CN109199892A

CN109199892A - Composition and its application method containing oxidant

Info

Publication number: CN109199892A
Application number: CN201810722263.1A
Authority: CN
Inventors: 远藤美幸; 上原淳
Original assignee: Hoyu Co Ltd
Current assignee: Hoyu Co Ltd
Priority date: 2017-06-30
Filing date: 2018-06-29
Publication date: 2019-01-15
Also published as: JP7199070B2; SG10201805455QA; JP2019011292A

Abstract

The present invention provides a kind of composition and its application method containing oxidant, the composition containing oxidant is sprayed in the form of blister agent from aerosol container, and it is used as hair dye or hair decoloration, de- stain, and preparation stability, alveolar substance and expansion rate can be promoted.Composition containing oxidant of the invention is to be sprayed in the form of blister agent from aerosol container, and mix with the agent containing alkaline agent and be used as hair dye or hair decoloration, de- stain；And, it is characterised in that contain (A) hydrocarbon and (B) oxidant.

Description

Composition and its application method containing oxidant

Technical field

The present invention relates to a kind of composition and its application method containing oxidant, the composition containing oxidant is from gas It is sprayed in the form of blister agent in mist container, and is used as hair dye or hair decoloration, de- stain.

Background technique

As hair treatment composition, the commonly known blister dosage form that effect is played and mixing a variety of chemical agents Hair dye or hair decoloration, de- stain.As this hair treatment composition, for example, known following hair dye, the hair dyeing Agent is by first dose containing alkaline agent and oxidation dye and second dose containing oxidant such as hydrogen peroxide (containing oxidant Composition) it is constituted, and when in use with blister dosage form application.

Compared with the composition used with liquid dosage form, this hair dye used with blister dosage form has feature below: The worry of dropping liquid is few, good to the smear and use feeling of hair.

All the time, such as the blister hair dye of patent document 1 is to be filled in pressing bubbling container to use, and by containing peroxide Change hydrogen, the lauroylamidopropyl betaine as amphoteric surfactant and lauryl hydroxyl sulfo betaine and as oil The composition etc. containing oxidant of the lauric acid of property ingredient etc. is constituted.

[existing technical literature]

[patent document]

Patent document 1: Japanese Unexamined Patent Publication 2007-314523 bulletin.

Summary of the invention

[problem to be solved by the invention]

But the problem that the composition disclosed in patent document 1 containing oxidant has preparation stability insufficient.In addition, In the case where the composition containing oxidant for being configured to spray in the form of blister agent from aerosol container, there is alveolar substance (plentiful Sense) and expansion rate difference problem.

The purpose of the present invention is to provide a kind of composition and its application method containing oxidant, the group containing oxidant Closing object is to be sprayed in the form of blister agent from aerosol container, and be used as hair dye or hair decoloration, de- stain, and can be promoted Preparation stability, alveolar substance and expansion rate.

[technical means to solve problem]

The present invention is based on following opinion, i.e. discovery can promote the preparation stabilization of the composition containing oxidant by allotment hydrocarbon Property, alveolar substance and expansion rate.In addition, the numerical value of the quality % about expression composition content, the case where using the solubilizer such as water Under, for the numerical value in the dosage form also comprising these solubilizer.

In order to reach the purpose, one embodiment of the present invention is a kind of composition containing oxidant, this contains oxidant Composition be sprayed in the form of blister agent from aerosol container, and mix with the agent containing alkaline agent and as hair dye or hair Hair decoloration, de- stain；And, it is characterised in that contain (A) hydrocarbon and (B) oxidant.(A) hydrocarbon can be atoleine.It is described Composition containing oxidant can further contain (C) polyalcohol.

Another embodiment of the present invention is the application method of the composition containing oxidant, and it is characterized in that, It include: the process for spraying the composition containing oxidant in the form of blister agent from aerosol container；And by the blister Agent is mixed with the blister agent containing alkaline agent, the process for preparing hair dye or preparing hair decoloration, de- stain.

[The effect of invention]

According to the present invention, preparation stability, alveolar substance and expansion rate can be promoted.

Detailed description of the invention

Nothing.

Specific embodiment

Hereinafter, being illustrated to the embodiment for embodying the composition of the invention containing oxidant.Containing oxidant Composition be for example configured to the hair dye containing alkaline agent and oxidant or hair decoloration, second dose of de- stain.As hair dyeing The concrete example of agent or hair decoloration, de- stain, such as can enumerate: the hair dye of two doses of formulas or hair decoloration, de- stain, Yi Jisan Hair dye or the hair decoloration of agent formula, de- stain etc..Hereinafter, to second constituted in the form of the composition containing oxidant is contained Hair dye or the hair decoloration of agent, the ingredient of de- stain are illustrated.

The decoloration of two doses of formula hairs, de- stain be, for example, by first dose at least containing alkaline agent and at least containing (B) oxidant the Two doses are constituted.

Second dose of de- stain (decoloration of two doses of formula hairs)

Second dose also contains (A) hydrocarbon etc. other than (B) oxidant, preferably further contains (C) polyalcohol.

(B) oxidant promotes the decolourising property of melanin contained by hair.As the concrete example of oxidant, such as can enumerate Hydrogen peroxide, urea peroxide, melamine peroxide, SODIUM PERCARBONATE, sodium perborate, potassium perborate, ammonium persulfate, persulfuric acid The mistake of potassium, sodium peroxydisulfate, sodium peroxide, potassium peroxide, peromag, barium peroxide, calper calcium peroxide, strontium peroxide, sulfate Hydrogen oxide addition product, phosphatic hydrogen peroxide addition product and hydrogen peroxide addition product of pyrophosphate etc..These oxidants Concrete example in, can be individually containing only a kind of, or can also combine containing two or more.

