CN109181422A - It is a kind of using fused cast refractories rubbed brick powder as the sand mo(u)ld special coating of main material production - Google Patents

It is a kind of using fused cast refractories rubbed brick powder as the sand mo(u)ld special coating of main material production Download PDF

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Publication number
CN109181422A
CN109181422A CN201810931751.3A CN201810931751A CN109181422A CN 109181422 A CN109181422 A CN 109181422A CN 201810931751 A CN201810931751 A CN 201810931751A CN 109181422 A CN109181422 A CN 109181422A
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Prior art keywords
brick powder
sand
rubbed brick
rubbed
special coating
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CN201810931751.3A
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CN109181422B (en
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龙沾卫
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Zhengzhou Yuandong Refractory Co Ltd
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Zhengzhou Yuandong Refractory Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04Homopolymers or copolymers of ethene
    • C09D123/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

Abstract

The present invention relates to a kind of using fused cast refractories rubbed brick powder as the sand mo(u)ld special coating of main material production, technical solution is, raw material including following weight: water 5.3-6.7kg, rubbed brick powder 10.75-14.75kg, xanthan gum 6-10g, polyethylene 38-42g, the rubbed brick powder the preparation method comprises the following steps: rubbed brick powder is dried, then it is carried out in ferromagnetic deironing device except iron program, control iron in rubbed brick powder in weight percent less than 0.05%, the present invention greatly reduces the cost of manufacture of fused cast refractories sand mo(u)ld coating, fused cast refractories per ton can saving color expense be about 200 yuan, the a large amount of rubbed brick powder that can not be reused in production process can all recycle use, through too strong magnetic except iron removes the iron content in rubbed brick powder, the fusing point of rubbed brick powder can be improved, fused cast refractories sand mo(u)ld high-temperature resistant coating can be met High temperature resistant requirement.Gaseous contamination brick face when not only resin being prevented to burn, the hard shell that coating is formed at high temperature can smoothly fall off naturally in brick output, improve the efficiency of brick face cleaning.

