CN109174592A - A kind of technique for the anti-marine organism corrsion of underwater metal surface - Google Patents

A kind of technique for the anti-marine organism corrsion of underwater metal surface Download PDF

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Publication number
CN109174592A
CN109174592A CN201811328433.4A CN201811328433A CN109174592A CN 109174592 A CN109174592 A CN 109174592A CN 201811328433 A CN201811328433 A CN 201811328433A CN 109174592 A CN109174592 A CN 109174592A
Authority
CN
China
Prior art keywords
layer
capsaicine
metal surface
paint
marine organism
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811328433.4A
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Chinese (zh)
Inventor
黄河
汤运浩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MEIZUAN ENERGY TECHNOLOGY (SHANGHAI) Co Ltd
American Drilling Deep Sea Energy Technology Research and Development Shanghai Co Ltd
Original Assignee
MEIZUAN ENERGY TECHNOLOGY (SHANGHAI) Co Ltd
American Drilling Deep Sea Energy Technology Research and Development Shanghai Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MEIZUAN ENERGY TECHNOLOGY (SHANGHAI) Co Ltd, American Drilling Deep Sea Energy Technology Research and Development Shanghai Co Ltd filed Critical MEIZUAN ENERGY TECHNOLOGY (SHANGHAI) Co Ltd
Priority to CN201811328433.4A priority Critical patent/CN109174592A/en
Publication of CN109174592A publication Critical patent/CN109174592A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/56Three layers or more
    • B05D7/58No clear coat specified
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2503/00Polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2504/00Epoxy polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2506/00Halogenated polymers
    • B05D2506/20Chlorinated polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2507/00Polyolefins
    • B05D2507/01Polyethylene

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of techniques for the anti-marine organism corrsion of underwater metal surface, and it includes following steps: step 1: carrying out sandblasting, derusting to metal surface;Step 2: brushing one layer of antifouling paint on metal surface to form antiseptic oil paint layer;Step 3: spraying one layer of capsaicine on antiseptic oil paint layer to form capsaicine layer, carry out step 4 immediately after capsaicine is dry;Step 4: the mixed paint being made of tung oil and capsaicine being coated in capsaicine layer surface, to form mixing paint layer.Combination and arrangement of the present invention by metal surface surface multi-layer structure, especially one layer of mixing paint layer being made of tung oil and capsaicine is coated again on the surface of capsaicine layer, strong capsaicine is enhanced for preventing the effect of marine organism corrsion, has achieved the effect that 1+1 > 2.To become it is a kind of it is more efficient prevent marine organism corrsion, and the technique of the strong anti-marine organism corrsion of underwater of adhesive force.