The lower limit of the content of (B) oxidant in second dose can be suitably set, preferably 0.1 mass % or more, and more preferable 1.0 Quality % or more, and then preferably 2.0 mass % or more, most preferably 3.0 mass % or more.It is 0.1 matter in the content of (B) oxidant In the case where measuring % or more, the decolourising property of melanin can be further promoted.In addition, the content of (B) oxidant in second dose The upper limit can be suitably set, preferably 15.0 mass % hereinafter, more preferable 9.0 mass % hereinafter, preferably 6.0 mass % or less in turn. (B) oxidant content be 15.0 mass % situations below under, the damage etc. of hair can be inhibited.

In the case where hydrogen peroxide to be formulated in second dose as (B) oxidant, in order to make the stabilization of hydrogen peroxide Property promoted, preferably second dose contains stabilizer, such as sodium stannate, ethylene glycol phenyl ether (phenoxetol), hydroxyl ethane diphosphine Acid or its salt.As hydroxyethane diphosphonic acid salt, such as four sodium of hydroxyethane diphosphonic acid and hydroxyethane diphosphonic acid two can be enumerated Sodium.

(A) hydrocarbon promotes preparation stability and alveolar substance.As the concrete example of hydrocarbon, such as can enumerate: paraffin (such as Japan's essence The Paraffin Wax 130:Mw562 etc. of wax company manufacture), olefin oligomerisation object (such as daylight chemistry (Nikkol Chemicals) the Syncelane 4SP:Mw335.63 to 1174.14 etc. of company's manufacture), polyisobutene, Parleam, Mineral oil, saualane (such as NIKKOL Squalane:Mw422.81 etc. of Nikko Chemical Company manufacture), polybutene (such as day The Emawet 015N:Mw580 etc. of oily company manufacture), polyethylene (such as the Performalene of Nikko Chemical Company manufacture 400Polyethylene:Mw400 etc.), microwax (such as Hi-Mic 1045 etc. of Jing La company of Japan manufacture), vaseline (such as Perfecta:Mw562 etc. of Sonne Born company manufacture), atoleine (such as the manufacture of Sonne Born company The Kaydol:Mw422 etc. of Carnation:Mw310, Sonne Born company manufacture), the different paraffin of lightweight (such as Croda The ARLAMOL HD etc. of Japan company manufacture), the different paraffin of light liquids (such as the IP Solvent of Chu Guangxingchan company manufacture 2028MU:Mw215.5 etc.), the different paraffin of heavy liquid (such as Parleam 24:Mw1314 etc. of You company manufacture), liquid Different paraffin (such as Parleam EX:Mw364 etc. of You company manufacture) and synthesis saualane etc..In these, can individually it contain There is only one kind, or can also combine containing two or more.In these, from the viewpoint of the excellent effect for promoting alveolar substance, preferably The different paraffin of atoleine, light liquids, the different paraffin of heavy liquid, more preferable atoleine.

(A) lower limit of the number average molecular weight of hydrocarbon can be suitably set, and be preferably chosen 200 or more, more preferably selected 250 or more, and then it is preferably chosen 300 or more.In addition, the upper limit of the number average molecular weight of (A) hydrocarbon can be suitably set, preferably Ground selection 1500 is hereinafter, more preferably selection 1200 hereinafter, be preferably chosen 900 or less in turn.By the way that the quantity of (A) hydrocarbon is flat Average molecular weight provides in the range, and promotes preparation stability and alveolar substance further.

The lower limit of the content of (A) ingredient in second dose can be suitably set, preferably 0.01 mass % or more, and more preferable 0.05 Quality % or more, and then preferably 0.1 mass % or more.If the content is 0.01 mass % or more, promote alveolar substance further. In addition, the upper limit of the content of (A) ingredient in second dose can be suitably set, preferably 35 mass % are hereinafter, more preferable 24 mass % Hereinafter, preferably 9 mass % or less in turn.If the content be 35 mass % hereinafter, if make preparation stability and expansion rate into one Step is promoted.

(C) polyalcohol promotes alveolar substance further.Therefore, (C) polyalcohol is preferably comprised for second dose.As (C) polyalcohol, Such as glycol and glycerol can be enumerated etc..As the concrete example of glycol, such as ethylene glycol, diethylene glycol, three second two can be enumerated Alcohol, polyethylene glycol, high polymerization polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, isoprene and 1,3 butylene glycol Deng.As the concrete example of glycerol, such as glycerol, two glycerol and polyglycereol can be enumerated etc..It, can be individually containing only one in these Kind, or can also combine containing two or more.In these, from make alveolar substance promoted excellent effect from the viewpoint of, preferably propylene glycol, Polyethylene glycol.

The lower limit of the content of (C) ingredient in second dose can be suitably set, preferably 0.05 mass % or more, and more preferable 0.1 Quality % or more, and then preferably 0.3 mass % or more.If the content is 0.05 mass % or more, promote alveolar substance further. In addition, the upper limit of the content of (C) ingredient in second dose can be suitably set, preferably 35 mass % are hereinafter, more preferable 25 mass % Hereinafter, preferably 9 mass % or less in turn.If the content be 35 mass % hereinafter, if make the decoloration after hair treatment, de- metachromia into One step is promoted.In addition, below being promoted will in the hair dye that stated, hair dyeing property.

Hair decoloration, de- stain optionally can be further containing the ingredients other than the ingredient, such as solubilizer, water solubility Polymer, inorganic matter system macromolecule, it is described other than oil components, surfactant, pH adjuster, sugar, preservative, stabilization Agent, plant extract, crude drug extract, vitamin, fragrance, antioxidant, complexing agent, ultraviolet absorbing agent etc..

However, being preferably substantially free of amphoteric surfactant in second dose.It is so-called to be substantially free of, it means without with not Amphoteric surfactant other than the mixed amphoteric surfactant of the form of evitable impurity is (by amphoteric surfactant Except allotment).Amphoteric surfactant is free of by second dose, preparation stability and expansion rate can be made further to be promoted.

