CN109203419B - Method for continuously preparing rubber-plastic blended microporous infiltrating irrigation pipe by multistage extruder - Google Patents
Method for continuously preparing rubber-plastic blended microporous infiltrating irrigation pipe by multistage extruder Download PDFInfo
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- CN109203419B CN109203419B CN201810799500.4A CN201810799500A CN109203419B CN 109203419 B CN109203419 B CN 109203419B CN 201810799500 A CN201810799500 A CN 201810799500A CN 109203419 B CN109203419 B CN 109203419B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
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- B—PERFORMING OPERATIONS; TRANSPORTING
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Abstract
A method for continuously and efficiently preparing a low-cost high-performance rubber-plastic blended microporous infiltrating irrigation pipe by a multistage extruder belongs to recycling of waste rubber. The rubber powder activated by the activation section of the co-rotating twin-screw extruder, the plastic melted and plasticized by the side feeding machine and the compatibilizer modifier are continuously mixed in the mixing section of the co-rotating twin-screw extruder, then extruded, cooled and shaped, and finally packaged by the traction machine and the winding machine to obtain the product. The method solves the problems of incomplete high-temperature rubber powder desulfurization and low-temperature plastic melting, poor mechanical property and strong odor in the simultaneous treatment of rubber powder and plastic, and the problems of long mixing time, discontinuity and poor product water seepage uniformity caused by intermittent mixing, and saves additives. Has the advantages of continuity, high efficiency, low cost, good water seepage uniformity, enhanced mechanical property, little smell, blockage resistance and the like.
Description
The technical field is as follows:
the invention relates to a novel method for preparing a rubber-plastic blended microporous infiltrating irrigation pipe, in particular to a method for preparing a rubber-plastic blended microporous infiltrating irrigation pipe by a multistage extruder, and belongs to the field of recycling of waste rubber and agricultural irrigation water conservation.
Background art:
china faces double problems that the annual output of waste tires is the first in the world and the per-capita fresh water resource is extremely limited, wherein the agricultural irrigation water accounts for 50% of the total water consumption, but the effective utilization coefficient of farmland irrigation water in China is only 0.50, so that the method has important significance in efficiently and environmentally utilizing waste tire rubber to solve the problem of agricultural irrigation water saving. Compared with other irrigation facilities such as a drip irrigation pipe and the like, the rubber-plastic blended microporous infiltrating irrigation pipe has the advantages of less ground evaporation loss, better water-saving effect, yield increase and the like, and has good development and application prospects.
The preparation method of Wang national English and the like (CN 1113596C), Chua Chongguang and the like (CN 1226340C) and all the existing rubber-plastic blended infiltrating irrigation pipes comprises the steps of firstly mixing and preheating rubber powder, various plastics and various additives which account for 45-79 percent of the weight of the raw materials in a stirrer for more than 10 minutes, and then adding the mixed materials into an extruding device such as an extruder with the highest set temperature of 145-210 ℃ for extrusion and shaping. The preparation method adopts a process of synchronously processing rubber powder and plastics, so that relatively high plastic proportion and reduction of mechanical property are required for extrusion molding; the material state difference of each mixing batch and the feeding mechanism in a hopper of the extrusion device also determine the nonuniformity of raw material components in the product, so that the water seepage uniformity is low; the rubber powder is desulfurized by being treated at high temperature for a long time, so that the product has large smell; besides the defects of the product, the preparation method has the defects of discontinuity, longer process time, low efficiency, higher cost, inconvenience for continuous production and the like.
As mentioned above, in the existing method for preparing the rubber-plastic blended microporous filtration irrigation pipe, various additives are added, especially, a foaming agent and a foaming auxiliary agent are most common, the foaming agent can influence the mechanical property of the product, the tensile strength of products such as Queen national English (CN 1113596C) is 3.8-4.3MPa, and the tensile strength of products such as Chuan Chou light (CN 1226340C) is 3.5-4.0 MPa. As another example, the addition of a lubricant was found to have an effect on the water permeability of the article during the testing. The various additives also have the properties of flammability and the like, and increase the potential safety hazard in the preparation process. More importantly, the chemical additives bring the possibility of water pollution caused by soaking and migrating chemical substances.