Description

A kind of technique for the anti-marine organism corrsion of underwater metal surface
Technical field
The present invention relates to marine organism corrsion protection technology fields, and in particular to one kind is used for the anti-ocean of underwater metal surface The technique of biological corrosion.
Background technique
Marine organism corrsion is because biological attachment, growth, breeding, metabolism and the dead corrosion being caused directly or indirectly are claimed For marine organism corrsion.Be exactly in brief biological attachment on material caused by biodeterioration and corrosion.
The marine organism corrsion problem of the infrastructure and essential industry facility be on active service in marine environment is serious, especially The marine organism corrsion problem of ship and ocean platform is more prominent, and marine organism corrsion, which has become, influences ship, coastal waters work Journey, ocean facility military service safety, the service life, reliability most important factor, cause the height weight of countries in the world government and industry Depending on.Therefore, greatly develop the anti-marine organism corrsion technology of ocean engineering, for ensure the military service safety of ocean engineering and ship with Reliability, reduces the generation of disaster sexual behavior event, and the service life for extending marine structure is of great significance.
The method that the technology of existing anti-marine organism corrsion generallys use plating or spray painting.It is carried out according to galvanoplastic Processing, not only the processing time is longer, once processing method is incorrect, also will affect the navigation of ship.According to the method for spray painting Hull outer surface is handled, for existing Secondary Anticorrosion for the poor for applicability of marine organism corrsion, complex process is at high cost It is high, and be extremely easy to fall off, cause anti-marine organism corrsion effect very undesirable.
Summary of the invention
The object of the present invention is to provide a kind of techniques for the anti-marine organism corrsion of underwater metal surface, to prevent or subtract Light corrosion of the marine organisms to metal product or equipment.
In order to achieve the above objectives, the present invention provides a kind of technique for the anti-marine organism corrsion of underwater metal surface, It includes following steps:
Step 1: sandblasting, derusting are carried out to metal surface;
Step 2: brushing one layer of antifouling paint on metal surface to form antiseptic oil paint layer;
Step 3: spraying one layer of capsaicine on antiseptic oil paint layer to form capsaicine layer, carried out immediately after capsaicine is dry Step 4;
Step 4: the mixed paint being made of tung oil and capsaicine being coated in capsaicine layer surface, to form mixing paint layer.
The above-mentioned technique for the anti-marine organism corrsion of underwater metal surface, wherein the antifouling paint is chlorination rubber Glue system synthetic resin coating, ethylene system synthetic resin coating, epoxy synthetic resin coating or polyurethane system synthetic resin Coating.
The above-mentioned technique for the anti-marine organism corrsion of underwater metal surface, wherein the mixed paint includes quality hundred Divide the tung oil that ratio is 50%-90% and the capsaicine that mass percent is 10%-50%.
The above-mentioned technique for the anti-marine organism corrsion of underwater metal surface, wherein the antiseptic oil paint layer, capsaicine The overall thickness of layer and mixing paint layer is 30-90 μm.
The above-mentioned technique for the anti-marine organism corrsion of underwater metal surface, wherein the antiseptic oil paint layer, capsaicine The overall thickness of layer and mixing paint layer is 45-60 μm.
The above-mentioned technique for the anti-marine organism corrsion of underwater metal surface, wherein the thickness of the antiseptic oil paint layer It is 15-20 μm;The capsaicine layer with a thickness of 15-20 μm;It is described mixing paint layer with a thickness of 15-20 μm.
Compared with the existing technology, the invention has the following advantages:
The property that the present invention is acted on by changing marine organism corrsion, reaches and prevents or mitigates marine organisms to metal product or set The purpose of standby corrosion.
Capsaicine (from pepper, capsicum or onion) is the active constituent of capsicum, and the low-surface-energy for low cost is nontoxic Antifouling paint, can be with antibacterial and the attachment for avoiding marine organisms.Tung oil is a kind of natural vegetable oil, it have rapidly it is dry, High temperature resistant, it is corrosion-resistant the features such as, be manufacture paint primary raw material, corrosion-resistant effect can be played.
Combination and arrangement of the present invention by metal surface surface multi-layer structure, especially on the surface of capsaicine layer One layer of mixing paint layer being made of tung oil and capsaicine is coated again, enhances strong capsaicine for preventing the work of marine organism corrsion With having achieved the effect that 1+1 > 2.To become, one kind is more efficient to prevent marine organism corrsion, and the new type water that adhesive force is strong Under anti-marine organism corrsion technique.Present invention process is extremely simple, and cost is very cheap, and materials are especially convenient, can answer extensively Anti- marine organism corrsion process demand is carried out for various underwater metal surfaces.It is more outstanding to be, through anticorrosion process of the present invention Multilayered structure adhesive force after processing on metal surface is strong, not easily to fall off, anti-marine organism corrsion significant effect.
Detailed description of the invention
Fig. 1 is the process flow chart that the present invention is used for the anti-marine organism corrsion of underwater metal surface;
Fig. 2 is that metal surface uses the structural schematic diagram after the anti-marine organism corrsion technique of the present invention.
Specific embodiment
Below in conjunction with attached drawing, by specific embodiment, the invention will be further described, these embodiments are merely to illustrate The present invention is not limiting the scope of the invention.
As shown in Figure 1, the present invention provides a kind of technique for the anti-marine organism corrsion of underwater metal surface 1, packet Containing following steps:
Step 1: sandblasting, derusting, to reach a kind of state that metal corrodes without own nature are carried out to metal surface 1;
Step 2: one layer of antifouling paint is brushed on metal surface 1 to form antiseptic oil paint layer 2, to reach normal underwater anti-corrosion Paint property states;
Step 3: spray one layer of capsaicine on antiseptic oil paint layer 2 to form capsaicine layer 3, after capsaicine is dry immediately into Row step 4;
Step 4: the mixed paint being made of tung oil and capsaicine being coated in 3 surface of capsaicine layer, paint layer 4 is mixed to be formed, is used for Reinforce capsaicine for preventing the effect of marine organism corrsion.
As shown in Fig. 2, after using anti-marine organism corrsion technique provided by the present invention, 1 surface of metal surface from it is interior to It is disposed with outside: antiseptic oil paint layer 2, capsaicine layer 3 and mixing paint layer 4.
In some embodiments, the antifouling paint is various antifouling paints available in the market;For example, described anti- Chlorinated rubber system synthetic resin coating, ethylene system synthetic resin coating, the epoxy synthesis that corruption paint can choose as thick-slurry type Cold coating or polyurethane system synthetic resin coating.
In some embodiments it may be preferred that the mixed paint includes the tung oil and quality hundred that mass percent is 50%-90% Divide the capsaicine than being 10%-50%.Preferably, the overall thickness of the antiseptic oil paint layer 2, capsaicine layer 3 and mixing paint layer 4 is 30-90μm.It is highly preferred that the overall thickness of the antiseptic oil paint layer 2, capsaicine layer 3 and mixing paint layer 4 is 45-60 μm.Most preferably Ground, the antiseptic oil paint layer 2 with a thickness of 15-20 μm;The capsaicine layer 3 with a thickness of 15-20 μm;The mixing paint layer 4 With a thickness of 15-20 μm.
In conclusion the property that the present invention is acted on by changing marine organism corrsion, reaches and prevents or mitigates marine organisms To the purpose of the corrosion of metal product or equipment.
Capsaicine (from pepper, capsicum or onion) is the active constituent of capsicum, and the low-surface-energy for low cost is nontoxic Antifouling paint, can be with antibacterial and the attachment for avoiding marine organisms.Tung oil is a kind of natural vegetable oil, it have rapidly it is dry, High temperature resistant, it is corrosion-resistant the features such as, be manufacture paint primary raw material, corrosion-resistant effect can be played.
Combination and arrangement of the present invention by metal surface surface multi-layer structure, especially on the surface of capsaicine layer One layer of mixing paint layer being made of tung oil and capsaicine is coated again, enhances strong capsaicine for preventing the work of marine organism corrsion With having achieved the effect that 1+1 > 2.To become, one kind is more efficient to prevent marine organism corrsion, and the new type water that adhesive force is strong Under anti-marine organism corrsion technique.Present invention process is extremely simple, and cost is very cheap, and materials are especially convenient, can answer extensively Anti- marine organism corrsion process demand is carried out for various underwater metal surfaces.It is more outstanding to be, through anticorrosion process of the present invention Multilayered structure adhesive force after processing on metal surface is strong, not easily to fall off, anti-marine organism corrsion significant effect.
It is discussed in detail although the contents of the present invention have passed through above preferred embodiment, but it should be appreciated that above-mentioned Description is not considered as limitation of the present invention.After those skilled in the art have read above content, for of the invention A variety of modifications and substitutions all will be apparent.Therefore, protection scope of the present invention should be limited to the appended claims.

