeneity improving effect, the high-speed homogeneous wave wheel is made of high polymer materials, and comprises the following components in percentage by mass:
30-65% of methyl ester derivative, 25-60% of thiophosphate derivative, 1-5% of mixed auxiliary agent, 1-5% of cross-linking agent, 15-45% of O-ethyl O- (4-methylthiophenyl) S-propyl phosphorodithioate and 2-15% of (T-4) -bis (diethyl dithiocarbamate-S, S') zinc.
Further, in order to obtain a high-speed homogeneous impeller with good homogeneity improving effect, the preparation method of the high-speed homogeneous impeller comprises the following steps:
step 1: adding 22-32% of ultrapure water with the conductivity of 1.25 muS/cm-3.15 muS/cm into a reaction kettle, starting a stirrer in the reaction kettle at the rotating speed of 125-375 rpm, and starting a heating pump to raise the temperature in the reaction kettle to 75-185 ℃; sequentially adding 30-65% of methyl ester derivatives and 1-5% of mixed auxiliary agents, stirring until the methyl ester derivatives and the mixed auxiliary agents are completely dissolved, adjusting the pH value to 5.5-8.5, adding 25-60% of thiophosphate derivatives, and adjusting the rotation speed of a stirrer to 255-315 rpm at the temperature of 90-395 ℃;
step 2: adding 15-45% of O-ethyl O- (4-methylthiophenyl) S-propyl dithiophosphate and 2-15% of (T-4) -bis (diethyl dithiocarbamate-S, S') zinc, and uniformly mixing;
and 3, step 3: adding 1-5% of cross-linking agent, setting the rotation speed of a stirrer at 75-235 rpm and the temperature at 90-265 ℃, keeping the state for 5-25 hours, discharging, and putting into a molding press to obtain the high-speed homogeneous impeller.
According to the invention, the upper pressure sealing cover is controlled to open and close through the upper telescopic oil cylinder, so that the automation degree of the device can be improved, and the addition of sewage to be treated is facilitated. Waterproof motor passes through the operation of funnel gear drive funnel pivot, and then drives the rotation of funnel stirring leaf, reaches the purpose to the even stirring of material, but also can make the liquid additive who adds and the pending sewage that blending tank upper end added carry out even mixture and stir in advance, and a pair of homogeneity wheelset is high-speed relative motion by the drive of even actuating mechanism in the homogeneous system, can not only improve stirring effect, can promote the reaction between additive and the pending sewage moreover. The support steel frame can control the height of the mixing tank relative to the support plane. The settling treatment tank is arranged to facilitate standing and settling of the sewage after reaction with the additive, so that clear water after treatment can be separated and settled bottom mud can be discharged outside. The device simple structure, stirring are efficient, and the homogeneity effect is ideal.
Drawings
FIG. 1 is a schematic structural view of the present invention;
FIG. 2 is a schematic structural view of a support steel frame according to the present invention;
FIG. 3 is a schematic view of the mixing tank of the present invention;
FIG. 4 is a schematic diagram of a separatory strainer funnel of the present invention;
FIG. 5 is a schematic view of the structure of the bearing shoe of the present invention;
FIG. 6 is a schematic diagram of the homogenization system of the present invention;
FIG. 7 is a schematic view showing the structure of a sedimentation treatment tank according to the present invention;
FIG. 8 is a schematic view of the structure of the supernatant zone in the present invention;
FIG. 9 is a schematic view showing the construction of the float fishing apparatus according to the present invention;
FIG. 10 is a graph showing the effect of O-ethyl O- (4-methylthiophenyl) S-propyl dithiophosphate on uniformity improvement rate in accordance with the present invention;
FIG. 11 is a schematic diagram showing the structural characteristics of the methyl ester derivative of the present invention;
FIG. 12 is a schematic representation of the molecular structural features of phosphorothioate derivatives of the present invention;
FIG. 13 is a schematic view showing the molecular structural characteristics of the oxysilane-based material according to the present invention.
In the figure: 1. the device comprises a supporting steel frame, 1-1 parts, a support driving motor, 1-2 parts, a transmission case, 1-3 parts, support ends, 1-4 parts, sliding rails, 1-5 parts, a continuous rack, 1-6 parts, support gears, 1-7 parts, an L-shaped support, 1-8 parts, a support, 1-9 parts, a vertical beam, 2 parts, a mixing tank, 2-1 parts, a homogeneous mixing bin body, 2-2 parts, a separating filter screen funnel, 2-2-1 parts, side wall openings, 2-2-2 parts, an outer gear ring, 2-2-3 parts, a funnel gear, 2-2-4 parts, a waterproof motor, 2-2-5 parts, a funnel stirring blade, 2-2-6 parts, a bearing base, 2-2-6-1 parts, a bearing accommodating groove, 2-2-6-2 parts, 2-2-6-3 parts of annular cavity, 2-2-6-4 parts of backstop bearing, 2-2-6-4 parts of cooling liquid inlet pipeline, 2-2-6-4 parts of cooling liquid outlet pipeline, 2-3 parts of liquid feeding pipeline, 2-4 parts of homogenizing system, 2-4-1 parts of homogenizing driving motor, 2-4-2 parts of speed reducer, 2-4-3 parts of homogenizing middle shaft, 2-4-4 parts of closed thrust bearing, 2-4-5 parts of high-speed homogenizing impeller, 2-5 parts of homogeneity degree detector, 3 parts of upper pressure sealing cover, 4 parts of upper connecting crank arm, 5 parts of upper telescopic oil cylinder, 6 parts of liquid discharging pipeline, 7 parts of settling tank, 7-1 parts of bottom mud discharging pipeline, 7-2 parts of floating object salvaging equipment, and 7-2-1 parts of floating object salvaging equipment, A salvaging motor 7-2-2, a salvaging cam 7-2-3, a salvaging driving rod 7-2-4, a salvaging driving arm 7-2-5, a salvaging rotating shaft 7-2-6, a salvaging frame 7-2-7, a salvaging crank arm 7-2-8, a salvaging steel wire 7-3, a tank body 7-5, a clear liquid zone 7-5-1, a COD sensor 7-5-2, a wing type dispersion plate 7-5-3, a square slow descending plate 7-5-4, a slow descending net 7-5, a detection port 7-6, a sludge accumulation zone 7-7, a sedimentation treatment tank water inlet pipeline 7-8, a sedimentation treatment tank water outlet pipeline 8, a control box, 9. radial connecting beam 10, funnel pivot.