Description

It is a kind of using fused cast refractories rubbed brick powder as the sand mo(u)ld special coating of main material production
Technical field
It is especially a kind of using fused cast refractories rubbed brick powder as the sand of main material production the present invention relates to zirconia-corundum refractory brick coating Mould special coating.
Background technique
In order to produce the fused cast refractories of higher quality, the sand mo(u)ld of fused cast refractories production at present has upgraded to resin sand sand mo(u)ld, sets Rouge sand sand mo(u)ld can generate carbon dioxide gas and other gases under the condition of high temperature in casting process, these gases can make brick Disadvantage more than face color pastiness, brick face stomata, in order to avoid these disadvantages, sand mo(u)ld inner core needs brushing high-temperature resistant coating, with painting Layer separation gas endangers fused cast refractories surface, and the high-temperature coatings that fused cast refractories sand mo(u)ld uses are helped with zirconium matter material of main part, with other Water based paint made of the non-auxiliary material of agent, coating cost is very big, 15000 yuan of zirconium quality high-temperature finished product coating market price per ton, 20 kilograms of mo(u)ld blacking dosage per ton, 300 yuan are converted into, this is a very big investment in fused cast refractories production process, occupies electricity Molten brick sells a certain proportion of profit, therefore the reduction of fused cast refractories sand mo(u)ld coating cost is imperative.
Fused cast refractories blank brick needs to finish, and so that fused cast refractories is reached final accurate dimensions, process of lapping is electric smelting Brick is ground by diamond abrasive tool, in order to avoid high temperature that friction is formed when grinding, it is therefore desirable to which recirculated water is played in grinding Cooling effect, recirculated water sedimentation basin can be entered with water flow by grinding the rubbed brick powder to get off, about 10 kilograms of the stock removal of brick per ton, be produced per year 10000 tons of fused cast refractories will generate 100 tons of rubbed brick powder.Due to rubbed brick powder metal impurities and other impurity (rubbed brick meal component itself From brick ingredient without different, the iron content that only diamond abrasive tool during the grinding process is ground away is mingled in rubbed brick powder, is made Its use value substantially reduces), it is consequently belonging to the waste product material of generation when fused cast refractories production, can no longer be used to fused cast refractories Raw materials for production, thus this is the huge loss in a production process, effective use of the rubbed brick powder in fused cast refractories production again It is one project necessarily faced of enterprise.
Summary of the invention
For above situation, for the defect for overcoming the prior art, the purpose of the present invention is just to provide one kind and is ground with fused cast refractories Brick powder is the sand mo(u)ld special coating of main material production, can effectively solve to produce coating using fused cast refractories rubbed brick powder, reduce cost The problem of.
The technical solution that the present invention solves is: a kind of using fused cast refractories rubbed brick powder as the dedicated painting of the sand mo(u)ld of main material production Material, the raw material including following weight: water 5.3-6.7kg, rubbed brick powder 10.75-14.75kg, xanthan gum 6-10g, polyethylene 38- 42g。
Preferably, the raw material including following weight: water 6kg, rubbed brick powder 12.75kg, xanthan gum 8g, polyethylene 40g.
The rubbed brick powder mainly includes the ingredient of following weight percent: silicon 17.48%, aluminium 50.89%, zirconium 27.56%, Iron 1.35%, sodium 1.46%, surplus are other ingredients (element and/impurity);
The rubbed brick powder the preparation method comprises the following steps: rubbed brick powder is dried, then carry out making except iron program in ferromagnetic deironing device Iron control is in weight percent less than 0.05% in rubbed brick powder.
A kind of preparation method of sand mo(u)ld special coating, comprising the following steps:
(1) water of 4.5-5.5kg is poured into blender, and 250g rubbed brick powder and 6-10g xanthan gum is added, and is stirred to mixed It closes uniform;
(2) remaining rubbed brick powder is added in mixture made from step (1), is stirred until homogeneous;
(3) 0.8-1.2kg water is poured into pot, and 38-42g polyethylene is added, be placed on stove fire, tanning is until poly- second Alkene melts completely;
(4) polyethylene solution of step (3) is poured into while hot in mixture made from step (2), stir evenly to get.
Preferably, the Baume degrees of sand mo(u)ld special coating obtained is 79-82.
The formula of the invention is reasonable, greatly reduces the cost of manufacture of fused cast refractories sand mo(u)ld coating, and fused cast refractories per ton can save painting Material expense is about 200 yuan, and 10,000 tons of fused cast refractories sand mo(u)lds can be 2,000,000 yuan of saving color expense, can not be reused in production process A large amount of rubbed brick powder can all recycle use, substantially increase the recycle value of rubbed brick powder, it is miscellaneous containing metal in rubbed brick powder Its fusing point reduces when matter, and metal impurities will affect brick face quality, but contains through too strong magnetic except iron removes the iron in rubbed brick powder Amount, the fusing point of rubbed brick powder can be improved, and fusing point can reach about 1690 DEG C to 1710 DEG C, can meet fused cast refractories sand mo(u)ld high-temperature resistant coating High temperature resistant requirement.The exactly sintered temperature of rubbed brick powder, thus it is higher using the grade of fit that rubbed brick powder is sand mo(u)ld coating, because To form one layer of hard shell after coating sintering, gaseous contamination brick face when not only resin being prevented to burn, what coating was formed at high temperature Hard shell can smoothly fall off naturally in brick output, and the cleaning of brick face is more convenient, improves the efficiency of brick face cleaning, be that fused cast refractories sand mo(u)ld applies Innovation on material has good social and economic benefit.