Solubilizer is, for example, to deploy in the case where liquid is made by second dose.As the example of used solubilizer, Such as water and organic solvent (solvent) can be enumerated.As the concrete example of organic solvent, such as ethyl alcohol, normal propyl alcohol, isopropyl can be enumerated Alcohol, methyl cellosolve, ethyl cellosolve, methyl carbitol, ethyl carbitol, benzylalcohol, benzyl carbinol, γ-phenyl propanol, cortex cinnamomi Alcohol, anisyl alcohol, to xylyl alcohol, alpha-alpha-dimethyl benzyl carbinol, α-phenylethanol, ethylene glycol phenyl ether (phenoxetol), benzene Oxygroup isopropanol, 2- benzyloxyethanol, N- alkyl pyrrolidone, alkylene carbonates and alkyl ether etc..These solubilizer In, it can be individually containing only one kind, or can also combine containing two or more.In these, from the other compositions in second dose of dissolution From the point of view of the excellent aspect of ability, water is preferably applied.In the case where using water as solvent, the content of the water in second dose (content when use) preferably 40 mass % or more, more preferable 50 mass % or more.

Water-soluble polymer decolourizes to hair, de- stain assigns appropriate viscosity.As water-soluble polymer, such as can lift Natural polymer, semi-synthetic macromolecule and synthesis macromolecule etc. out.As the concrete example of natural polymer, such as can enumerate Starch, guar gum, locust bean gum, Wen Quince seed, carrageenan, galactan, gum arabic, bassora gum, pectin, sweet dew are poly- Sugar, Xanthan gum, glucan, succinoglycan, curdlan, sodium hyaluronate, gelatin, casein, albumin, collagen, dextrin, And poly- maltotriose (pulullan polysaccharide) etc..

As semi-synthetic high molecular concrete example, for example, can enumerate avicel cellulose, methylcellulose, ethyl cellulose, Hydroxyethyl cellulose, hydroxyethyl cellulose dimethyl diallyl ammonium chloride, hydroxypropyl cellulose, carboxymethyl cellulose, carboxylic first Base sodium cellulosate, hydroxypropyl methyl cellulose, cationized cellulose, cationized guar gum, starch phosphate, alginic acid third Diol ester and alginate etc..

It as the high molecular concrete example of synthesis, such as can enumerate: Vinylcaprolactam homopolymer, polyvinyl alcohol (Polyvinyl alcohol；PVA), polyvinylpyrrolidone (Polyvinylpyrrolidone；PVP), vinyl pyrrolidone-acetic acid second Enester (VP/VA) copolymer, polyvinyl butyral, polyvinyl methyl ether, carboxyl vinyl polymer, Sodium Polyacrylate, Polyacrylamide, polyethylene oxide, ethylene oxide-propylene oxide block copolymer, acrylic acid/alkyl acrylate copolymer, Polychloride dimethylated methylene phenylpiperidines (polychloride dimethyl dimethylene pyrrolidines) (polyquaternium -6) (Mercoat The manufacture of 100:Merck company), by the half ester or methyl-prop of itaconic acid and polyoxyethylene (hereinafter also referred to " POE ") alkyl ether Olefin(e) acid is with the ester of POE alkyl ether and selected from least one of acrylic acid, methacrylic acid and these Arrcostab monomer institute structure At copolymer., can be individually containing only one kind in these, or can also combine containing two or more.

As the high molecular concrete example of inorganic matter system, such as bentonite, aluminum magnesium silicate, synthetic soapstone, lithium can be enumerated and covered De- stone and silicic acid anhydride etc.., can be individually containing only one kind in these, or can also combine containing two or more.

Oil components especially assign moist sense to hair.Therefore, hair decoloration, de- stain can not undermine effect of the present invention In the range of contain the oil components other than the oil components.As oil components, for example, can enumerate grease, wax class, ester oil, Higher alcohol, higher fatty acids, alkyl glycerylether and silicone etc..In these, from the preparation stability, decoloration, de- for making second dose From the viewpoint of the excellent effect that metachromia, anti-scalp pollution effects are promoted, preferred higher alcohol.Come from the viewpoint for promoting the effect It sees, the lower limit preferably 0.001 mass % or more of the content in second dose in the case where allotment higher alcohol, more preferable 0.01 matter Measure % or more, and then preferably 0.05 mass % or more.In addition, the upper limit of the content is excellent from the viewpoint of promoting the effect 20 mass % are selected hereinafter, more preferable 10 mass % is hereinafter, preferably 5 mass % or less in turn.

As the concrete example of grease, such as thorn A Ganshu (Argania Spinosa) benevolence oil, olive oil (olive can be enumerated Oil), camellia oil, shea butter, almond oil, safflower oil, sunflower oil, soybean oil, cottonseed oil, sesame oil, corn oil, vegetable seed Oil, rice bran oil, rice embryo oil, grape seed oil, avocado oil, macadimia nut oil, castor oil, coconut oil, evening primrose oil, almond Oil, Apricot kernel oil, persic oil, palm oil and egg oil etc..As the concrete example of wax class, for example, can enumerate lanolin, beeswax, Bear ground lira wax, Brazil wax and SIMMONDSIA CHINENSIS SEED OIL etc..

As the concrete example of ester oil, for example, can enumerate diisopropyl adipate, isopropyl myristate, Octanoic acid, hexadecyl ester, Isononyl isononanoate, myristic acid octyldodecyl, isopropyl palmitate, stearyl stearate, myristic acid nutmeg Ester, myristic acid isotridecyl ester, palmitinic acid 2- ethylhexyl, ricinoleic acid octyldodecyl, with 10 to 30 The fatty acid cholesterol ester of carbon number/fatty acid lanosterol ester, cetyl lactate, acetic acid lanolin, two -2- ethyl hexyl of ethylene glycol Acid esters, pentaerythritol fatty ester, dipentaerythritol aliphatic ester, capric acid cetyl, tricaprylin, malic acid two are different hard Rouge ester, dioctyl succinate, 2 ethyl hexanoic acid cetyl and isostearic acid rilanit special etc..