Detailed Description
The present invention is further described below.
As shown in fig. 1 to 9, a high salinity mine water treatment device comprises a mixing tank 2, a plurality of supporting steel frames 1 fixedly connected to the outer side of the lower part of the mixing tank 2, an upper connecting crank arm 4, an upper telescopic oil cylinder 5 and a sedimentation treatment tank 7;
the supporting steel frame 1 comprises supports 1-8, a pair of vertical beams 1-9 which are fixedly connected to the supports 1-8 in parallel, L-shaped supports 1-7 arranged on one sides of the pair of vertical beams 1-9 and support driving motors 1-1 arranged on one sides of the pair of vertical beams 1-9; a pair of vertical beams 1-9 are respectively provided with a longitudinally extending continuous rack 1-5 and a longitudinally extending slide rail 1-4 at the same side; the upper part and the lower part of the vertical section of the L-shaped bracket 1-7 corresponding to the position of the continuous rack 1-5 are respectively provided with a bracket gear 1-6, and the bracket gear 1-6 is rotatably connected to the vertical section of the L-shaped bracket 1-7 through a gear rotating shaft at the center of the bracket gear; a sliding groove is formed in the position, corresponding to the sliding rail 1-4, of the vertical section of the L-shaped support 1-7, the sliding groove is sleeved outside the sliding rail 1-4 in a sliding mode, and the support end 1-3 on the horizontal section of the L-shaped support 1-7 is fixedly connected with the outer side wall of the mixing tank 2; the support driving motor 1-1 is fixedly connected to one side of the L-shaped support 1-7, which is far away from the support gear 1-6, an output shaft of the support driving motor is connected with an input end of a transmission case 1-2 fixedly connected to one side of the L-shaped support 1-7, and an output end of the transmission case 1-2 is connected with gear rotating shafts of the two support gears 1-6;
an upper pressure sealing cover 3 for sealing the mixing tank 2 is arranged at the upper opening end of the mixing tank 2, and a liquid discharge pipeline 6 communicated with the inner cavity of the mixing tank 2 is fixedly connected at the bottom end of the mixing tank 2; one end of the upper connecting crank arm 4 is fixedly connected with the upper end face of the upper pressure sealing cover 3, and the other end of the upper connecting crank arm is hinged with a hinge seat fixedly connected to the outer side of the upper end of the mixing tank 2; one end of an upper telescopic oil cylinder 5 is hinged with the outer side of the hinged end of the upper connecting crank arm 4, and the other end of the upper telescopic oil cylinder is hinged with the middle part of the tank body of the mixing tank 2, so that the upper pressure sealing cover 3 is controlled to be closed or opened through telescopic action;
the mixing tank 2 comprises a homogeneous mixing cabin body 2-1 with a jacket structure, a jacket of the homogeneous mixing cabin body 2-1 is filled with a heat transfer medium, a heat medium pipeline communicated with the jacket space of the homogeneous mixing cabin body 2-1 is connected to the outside of the homogeneous mixing cabin body, and the other end of the heat medium pipeline is connected with a heat medium supply source;
a liquid adding pipeline 2-3 which is obliquely arranged, a separating screen funnel 2-2 which is horizontally placed and can rotate relative to the homogenizing mixing cabin body 2-1 and a homogenizing system 2-4 are sequentially arranged in the homogenizing mixing cabin body 2-1 from top to bottom, a plurality of side wall openings 2-2-1 are distributed on the side wall of the separating screen funnel 2-2, a plurality of small holes are distributed on the surface of the bottom plate of the separating screen funnel 2-2, the rotating center of the bottom plate is connected with a funnel rotating shaft 10 through a bearing bottom support 2-2-6 which is fixedly connected with the bottom plate, and the lower end of the funnel rotating shaft 10 in the separating screen funnel 2-2 is connected with a funnel stirring blade 2-2-5 which is in clearance fit with the inner part of the lower end of the homogenizing mixing cabin body 2-1; the funnel rotating shaft 10 is sleeved with an outer gear ring 2-2-2 at the upper end of the outer part of the separating filter screen funnel 2-2, and the outer gear ring 2-2-2 is fixedly connected with the funnel rotating shaft 10 through a radial connecting beam 9; a waterproof motor 2-2-4 is fixedly connected on the inner side wall of the homogeneous mixing cabin body 2-1 corresponding to the outer gear ring 2-2-2, a funnel gear 2-2-3 is assembled on an output shaft of the waterproof motor 2-2-4, and the funnel gear 2-2-3 is meshed with the outer gear ring 2-2-2; the liquid outlet end of the liquid adding pipeline 2-3 is positioned above the separating filter screen funnel 2-2, and the liquid inlet end thereof penetrates through the side wall of the homogeneous mixing cabin body 2-1 and then is connected with a liquid adding source;
