CN109216784B - Power lithium ion battery pack for vehicle - Google Patents

Power lithium ion battery pack for vehicle Download PDF

Info

Publication number
CN109216784B
CN109216784B CN201710514112.2A CN201710514112A CN109216784B CN 109216784 B CN109216784 B CN 109216784B CN 201710514112 A CN201710514112 A CN 201710514112A CN 109216784 B CN109216784 B CN 109216784B
Authority
CN
China
Prior art keywords
battery
battery module
voltage
battery pack
module
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201710514112.2A
Other languages
Chinese (zh)
Other versions
CN109216784A (en
Inventor
不公告发明人
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Hengjinyuan Electronic Technology Co ltd
Original Assignee
Qingdao Hengjinyuan Electronic Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Hengjinyuan Electronic Technology Co ltd filed Critical Qingdao Hengjinyuan Electronic Technology Co ltd
Priority to CN201710514112.2A priority Critical patent/CN109216784B/en
Publication of CN109216784A publication Critical patent/CN109216784A/en
Application granted granted Critical
Publication of CN109216784B publication Critical patent/CN109216784B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4207Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells for several batteries or cells simultaneously or sequentially
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/04Construction or manufacture in general
    • H01M10/0404Machines for assembling batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/058Construction or manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/425Structural combination with electronic components, e.g. electronic circuits integrated to the outside of the casing
    • H01M10/4257Smart batteries, e.g. electronic circuits inside the housing of the cells or batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44Methods for charging or discharging
    • H01M10/441Methods for charging or discharging for several batteries or cells simultaneously or sequentially
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44Methods for charging or discharging
    • H01M10/446Initial charging measures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/48Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
    • H01M10/482Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte for several batteries or cells simultaneously or sequentially
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/48Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
    • H01M10/486Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte for measuring temperature
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/425Structural combination with electronic components, e.g. electronic circuits integrated to the outside of the casing
    • H01M2010/4271Battery management systems including electronic circuits, e.g. control of current or voltage to keep battery in healthy state, cell balancing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00Batteries for particular applications
    • H01M2220/20Batteries in motive systems, e.g. vehicle, ship, plane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The invention provides a power lithium ion battery pack for a vehicle, wherein the battery pack comprises a plurality of battery modules, wherein each battery module comprises a plurality of single batteries; the battery pack further comprises a controller, a battery module detection device and a bypass device; when the battery module detection device detects that the parameters of the battery module are abnormal, the bypass device is started, and the battery module is moved out of a loop of the battery pack; when the battery module detects that the parameters of the battery module are recovered to be within the normal range, the bypass device is closed, and the battery module is moved back to the circuit of the battery pack; the battery pack can monitor and adjust the working state of the battery module in time, thereby ensuring the normal working state of the battery module and avoiding the service life attenuation of the battery module caused by abnormal charging and discharging.