Specific embodiment
Specific embodiments of the present invention will be described in further detail with reference to embodiments.
Embodiment 1
The present embodiment sand mo(u)ld special coating includes the raw material of following weight: water 5.3kg, rubbed brick powder 10.75kg, xanthan gum 6g, polyethylene 38g.
The rubbed brick powder mainly includes the ingredient of following weight percent: silicon 17.48%, aluminium 50.89%, zirconium 27.56%, Iron 1.35%, sodium 1.46%, surplus are other ingredients (element and/impurity);
The rubbed brick powder the preparation method comprises the following steps: rubbed brick powder is dried, then carry out making except iron program in ferromagnetic deironing device Iron control is in weight percent less than 0.05% in rubbed brick powder.
The preparation method of the present embodiment sand mo(u)ld special coating, comprising the following steps:
(1) water of 4.5kg is poured into blender, and 250g rubbed brick powder and 6g xanthan gum is added, and is stirred to uniformly mixed;
(2) remaining rubbed brick powder is added in mixture made from step (1), is stirred until homogeneous;
(3) 0.8kg water is poured into pot, and 38g polyethylene is added, be placed on stove fire, tanning is until polyethylene is complete Melt;
(4) polyethylene solution of step (3) is poured into while hot in mixture made from step (2), stir evenly to get.
Preferably, the Baume degrees of sand mo(u)ld special coating obtained is 79.
Embodiment 2
The present embodiment sand mo(u)ld special coating includes the raw material of following weight: water 6kg, rubbed brick powder 12.75kg, xanthan gum 8g, Polyethylene 40g.
The rubbed brick powder mainly includes the ingredient of following weight percent: silicon 17.48%, aluminium 50.89%, zirconium 27.56%, Iron 1.35%, sodium 1.46%, surplus are other ingredients (element and/impurity);
The rubbed brick powder the preparation method comprises the following steps: rubbed brick powder is dried, then carry out making except iron program in ferromagnetic deironing device Iron control is in weight percent less than 0.05% in rubbed brick powder.
The preparation method of the present embodiment sand mo(u)ld special coating, comprising the following steps:
(1) water of 5kg is poured into blender, and 250g rubbed brick powder and 8g xanthan gum is added, and is stirred to uniformly mixed;
(2) remaining rubbed brick powder is added in mixture made from step (1), is stirred until homogeneous;
(3) 1kg water is poured into pot, and 40g polyethylene is added, be placed on stove fire, tanning is until polyethylene melts completely Change;
(4) polyethylene solution of step (3) is poured into while hot in mixture made from step (2), stir evenly to get.
Preferably, the Baume degrees of sand mo(u)ld special coating obtained is 80.5.
Embodiment 3
The present embodiment sand mo(u)ld special coating includes the raw material of following weight: water 6.7kg, rubbed brick powder 14.75kg, xanthan gum 10g, polyethylene 42g.
The rubbed brick powder mainly includes the ingredient of following weight percent: silicon 17.48%, aluminium 50.89%, zirconium 27.56%, Iron 1.35%, sodium 1.46%, surplus are other ingredients (element and/impurity);
The rubbed brick powder the preparation method comprises the following steps: rubbed brick powder is dried, then carry out making except iron program in ferromagnetic deironing device Iron control is in weight percent less than 0.05% in rubbed brick powder.
The preparation method of the present embodiment sand mo(u)ld special coating, comprising the following steps:
(1) water of 5.5kg is poured into blender, and 250g rubbed brick powder and 10g xanthan gum is added, and stirring is equal to mixing It is even;
(2) remaining rubbed brick powder is added in mixture made from step (1), is stirred until homogeneous;
(3) 1.2kg water is poured into pot, and 42g polyethylene is added, be placed on stove fire, tanning is until polyethylene is complete Melt;
(4) polyethylene solution of step (3) is poured into while hot in mixture made from step (2), stir evenly to get.
Preferably, the Baume degrees of sand mo(u)ld special coating obtained is 82.
There is above situation to can be seen that the fusion temperatures of fused cast refractories at 2000 DEG C or more, cast temperature at 1800 DEG C or so, The maximum temperature that solution enters sand mo(u)ld contact sand mo(u)ld is 1800 DEG C, and 1800 DEG C are cooled to used time about 8 minutes of 1700 DEG C, rubbed brick powder It is interior containing metal impurities when its fusing point reduce, and metal impurities will affect brick face quality, but through too strong magnetic except iron removes mill The fusing point of iron content in brick powder, rubbed brick powder can be improved, and fusing point can reach about 1690 DEG C to 1710 DEG C, can meet fused cast refractories sand The high temperature resistant requirement of mould high-temperature resistant coating uses mill since this temperature range is exactly the sintered temperature of rubbed brick powder Brick powder is that the grade of fit of sand mo(u)ld coating is higher, is not only hindered through practical application using one layer of hard shell is formed after coating of the present invention sintering Gaseous contamination brick face when only resin burns, the hard shell that coating is formed at high temperature can smoothly fall off naturally in brick output, brick face It is more convenient to clear up, and compared with prior art, the formula of the invention is reasonable, greatly reduces being fabricated to for fused cast refractories sand mo(u)ld coating This, fused cast refractories per ton can saving color expense be about 200 yuan, 10,000 tons of fused cast refractories sand mo(u)lds can be 2,000,000 yuan of saving color expense, raw The a large amount of rubbed brick powder that can not be reused during production can all recycle use, substantially increase the recycling valence of rubbed brick powder Value, the cleaning of brick face is more convenient, improves the efficiency of brick face cleaning, is the innovation on fused cast refractories sand mo(u)ld coating, there is good society And economic benefit.