a bearing accommodating groove 2-2-6-1 which is sunken downwards is formed in the center of the bearing bottom support 2-2-6, and an annular cavity 2-2-6-2 is formed in the bearing bottom support 2-2-6 in a manner of surrounding the bearing accommodating groove 2-2-6-1; a backstop bearing 2-2-6-3 is fixedly assembled in the bearing accommodating groove, and the inner ring of the backstop bearing 2-2-6-3 is fixedly connected with a funnel rotating shaft 10; the annular cavity 2-2-6-2 is respectively connected with a cooling liquid inlet pipeline 2-2-6-4 and a cooling liquid outlet pipeline 2-2-6-5 which are communicated with the inner cavity of the annular cavity, and the cooling liquid inlet pipeline 2-2-6-4 and the cooling liquid outlet pipeline 2-2-6-5 are respectively connected with a cooling source and a cooling liquid recovery box after radially penetrating through a separating screen funnel 2-2 and a homogenizing mixing cabin body 2-1;
the homogenizing system 2-4 comprises a pair of homogenizing middle shafts 2-4-3 arranged side by side, a pair of homogenizing middle shafts 2-4-3 are respectively sleeved with a pair of corresponding homogenizing impeller sets in the middle in a rotatable manner, each homogenizing impeller set consists of a plurality of high-speed homogenizing impellers 2-4-5, and the high-speed homogenizing impellers 2-4-5 in the pair of homogenizing impeller sets are meshed; the two opposite ends of the pair of homogeneous middle shafts 2-4-3 respectively penetrate out of the homogeneous mixing cabin body 2-1 in a rotatable way and then are respectively connected with the output parts of the homogeneous driving mechanisms fixedly connected with the two outer sides of the homogeneous mixing cabin body 2-1; the other end of the homogenizing middle shaft 2-4-3, which is far away from the driving mechanism, is rotatably connected with the inner side wall of the homogenizing mixing bin body 2-1 through a closed thrust bearing 2-4-4;
the sedimentation treatment tank 7 comprises a tank body 7-3 with an opening at the upper end, a floating object salvage device 7-2 arranged inside the tank body 7-3, a tank body bracket 7-4 fixedly supported outside the tank body 7-3, a sedimentation treatment tank water inlet pipeline 7-7 fixedly connected to the upper end of the tank body 7-3, a bottom mud discharge pipeline 7-1 communicated with the bottom of an inner cavity of the tank body 7-3 and fixedly connected to the bottom end of the tank body 7-3, and a sedimentation treatment tank water outlet pipeline 7-8 communicated with the middle of the inner cavity of the tank body 7-3 and fixedly connected to one side of the tank body 7-3; a clear liquid zone 7-5 is formed in the middle of the inner part of the tank body 7-3, and a sludge accumulation zone 7-6 is formed at the bottom of the tank body 7-3; the liquid inlet end of the water inlet pipeline 7-7 of the sedimentation treatment tank is communicated with the liquid outlet end of the liquid discharge pipeline 6;
the clear liquid area 7-5 is provided with dispersion plate units from top to bottom in sequence, the device comprises a slow descending plate unit and a slow descending net 7-5-4, wherein the dispersing plate unit is composed of a plurality of wing-shaped dispersing plates 7-5-2 arranged side by side, adjacent wing-shaped dispersing plates 7-5-2 are fixedly connected through connecting rods, the slow descending plate unit is composed of a plurality of square slow descending plates 7-5-3 arranged side by side, adjacent square slow descending plates 7-5-3 are fixedly connected through connecting rods, the water inlet end of a water outlet pipeline 7-8 of a sedimentation treatment pool is positioned at the lower part of the slow descending net 7-5-4, a detection port 7-5-5 is arranged at the upper part of the dispersing plate unit in a clear liquid area 7-5, and a detection pipeline which is communicated with the inner cavity of the detection port 7-5-5 and is provided with a stop valve.