The invention content is as follows:
the invention aims to solve the problems of discontinuous process section, long time, low efficiency, high preparation cost, low water seepage uniformity, poor mechanical property and high odor existing in the conventional preparation method of the rubber-plastic blended microporous infiltrating irrigation pipe, and provides a novel method for continuously and efficiently preparing the low-cost high-performance rubber-plastic blended microporous infiltrating irrigation pipe by using a multi-stage extruder.
The purpose of the invention is realized by the following processes: the co-rotating double-screw extruder is sequentially divided into an activation section, a mixing section and a discharge section according to the number of sections of a machine barrel, wherein the machine barrel of the discharge section is connected with a feed port of the machine barrel of the extrusion sizing extruder, and one or two side feeders are connected with the last section of the machine barrel of the activation section of the co-rotating double-screw extruder; adding the waste rubber powder into a feeding device of a co-rotating double-screw extruder, controlling the temperature of an activation section cylinder of the co-rotating double-screw extruder to be 100-120 ℃, adding the plastic and the compatibilization modifier into a feeding device of a side feeding machine, controlling the temperature of a side feeding machine cylinder to be 100-180 ℃, controlling the temperature of a mixing section of the co-rotating double-screw extruder to be 120-160 ℃, controlling the temperature of a discharge section cylinder to be 110-150 ℃, feeding the mixed rubber-plastic blended melt into an extrusion sizing extruder from the co-rotating double-screw extruder, controlling the temperatures of the extrusion sizing extruder cylinder and a machine head to be 120-170 ℃, controlling the rotating speed of the co-rotating double-screw extruder to be 50-350 rpm, controlling the rotating speed of the side feeding machine to be 10-300 rpm, controlling the rotating speed of the extrusion sizing extruder to be 30-200 rpm, controlling the material to act for 2-5 minutes in the whole preparation device, then extruding the material by the machine, and then the obtained product is passed through a traction machine and a packaging and winding machine to obtain the packaged finished product of the rubber-plastic blended microporous infiltrating irrigation pipe.
The used waste rubber powder is one or a mixture of more of tread, sidewall, tire top, tire skin rubber powder or car tire rubber powder of the heavy-duty radial tire, and the weight ratio of the waste rubber powder to the raw materials is preferably 70-85%.
The plastic is one or a mixture of more of low density polyethylene, linear low density polyethylene, high density polyethylene and polypropylene, and preferably accounts for 10-25% of the weight of the raw materials.
The compatibilization modifier is one or a mixture of more of ethylene-vinyl acetate copolymer, graft copolymer and saturated thermoplastic styrene-butadiene rubber, and preferably accounts for 5-15% of the weight of the raw materials.
The co-rotating twin-screw extruder used is preferably one of a parallel co-rotating twin-screw extruder or a conical co-rotating twin-screw extruder.
The diameter or average screw diameter of the screw of the co-rotating double-screw extruder is preferably 28 mm-75 mm, the length-diameter ratio is preferably 20: 1-36: 1, wherein the lengths of the activation section, the mixing section and the discharge section are represented by the number of the machine barrels, preferably 2-5 sections, 2-6 sections and 1 section respectively, each machine barrel corresponds to 1 heating zone, and 5-9 heating zones are preferably provided.
The side feeder is preferably one of a single rotor or a double rotor machine, or any combination of the two.
The diameter of the rotor or the average diameter of the rotor of the side feeder is preferably 20 mm-50 mm, the length-diameter ratio is preferably 8: 1-24: 1, and the heating areas are preferably 2-6.
The extrusion molding extruder used is preferably one of a single-screw extruder or a conical counter-rotating twin-screw extruder.
The diameter of the screw of the extrusion molding extruder or the average screw diameter is preferably 35-90 mm, the length-diameter ratio is preferably 8: 1-36: 1, the heating area is preferably 3-10, and the extruder head can adopt one of a single head, a double head or a multi-head.
The preparation method of the rubber-plastic blended microporous infiltrating irrigation pipe which is prepared by mixing rubber powder, plastic and additives and then extruding and shaping and the performance of the obtained product are compared and examined. The process defects, contradictions and product performance influences caused by the process defects and contradictions of synchronous processing of rubber powder and plastics and feeding and extruding after mixing are discovered. The invention breaks through the prior process method for synchronously processing the rubber powder and the plastic, realizes a preparation method for differentially processing the rubber powder and the plastic through the extruder and continuously mixing and extruding through a large number of types and combinations of the extruder, screw configurations and combinations, temperature control of each section, matching control of rotating speed and design and experiments of a formula, solves the product performance problems of lower water seepage uniformity, poorer mechanical property and more serious smell of a product, and also realizes the continuous, high-efficiency and low-cost production process.