Claims (6)

1. a kind of using fused cast refractories rubbed brick powder as the sand mo(u)ld special coating of main material production, which is characterized in that including following weight Raw material: water 5.3-6.7kg, rubbed brick powder 10.75-14.75kg, xanthan gum 6-10g, polyethylene 38-42g.
2. sand mo(u)ld special coating according to claim 1, which is characterized in that preferred, the raw material including following weight: water 6kg, rubbed brick powder 12.75kg, xanthan gum 8g, polyethylene 40g.
3. sand mo(u)ld special coating according to claim 1 or 2, which is characterized in that rubbed brick powder mainly includes following weight hundred Divide the ingredient of ratio: silicon 17.48%, aluminium 50.89%, zirconium 27.56%, iron 1.35%, sodium 1.46%.
4. sand mo(u)ld special coating according to claim 3, which is characterized in that rubbed brick powder the preparation method comprises the following steps: by rubbed brick powder It dries, then carries out controlling iron in rubbed brick powder in weight percent less than 0.05% except iron program in ferromagnetic deironing device.
5. a kind of preparation method of sand mo(u)ld special coating as claimed in claim 4, which comprises the following steps:
(1) water of 4.5-5.5kg is poured into blender, and 250g rubbed brick powder and 6-10g xanthan gum is added, and stirring is equal to mixing It is even;
(2) remaining rubbed brick powder is added in mixture made from step (1), is stirred until homogeneous;
(3) 0.8-1.2kg water is poured into pot, and 38-42g polyethylene is added, be placed on stove fire, tanning is until polyethylene is complete It is complete to melt;
(4) polyethylene solution of step (3) is poured into while hot in mixture made from step (2), stir evenly to get.
6. the preparation method of sand mo(u)ld special coating according to claim 5, which is characterized in that sand mo(u)ld special coating obtained Baume degrees be 79-82.
CN201810931751.3A 2018-08-16 2018-08-16 Special coating for sand mold produced by using fused brick grinding powder as main raw material Active CN109181422B (en)

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CN201810931751.3A CN109181422B (en) 2018-08-16 2018-08-16 Special coating for sand mold produced by using fused brick grinding powder as main raw material

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Application Number Priority Date Filing Date Title
CN201810931751.3A CN109181422B (en) 2018-08-16 2018-08-16 Special coating for sand mold produced by using fused brick grinding powder as main raw material

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CN109181422B CN109181422B (en) 2020-06-30

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2992960A (en) * 1958-06-18 1961-07-18 Various Assignees High temperature resistant materials containing boron and method of manufacture thereof
GB901784A (en) * 1960-04-13 1962-07-25 Carborundum Co Oxidation-resistant ceramics and methods of manufacturing the same
CN101570650A (en) * 2008-04-30 2009-11-04 北京通达耐火技术股份有限公司 Preparation method for wear resistant fire-retardant coating
CN101709161A (en) * 2009-12-01 2010-05-19 闫友平 Water-based paint for centrifugally casing stainless steel tube
CN104353777A (en) * 2014-11-05 2015-02-18 襄阳聚力炉衬材料有限公司 Cast iron evaporative pattern coating and preparation method thereof
CN105522112A (en) * 2016-01-07 2016-04-27 上海交通大学 High-collapsibility ceramic shell for manufacturing magnesium alloy fusible pattern and preparation method for high-collapsibility ceramic shell
CN107952929A (en) * 2017-11-23 2018-04-24 山东蒙沃变速器有限公司 A kind of water base lost foam casting coating

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2992960A (en) * 1958-06-18 1961-07-18 Various Assignees High temperature resistant materials containing boron and method of manufacture thereof
GB901784A (en) * 1960-04-13 1962-07-25 Carborundum Co Oxidation-resistant ceramics and methods of manufacturing the same
CN101570650A (en) * 2008-04-30 2009-11-04 北京通达耐火技术股份有限公司 Preparation method for wear resistant fire-retardant coating
CN101709161A (en) * 2009-12-01 2010-05-19 闫友平 Water-based paint for centrifugally casing stainless steel tube
CN104353777A (en) * 2014-11-05 2015-02-18 襄阳聚力炉衬材料有限公司 Cast iron evaporative pattern coating and preparation method thereof
CN105522112A (en) * 2016-01-07 2016-04-27 上海交通大学 High-collapsibility ceramic shell for manufacturing magnesium alloy fusible pattern and preparation method for high-collapsibility ceramic shell
CN107952929A (en) * 2017-11-23 2018-04-24 山东蒙沃变速器有限公司 A kind of water base lost foam casting coating

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