As the concrete example of higher alcohol, such as cetanol (hexadecanol), 2- hexyl decyl alcohol, stearyl alcohol, different hard can be enumerated Lipidol, cetostearyl alcohol, oleyl alcohol, arachidic alcohol, docosyl alcohol, 2- octyldodecanol, laruyl alcohol, myristyl alcohol, decyl alkane Alcohol and lanolin alcohol etc..

As the concrete example of higher fatty acids, such as lauric acid, myristic acid, palmitinic acid, stearic acid, behenyl can be enumerated Acid, isostearic acid, 12- hydroxy stearic acid, oleic acid, lanoceric acid etc..As the concrete example of alkyl glycerylether, such as shark can be enumerated Liver alcohol, chimyl alcohol, selachyl alcohol and iso stearyl glycerin ether etc..

As the concrete example of silicone, such as dimethyl polysiloxane (silicon spirit), methyl phenyl silicone, ten first can be enumerated The modified dimethyl polysiloxane of base cyclopentasiloxane, ten diformazan basic rings, six siloxanes, terminal hydroxyl, high polymerizing silicone, polyethers change Property silicone (such as (PEG (Polyethyleneglycol；Polyethylene glycol)/PPG (Polypropyleneglycol；Poly- the third two Alcohol)/butylene/dimethyl polysiloxane) copolymer), amino modified silicone, glycine betaine modified silicone, alkyl-modified silicone, alcoxyl Base modified silicone, sulfhydryl modified silicone, carboxy-modified silicone and fluorine richness silicone etc..In these oil components, can individually it contain There is only one kind, or can also combine containing two or more.

Surfactant is to make hair decoloration when in use as the ingredient for being used to make emulsifier or each ingredient solubilization, take off Stain emulsification or solubilising perhaps adjust viscosity or promote viscosity stability.Therefore, hair decoloration, de- stain can not damage And contain surfactant in the range of effect of the present invention.As surfactant, anionic surfactant, sun can be enumerated Ionic surfactant and nonionic surfactant.In these, from the sight for the excellent effect for promoting preparation stability From the point of view of point, preferred nonionic surfactant.In addition, preferred cationic surface is living from the viewpoint of making sense of touch promotion Property agent.

As the concrete example of anionic surfactant, such as alkyl ether sulfate, alkyl sulfate, alkyl can be enumerated Ether sulfuric ester salt, alkenyl ether sulfates, alkenyl sulfate, alkene sulfonate, alkane sulfonate, Salt of saturated fatty acid or unsaturation Fatty acid salt, alkyl ether carboxy acid salt or alkenyl ether carboxylate, α-sulfone fatty acid salt, N- acyl amino acid type surfactant, phosphorus Acid monoester or di(2-ethylhexyl)phosphate ester type surfactant, sulfosuccinate, N- alkanoyl methyl tauride and these derivative Deng.The concrete example of the counter ion counterionsl gegenions of anion base as these surfactants, for example, can enumerate sodium ion, potassium ion, with And triethanolamine etc..More specifically, as alkyl ether sulphate salts, such as POE laurel ether sodium sulfate can be enumerated.As alkyl The concrete example of sulfate, such as NaLS and cetyl sulfate can be enumerated etc..Derivative as alkyl sulfate The concrete example of object, such as POE NaLS can be enumerated etc..As the concrete example of sulfosuccinate, such as sulphur can be enumerated Base succinic acid lauryl disodium etc..As the concrete example of N- alkanoyl methyl tauride, such as N- stearyl-N- can be enumerated N-methyltaurine sodium etc..

As the concrete example of cationic surfactant, such as Trimethyllaurylammonium chloride, cetyl can be enumerated Base trimethyl ammonium, chlorination stearyl trimethyl ammonium, alkyl trimethylammonium chloride, chloro distearyl dimethyl ammonium, cetyl Base trimethyl ammonium, bromination stearyl trimethyl ammonium, ethyl sulfuric acid lanoceric acid ethyldimonium dimethyl ammonium, stearyl front three Base sucramin, cetyltrimethylammonium sucramin, methyl chloride acryloyloxyethyl trimethyl ammonium, methylsulfuric acid behenyl base front three Base ammonium, behenyl base dimethyl amine, behenic acid diethylamino buserelin, behenic acid dimethylaminopropyl amide, behenic acid Dimethyl aminoethyl amide, stearyl dimethyl amine, palm oxygroup propyl-dimethyl amine, stearic oxygroup propyl-dimethyl amine, And stearic acid dimethylaminopropyl amide etc..As the concrete example of alkyl trimethylammonium chloride, such as chlorination mountain can be enumerated Yu base trimethyl ammonium and chlorination peanut base trimethyl ammonium etc..From promoted sense of touch from the viewpoint of, in second dose deploy sun from The lower limit of content in the case where sub- property surfactant preferably 0.001 mass % or more, more preferable 0.01 mass % or more, into And it is preferred that 0.05 mass % or more.In addition, from promoted sense of touch from the viewpoint of, the upper limit of the content preferably 20 mass % hereinafter, More preferable 10 mass % is hereinafter, preferably 5 mass % or less in turn.

As the concrete example of nonionic surfactant, such as ether type nonionic surfactant, ester type can be enumerated Nonionic surfactant and alkyl glucoside etc..As the concrete example of ether type nonionic surfactant, such as can Enumerate POE cetyl ether (ceteth (Ceteth)), BRIJ 76 (stereth (Steareth)), POE behenyl ether, POE oil ether (oleth (Oleth)), POE laurel ether (laureth (Laureth)), POE octyldodecyl ether, POE The different stearyl ether of hexyl decyl ethers, POE, the different phenylate of POE, POE octyl phenyl ether, POE polyoxypropylene cetyl ether, POE polyoxy are sub- Propyl decyl alkyl ether etc..