The floater fishing equipment 7-2 comprises a fishing frame 7-2-6 fixedly connected to the upper end of the tank body 7-3, a fishing driving mechanism fixedly connected to the upper part of the fishing frame 7-2-6, fishing rotating shafts 7-2-5 which are arranged in parallel and respectively rotatably connected to two opposite sides of the fishing frame 7-2-6, and a plurality of pairs of fishing crank arms 7-2-7 which are arranged opposite to each other and respectively fixedly connected to the two fishing rotating shafts 7-2-5; one end of each pair of fishing crank arms 7-2-7 far away from the fishing rotating shaft 7-2-5 extends into the tank body 7-3 and is connected with the fishing crank arms through fishing steel wires 7-2-8; the fishing driving mechanism comprises a fishing motor 7-2-1 and a fishing cam 7-2-2 assembled on an output shaft of the fishing motor 7-2-1, eccentric connection points on the fishing cam 7-2-2 are respectively hinged with the inner ends of two fishing driving rods 7-2-3, the two fishing driving rods 7-2-3 are respectively hinged with the inner ends of two fishing driving arms 7-2-4 which are arranged opposite to each other, and the outer ends of the two fishing driving arms 7-2-4 are respectively fixedly connected with one ends of two fishing rotating shafts 7-2-5. The diameter of the fishing cam 7-2-2 is 5 cm-10 cm; preferably, the number of the fishing crank arms 7-2-7 on each fishing rotating shaft 7-2-5 is 11; the distance between the adjacent fishing crank arms 7-2-7 is 40 cm-60 cm.
The homogenizing driving mechanism is formed by connecting a homogenizing driving motor 2-4-1 and a speed reducer 2-4-2.
The device also comprises a control box 8, wherein a rotating speed sensor is arranged on the speed reducer 2-4-2, and the heat medium supply source and the liquid adding source are respectively a heat medium supply pump connected with the heat medium source and a liquid adding pump connected with the liquid source;
the control box 8 is respectively connected with a bracket driving motor 1-1, a homogeneous driving motor 2-4-1, a rotating speed sensor, a heat medium supply pump, a liquid feeding pump, a waterproof motor 2-2-4 and a fishing motor 7-2-1.
The number of the supporting steel frames 1 is 3, and the supporting steel frames are uniformly distributed on the outer side of the mixing tank 2;
the wall thickness of the homogeneous mixing cabin body 2-1 is 2 mm-50 mm;
the separating filter screen funnel 2-2 is positioned at the position 25 mm-55 mm above the waist part of the homogeneous mixing cabin body 2-1;
the included angle between the liquid feeding pipeline 2-3 and the horizontal direction is 10-32 degrees;
the funnel stirring blade 2-2-5 consists of a circular ring sleeved outside the funnel rotating shaft 10 and a radial connecting rod for connecting the circular ring and the funnel rotating shaft 10;
the thickness of the pore canal 2-2-1-1 is 20 mm-30 mm.
The homogenizing degree detector 2-5 is arranged inside the homogenizing mixing cabin body 2-1, and the homogenizing degree detector 2-5 is connected with the control box 8.
The number of the high-speed homogenizing wave wheels 2-4-5 is 10, the adjacent high-speed homogenizing wave wheels 2-4-5 are arranged at equal intervals, the distance is 5 mm-12 mm, and the shape of the high-speed homogenizing wave wheels 2-4-5 is ratchet-shaped.
The bottom of the tank body 7-3 is in an inverted frustum shape, and a COD sensor 7-5-1 connected with a control box 8 is arranged in a clear liquid zone 7-5.
The distance between the two bracket gears 1-6 is 15 cm-25 cm.
The high-speed homogeneous impeller 2-4-5 is made of high polymer materials and comprises the following components in percentage by mass:
30-65% of methyl ester derivative, 25-60% of thiophosphate derivative, 1-5% of mixed auxiliary agent, 1-5% of cross-linking agent, 15-45% of O-ethyl O- (4-methylthiophenyl) S-propyl phosphorodithioate and 2-15% of (T-4) -bis (diethyl dithiocarbamate-S, S') zinc.
The cross-linking agent is any one of sodium diisopropyl dithiophosphate, isoamyl and isopropyl) zinc dithiophosphate and tetraphenyl (bisphenol-A) diphosphate.
The molecular structure of the methyl ester derivative is characterized as shown in figure 11, wherein R is alkyl with 1-8 carbon atoms.
The molecular structure of the phosphorothioate derivative is characterized as shown in FIG. 12, and the molecular formula is as follows: C10H15O3PS 2; molecular weight: 278.343.
the mixing auxiliary agent is an oxysilane substance, the molecular structural formula of the mixing auxiliary agent is shown in figure 13, and the molecular formula of the molecular structure is as follows: C16H20O2 Si.
The preparation method of the high-speed homogeneous impeller 2-4-5 comprises the following steps:
step 1: adding 22-32% of ultrapure water with the conductivity of 1.25 muS/cm-3.15 muS/cm into a reaction kettle, starting a stirrer in the reaction kettle at the rotating speed of 125-375 rpm, and starting a heating pump to raise the temperature in the reaction kettle to 75-185 ℃; sequentially adding 30-65% of methyl ester derivatives and 1-5% of mixed auxiliary agents, stirring until the methyl ester derivatives and the mixed auxiliary agents are completely dissolved, adjusting the pH value to 5.5-8.5, adding 25-60% of thiophosphate derivatives, and adjusting the rotation speed of a stirrer to 255-315 rpm at the temperature of 90-395 ℃;
step 2: adding 15-45% of O-ethyl O- (4-methylthiophenyl) S-propyl dithiophosphate and 2-15% of (T-4) -bis (diethyl dithiocarbamate-S, S') zinc, and uniformly mixing;
and 3, step 3: adding 1-5% of cross-linking agent, stirring at 75-235 rpm and 90-265 deg.C, holding the state for 5-25 hr, discharging, and molding to obtain the high-speed homogeneous impeller 2-4-5.