Claims (6)

1. a kind of technique for the anti-marine organism corrsion of underwater metal surface, which is characterized in that it includes following steps: step 1: sandblasting, derusting are carried out to metal surface;Step 2: brushing one layer of antifouling paint on metal surface to form antiseptic oil paint layer; Step 3: spraying one layer of capsaicine on antiseptic oil paint layer to form capsaicine layer, carry out step immediately after capsaicine is dry 4;Step 4: the mixed paint being made of tung oil and capsaicine being coated in capsaicine layer surface, to form mixing paint layer.
2. being used for the technique of the anti-marine organism corrsion of underwater metal surface as described in claim 1, which is characterized in that described anti- Corruption paint is chlorinated rubber system synthetic resin coating, ethylene system synthetic resin coating, epoxy synthetic resin coating or poly- amino Formic acid system synthetic resin coating.
3. being used for the technique of the anti-marine organism corrsion of underwater metal surface as described in claim 1, which is characterized in that described mixed Close enamel-cover containing mass percent be 50%-90% tung oil and mass percent be 10%-50% capsaicine.
4. being used for the technique of the anti-marine organism corrsion of underwater metal surface as described in claim 1, which is characterized in that described anti- The overall thickness of rotten skin of paint, capsaicine layer and mixing paint layer is 30-90 μm.
5. being used for the technique of the anti-marine organism corrsion of underwater metal surface as claimed in claim 4, which is characterized in that described anti- The overall thickness of rotten skin of paint, capsaicine layer and mixing paint layer is 45-60 μm.
6. being used for the technique of the anti-marine organism corrsion of underwater metal surface as claimed in claim 5, which is characterized in that described anti- Rotten skin of paint with a thickness of 15-20 μm;The capsaicine layer with a thickness of 15-20 μm;It is described mixing paint layer with a thickness of 15-20 μm。
CN201811328433.4A 2018-11-09 2018-11-09 A kind of technique for the anti-marine organism corrsion of underwater metal surface Pending CN109174592A (en)

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CN201811328433.4A CN109174592A (en) 2018-11-09 2018-11-09 A kind of technique for the anti-marine organism corrsion of underwater metal surface

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CN201811328433.4A CN109174592A (en) 2018-11-09 2018-11-09 A kind of technique for the anti-marine organism corrsion of underwater metal surface

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5629045A (en) * 1992-09-17 1997-05-13 Richard L. Veech Biodegradable nosiogenic agents for control of non-vertebrate pests
CN101573266A (en) * 2006-10-26 2009-11-04 Ppg有限责任公司 Fouling release new building coating process
CN104549961A (en) * 2014-12-10 2015-04-29 青岛无为保温材料有限公司 Ship anti-pollution method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5629045A (en) * 1992-09-17 1997-05-13 Richard L. Veech Biodegradable nosiogenic agents for control of non-vertebrate pests
CN101573266A (en) * 2006-10-26 2009-11-04 Ppg有限责任公司 Fouling release new building coating process
CN104549961A (en) * 2014-12-10 2015-04-29 青岛无为保温材料有限公司 Ship anti-pollution method

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
肖千云等: "《舰船腐蚀与防护技术》", 31 December 2012 *
荆建刚等: "《鲁山览胜》", 31 January 2010 *
赵怡: "《中国石油化工科技信息指南 2003年 下》", 31 July 2003 *

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Application publication date: 20190111

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