As the concrete example of ester type nonionic surfactant, for example, can enumerate POE sorbitan monooleate, POE sorbitan monostearate, POE sorbitan monopalmitate, POE Span-20, the mountain POE Pears sugar alcohol acid anhydride trioleate, monostearate POE glyceride, list myristic acid POE glyceride, four oleate of POE D-sorbite, Six stearate of POE D-sorbite, POE D-sorbite monolaurate, POE D-sorbite beeswax, polyethylene glycol monooleate, Polyethylene glycol mono stearate, polyethylene glycol monolaurate, lipophilic glyceryl monooleate, lipophilic glycerol monostearate Ester, self-emulsifying type glycerin monostearate, sorbitan monooleate, Span-83, sorbitan Trioleate, sorbitan monostearate, sorbitan monopalmitate, Span-20, sucrose Aliphatic ester, ten polyglycerol ester of mono laurate, ten polyglycerol ester of monostearate, ten polyglycerol ester of single oleic acid, single myristic acid ten Polyglycerol ester and POE reduction lanolin etc..

As the concrete example of alkyl glucoside, for example, can enumerate alkyl (carbon number 8 to 16) glucoside, POE methyl glucosamine, And bis- oleic acid methyl glucosamine of POE etc..In the concrete example of these surfactants, it can individually contain only one kind, or can also group It closes containing two or more.

In the case where nonionic surfactant contains polyoxyethylene chain, the addition molal quantity of ethylene oxide is preferred 2 to 50.In the case where within the scope of this, promote preparation stability further.Nonionic surfactant is deployed in second dose In the case where agent, from the viewpoint of promoting preparation stability, the blending amount of nonionic surfactant is relative to (A) hydrocarbon The mass ratio (nonionic surfactant/(A) ingredient) preferably 0.001 to 20 of blending amount, more preferable 0.01 to 10, Jin Eryou Select 0.05 to 5.

PH adjuster is deployed to adjust mixture pH value when in use.As pH adjuster, can enumerate Inorganic acid, organic acid and these salt etc..As concrete example of inorganic acid, such as phosphoric acid, hydrochloric acid, nitric acid, sulphur can be enumerated Acid and boric acid etc..In turn, as the concrete example of phosphoric acid, such as orthophosphoric acid, polyphosphoric acid, pyrophosphoric acid and metaphosphoric acid can be enumerated Deng.As the concrete example of organic acid, such as citric acid, tartaric acid, lactic acid, malic acid, succinic acid, fumaric acid, Malaysia can be enumerated Acid, gluconic acid, glucuronic acid and benzoic acid etc..As the concrete example of salt, such as sodium salt, sylvite and ammonium salt can be enumerated Deng.It as the concrete example of sugar, such as can enumerate: the monosaccharide such as glucose, galactolipin；Maltose, sucrose, fructose, trehalose etc. two Sugar；And sugar alcohol etc..As the concrete example of preservative, for example, can enumerate p-hydroxybenzoate, methyl p-hydroxybenzoate, with And sodium benzoate etc..As the concrete example of stabilizer, such as phenaetin, 8-hydroxyquinoline, antifebrin, pyrophosphoric acid can be enumerated Sodium, barbiturates, uric acid and tannic acid etc..As the concrete example of antioxidant, such as Vitamin C acids and sulfurous acid can be enumerated Salt etc..As the concrete example of complexing agent, such as edetic acid(EDTA) (ethylenediamine tetra-acetic acid (EDTA)), natrium adetate can be enumerated, according to ground Sour four sodium, diethylenetriamine pentaacetic acid and its esters, ethylenediamine hydroxyethyl triacetic acid and its esters and hydroxyethane diphosphonic acid (HEDP) and its esters etc..

Second dose of form for taking aerosol, but the preservation dosage form in aerosol container is not particularly limited.For example, 25 DEG C Dosage form can enumerate the liquids such as aqueous solution or lotion, glue, white shape etc., the liquids such as particularly preferred aqueous solution or lotion.Second dose It is to be sprayed from aerosol container with blister dosage form when in use.Second dose be with well-known stock solution and foaming agent together It is filled in container.As stock solution or the concrete example of foaming agent, such as liquefied petroleum gas (LPG), dimethyl ether can be enumerated (DME), nitrogen and carbon dioxide etc..In these, one kind can be used only, also can be used in combination two or more.As stock solution Or foaming agent, particularly preferred liquefied petroleum gas, first dose or second dose of stoste (composition of the state without stock solution) with In the range of the preferred 90:10 to 98:2 of the mass ratio of stock solution.

First dose of de- stain (decoloration of two doses of formula hairs)

First dose contains alkaline agent.Alkaline agent contained by first dose plays following effect: promoting the oxidant contained by second dose Effect promotes the decolorizing effect of hair and/or takes off dye effect.In addition, below being promoted will in the hair dye that stated, hair dyeing property.

As the concrete example of alkaline agent, for example, can enumerate ammonia, alkanolamine, silicate, carbonate, bicarbonate, metasilicate, Sulfate, chloride, phosphate, organic amine, basic amino acid and hydroxide of alkali or alkaline earth metal etc..As The concrete example of alkanolamine, such as monoethanolamine and triethanolamine can be enumerated etc..As the concrete example of silicate, such as can lift Sodium metasilicate and potassium silicate etc. out.As the concrete example of carbonate, such as sodium carbonate and ammonium carbonate can be enumerated etc..As carbon The concrete example of sour hydrogen salt, such as sodium bicarbonate and ammonium hydrogen carbonate can be enumerated etc..As the concrete example of metasilicate, such as can Enumerate sodium metasilicate and potassium metasilicate etc..As the concrete example of sulfate, such as ammonium sulfate can be enumerated etc..As chloride Concrete example, such as ammonium chloride can be enumerated etc..As phosphatic concrete example, such as ammonium dihydrogen phosphate, phosphoric acid hydrogen two can be enumerated Ammonium, sodium dihydrogen phosphate, disodium hydrogen phosphate and tertiary sodium phosphate etc..As the concrete example of organic amine, such as 2- amino-can be enumerated 2- methyl-1-propyl alcohol (AMP), 2- amino-2-methyl-1,3- propylene glycol, guanidine and 1- amino-2- propyl alcohol (MIPA) etc..As The concrete example of basic amino acid, such as arginine and lysine can be enumerated etc..Hydroxide as alkali or alkaline earth metal The concrete example of object, such as sodium hydroxide and potassium hydroxide can be enumerated etc..In these alkaline agents, it can individually contain only one kind, or It can combine containing two or more.In these, from the viewpoint of the excellent effect of luminance raising for making hair, preferably apply Ammonia, ammonium salt, alkanolamine, carbonate.