The following examples further illustrate the content of the present invention, which is an important component of the present invention as the high-speed homogeneous pulsator 2-4-5, because of its existence, the service life of the whole apparatus is increased, and it plays a key role in the safe and smooth operation of the whole apparatus. To this end, the following examples further demonstrate that the components of the present invention exhibit physical characteristics that are higher than those of other related patents.
Example 1
The high-speed homogeneous impeller 2-4-5 is manufactured according to the following steps, and comprises the following components by mass percent:
step 1: adding 22% of ultrapure water with the conductivity of 1.25 muS/cm into the reaction kettle, starting a stirrer in the reaction kettle at the rotating speed of 125rpm, and starting a heating pump to raise the temperature in the reaction kettle to 75 ℃; sequentially adding 30% of methyl ester derivative and 1% of mixed auxiliary agent, stirring until the methyl ester derivative and the mixed auxiliary agent are completely dissolved, adjusting the pH value to 5.5, adding 25% of thiophosphate derivative, and adjusting the rotation speed of a stirrer to 255rpm at the temperature of 90 ℃;
step 2: adding 15-45% of O-ethyl O- (4-methylthiophenyl) S-propyl dithiophosphate and 2% of (T-4) -bis (diethyl dithiocarbamate-S, S') zinc, and uniformly mixing;
and 3, step 3: adding cross-linking agent 1%, stirring at 75rpm and 90 deg.C, holding the state for 5 hr, discharging, and molding to obtain high-speed homogeneous impeller 2-4-5.
Example 2
The high-speed homogeneous impeller 2-4-5 is manufactured according to the following steps, and comprises the following components by mass percent:
step 1: adding 32% of ultrapure water with the conductivity of 3.15 mu S/cm into the reaction kettle, starting a stirrer in the reaction kettle at the rotating speed of 375rpm, and starting a heating pump to raise the temperature in the reaction kettle to 185 ℃; sequentially adding 65% of methyl ester derivative and 5% of mixed auxiliary agent, stirring until the methyl ester derivative and the mixed auxiliary agent are completely dissolved, adjusting the pH value to 8.5, adding 60% of thiophosphate derivative, and adjusting the rotation speed of a stirrer to 315rpm at 395 ℃;
step 2: adding 45% of O-ethyl O- (4-methylthiophenyl) S-propyl dithiophosphate and 15% of (T-4) -bis (diethyl dithiocarbamate-S, S') zinc, and uniformly mixing;
and 3, step 3: adding cross-linking agent 5%, stirring at 235rpm and 265 deg.C, holding the state for 25 hr, discharging, and molding to obtain high-speed homogeneous impeller 2-4-5.
Example 3
The high-speed homogeneous impeller 2-4-5 is manufactured according to the following steps, and comprises the following components by mass percent:
step 1: adding 29 percent of ultrapure water with the conductivity of 1.315 mu S/cm into a reaction kettle, starting a stirrer in the reaction kettle at the rotating speed of 178rpm, and starting a heating pump to raise the temperature in the reaction kettle to 85 ℃; sequentially adding 39% of methyl ester derivative and 4% of mixed auxiliary agent, stirring until the methyl ester derivative and the mixed auxiliary agent are completely dissolved, adjusting the pH value to 5.8, adding 40% of thiophosphate derivative, and adjusting the rotation speed of a stirrer to 300rpm at the temperature of 90 ℃;
step 2: adding 40% of O-ethyl O- (4-methylthiophenyl) S-propyl dithiophosphate and 10% of (T-4) -bis (diethyl dithiocarbamate-S, S') zinc, and uniformly mixing;
and 3, step 3: adding 3% cross-linking agent, stirring at 90rpm and 91 deg.C, holding the state for 8 hr, discharging, and molding to obtain high-speed homogeneous impeller 2-4-5.
Comparative example
The comparison example is the use condition of a high-speed homogenizing impeller of a certain brand sold in the market in the oil product mixing and sorting process.
The high-speed homogeneous wave wheel 2-4-5 prepared in the embodiment 1-3 and the high-speed homogeneous wave wheel described in the comparative example are used for comparing the use conditions of the oil product mixing process, and the volume resistivity, the oil separation degree, the viscosity reduction rate and the mixing uniformity improvement rate are taken as technical indexes for statistics, and the results are shown in table 1:
table 1 shows the comparison results of various parameters of the high-speed homogenizing impeller described in examples 1 to 3 and the comparative example when used in the oil product mixing process, and it can be seen from table 1 that the volume resistivity, the oil separation degree, the viscosity reduction rate, and the mixing uniformity improvement rate of the high-speed homogenizing impeller 2-4-5 of the present invention are all higher than those of the products produced by the prior art.
Further, as shown in FIG. 10, the influence of the O-ethyl O- (4-methylthiophenyl) S-propyl phosphorodithioate ratio on the uniformity improvement rate is shown. As seen in the figure, the doping amount of the high-speed homogeneous impeller 2-4-5 material is important for improving the product performance, and the doping amount is greatly superior to that of the existing product in the aspect of uniformity improvement rate.