Description

Power lithium ion battery pack for vehicle
Technical Field
The invention relates to the technical field of batteries, in particular to a power lithium ion battery pack for a vehicle.
Background
In order to meet the power and energy requirements of electric vehicles, the power batteries of the electric vehicles must be used in groups. Meanwhile, due to the requirements on the arrangement and control of the battery pack, the battery cells are usually combined into small battery modules in series and parallel, and then the battery modules are connected in series to meet the requirements of the vehicle on power. At present, a battery pack used in an electric vehicle is generally formed by connecting a plurality of battery monomers in parallel and in series, and the voltage at the output end of the battery pack can be improved by connecting the plurality of battery monomers in series. However, when the single cell is abnormal, the operation of the entire battery pack is affected.
Disclosure of Invention
The invention provides a power lithium ion battery pack for a vehicle, wherein the battery pack comprises a plurality of battery modules, wherein each battery module comprises a plurality of single batteries; the battery pack also comprises a controller, a battery module detection device and a bypass device; when the battery module detection device detects that the parameters of the battery module are abnormal, the bypass device is started, and the battery module is moved out of a loop of the battery pack; when the battery module detects that the parameters of the battery module are recovered to be within the normal range, the bypass device is closed, and the battery module is moved back to the circuit of the battery pack; the battery pack can monitor and adjust the working state of the battery module in time, thereby ensuring the normal working state of the battery module and avoiding the service life attenuation of the battery module caused by abnormal charging and discharging.
The specific scheme is as follows:
a power lithium ion battery pack for a vehicle, wherein the battery pack comprises a plurality of battery modules, wherein each battery module comprises a plurality of single batteries; the battery pack also comprises a controller, a battery module detection device and a bypass device; when the battery module detection device detects that the parameters of the battery module are abnormal, the bypass device is started, and the battery module is moved out of a loop of the battery pack; and when the battery module detection device detects that the parameters of the battery module are restored to be within the normal range, the bypass device is closed, and the battery module is moved back to the circuit of the battery pack.
Furthermore, the battery module comprises a single battery detection device and a battery bypass device; when the single battery detection device detects that the parameters of the single battery are abnormal, the battery bypass device is started, and the single battery is moved out of a loop of the battery module; and when the single battery detection device detects that the parameters of the single batteries are recovered to be within the normal range, the bypass device is closed, and the single batteries are moved back to the loop of the battery module.
Further, the parameters detected by the battery module detection device are selected from voltage, temperature and heating speed.
Further, the parameters detected by the single battery detection device are selected from voltage, temperature and heating speed.
Further, the parameter detected by the battery module detecting device comprises a temperature rising speed.
Further, the parameter detected by the single battery detection device comprises a temperature rise speed.
Further, the method for preparing the battery pack comprises the step of forming and matching the single lithium ion battery.
The formation and matching steps of the single lithium ion battery comprise:
1) providing a group of lithium ion batteries to be formed, carrying out pulse charging on the batteries by using current of 0.02-0.05C, and stopping charging until the charging is cut off to voltage; wherein the pulse time is 0.1-10min, the interval time is 30-120s, and the charging cut-off voltage is 4.2-4.35V;
2) discharging the battery at a current of 0.05-0.2C until the discharge cutoff voltage is 2.7-2.8V;
3) repeating the step 1-2 for 0-3 times;
4) standing and aging for 1-5 days;
5) extracting electrolyte which is not immersed into the electrode in the battery shell, re-injecting new electrolyte, and sealing;
6) charging the battery with a current of 1-5C until the charging cut-off voltage is 4.2-4.35V, and discharging the battery with a current of 1-5C until the discharging cut-off voltage is 2.7-2.8V;
7) repeating the step 6 for 0-5 times, recording the capacity of the battery and the temperature of the battery, and matching the batteries with the capacity difference of 3% and the temperature difference of 5 ℃ into a group.
The invention has the following beneficial effects:
1. by monitoring the working state of the battery module/single battery and adjusting the working state in time, the normal working state of the battery module/single battery is ensured, and the service life attenuation of the battery module/single battery due to long-term abnormal charging and discharging is avoided.