The invention adopts a co-rotating double-screw extruder and a side feeder to separate rubber powder and plastic. Taking a similar compatibility principle as a core, realizing the surface activation of the rubber powder in an activation section of a co-rotating double-screw extruder by the research of preheating and shearing the waste rubber powder by a screw under different temperature and time conditions; the fusion plasticization and modification of the plastic are realized in the side feeding machine through the research of different compatibilization modifiers on the surface modification of different plastics under the conditions of different temperatures and different times; by researching the uniform dispersion of the rubber powder in the plastic continuous phase in the mixing process, the activated rubber powder and the modified plastic obtained under different process conditions realize the uniform mixing distribution of a large amount of rubber powder in a small amount of plastic continuous phase in the mixing section of a co-rotating twin-screw extruder, and the water seepage uniformity of the microporous infiltrating irrigation pipe is obviously improved; meanwhile, in the mixing process of the mixing section of the co-rotating twin-screw extruder, due to similar compatibility, the combination of the activated rubber powder in a plastic continuous phase can be tighter, a stable dispersion and compatibility structure is formed, the stable dispersion and compatibility structure is a fundamental guarantee of strong mechanical property of products, meanwhile, the proportion of the rubber powder in a formula can be improved, the usage amount of the plastic is reduced, the higher proportion of the rubber powder can increase the number of micropores and enlarge the aperture of the micropores, therefore, a foaming agent and other auxiliary agents are saved, the cost is effectively reduced, the anti-blocking performance is improved, and more importantly, the potential safety hazard of flammable additives in the processing process and the possibility of water pollution caused by chemical substances caused by soaking and emigration brought by the chemical additives are avoided. The mixed rubber-plastic blended melt continuously and quantitatively enters an extrusion molding extruder through a discharge section of a co-rotating double-screw extruder, and is rapidly extruded and molded in the extrusion molding extruder with lower temperature, so that the rubber powder is treated at lower temperature and obviously shortened in time in the whole process compared with other process methods, and does not generate serious smell due to desulfurization, thereby being beneficial to the environmental safety in the water delivery and seepage processes. According to the above method, it is considered that when a plurality of plastics are used and there is a large difference in melting temperature thereof, two side feeders can be used for the respective processes. Meanwhile, the extrusion molding extruder can adopt a single-head or double-head or even multi-head co-extrusion mode, so that the production efficiency is further improved.
According to the preparation method, the preparation of the rubber-plastic blended microporous infiltrating irrigation pipe with low cost and high performance is realized, the rubber powder, the plastic and the compatibilizer modifier are respectively added into the feeding device, finished product packaging can be carried out at a packaging and winding machine, no other operation is needed, the materials are processed in the whole device for 2-5 minutes, the whole process continuity and high efficiency are realized, and the method is completely suitable for large-scale continuous production.
Description of the drawings:
FIG. 1 is a schematic diagram of the process of the present invention. Wherein, 1-a co-rotating twin-screw extruder; 2-feeding device of co-rotating double screw extruder; 3-side feeder feeding device; 4-side feeder; 5-extrusion and shaping extruder.
The specific implementation mode is as follows:
the invention is further described below with reference to specific embodiments.