The working method of the device comprises the following steps:
step 1: the material to be processed enters the mixing tank 2 through a guide pipe, the upper pressure sealing cover 3 slowly descends through being connected with the crank arm 4 under the action of the upper telescopic oil cylinder 5 and is fitted with the mixing tank 2 to realize sealing;
step 2: when the support dispatching needs to be adjusted, three support driving motors 1-1 in the three support steel frames 1 are controlled to synchronously operate, and the transmission boxes 1-2 are driven to operate; the transmission case 1-2 simultaneously drives the support gear 1-6 to rotate in the same direction, so that the support gear 1-6 drives the L-shaped support 1-7 to ascend and descend, and the sliding groove arranged at the vertical section of the L-shaped support 1-7 is sleeved outside the sliding rail 1-4 in a sliding manner, so that the L-shaped support 1-7 can be ensured not to be separated from the vertical beam 1-9 in the ascending or descending process; when the bracket gear 1-6 rotates anticlockwise, the L-shaped bracket 1-7 is in a rising state; when the support gear 1-6 rotates clockwise, the L-shaped support 1-7 is in a descending state;
and 3, step 3: in the mixing tank 2, a material to be treated enters the separating screen funnel 2-2 through the liquid adding pipeline 2-3, the liquid adding pipeline 2-3 is obliquely arranged, the entered material acts on the separating screen funnel 2-2, the separating screen funnel 2-2 rotates while performing filtering operation, and the rotating separating screen funnel 2-2 performs filtering, so that the filtering effect is better; the two homogenizing driving mechanisms drive the two pairs of homogenizing impeller groups to move oppositely, and the high-speed homogenizing impellers in the pair of homogenizing impeller groups are meshed, so that the material can achieve a homogenizing effect and further enter the lower part of the homogenizing mixing bin body 2-1; the homogeneity degree detector 2-5 carries out induction reaction on the homogeneity degree of the material entering the lower part of the homogeneous mixing bin body 2-1 and detects the homogeneity degree; when the homogeneity degree does not meet the detection standard, the homogeneity degree detector 2-5 sends an electric signal to the control box 8, and the controller 8 gives an alarm through an alarm connected with the controller.
And 4, step 4: in the separating filter screen funnel 2-2, the waterproof motor 2-2-4 is switched on and then operates to drive the funnel gear 2-2-3 to rotate, and then the funnel gear 2-2-3 drives the funnel rotating shaft 10 to operate to drive the funnel stirring blade 2-2-5 to rotate, so that the materials are uniformly stirred; after being stirred, the materials flow out of the openings 2-2-1 on the bottom plate and the side wall of the separating filter screen funnel 2-2 and enter a sedimentation treatment tank 7 for sedimentation;
and 6, step 6: in the floater salvaging equipment 7-2, after a salvaging motor 7-2-1 is powered on, a salvaging cam 7-3-2 is driven to operate, and then a salvaging driving rod 7-2-3 and a salvaging driving arm 7-2-4 are driven to swing back and forth so as to drive a salvaging rotating shaft 7-2-5 to rotate back and forth and drive a salvaging crank arm 7-2-2 on the lower side to swing up and down, thereby realizing the salvaging of floaters; the salvaged floating objects are hung on the salvage steel wires 7-2-8 and can be removed in a manual mode in the process of salvage or after the salvage is finished;
and 7, step 7: in the bearing bottom support 2-2-6, cooling liquid enters from a cooling liquid inlet pipeline 2-2-6-4 and flows into the annular cavity 2-2-6-2 through a cooling liquid outlet pipeline 2-2-6-4, and then is discharged from the cooling liquid outlet pipeline 2-2-6-4; and cooling the stop bearing 2-2-6-3.
Claims (7)
1. A high-salinity mine water treatment device comprises a mixing tank (2) and a plurality of supporting steel frames (1) fixedly connected to the outer side of the lower portion of the mixing tank (2), and is characterized by further comprising an upper connecting crank arm (4), an upper telescopic oil cylinder (5) and a sedimentation treatment tank (7);
the supporting steel frame (1) comprises supports (1-8), a pair of vertical beams (1-9) which are fixedly connected to the supports (1-8) in parallel, L-shaped supports (1-7) arranged on one sides of the vertical beams (1-9) and support driving motors (1-1) arranged on one sides of the vertical beams (1-9); a pair of vertical beams (1-9) are respectively provided with a longitudinally extending continuous rack (1-5) and a longitudinally extending slide rail (1-4) at the same side; the upper part and the lower part of the vertical section of the L-shaped bracket (1-7) corresponding to the position of the continuous rack (1-5) are respectively provided with a bracket gear (1-6), and the bracket gear (1-6) is rotatably connected to the vertical section of the L-shaped bracket (1-7) through a gear rotating shaft at the center of the bracket gear; a chute is formed in the position, corresponding to the sliding rail (1-4), of the vertical section of the L-shaped support (1-7), the chute is sleeved outside the sliding rail (1-4) in a sliding mode, and a support end (1-3) on the horizontal section of the L-shaped support (1-7) is fixedly connected with the outer side wall of the mixing tank (2); the support driving motor (1-1) is fixedly connected to one side of the L-shaped support (1-7) departing from the support gears (1-6), an output shaft of the support driving motor is connected with an input end of a transmission case (1-2) fixedly connected to one side of the L-shaped support (1-7), and an output end of the transmission case (1-2) is connected with gear rotating shafts of the two support gears (1-6);