2. In the process of early formation, metal ions in the active material are inevitably partially dissolved into the electrolyte, and the process of forming the SEI film can also influence the composition of the electrolyte, and the influence can influence the performance of the battery, so that after the formation is finished, the electrolyte with changed components is extracted, and new electrolyte is injected again, and the storage life of the battery can be prolonged.
3. Concentration polarization on the surface of the electrode is eliminated by charging with a small current pulse, so that a uniform and stable SEI film is formed. The active material of the electrode was sufficiently activated by a large current charge-discharge cycle, and the rate performance of the battery was measured.
4. The heating value among different batteries is amplified by increasing the current, so that batteries with similar capacity and the same heat dissipation are configured into a battery pack more accurately according to the capacity and the heating value of the batteries, and the uniformity of the battery pack is improved.
The battery pack which is long in service life, stable in performance and good in single battery performance consistency is constructed by the method.
Detailed Description
The present invention will be described in more detail below with reference to specific examples, but the scope of the present invention is not limited to these examples.
Example 1
1) Providing a lithium ion battery to be formed, carrying out pulse charging on the battery with the current of 0.05C, and stopping charging until the voltage is cut off; wherein the pulse time is 10min, the interval time is 120s, and the charging cut-off voltage is 4.35V;
2) discharging the battery at a current of 0.2C to a discharge cutoff voltage, wherein the discharge cutoff voltage is 2.8V;
3) repeating the step 1-2 for 3 times;
4) standing and aging for 5 days;
5) the electrolyte which is not immersed in the electrode in the battery shell is extracted out, new electrolyte is injected again, and the sealing is carried out, wherein the new electrolyte comprises 1.2mol/L lithium hexafluorophosphate and the volume ratio is 1: 2: 1 of dimethyl carbonate, ethyl carbonate, a non-aqueous solvent consisting of ethyl methyl carbonate, and 5% of fluoroethylene carbonate;
6) charging the battery with a current of 5C until the charging cut-off voltage is 4.35V, discharging the battery with a current of 5C until the discharging cut-off voltage is 2.8V;
7) repeating the step 6 for 5 times, recording the capacity of the battery and the temperature of the battery, and matching the batteries with the capacity difference of 3% and the temperature difference of 5 ℃ into a group;
8) forming the batteries in the same group into a battery pack, wherein the battery pack comprises 8 battery modules, and each battery module comprises 10 single batteries; the battery pack also comprises a controller, a battery module detection device and a bypass device; when the battery module detection device detects that the voltage of a certain battery module deviates from the average module voltage by more than 10%, starting the bypass device, and moving the battery module out of a loop of the battery pack; when the battery module detection device detects that the voltage of the battery module deviates from the average module voltage by less than 5%, the bypass device is closed, and the battery module is moved back to the circuit of the battery pack.
Example 2
1) Providing a lithium ion battery to be formed, carrying out pulse charging on the battery with the current of 0.02C, and stopping charging until the voltage is cut off; wherein the pulse time is 0.1min, the interval time is 30s, and the charging cut-off voltage is 4.2V;
2) discharging the battery at a current of 0.05C to a discharge cutoff voltage, wherein the discharge cutoff voltage is 2.7V;
3) repeating the step 1-2 for 0 times;
4) standing and aging for 1 day;
5) the electrolyte which is not immersed in the electrode in the battery shell is extracted out, new electrolyte is injected again, and the sealing is carried out, wherein the new electrolyte comprises 1.2mol/L lithium hexafluorophosphate and the volume ratio is 1: 2: 1 of dimethyl carbonate, ethyl carbonate, a non-aqueous solvent consisting of ethyl methyl carbonate, and 5% of fluoroethylene carbonate;
6) charging the battery with the current of 1C until the charging cut-off voltage is 4.2V, discharging the battery with the current of 1C until the discharging cut-off voltage is 2.7V;
7) repeating the step 6 for 1 time, recording the capacity of the battery and the temperature of the battery, and matching the batteries with the capacity difference of 1% and the temperature difference of 2 ℃ into a group;