Example 1: the homodromous double-screw extruder 1 is a conical homodromous double-screw extruder with the length-diameter ratio of 20:1 and the average screw diameter of 60 mm; the side feeder 4 is one single-rotor machine with the length-diameter ratio of 24:1 and the rotor diameter of 40 mm; the extrusion molding extruder 5 adopts a conical counter-rotating double-screw extruder with the length-diameter ratio of 20:1 and the average screw diameter of 70mm, and the machine head adopts double machine heads. The number of the activating section machine barrels of the co-rotating twin-screw extruder 1 is 2, the temperature is 100 ℃ and 120 ℃ in sequence, the number of the mixing section machine barrels is 2, the temperature is 150 ℃ and 160 ℃ in sequence, the number of the discharging section machine barrels is 1, and the temperature is 140 ℃; the side feeder 4 has 6 heating zones with the temperature of 130 ℃, 150 ℃, 170 ℃ and 160 ℃ in sequence; the extrusion shaping extruder 5 has 6 heating zones, and the temperature is 120 ℃, 130 ℃, 150 ℃ and 130 ℃ in sequence. After the temperature reaches the set temperature and is stable, adding the sidewall rubber powder of the waste truck radial tire accounting for 70 percent of the weight of the raw materials into a feeding device 2 of a co-rotating double-screw extruder, and adding the high-density polyethylene accounting for 10 percent of the weight of the raw materials, the low-density polyethylene accounting for 15 percent of the weight of the raw materials and the ethylene-vinyl acetate copolymer accounting for 5 percent of the weight of the raw materials into a feeding device 3 of a side feeding machine. And starting the extrusion sizing extruder 5, the co-rotating double-screw extruder 1 and the side feeder 4 in sequence, and starting the feeding device 2 of the co-rotating double-screw extruder and the feeding device 3 of the side feeder to start feeding. At the moment, the rotating speed of the co-rotating double-screw extruder 1 is 150rpm, the rotating speed of the side feeder 4 is 80rpm, the rotating speed of the extrusion shaping extruder 5 is 150rpm, the materials act for 4 minutes in the whole set of preparation device, the temperature of an extrusion shaping pipe is 150 ℃, and the materials are cooled to 30 ℃ through a cooling water tank.
The prepared rubber-plastic blended microporous infiltration irrigation pipe has the outer diameter of 20mm, the wall thickness of 3.5mm, the tensile strength of 5.0MPa, the water seepage amount of about 15L/(mxh) under the water inlet pressure of 0.05MPa on the ground and the water seepage uniformity of more than 80 percent, the smelling concentration of the smell is obviously less than that of the like products sold on the market under the condition that the nose is close to the outer wall of the rubber-plastic blended microporous infiltration irrigation pipe, and the buried underground water-flowing experiment shows that the change rate of the water seepage amount of the rubber-plastic blended microporous infiltration irrigation pipe is more than 20 percent less than that of the like products sold on the market under the same water inlet pressure, so that the effect of enhancing the anti-blocking.
Example 2: the co-rotating twin-screw extruder 1 is a parallel co-rotating twin-screw extruder with the length-diameter ratio of 36:1 and the screw diameter of 30 mm; the side feeder 4 is one double-rotor machine with the length-diameter ratio of 10:1 and the rotor diameter of 20 mm; the extrusion molding extruder 5 is a single screw extruder with the length-diameter ratio of 12:1 and the screw diameter of 40mm, and the machine head is a single machine head. The number of the barrels of the activation section of the co-rotating twin-screw extruder 1 is 3, the temperature is 100 ℃, 110 ℃ and 110 ℃ in sequence, the number of the barrels of the mixing section is 5, the temperature is 130 ℃, 140 ℃, 145 ℃ and 140 ℃ in sequence, the number of the barrels of the discharge section is 1, and the temperature is 130 ℃; the side feeder 4 is provided with 2 heating zones, and the temperature is 130 ℃ and 150 ℃ in sequence; the extrusion shaping extruder 5 has 4 heating zones, and the temperature is 120 ℃, 140 ℃ and 130 ℃ in sequence. After the temperature reaches the set temperature and is stable, adding the top rubber powder of the waste truck radial tire accounting for 80 percent of the weight of the raw materials into a feeding device 2 of a co-rotating double-screw extruder, and adding high-density polyethylene accounting for 12 percent of the weight of the raw materials, maleic anhydride grafted and saturated thermoplastic styrene-butadiene rubber accounting for 4 percent of the weight of the raw materials into a feeding device 3 of a side feeder. And starting the extrusion sizing extruder 5, the co-rotating double-screw extruder 1 and the side feeder 4 in sequence, and starting the feeding device 2 of the co-rotating double-screw extruder and the feeding device 3 of the side feeder to start feeding. At the moment, the rotating speed of the co-rotating double-screw extruder 1 is 240rpm, the rotating speed of the side feeder 4 is 150rpm, the rotating speed of the extrusion shaping extruder 5 is 180rpm, the materials act for 3 minutes in the whole set of preparation device, the temperature of an extrusion shaping pipe is 140 ℃, and the materials are cooled to 30 ℃ through a cooling water tank.