an upper pressure sealing cover (3) for sealing the mixing tank (2) is arranged at the upper opening end of the mixing tank (2), and a liquid discharge pipeline (6) communicated with the inner cavity of the mixing tank (2) is fixedly connected at the bottom end of the mixing tank; one end of the upper connecting crank arm (4) is fixedly connected with the upper end face of the upper pressure sealing cover (3), and the other end of the upper connecting crank arm is hinged with a hinge seat fixedly connected to the outer side of the upper end of the mixing tank (2); one end of the upper telescopic oil cylinder (5) is hinged with the outer side of the hinged end of the upper connecting crank arm (4), and the other end of the upper telescopic oil cylinder is hinged with the middle part of the tank body of the mixing tank (2) so as to control the covering or the opening of the upper pressure sealing cover (3) through telescopic action;
the mixing tank (2) comprises a homogeneous mixing cabin body (2-1) with a jacket structure, a jacket of the homogeneous mixing cabin body (2-1) is filled with heat transfer media, the outside of the homogeneous mixing cabin body (2-1) is connected with a heat medium pipeline communicated with the jacket space of the homogeneous mixing cabin body, and the other end of the heat medium pipeline is connected with a heat medium supply source;
a liquid adding pipeline (2-3) which is obliquely arranged, a separating screen funnel (2-2) which is horizontally placed and can rotate relative to the homogenizing mixing cabin body (2-1) and a homogenizing system (2-4) are sequentially arranged in the homogenizing mixing cabin body (2-1) from top to bottom, a plurality of side wall open pores (2-2-1) are arranged on the side wall of the separating screen funnel (2-2) all over, a plurality of small holes are arranged on the bottom plate of the separating screen funnel (2-2) all over the surface of the separating screen funnel, the rotating center of the bottom plate is connected with a funnel rotating shaft (10) through a bearing bottom support (2-2-6) fixedly connected with the bottom plate, and the lower end of the funnel rotating shaft (10) in the separating screen funnel (2-2) is connected with a funnel stirring blade (2-2-5) in clearance fit with the inner part of the lower end of the homogenizing and mixing bin body (2-1); an outer gear ring (2-2-2) is sleeved at the upper end of the funnel rotating shaft (10) outside the separating filter screen funnel (2-2), and the outer gear ring (2-2-2) is fixedly connected with the funnel rotating shaft (10) through a radial connecting beam (9); a waterproof motor (2-2-4) is fixedly connected to the inner side wall of the homogeneous mixing cabin body (2-1) corresponding to the outer gear ring (2-2-2), a funnel gear (2-2-3) is assembled on an output shaft of the waterproof motor (2-2-4), and the funnel gear (2-2-3) is meshed with the outer gear ring (2-2-2); the liquid outlet end of the liquid adding pipeline (2-3) is positioned above the separating filter screen funnel (2-2), and the liquid inlet end of the liquid adding pipeline penetrates through the side wall of the homogenizing and mixing cabin body (2-1) and then is connected with a liquid adding source;
a bearing accommodating groove (2-2-6-1) which is sunken downwards is formed in the center of the bearing bottom support (2-2-6), and an annular cavity (2-2-6-2) is formed in the bearing bottom support (2-2-6) in a manner of surrounding the bearing accommodating groove (2-2-6-1); a retaining bearing (2-2-6-3) is fixedly assembled in the bearing accommodating groove, and the inner ring of the retaining bearing (2-2-6-3) is fixedly connected with the funnel rotating shaft (10); the annular cavity (2-2-6-2) is respectively connected with a cooling liquid inlet pipeline (2-2-6-4) and a cooling liquid outlet pipeline (2-2-6-5) which are communicated with the inner cavity of the annular cavity, and the cooling liquid inlet pipeline (2-2-6-4) and the cooling liquid outlet pipeline (2-2-6-5) are respectively connected with a cooling source and a cooling liquid recovery box after radially penetrating through the separating screen funnel (2-2) and the homogeneous mixing bin body (2-1);
the homogenizing system (2-4) comprises a pair of homogenizing middle shafts (2-4-3) which are arranged side by side, and a pair of corresponding homogenizing impeller sets are respectively and rotatably sleeved at the middle parts of the pair of homogenizing middle shafts (2-4-3), each homogenizing impeller set consists of a plurality of high-speed homogenizing impellers (2-4-5), and the high-speed homogenizing impellers (2-4-5) in the pair of homogenizing impeller sets are meshed; the two opposite ends of the pair of homogeneous middle shafts (2-4-3) respectively penetrate out of the homogeneous mixing cabin body (2-1) in a rotatable way and then are respectively connected with the output parts of the homogeneous driving mechanisms fixedly connected with the two sides outside the homogeneous mixing cabin body (2-1); the other end of the homogenizing middle shaft (2-4-3) far away from the driving mechanism is rotationally connected with the inner side wall of the homogenizing mixing cabin body (2-1) through a closed thrust bearing (2-4-4);