8) forming the batteries in the same group into a battery pack, wherein the battery pack comprises 8 battery modules, and each battery module comprises 10 single batteries; the battery pack also comprises a controller, a battery module detection device and a bypass device; when the battery module detection device detects that the voltage of a certain battery module deviates from the average module voltage by more than 10%, starting the bypass device, and moving the battery module out of a loop of the battery pack; when the battery module detects that the voltage of the battery module is within 5% of the average module voltage, closing a bypass device, and moving the battery module back to a loop of a battery pack, wherein the battery module comprises a single battery detection device and a battery bypass device; when the single battery detection device detects that the deviation between the voltage of a certain single battery and the average battery voltage is greater than 10%, the battery bypass device is started, and the single battery is moved out of a loop of the battery module; and when the single battery detection device detects that the voltage of the single battery deviates from the average battery voltage by less than 5%, closing the bypass device, and moving the single battery back to the loop of the battery module.
Example 3
1) Providing a lithium ion battery to be formed, carrying out pulse charging on the battery with the current of 0.03C, and stopping charging until the voltage is cut off; wherein the pulse time is 2min, the interval time is 40s, and the charging cut-off voltage is 4.3V;
2) discharging the battery at a current of 0.1C to a discharge cutoff voltage, wherein the discharge cutoff voltage is 2.75V;
3) repeating the step 1-2 for 2 times;
4) standing and aging for 3 days;
5) the electrolyte which is not immersed in the electrode in the battery shell is extracted out, new electrolyte is injected again, and the sealing is carried out, wherein the new electrolyte comprises 1.2mol/L lithium hexafluorophosphate and the volume ratio is 1: 2: 1 of dimethyl carbonate, ethyl carbonate, a non-aqueous solvent consisting of ethyl methyl carbonate, and 5% of fluoroethylene carbonate;
6) charging the battery by using the current of 3C until the charging cut-off voltage is 4.25V, and discharging the battery by using the current of 3C until the discharging cut-off voltage is 2.75V;
7) repeating the step 6 for 3 times, recording the capacity of the battery and the temperature of the battery, and matching the batteries with the capacity difference of 2% and the temperature difference of 3 ℃ into a group;
8) forming the batteries in the same group into a battery pack, wherein the battery pack comprises 8 battery modules, and each battery module comprises 10 single batteries; the battery pack also comprises a controller, a battery module detection device and a bypass device; when the battery module detection device detects that the deviation between the temperature of a certain battery module and the average module temperature is more than 15%, starting the bypass device, and moving the battery module out of a loop of the battery pack; when the battery module detects that the temperature of the battery module is within 5% of the average module temperature, the bypass device is closed and the battery module is moved back to the battery pack loop. The battery module comprises a single battery detection device and a battery bypass device; when the single battery detection device detects that the deviation between the temperature of a certain single battery and the average battery temperature is larger than 15%, the battery bypass device is started, and the single battery is moved out of a loop of the battery module; and when the single battery detection device detects that the temperature of the single battery deviates from the average battery temperature by less than 5%, closing the bypass device, and moving the single battery back to the loop of the battery module.
Example 4
1) Providing a lithium ion battery to be formed, carrying out pulse charging on the battery with the current of 0.04C, and stopping charging until the charging is cut off to the voltage; wherein the pulse time is 8min, the interval time is 80s, and the charging cut-off voltage is 4.25V;
2) discharging the battery at a current of 0.15C to a discharge cutoff voltage, wherein the discharge cutoff voltage is 2.75V;
3) repeating the step 1-2 for 2 times;
4) standing and aging for 2 days;
5) the electrolyte which is not immersed in the electrode in the battery shell is extracted out, new electrolyte is injected again, and the sealing is carried out, wherein the new electrolyte comprises 1.2mol/L lithium hexafluorophosphate and the volume ratio is 1: 2: 1 of dimethyl carbonate, ethyl carbonate, a non-aqueous solvent consisting of ethyl methyl carbonate, and 5% of fluoroethylene carbonate;
6) charging the battery by using the current of 4C until the charging cut-off voltage is reached, wherein the charging cut-off voltage is 4.25V, discharging the battery by using the current of 4C until the discharging cut-off voltage is reached, and wherein the discharging cut-off voltage is 2.75V;
7) repeating the step 6 for 4 times, recording the capacity of the battery and the temperature of the battery, and matching the batteries with the capacity difference of within 1% and the temperature difference of within 3 ℃ into a group;