The prepared rubber-plastic blended microporous infiltration irrigation pipe has the outer diameter of 12mm, the wall thickness of 2mm, the tensile strength of 4.6MPa, the water seepage amount of about 8L/(mxh) under the ground water inlet pressure of 0.05MPa and the water seepage uniformity of more than 80 percent, the smelling concentration of the smell is obviously less than that of the like products sold on the market under the condition that the nose is close to the outer wall of the rubber-plastic blended microporous infiltration irrigation pipe, and the buried underground water-flowing experiment shows that the change rate of the water seepage amount of the rubber-plastic blended microporous infiltration irrigation pipe is more than 20 percent less than that of the like products sold on the market under the same water inlet pressure after long-time water seepage, so that the effect of enhancing.
Example 3: the co-rotating double-screw extruder 1 is a parallel co-rotating double-screw extruder with the length-diameter ratio of 28:1 and the screw diameter of 75 mm; the side feeder 4 is a double-rotor machine with the length-diameter ratio of 16:1 and the rotor diameter of 50 mm; the extrusion molding extruder 5 is a single screw extruder with the length-diameter ratio of 16:1 and the screw diameter of 90mm, and the machine head adopts a plurality of machine heads. The number of the activating section machine barrels of the co-rotating twin-screw extruder 1 is 2, the temperature is 100 ℃ and 120 ℃ in sequence, the number of the mixing section machine barrels is 4, the temperature is 150 ℃, 165 ℃ and 150 ℃ in sequence, the number of the discharging section machine barrels is 1, and the temperature is 140 ℃; the side feeder 4 is provided with 4 heating zones, and the temperature is 140 ℃, 170 ℃, 180 ℃ and 170 ℃ in sequence; the extrusion shaping extruder 5 has 5 heating zones with the temperature of 120 ℃, 140 ℃, 150 ℃ and 145 ℃ in sequence. After the temperature reaches the set temperature and is stable, adding the waste truck radial tire carcass rubber powder accounting for 30 percent of the weight of the raw materials and the sidewall rubber powder accounting for 55 percent of the weight of the raw materials into a feeding device 2 of a co-rotating double-screw extruder, and adding the polypropylene accounting for 10 percent of the weight of the raw materials and the saturated thermoplastic styrene-butadiene rubber accounting for 5 percent of the weight of the raw materials into a feeding device 3 of a side feeding machine. And starting the extrusion sizing extruder 5, the co-rotating double-screw extruder 1 and the side feeder 4 in sequence, and starting the feeding device 2 of the co-rotating double-screw extruder and the feeding device 3 of the side feeder to start feeding. At the moment, the rotating speed of the co-rotating double-screw extruder 1 is 200rpm, the rotating speed of the side feeder 4 is 120rpm, the rotating speed of the extrusion shaping extruder 5 is 150rpm, the materials act for 3.5 minutes in the whole set of preparation device, the temperature of an extrusion shaping pipe is 150 ℃, and the materials are cooled to 30 ℃ through a cooling water tank.
The prepared rubber-plastic blended microporous infiltration irrigation pipe has the outer diameter of 16mm, the wall thickness of 2.5mm, the tensile strength of 4.8MPa, the water seepage amount of about 13L/(mxh) under the ground water inlet pressure of 0.05MPa and the water seepage uniformity of more than 80 percent, the smelling odor concentration is obviously less than that of the like products sold on the market under the condition that the nose is close to the outer wall of the rubber-plastic blended microporous infiltration irrigation pipe, and the buried underground water-passing experiment shows that the change rate of the water seepage amount of the rubber-plastic blended microporous infiltration irrigation pipe is more than 20 percent less than that of the like products sold on the market under the same water inlet pressure, so that the effect of enhancing the anti-blocking performance is achieved.
Claims (10)
1. A method for continuously preparing a rubber-plastic blended microporous infiltrating irrigation pipe by a multistage extruder is characterized by comprising the following steps: the co-rotating double-screw extruder is sequentially divided into an activation section, a mixing section and a discharge section according to the number of sections of a machine barrel, wherein the machine barrel of the discharge section is connected with a feed port of the machine barrel of the extrusion sizing extruder, and one or two side feeders are connected with the last section of the machine barrel of the activation section of the co-rotating double-screw extruder; adding the waste rubber powder into a feeding device of a co-rotating double-screw extruder, controlling the temperature of an activation section cylinder of the co-rotating double-screw extruder to be 100-120 ℃, adding the plastic and the compatibilization modifier into a feeding device of a side feeding machine, controlling the temperature of the side feeding machine cylinder to be 100-180 ℃, controlling the temperature of a mixing section cylinder of the co-rotating double-screw extruder to be 120-160 ℃, controlling the temperature of a discharge section cylinder to be 110-150 ℃, feeding the mixed rubber-plastic blended melt into an extrusion sizing extruder from the co-rotating double-screw extruder, controlling the temperatures of the extrusion sizing extruder cylinder and a machine head to be 120-170 ℃, controlling the rotating speed of the co-rotating double-screw extruder to be 50-350 rpm, controlling the rotating speed of the side feeding machine to be 10-300 rpm, controlling the rotating speed of the extrusion sizing extruder to be 30-200 rpm, enabling the material to act for 2-5 minutes in the whole preparation device, extruding by the, cooling the mixture to below 40 ℃ through a cooling water tank, shaping, and obtaining a finished product of the packaged rubber-plastic blended microporous infiltrating irrigation pipe through a tractor and a packaging winder; the weight ratio of the waste rubber powder to the raw materials is 70-85 percent; the weight ratio of the plastic to the raw material is 10-25%; the weight ratio of the compatibilization modifier to the raw materials is 5-15%.