It decolourizes about hair when using, the content of de- stain i.e. first dose and the alkaline agent in second dose of mixture, In the case that hair decoloration, de- stain are applied to common decoloration, de- dye processing, preferably become 7 to 12 range with pH value Amount allotment, more preferably with pH value as 9 to 12 range amount allotment.By the way that the pH value of mixture is set as 7 or more, can promote Into the effect of oxidant contained by second dose.By the way that the pH value of mixture is set as 12 hereinafter, smearing hair can be inhibited to decolourize, de- Stain is damaged caused by hair.In addition, the pH value of hair decoloration, de- stain is set to the original of the decoloration of measurement hair, de- stain PH value of the liquid at 25 DEG C.

First dose contains each of effect that is usually contained in hair decoloration, de- stain and not undermining each ingredient Ingredient.For example, can be in the range of not undermining effect of the present invention suitably containing the ingredient contained by described second dose.

First dose of dosage form is not particularly limited, and as concrete example, 25 DEG C of dosage form can for example enumerate aqueous solution or lotion Etc. liquids, glue, foam-like, white shape, solid-like etc..In addition, aerosol, non-aerosol etc. can also be made.In addition, aerosol In the case of, well-known stock solution and foaming agent can be applied.As solid-like, powdered, granular, ingot shape etc. can be enumerated.Separately Outside, Metallic stearates such as adjustable dispersing agent, such as calcium stearate, magnesium stearate in the case where solid shaped dosage forms, sodium sulphate, Talcum, lactose and low degree of substitution hydroxypropyl cellulose.In these, one kind can be used only, also can be used in combination two or more.Due to Second dose be aerosol blister dosage form, therefore from promoted use when operability from the viewpoint of, first dose preferably take with Second dose of identical form.

Three doses of formula hair decolorations, de- stain can be by being made it for the ingredient in first dose of two doses of formula hair decolorations, de- stain His agent and constitute.Such as constituted by following three doses: first dose containing alkaline agent, having and decolourize with two doses of formula hairs, is de- Second dose of second dose of identical composition of stain, and with from first dose of two doses of formula hairs decoloration, de- stain Fall the third agent of the composition of alkaline agent.The three doses of formula hairs so constituted decolourize, de- stain has good storage stability.

Two doses of formula hair dyes be, for example, by first dose at least containing alkaline agent and oxidation dye and at least containing oxidant second Agent is constituted.Hereinafter, being illustrated centered on the difference of hair decoloration, de- stain.

(second dose of two doses of formula hair dyes)

Second dose of hair dye is for example with second dose of identical composition with hair decoloration, de- stain.

(first dose of two doses of formula hair dyes)

First dose of hair dye is for example containing alkaline agent and oxidation dye.It is and above as the example of the alkaline agent contained by first dose It is middle identical as hair decoloration, the alkaline agent for taking off the concrete example of alkaline agent used in stain and illustrating.Oxidation dye is can be by Oxidation polymerization caused by oxidant causes the compound of colour developing, is classified as dyestuff intermediate and coupling agent, oxidation dye is preferred Contain dyestuff intermediate and coupling agent.

As dyestuff intermediate, such as p-phenylenediamine, Toluene-2,4-diisocyanate can be enumerated, 5- diamines (to toluenediamine), N- phenyl-right Phenylenediamine, 4,4'- diamino-diphenyl amine, para-aminophenol, o-aminophenol, p-methylaminophenol, N, bis- (the 2- hydroxyls of N- Ethyl)-p-phenylenediamine, 2- hydroxyethyl-p-phenylenediamine, adjacent chloro- p-phenylenediamine, 4- amino-metacresol, 2- amino-4-hydroxy Ethylamino methyl phenyl ethers anisole, 2,4- diaminophenol, 1- hydroxyethyl -4,5- diamino-pyrazole and these salt etc..As salt Concrete example, such as hydrochloride and sulfate can be enumerated etc..It, can be individually containing only in the concrete example of these dyestuff intermediates One kind, or can also combine containing two or more.

Coupling agent develops the color and in conjunction with dyestuff intermediate.As coupling agent, such as resorcinol, 5- ammonia can be enumerated Base-o-cresol, m-aminophenol, alpha-Naphthol, 5- (2- Hydroxy-ethylamino) -2- methylphenol, m-phenylene diamine (MPD), 2,4- diamino Phenoxetol, Toluene-3,4-dithiol, 4- diamines, 2,6- diamino-pyridine, diphenylamine, N, N- diethyl-m-aminophenol, phenyl first Base pyrazolone, 1,5- dihydroxy naphthlene and these salt etc..As the concrete example of salt, such as hydrochloride and sulphur can be enumerated Hydrochlorate etc.., can be individually containing only one kind in the concrete example of these coupling agents, or can also combine containing two or more.Oxidation dye The tone of hair can be made to occur various change, thus preferably by selected from dyestuff intermediate at least one of the concrete example, It is constituted at least one of the concrete example selected from coupling agent.First dose can suitably contain such as " quasi drug raw material mark The oxidation dye that standard " (in June, 2006 distribution, Yao Shi newspaper office, Japan) is included is as the dye other than the oxidation dye Material.