8) forming the batteries in the same group into a battery pack, wherein the battery pack comprises 8 battery modules, and each battery module comprises 10 single batteries; the battery pack also comprises a controller, a battery module detection device and a bypass device; when the battery module detection device detects that the temperature rising speed of a certain battery module is higher than the average module temperature rising speed by 8 percent, the bypass device is started, and the battery module is moved out of a loop of the battery pack; and when the battery module detects that the temperature rising speed of the battery module is within 3% of the average module temperature rising speed, closing the bypass device, and moving the battery module back to the circuit of the battery pack. The battery module comprises a single battery detection device and a battery bypass device; when the single battery detection device detects that the temperature rise speed of a certain single battery is higher than the average battery temperature rise speed by 8 percent, the battery bypass device is started, and the single battery is moved out of a loop of the battery module; and when the single battery detection device detects that the deviation of the temperature rise speed of the single battery and the average battery temperature rise speed is less than 3%, closing the bypass device, and moving the single battery back to the loop of the battery module.
Example 5
1) Providing a lithium ion battery to be formed, carrying out pulse charging on the battery with the current of 0.03C, and stopping charging until the voltage is cut off; wherein the pulse time is 5min, the interval time is 60s, and the charging cut-off voltage is 4.3V;
2) discharging the battery at a current of 0.1C to a discharge cutoff voltage, wherein the discharge cutoff voltage is 2.8V;
3) repeating the step 1-2 for 1 time;
4) standing and aging for 2 days;
5) the electrolyte which is not immersed in the electrode in the battery shell is extracted out, new electrolyte is injected again, and the sealing is carried out, wherein the new electrolyte comprises 1.2mol/L lithium hexafluorophosphate and the volume ratio is 1: 2: 1 of dimethyl carbonate, ethyl carbonate, a non-aqueous solvent consisting of ethyl methyl carbonate, and 5% of fluoroethylene carbonate;
6) charging the battery by using the current of 2C until the charging cut-off voltage is reached, wherein the charging cut-off voltage is 4.3V, discharging the battery by using the current of 2C until the discharging cut-off voltage is reached, and wherein the discharging cut-off voltage is 2.8V;
7) repeating the step 6 for 4 times, recording the capacity of the battery and the temperature of the battery, and matching the batteries with the capacity difference of within 1% and the temperature difference of within 2 ℃ into a group;
8) forming the batteries in the same group into a battery pack, wherein the battery pack comprises 8 battery modules, and each battery module comprises 10 single batteries; the battery pack also comprises a controller, a battery module detection device and a bypass device; when the battery module detection device detects that the temperature rising speed of a certain battery module is higher than the average module temperature rising speed by 5 percent, the bypass device is started, and the battery module is moved out of a loop of the battery pack; and when the battery module detects that the temperature rising speed of the battery module is within 2 percent of the average module temperature rising speed, closing the bypass device, and moving the battery module back to the circuit of the battery pack. The battery module comprises a single battery detection device and a battery bypass device; when the single battery detection device detects that the temperature rise speed of a certain single battery is higher than the average battery temperature rise speed by 5 percent, the battery bypass device is started, and the single battery is moved out of a loop of the battery module; and when the single battery detection device detects that the deviation of the temperature rise speed of the single battery and the average battery temperature rise speed is within 2%, closing the bypass device, and moving the single battery back to the loop of the battery module.
Comparative example 1
Selecting a group of lithium ion batteries, carrying out charge-discharge circulation for three times, wherein the charge cut-off voltage is 4.2V, and the discharge cut-off voltage is 2.7V, and measuring the capacity of the lithium ion batteries;
2) and preparing a group of lithium ion batteries with the capacity difference within 1 percent.
8) And forming the batteries in the same group into a battery pack, wherein the battery pack comprises 8 battery modules, and each battery module comprises 10 single batteries.
Test and results
The battery uniformity performance test, which is to test the capacities of the unit cells in the batteries of examples 1 to 5 and comparative example 1 after cycling at normal temperature for 300 times, and calculate the maximum capacity difference of the battery modules in the battery pack and the percentage of the maximum capacity difference in the battery, shows that the deterioration between the battery modules and between the batteries of the battery pack of comparative example 1 is severe.
TABLE 1
Figure BDA0001336256050000061
Figure BDA0001336256050000071
While the present invention has been described in detail with reference to the preferred embodiments, it should be understood that the above description should not be taken as limiting the invention.