the sedimentation treatment tank (7) comprises a tank body (7-3) with an opening at the upper end, a floater fishing device (7-2) arranged inside the tank body (7-3), a tank body bracket (7-4) fixedly supported outside the tank body (7-3), a sedimentation treatment tank water inlet pipeline (7-7) fixedly connected to the upper end of the tank body (7-3), a bottom mud discharge pipeline (7-1) communicated with the bottom of an inner cavity of the tank body (7-3) and fixedly connected to the bottom end of the tank body (7-3), and a sedimentation treatment tank water outlet pipeline (7-8) communicated with the middle of the inner cavity of the tank body (7-3) and fixedly connected to one side of the tank body (7-3); a clear liquid zone (7-5) is formed in the middle of the inner part of the tank body (7-3), and a sludge accumulation zone (7-6) is formed at the bottom of the inner part of the tank body (7-3); the liquid inlet end of the water inlet pipeline (7-7) of the sedimentation treatment tank is communicated with the liquid outlet end of the liquid discharge pipeline (6);
the clear liquid area (7-5) is provided with dispersion plate units from top to bottom in sequence, the device comprises slow descending plate units and slow descending nets (7-5-4), wherein each dispersing plate unit consists of a plurality of wing-shaped dispersing plates (7-5-2) which are arranged side by side, adjacent wing-shaped dispersing plates (7-5-2) are fixedly connected through connecting rods, each slow descending plate unit consists of a plurality of square slow descending plates (7-5-3) which are arranged side by side, adjacent square slow descending plates (7-5-3) are fixedly connected through connecting rods, the water inlet end of a water outlet pipeline (7-8) of a sedimentation treatment pool is positioned at the lower part of each slow descending net (7-5-4), a detection port (7-5-5) is formed in the upper part of each dispersing plate unit of a clear liquid area (7-5), and a detection pipeline which is communicated with the inner cavity of the detection port (7-5-5) and is provided with a stop valve;
the floating object fishing equipment (7-2) comprises a fishing frame (7-2-6) fixedly connected to the upper end of the tank body (7-3), a fishing driving mechanism fixedly connected to the upper part of the fishing frame (7-2-6), fishing rotating shafts (7-2-5) which are arranged in parallel and respectively rotatably connected to two opposite sides of the fishing frame (7-2-6), and a plurality of pairs of fishing crank arms (7-2-7) which are arranged oppositely and respectively fixedly connected to the two fishing rotating shafts (7-2-5); one end of each pair of fishing crank arms (7-2-7) far away from the fishing rotating shaft (7-2-5) extends into the tank body (7-3) and is connected with the tank body through fishing steel wires (7-2-8); the fishing driving mechanism comprises a fishing motor (7-2-1) and a fishing cam (7-2-2) assembled on an output shaft of the fishing motor (7-2-1), eccentric connection points on the fishing cam (7-2-2) are respectively hinged with the inner ends of two fishing driving rods (7-2-3), the two fishing driving rods (7-2-3) are respectively hinged with the inner ends of two fishing driving arms (7-2-4) which are arranged oppositely, and the outer ends of the two fishing driving arms (7-2-4) are respectively fixedly connected with one end of two fishing rotating shafts (7-2-5).
2. The high-salinity mine water treatment device according to claim 1, wherein the homogenizing driving mechanism is formed by connecting a homogenizing driving motor (2-4-1) and a speed reducer (2-4-2).
3. The high-salinity mine water treatment device according to claim 1 or 2, characterized by further comprising a control box (8), wherein the speed reducer (2-4-2) is provided with a rotation speed sensor, and the heat medium supply source and the liquid adding source are respectively a heat medium supply pump connected with the heat medium source and a liquid adding pump connected with the liquid source;
the control box (8) is respectively connected with the bracket driving motor (1-1), the homogeneous driving motor (2-4-1), the rotating speed sensor, the heat medium supply pump, the liquid feeding pump, the waterproof motor (2-2-4) and the fishing motor (7-2-1).
4. The high-salinity mine water treatment device according to claim 3, characterized by further comprising a homogeneity degree detector (2-5) arranged inside the homogeneous mixing cabin body (2-1), wherein the homogeneity degree detector (2-5) is connected with the control box (8).
5. The high-salinity mine water treatment device according to claim 4, characterized in that the number of the high-speed homogenizing wave wheels (2-4-5) is 10, the adjacent high-speed homogenizing wave wheels (2-4-5) are arranged at equal intervals, the interval is between 5mm and 12mm, and the shape of the high-speed homogenizing wave wheels (2-4-5) is ratchet-shaped.
6. A high salinity mine water treatment device according to claim 5, characterized in that the bottom of the tank body (7-3) is of an inverted frustum shape, and a COD sensor (7-5-1) connected with the control box (8) is arranged in the clear liquid region (7-5).
7. The high-salinity mine water treatment device according to claim 6, characterized in that the distance between the two rack gears (1-6) is 15 cm-25 cm.
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| CN201811172717.9A CN109225026B (en) | 2018-10-09 | 2018-10-09 | High-salinity mine water treatment device |
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| CN203307613U (en) * | 2013-04-28 | 2013-11-27 | 巢湖市翔宇渔具有限公司 | High-temperature reaction kettle for dyeing fishing net |
| KR101577348B1 (en) * | 2015-06-02 | 2015-12-14 | 수생태복원(주) | Multi water treatment apparatus |
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