The lower limit of the content of oxidation dye in hair dye can be suitably set, preferably 0.01 mass % or more, and more preferable 0.1 Quality % or more, and then preferably 0.5 mass % or more.It, especially can be into if the content of oxidation dye is 0.01 mass % or more One step improves color.

The upper limit of the content of oxidation dye in hair dye can be suitably set, and preferably 10 mass % are hereinafter, more preferable 7 matter % is measured hereinafter, preferably 5 mass % or less in turn.If oxidation dye content be 10 mass % hereinafter, if especially using solubilising In the case where agent, the dissolubility to solubilizer can be promoted.

In addition, first dose optionally further can also decolourize containing the ingredient other than the ingredient, such as the hair, is de- Ingredient contained by first dose, second dose of stain.

Three doses of formula hair dyes can be constituted and other agent are made in the ingredient in first dose by two doses of formula hair dyes.Such as by with Lower three doses are constituted: first dose containing alkaline agent and oxidation dye, with identical with second dose of two doses of formula hair dyes Second dose and the third with the composition for removing alkaline agent and oxidation dye from first dose of two doses of formula hair dyes of composition Agent.

Then, the application method of the composition containing oxidant of present embodiment is illustrated below.

Firstly, thus preparing the decoloration of the hair dye or hair that are made of the multi-agent, each dose of mixing of de- stain containing alkali After hair dye or the hair decoloration of agent, oxidant etc., the mixture of de- stain, it is applied on hair.In addition, each dose all with In the case that aerosol is constituted, after multi-agent can also being made to spray respectively with blister, mixture is applied on hair, or on one side will be each Agent is applied on hair to be mixed on hair on one side.Mixed method is not particularly limited, such as stirring rod or hairbrush etc. can be used And stirred with hand, it is possible to use stirring-head and electrodynamic type blender etc..Hair dye or hair decoloration, de- painting of the stain on hair Smear can using well-known method, such as so that the hair dye or hair is decolourized, de- stain be attached to have on thin gloves hand, On comb (comb) or hairbrush and it is applied to the method on hair.

After mixture is applied on hair, after the predetermined time, progress conventionally will be applied to hair with water The process that mixture on hair is washed off.Then, it preferably carries out conventionally using water using hair composition cleaning hair is washed The process of flushing.As long as the cleaning for washing hair composition for hair is used, then it is not particularly limited, can applies well-known Wash hair composition.Then, it preferably carries out conventionally carrying out hair care processing to hair using shield hair composition, uses water The process of flushing.As long as the hair care for protecting hair composition for hair is used, then it is not particularly limited, can applies well-known Protect hair composition.Well-known shield hair composition can be applied using the treatment process of shield hair composition.Then, preferably Conventionally made the process of trichoxerosis.

According to the composition containing oxidant for being used as hair dye or hair decoloration, de- stain of the embodiment, can obtain Obtain following such effect.

(1) composition containing oxidant of present embodiment contains (A) hydrocarbon and (B) oxidant.Therefore, make the combination containing oxidant The preparation stability of object is promoted.In addition, promoting alveolar substance and expansion rate when from aerosol container with the ejection of blister dosage form.

(2) in present embodiment, in the case where further containing (C) polyalcohol, mention alveolar substance (plentiful sense) further It rises.

In addition, the embodiment can change as described below.

In the hair dye, it can suitably contain such as " quasi drug raw material mark in the range of not undermining effect of the present invention The direct dyes that standard " (in June, 2006 distribution, Yao Shi newspaper office) is included is as the dyestuff other than the oxidation dye.As The additional direct dyes used sometimes for adjustment hair dyeing tone, can illustrate various acid dyes, basic dye, nitro dye Material, natural dye, disperse dyes and HC (Hair Color；Color development) dyestuff etc..

In the composition containing oxidant of the embodiment, (A) to (C) if each ingredient be formulated to when stored In composition containing oxidant, a part for other each ingredients for constituting each dose can also be configured to other agent, further Increase dosage form number.In this composition, preparation stability can be also promoted.

As long as the hair dye or hair of the embodiment decolourize, de- stain plays effect of the invention, can also incite somebody to action Constitute the hair dye or hair decoloration, a part of each ingredient contained by each dose of de- stain is configured to other agent, increase Dosage form number.

Then, additional record can be according to the embodiment and other and the technical idea grasped below.(A) at The content divided is the composition containing oxidant described in 0.01 mass % to 35 mass %.

[embodiment]

Then, Examples and Comparative Examples are enumerated to be more particularly described the embodiment.In addition, the present invention does not limit In the composition that embodiment column is recorded.

First dose containing the oxide hair dye of each ingredient shown in table 1 to table 3 is prepared respectively, as the composition containing oxidant Second dose.In addition, the numerical value in the column of each ingredient of expression in each table indicates the content of the ingredient on the column, the unit of the content For quality %.In addition, the label of " (A) " to " (C) " indicates that each (A) ingredient is extremely documented by the scheme with present application in table (C) the corresponding compound of ingredient.On the other hand, the label of " (a) " indicates ingredient (A) documented by the scheme of present application in table Control compounds.The parenthetic numerical value of chemical combination name POE indicates the addition molal quantity of E.O..It is aoxidized shown in table 1 to table 3 First dose of hair dye and second dose is to be filled into inhalator jar by the aerial fog type to be mixed with as the LPG of stock solution respectively And it prepares.The mass ratio of stoste and LPG are set as 95:5.First dose is sprayed in the form of blister composition respectively with second dose, First dose is mixed and is prepared with the mass ratio of 1:1 with second dose the oxide hair dye of blister.

Resulting oxide hair dye is applied to topknot (10cm, the Beaulax corporation of dark hair and white hair using hairbrush Make) on (hereinafter referred to as topknot), placed 30 minutes at 30 DEG C.Then, the oxide hair dye being attached on topknot is washed with water After falling, 2 hair washings are implemented (as hair composition is washed, for the Bigen Treatment of Hoyu company manufacture to topknot Shampoo) and 1 hair care is (as shield hair composition, for the Bigen Treatment Rinse of Hoyu company manufacture).This Outside, it washes hair composition and shield hair composition is rinsed with water in per treatment respectively.Then, using warm wind that topknot is dry Afterwards, it places one day.