Claims (6)

1. A power lithium ion battery pack for a vehicle is characterized in that,
1) the lithium ion battery is to be formed, the battery is subjected to pulse charging at the current of 0.05C, and the charging is stopped until the voltage is cut off; wherein the pulse time is 10min, the interval time is 120s, and the charging cut-off voltage is 4.35V;
2) discharging the battery at a current of 0.2C to a discharge cutoff voltage, the discharge cutoff voltage being 2.8V;
3) repeating the steps 1-2 for 3 times;
4) standing and aging for 5 days;
5) extracting electrolyte which is not immersed into the electrode in the battery shell, re-injecting new electrolyte, and sealing, wherein the new electrolyte comprises 1.2mol/L lithium hexafluorophosphate and a volume ratio of 1: 2: 1 of dimethyl carbonate, ethyl carbonate, a non-aqueous solvent consisting of ethyl methyl carbonate, and 5% of fluoroethylene carbonate;
6) charging the battery with a current of 5C until the charging cut-off voltage is 4.35V, discharging the battery with a current of 5C until the discharging cut-off voltage is 2.8V;
7) repeating the step 6 for 5 times, recording the capacity of the battery and the temperature of the battery, and matching the batteries with the capacity difference of less than 3% and the temperature difference of less than 5 ℃ into a group; wherein the battery pack includes a plurality of battery modules, wherein a battery module includes a plurality of unit cells; the battery pack also comprises a controller, a battery module detection device and a bypass device; when the battery module detection device detects that the parameters of the battery module are abnormal, the bypass device is started, and the battery module is moved out of a loop of the battery pack; when the battery module detection device detects that the parameters of the battery module are recovered to be within the normal range, the bypass device is closed, and the battery module is moved back to the circuit of the battery pack;
the battery module comprises a single battery detection device and a battery bypass device; when the single battery detection device detects that the parameters of the single battery are abnormal, the battery bypass device is started, and the single battery is moved out of a loop of the battery module; and when the single battery detection device detects that the parameters of the single batteries are recovered to be within the normal range, the bypass device is closed, and the single batteries are moved back to the loop of the battery module.
2. The battery pack according to claim 1, wherein the parameter detected by the battery module detecting means is selected from the group consisting of voltage, temperature, and temperature rising rate.
3. The battery pack according to claim 1, wherein the parameters detected by the cell detection means are selected from the group consisting of voltage, temperature, and temperature rise rate.
4. The battery pack according to claim 2, wherein the parameter detected by the battery module detecting means includes a temperature rise rate.
5. The battery pack according to claim 3, wherein the parameter detected by the cell detection means includes a temperature rise rate.
6. A method of manufacturing a battery according to any of claims 1 to 5, comprising the step of grouping the cells after activation of the cells.
CN201710514112.2A 2017-06-29 2017-06-29 Power lithium ion battery pack for vehicle Active CN109216784B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710514112.2A CN109216784B (en) 2017-06-29 2017-06-29 Power lithium ion battery pack for vehicle