2. The process according to claim 1, wherein the crumb rubber is one or more of tread, sidewall, summit, skim rubber or car tire rubber of a heavy duty radial tire.
3. A process according to claim 1, wherein the plastic used is a mixture of one or more of low density polyethylene, high density polyethylene and polypropylene.
4. The process as claimed in claim 1, wherein the compatibilizer modifier is one or more of ethylene-vinyl acetate copolymer, graft copolymer, and saturated thermoplastic styrene-butadiene rubber.
5. The process as claimed in claim 1, wherein the twin-screw co-rotating extruder used is one of a parallel co-rotating twin-screw extruder and a conical co-rotating twin-screw extruder.
6. The method of claim 1 or 5, wherein the diameter or average screw diameter of the screw of the co-rotating twin-screw extruder is 28 mm-75 mm, the length-diameter ratio is 20: 1-36: 1, the lengths of the activating section, the mixing section and the discharging section are respectively 2-5 sections, 2-6 sections and 1 section according to the number of the machine barrels, each machine barrel corresponds to 1 heating zone, and the number of the heating zones is 5-9.
7. The method of claim 1, wherein the side feeder is one of a single rotor or a twin rotor machine, or any combination of the two.
8. A process according to claim 1 or 7, characterized in that the diameter of the rotor or the average rotor diameter of the side feeder used is 20mm to 50mm, the length to diameter ratio is 8:1 to 24:1 and the number of heating zones is 2 to 6.
9. The method of claim 1, wherein the extrusion-molding extruder is one of a single-screw extruder and a conical counter-rotating twin-screw extruder.
10. The method according to claim 1 or 9, wherein the diameter of the screw or the average screw diameter of the extrusion sizing extruder is 35mm to 90mm, the length-diameter ratio is 8:1 to 36:1, the number of heating zones is 3 to 10, and the extruder head is one of a single head, a double head and a multi-head.
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| CN201810799500.4A CN109203419B (en) | 2018-07-19 | 2018-07-19 | Method for continuously preparing rubber-plastic blended microporous infiltrating irrigation pipe by multistage extruder |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000043032A (en) * | 1998-07-31 | 2000-02-15 | Toyo Tire & Rubber Co Ltd | Consecutive kneading extruder for rubber |
| CN201833574U (en) * | 2010-10-22 | 2011-05-18 | 中国石油化工股份有限公司 | Feeding and producing device for melting sides of high molecular materials |
| CN201960730U (en) * | 2010-12-25 | 2011-09-07 | 金发科技股份有限公司 | Serial type extruder |
| CN203566909U (en) * | 2013-11-20 | 2014-04-30 | 南京诚盟机械有限公司 | Multi-screw measuring feeding and mixing conveying system |
-
2018
- 2018-07-19 CN CN201810799500.4A patent/CN109203419B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000043032A (en) * | 1998-07-31 | 2000-02-15 | Toyo Tire & Rubber Co Ltd | Consecutive kneading extruder for rubber |
| CN201833574U (en) * | 2010-10-22 | 2011-05-18 | 中国石油化工股份有限公司 | Feeding and producing device for melting sides of high molecular materials |
| CN201960730U (en) * | 2010-12-25 | 2011-09-07 | 金发科技股份有限公司 | Serial type extruder |
| CN203566909U (en) * | 2013-11-20 | 2014-04-30 | 南京诚盟机械有限公司 | Multi-screw measuring feeding and mixing conveying system |
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