Using method shown below to make second dose sprayed from inhalator jar with blister when alveolar substance (plentiful sense) and hair Bubble speed is assessed.In addition, using method shown below to second dose of preparation stability before being filled into inhalator jar It is assessed.In addition, being assessed using method shown below the hair dyeing of hair dyeing treated topknot.

(alveolar substance (plentiful sense))

Second dose of alveolar substance is assessed with the plentiful sense judged according to the feeling and appearance that are touched when steeping with hand.Specifically, Second dose of 3g of each example is ejected on plate from aerosol container under conditions of 25 DEG C.It is observed by 10 function auditors The shape of (function assessment) bubble and elastic force when being touched with hand, and assessed by following benchmark.By the shape retention of bubble, bullet The very high situation of power is considered as excellent (5 points), and shape retention, elastic high situation are considered as good (4 points), will Though keep shape it is elastic be not that high situation is considered as fine (3 points), by shape retention, elastic slightly lower feelings Condition is considered as slightly bad (2 points), will not keep shape and elastic low-down situation is considered as bad (1 point), grading with this 5 etc. Row scoring.Average value is calculated to the appraisal result of each function auditor, by average value be 4.6 points or more be considered as " it is excellent: 5 ", general 3.6 points are considered as " well: 4 ", 2.6 points being considered as less than 3.6 points " still: 3 ", small by 1.6 points or more less than 4.6 points Be considered as in 2.6 points " it is slightly bad: 2 ", and will be considered as less than 1.6 points " it is bad: 1 ", the result as alveolar substance assessment 1.

(expansion rate)

Second dose of expansion rate is assessed.Specifically, first under conditions of 25 DEG C from aerosol container by each example Second dose of 6g be ejected into the plastic containers of 30mL (internal diameter 30mm × height 55mm).Measurement is from after rigid spray until bubble Time until the height of topmost arrival container upper end (until being completely filled with).By the time until being completely filled with less than 4 seconds It is considered as " excellent: 5 ", 4 seconds to be considered as less than 8 seconds " good: 4 ", 8 seconds to be considered as less than 12 seconds " still: 3 ", by 12 Second it was considered as less than 16 seconds " slightly bad: 2 ", and 16 seconds or more to be considered as " bad: 1 ", 2 result to be assessed as alveolar substance.

(second dose of preparation stability)

About second dose of the preparation stability as lotion, be put into vial and 50 DEG C place 7 days after, by 5 functions Auditor presses the discrete state of second dose of following benchmark visually ranks, is thus judged.Complete unsegregated situation is considered as Excellent (5 points) almost unsegregated situation will be considered as good (4 points), will slightly visible separation the case where be considered as fine (3 points), will Slightly mostly visible separation the case where be considered as slightly bad (2 points), the case where a large amount of visible separation, is considered as bad (1 point), with this 5 Grade scores.Average value is calculated to the appraisal result of each function auditor, by average value be 4.6 points or more be considered as " it is excellent: 5 ", 3.6 points are considered as less than 4.6 points " good: 4 ", 2.6 points to be considered as less than 3.6 points " still: 3 ", by 1.6 points It is considered as less than 2.6 points " slightly bad: 2 ", and will to be considered as less than 1.6 points " bad: 1 ", as assessment result.

(hair dyeing property)

The hair dyeing of hair dyeing treated topknot about each example, by 5 function auditors by following under standard sources Benchmark assesses the color range estimation of hair dyeing treated the topknot of each example, thus judge whether hair dyeing property is excellent.With Excellent (5 points), good (4 points), still (3 points), slightly bad (2 points) and bad (1 point) this 5 grades score, to each official Can auditor appraisal result calculate average value, by average value be 4.6 points or more be considered as " it is excellent: 5 ", by 3.6 points less than 4.6 points are considered as " well: 4 ", 2.6 points being considered as less than 3.6 points " still: 3 ", 1.6 points being considered as less than 2.6 points It is " slightly bad: 2 ", and will to be considered as less than 1.6 points " bad: 1 ", as assessment result.

[table 1]

[table 2]

[table 3]

As shown in table 1, table 2, about each embodiment, confirming each evaluation item is the still above result.Such as the reality of table 2 It applies shown in example 2 and embodiment 15 like that, in the case where confirming without amphoteric surfactant, especially expansion rate and preparation is steady Qualitative further promotion.About the comparative example 1 for replacing (A) ingredient containing lanolin, confirm relative to each embodiment and alveolar substance The assessment of (plentiful sense) is poor.About the comparative example 2 for being free of (A) ingredient, confirm relative to each embodiment and preparation stability Assessment it is poor.

In addition, making the composition for removing dyestuff from each embodiment respectively, decoloration, de- stain is made and being commented Estimate, as a result alveolar substance, expansion rate, preparation stability and decoloration, de- metachromia obtain the assessment same with each embodiment.

Claims

1. a kind of composition containing oxidant, be sprayed in the form of blister agent from aerosol container, and with the agent containing alkaline agent It mixes and is used as hair dye or hair decoloration, de- stain；

And, it is characterised in that contain (A) hydrocarbon and (B) oxidant.

2. the composition according to claim 1 containing oxidant, which is characterized in that (A) hydrocarbon is atoleine.

3. the composition according to claim 1 or 2 containing oxidant, which is characterized in that further contain (C) polyalcohol.

4. a kind of application method of the composition containing oxidant, to contain oxidant according to any one of claims 1 to 3 Composition application method；

And characterized by comprising the composition containing oxidant is sprayed in the form of blister agent from aerosol container Process；And the blister agent is mixed with the blister agent containing alkaline agent, prepare hair dye or prepares hair decoloration, take off stain Process.