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710514112.2A CN109216784B (en) 2017-06-29 2017-06-29 Power lithium ion battery pack for vehicle

Publications (2)

Publication Number Publication Date
CN109216784A CN109216784A (en) 2019-01-15
CN109216784B true CN109216784B (en) 2021-12-14

Family

ID=64960517

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710514112.2A Active CN109216784B (en) 2017-06-29 2017-06-29 Power lithium ion battery pack for vehicle

Country Status (1)

Country Link
CN (1) CN109216784B (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003134683A (en) * 2001-10-29 2003-05-09 Nissan Motor Co Ltd Controller for battery pack
JP2010239711A (en) * 2009-03-30 2010-10-21 Japan Research Institute Ltd Battery control device, vehicle, and method of controlling the battery
CN102742066A (en) * 2010-02-08 2012-10-17 福图知识产权股份公司 High-current battery system and method for controlling a high-current battery system
CN204334072U (en) * 2015-01-15 2015-05-13 上海电力设计院有限公司 The battery pack of energy isolated fault battery module
CN105914333A (en) * 2015-03-16 2016-08-31 中国新能源汽车有限公司 Battery pack and connecting circuits of battery modules

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6977483B2 (en) * 2002-08-23 2005-12-20 Nissan Motor Co., Ltd. Battery pack malfunction detection apparatus and method for detecting a disconnection at a connecting line between a given cell and a corresponding detection terminal
US20100164437A1 (en) * 2008-10-24 2010-07-01 Mckinley Joseph P Battery formation and charging system and method
CN101728579A (en) * 2008-10-28 2010-06-09 天空能源(洛阳)有限公司 Rapid forming method of lithium ion power battery
CN201364934Y (en) * 2009-02-27 2009-12-16 比亚迪股份有限公司 Maintenance device for carrying out capacity grading matching on power battery pack
CN104218267B (en) * 2014-07-30 2016-06-01 浙江超威创元实业有限公司 A kind of lithium ion battery divides appearance method for group matching

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003134683A (en) * 2001-10-29 2003-05-09 Nissan Motor Co Ltd Controller for battery pack
JP2010239711A (en) * 2009-03-30 2010-10-21 Japan Research Institute Ltd Battery control device, vehicle, and method of controlling the battery
CN102742066A (en) * 2010-02-08 2012-10-17 福图知识产权股份公司 High-current battery system and method for controlling a high-current battery system
CN204334072U (en) * 2015-01-15 2015-05-13 上海电力设计院有限公司 The battery pack of energy isolated fault battery module
CN105914333A (en) * 2015-03-16 2016-08-31 中国新能源汽车有限公司 Battery pack and connecting circuits of battery modules

Also Published As

Publication number Publication date
CN109216784A (en) 2019-01-15

Similar Documents

Publication Publication Date Title
CN107293812B (en) Formation and matching method of lithium ion battery
CN110416626B (en) Formation method of lithium ion battery
JP7076495B2 (en) How to quickly group and repair used batteries
CN102208685B (en) Processing method for formation of lithium ion batteries
CN110611133B (en) Charging method of lithium ion battery management system
CN102185166B (en) Battery forming and repairing method
CN106997960B (en) Formation and capacity grading method for lithium ion battery
CN105070963A (en) Method for optimizing high-magnification power lithium ion battery SEI film
CN110323506B (en) Formation stabilizing method for lithium ion battery before storage
CN111162337A (en) Formation method of power lithium ion battery for high-temperature environment
CN111276755A (en) Preparation method of lithium ion battery with long storage performance
CN104201420A (en) Formation process for reducing self-discharge rate of battery core
CN109216784B (en) Power lithium ion battery pack for vehicle
CN111725556A (en) Storage method of lithium iron phosphate battery
CN112038703B (en) Preparation method of lithium ion battery
CN112103581B (en) Preparation method of lithium ion battery
CN111416157B (en) Preparation method of ternary lithium ion battery
CN114879053A (en) Method for predicting service life of energy storage lithium iron phosphate battery
US20110043169A1 (en) Charging Algorithm for Lithium Batteries
CN112117505B (en) Formation and grading control method and formation and grading control system
CN111725557A (en) Activation method of lithium manganate battery
CN111755764A (en) Method for reducing polarization of lithium battery
CN110911767A (en) Formation method of lithium ion battery with composite anode
CN112186260A (en) Formation method of lithium ion battery
CN111430786A (en) Pre-activation method of lithium ion battery before use

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant