CN109186178A - A kind of exhaust gas recovery system and method applied to dry ice production system - Google Patents

A kind of exhaust gas recovery system and method applied to dry ice production system Download PDF

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Publication number
CN109186178A
CN109186178A CN201811062687.6A CN201811062687A CN109186178A CN 109186178 A CN109186178 A CN 109186178A CN 201811062687 A CN201811062687 A CN 201811062687A CN 109186178 A CN109186178 A CN 109186178A
Authority
CN
China
Prior art keywords
dry ice
production system
tail gas
carbon dioxide
ice production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811062687.6A
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Chinese (zh)
Inventor
李大海
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HUIZHOU KAIMEITE GASES CO Ltd
Original Assignee
HUIZHOU KAIMEITE GASES CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HUIZHOU KAIMEITE GASES CO Ltd filed Critical HUIZHOU KAIMEITE GASES CO Ltd
Priority to CN201811062687.6A priority Critical patent/CN109186178A/en
Publication of CN109186178A publication Critical patent/CN109186178A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/50Carbon dioxide
    • C01B32/55Solidifying
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0257Construction and layout of liquefaction equipments, e.g. valves, machines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00Processes characterised by the type or other details of the feed stream
    • F25J2210/80Carbon dioxide

Abstract

The present invention discloses a kind of exhaust gas recovery system and method applied to dry ice production system, includes the following steps: step S1: the tail gas of dry-ice machine being introduced to vaporizer and is gasified;Step S2: the gaseous carbon dioxide after gasification is input to recycling general pipeline;Step S3: recycling general pipeline is pressurizeed by air blower gaseous carbon dioxide being input to circulating water pool, carries out cold recovery to gaseous carbon dioxide by circulating water pool;Step S4: the gaseous carbon dioxide after cold recovery is input to the feedstock input of gas storage device.Exhaust gas recovery system and method applied to dry ice production system of the invention, design is simple, realizes the recycling of tail gas, substantially increases the utilization rate to raw material, reduces the discharge of greenhouse gases, and realize cold recovery to tail gas, reduces energy consumption.

Description

A kind of exhaust gas recovery system and method applied to dry ice production system
Technical field
The present invention relates to dry ice production technical fields, and in particular, to a kind of tail gas applied to dry ice production system time Receive system and method.
Background technique
Dry ice is widely applied in all kinds of occasions, is please referred to shown in Fig. 1, for dry ice production system in the prior art Structural schematic diagram, traditional dry ice production method process flow, generally by gaseous carbon dioxide pass through unstripped gas pipeline Then again will to liquid CO 2 process units by processes such as the cooling of device, compression, de- hydrocarbon, purification, liquefaction purifications Liquid CO 2 is delivered to dry-ice machine from storage tank and is manufactured, and during dry-ice machine produces dry ice, a part is (about 60%) liquid CO 2 is gasified, and tail gas emptying is become, and the liquid CO 2 of another part (about 40%) is gasified Carbon dioxide take away heat and cool down rapidly, to form bulk dry ice, above-mentioned dry ice in bulk is squeezed dry-ice machine high pressure grinding tool Pressure forms molding dry ice.Traditional dry ice production method design is simple, still, high to the waste of raw material, high production cost, Meanwhile the discharge of the carbon dioxide of gasification leads to cryogenic gas loss of refrigeration capacity and the pollution to environment.Therefore, we need one Kind environmental protection, energy-efficient dry ice production system.
Summary of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of exhaust gas recovery system applied to dry ice production system and side Method.
According to the first aspect of the invention, the present invention provides a kind of exhaust gas recovery system applied to dry ice production system, The dry ice production system includes: sequentially connected gas storage device, liquid CO 2 process units and dry-ice machine, tail gas Recovery system includes: vaporizer, recycling general pipeline, air blower and follows bad pond;The input terminal of vaporizer and the tail gas of dry-ice machine Output end connection;The output end of vaporizer is connect with the input terminal of recycling general pipeline;Recycle general pipeline output end and air blower it is defeated Enter end connection;The output end of air blower and the input terminal of circulating water pool connect;The output end and gas storage device of circulating water pool Connection.
According to an embodiment of the present invention, buffer air bag is provided between air blower and circulating water pool.
According to the second aspect of the invention, the present invention provides a kind of method for recovering tail gas applied to dry ice production system, It is included the following steps: based on the exhaust gas recovery system for being applied to dry ice production system described in the first aspect of the present invention
Step S1: the tail gas of dry-ice machine is introduced to vaporizer and is gasified;
Step S2: the gaseous carbon dioxide after gasification is input to recycling general pipeline gasification;
Step S3: recycling general pipeline is pressurizeed by air blower gaseous carbon dioxide being input to circulating water pool, and recirculated water is passed through Pond carries out cold recovery to gaseous carbon dioxide;And
Step S4: the gaseous carbon dioxide after cold recovery is input to the feedstock input of gas storage device.
According to an embodiment of the present invention, the gaseous carbon dioxide temperature after gasifying in step S1 is -3~-1 Celsius Degree.
According to an embodiment of the present invention, the gaseous carbon dioxide temperature in step S4 Jing Guo cold recovery is 20~25 Degree Celsius.
According to an embodiment of the present invention, the moulding pressure of air blower is 0.4~0.6MPa.
According to an embodiment of the present invention, further include step S3.1 between step S3 and step S4: passing through buffer air bag The air-flow of recycling general pipeline is buffered.
According to an embodiment of the present invention, the pressure in buffer air bag is 10~15KPa.
The beneficial effect that the present invention is different from the prior art is: the tail gas recycle applied to dry ice production system of the invention System and method, design is simple, realizes the recycling of tail gas, substantially increases the utilization rate to raw material, reduce greenhouse The discharge of gas, and cold recovery is realized to tail gas, reduce energy consumption.
Detailed description of the invention
The drawings described herein are used to provide a further understanding of the present application, constitutes part of this application, this Shen Illustrative embodiments and their description please are not constituted an undue limitation on the present application for explaining the application.In the accompanying drawings:
Fig. 1 is the structural schematic diagram of dry ice production system in the prior art;
Fig. 2 is the structural schematic diagram for being applied to the exhaust gas recovery system of dry ice production system in the application.
Specific embodiment
Multiple embodiments of the invention will be disclosed below, as clearly stated, details in many practices will with Illustrate together in lower narration.It should be appreciated, however, that the details in these practices is not applied to limit the present invention.That is, In some embodiments of the invention, the details in these practices is non-essential.
It please refers to shown in Fig. 2, is the structural representation for being applied to the exhaust gas recovery system of dry ice production system in the application Figure.
The present invention provides a kind of exhaust gas recovery system applied to dry ice production system, which includes successively Gas storage device 10, liquid CO 2 process units 20 and the dry-ice machine 30 of connection, wherein unstrpped gas, that is, gaseous state two Carbonoxide is inputted by the feedstock input of gas storage device 10, and gaseous carbon dioxide is input to liquid titanium dioxide by pipeline Carbon process units 20, gaseous carbon dioxide is by the cooling of liquid CO 2 process units 20, compression, de- hydrocarbon, purification, liquefaction Liquid CO 2 is made in the processes such as purification, and then liquid CO 2 is input to dry-ice machine 30, and liquid CO 2 passes through dry Molding dry ice is made in ice maker 30, and tail gas is discharged by its tail gas output end.
Exhaust gas recovery system includes vaporizer 101, recycling general pipeline 102, air blower 103 and follows bad pond 104, vaporizer 101 input terminal is connect with the tail gas output end of dry-ice machine 30, the output end of vaporizer 101 and the input terminal of recycling general pipeline 102 The output end of connection, recycling general pipeline 102 is connect with the input terminal of air blower 103, the output end of air blower 103 and circulating water pool Input terminal connection, the connection of the output end and gas storage device 10 of circulating water pool, wherein tail gas adds in exhaust gas recovery system Work process please refers to the content that front is applied to the method for recovering tail gas of dry ice production system, is not repeating herein.
Please continue to refer to shown in Fig. 2, in a preferred embodiment, recycles and be provided with buffering between general pipeline 102 and air blower 103 Air bag 105, wherein the quantity of buffer air bag 105 is multiple, and the air-flow that recycling general pipeline 102 is exported needs first to fill buffer air bag 105 It is further continued for conveying towards 103 direction of air blower after full, so realizes and level-one or multistage are carried out to the air-flow that recycling general pipeline 102 is exported Buffering, is additionally provided with switch valve 106 between each buffer air bag 105 and the connection of air blower 103, is controlled by switch valve 106 105 start and stop of buffer air bag, to realize the control to productive temp.
Please continue to refer to shown in Fig. 2, the present invention also provides a kind of method for recovering tail gas applied to dry ice production system, should Method for recovering tail gas is mainly used for recycling the tail gas in dry ice production system, which is about -10~-8 degrees Celsius, Main component includes a large amount of gaseous carbon dioxide and a small amount of drikold, and the method for recovering tail gas of the application is main Tail gas is recycled, so that the tail gas is converted into the unstrpped gas that front end inputs in dry ice production system, realize energy-saving ring It protects, reduces the purpose of production cost.Used equipment or device can be set from using routine on the market in this application Standby or device.
Method for recovering tail gas applied to dry ice production system includes the following steps:
Step S1: being introduced to vaporizer 101 for the tail gas for the dry-ice machine 30 for producing dry ice, then right by vaporizer 101 Tail gas gasifies, so that a small amount of drikold gasification being mixed in tail gas, avoids influencing the equipment of process below Work, for example, avoiding drikold from damaging in high-speed flow to equipment, to guarantee the tail gas recycle process Stability, the gaseous carbon dioxide after wherein vaporizer 101 is gasified are volume -3~-1 degree Celsius.
Step S2: being input to recycling general pipeline 102 for the gaseous carbon dioxide after gasification, passes through 102 pairs of general pipeline gasifications of recycling Gaseous carbon dioxide afterwards is collected.
Step S3: recycling general pipeline 102 is pressurizeed by air blower 103 gaseous carbon dioxide being input to circulating water pool, wherein The moulding pressure of air blower 103 is 0.4~0.6MPa, and wherein the conveyance conduit in circulating water pool is designed to coil form, and Water temperature is set as 30~35 degrees Celsius in circulating water pool, carries out cold recovery to gaseous carbon dioxide by circulating water pool, at this point, The temperature of gaseous carbon dioxide is 20~25 degrees Celsius, realizes cold recovery, reduces energy consumption.
Step S4: the gaseous carbon dioxide after cold recovery is input to the feedstock input of gas storage device 10, such as This, completes to utilize the tail gas recycle of dry-ice machine 30, reduces the discharge of carbon dioxide.
In a preferred embodiment of the invention, further includes step S3.1 between step S3 and step S4: passing through buffer air bag 105 The air-flow of recycling general pipeline 102 is buffered, to prevent excessive to recycling 102 output gas flow pressure of general pipeline and cause air blower 103 damage, wherein the pressure of buffer air bag 105 is about 10~15KPa.
In conclusion the exhaust gas recovery system and method applied to dry ice production system of the invention, design is simple, real The recycling of existing tail gas, substantially increases the utilization rate to raw material, reduces the discharge of greenhouse gases, and realize to tail gas Cold recovery reduces energy consumption.
The upper only embodiments of the present invention, are not intended to restrict the invention.For those skilled in the art For, the invention may be variously modified and varied.All any modifications made in spirit and principles of the present invention are equally replaced It changes, improve, should all be included within scope of the presently claimed invention.

Claims (8)

1. a kind of exhaust gas recovery system applied to dry ice production system, which includes: sequentially connected gas Storage device, liquid CO 2 process units and dry-ice machine, which is characterized in that exhaust gas recovery system includes: vaporizer, returns It receives general pipeline, air blower and follows bad pond;The input terminal of the vaporizer is connect with the tail gas output end of the dry-ice machine;It is described The output end of vaporizer is connect with the input terminal of recycling general pipeline;The output end of the recycling general pipeline and the input terminal of the air blower Connection;The output end of the air blower is connect with the input terminal of the circulating water pool;The output end of the circulating water pool with it is described The connection of gas storage device.
2. the exhaust gas recovery system according to claim 1 applied to dry ice production system, which is characterized in that the recycling Buffer air bag is provided between general pipeline and the air blower.
3. a kind of method for recovering tail gas applied to dry ice production system, it is applied to based on claim 1 to 2 is any described The exhaust gas recovery system of dry ice production system, which is characterized in that it includes the following steps:
Step S1: being introduced to vaporizer for the tail gas of dry-ice machine and gasify,;
Step S2: the gaseous carbon dioxide after gasification is input to recycling general pipeline gasification;
Step S3: recycling general pipeline is pressurizeed by air blower gaseous carbon dioxide being input to circulating water pool, and circulating water pool pair is passed through Gaseous carbon dioxide carries out cold recovery;And
Step S4: the gaseous carbon dioxide after cold recovery is input to the feedstock input of gas storage device.
4. the method for recovering tail gas according to claim 3 applied to dry ice production system, which is characterized in that the step Gaseous carbon dioxide temperature after gasifying in S1 is -3~-1 degree Celsius.
5. the method for recovering tail gas according to claim 3 applied to dry ice production system, which is characterized in that the step Gaseous carbon dioxide temperature in S4 Jing Guo cold recovery is 20~25 degrees Celsius.
6. the method for recovering tail gas according to claim 3 applied to dry ice production system, which is characterized in that the air blast The moulding pressure of machine is 0.4~0.6MPa.
7. the method for recovering tail gas according to claim 3 applied to dry ice production system, which is characterized in that the step Further include step S3.1 between S3 and step S4: being buffered by air-flow of the buffer air bag to recycling general pipeline.
8. the method for recovering tail gas according to claim 7 applied to dry ice production system, which is characterized in that the buffering Pressure in air bag is 10~15KPa.
CN201811062687.6A 2018-09-12 2018-09-12 A kind of exhaust gas recovery system and method applied to dry ice production system Pending CN109186178A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811062687.6A CN109186178A (en) 2018-09-12 2018-09-12 A kind of exhaust gas recovery system and method applied to dry ice production system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811062687.6A CN109186178A (en) 2018-09-12 2018-09-12 A kind of exhaust gas recovery system and method applied to dry ice production system

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Publication Number Publication Date
CN109186178A true CN109186178A (en) 2019-01-11

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022011901A1 (en) * 2020-07-15 2022-01-20 厦门理工学院 Tail gas treatment system for solid co2 cleaning machine

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022011901A1 (en) * 2020-07-15 2022-01-20 厦门理工学院 Tail gas treatment system for solid co2 cleaning machine

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Application publication date: 20190111

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