CN109164535A - A kind of high-power glass optical fiber - Google Patents

A kind of high-power glass optical fiber Download PDF

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Publication number
CN109164535A
CN109164535A CN201811145804.5A CN201811145804A CN109164535A CN 109164535 A CN109164535 A CN 109164535A CN 201811145804 A CN201811145804 A CN 201811145804A CN 109164535 A CN109164535 A CN 109164535A
Authority
CN
China
Prior art keywords
parts
surrounding layer
fibre core
optical fiber
glass optical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811145804.5A
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Chinese (zh)
Inventor
刘红娟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhenjiang Microcore Photonic Technology Co Ltd
Original Assignee
Zhenjiang Microcore Photonic Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhenjiang Microcore Photonic Technology Co Ltd filed Critical Zhenjiang Microcore Photonic Technology Co Ltd
Priority to CN201811145804.5A priority Critical patent/CN109164535A/en
Publication of CN109164535A publication Critical patent/CN109164535A/en
Pending legal-status Critical Current

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02Optical fibres with cladding with or without a coating
    • G02B6/02395Glass optical fibre with a protective coating, e.g. two layer polymer coating deposited directly on a silica cladding surface during fibre manufacture
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/078Glass compositions containing silica with 40% to 90% silica, by weight containing an oxide of a divalent metal, e.g. an oxide of zinc
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/12Silica-free oxide glass compositions
    • C03C3/16Silica-free oxide glass compositions containing phosphorus

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  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Glass Compositions (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)

Abstract

The present invention relates to a kind of high-power glass optical fibers, including fibre core and the surrounding layer being placed in outside fibre core, the fibre core and the surrounding layer are glass material, the core diameter is 80~90 μm, the surrounding layer is with a thickness of 100~180 μm, the fibre core is the glass material based on phosphate, and the surrounding layer is the glass material based on silicate.By the present invention in that using phosphate as fibre core, the high advantage of phosphate fibre core efficiency of transmission is given full play to, the generally existing photon the Opacitization of silica fibre is greatly reduced by using silicate as surrounding layer and takes full advantage of the stability of silicate glass.

Description

A kind of high-power glass optical fiber
Technical field
The present invention relates to a kind of optical fiber more particularly to a kind of high-power glass optical fibers.
Background technique
Optical fiber is writing a Chinese character in simplified form for optical fiber, is a kind of fiber made of glass or plastics, can be used as light conduction tool.It passes Defeated principle is the total reflection of light ' '.Fine optical fiber is encapsulated in plastic sheath, allows it to be bent and be unlikely to be broken.It is logical Often, the emitter of one end of optical fiber uses light emitting diode (light emitting diode, LED) or beam of laser by light Pulse is sent to optical fiber, and the reception device of the other end of optical fiber detects pulse using light-sensitive element.
In daily life, due to light in the conduction loss of optical fiber, light more much lower than the loss that electricity is conducted in electric wire Fibre is used as the information transmitting of long range.
Existing glass optical fiber mostly uses silicate glass or phosphate glass as fibre core, and silicate glass is with respect to phosphoric acid The advantage of salt glass optical fiber are as follows: there is preferable stability and can be welded with silica fibre, the advantage of phosphate glass optical fiber Are as follows: efficiency of transmission with higher can reduce the length of activation optical fiber, and the inhibition with significant photon the Opacitization is imitated It answers.The diameter of optical fiber directly influences the efficiency of transmission of optical fiber, and the thickness of surrounding layer directly influences the degree of protection to fibre core, But the larger increase that will lead to volume of thickness.
Summary of the invention
The present invention in order to give full play to the advantage of phosphate optical fiber and silicate fibers, pass through balance fibre diameter realize it is high Effect transmission.The present invention provides a kind of high-power glass optical fibers.
The technical solution used in the present invention are as follows: a kind of high-power glass optical fiber including fibre core and is placed in outside fibre core Surrounding layer, the fibre core and the surrounding layer are glass material, and the core diameter is 80~90 μm, the outsourcing thickness Degree is 100~180 μm, and the fibre core is the glass material based on phosphate, and the surrounding layer is based on silicate Glass material.
Further, the fibre core includes the component of following mass fraction:
40 ~ 80 parts of phosphorous oxide
10 ~ 30 parts of magnesia
10 ~ 20 parts of potassium oxide
10 ~ 15 parts of aluminium oxide
20 ~ 25 parts of lanthana
2 ~ 3 parts of dispersing agent.
Further, the core diameter and the surrounding layer thickness proportion are 1:1 ~ 2.
Further, the core diameter and the surrounding layer thickness proportion are 1:1.5.
Further, the surrounding layer includes the component of following mass fraction:
60 ~ 80 parts of silica;
20 ~ 30 parts of lithia;
10 ~ 30 parts of sodium oxide molybdena;
10 ~ 20 parts of magnesia;
5 ~ 8 parts of dispersing agent.
Further, the surrounding layer includes the component of following mass fraction:
65 ~ 76 parts of silica;
20 ~ 25 parts of lithia;
15 ~ 30 parts of sodium oxide molybdena;
15 ~ 20 parts of magnesia;
5 ~ 7 parts of dispersing agent.
Beneficial effect caused by the present invention includes: to give full play to phosphoric acid by the present invention in that use phosphate as fibre core The high advantage of salt fibre core efficiency of transmission greatly reduces the generally existing photon the Opacitization of silica fibre, by using silicic acid Salt takes full advantage of the stability of silicate glass as surrounding layer, can effectively resist the erosion from external environment, simultaneously It can be welded to connect with silica fibre.Core diameter and surrounding layer thickness in the present invention can both play the role of protecting fibre core It can guarantee high efficiency of transmission again.
Specific embodiment
Further details of explanation is done to the present invention combined with specific embodiments below, it should be appreciated that of the invention Protection scope is not limited by the specific implementation.
Embodiment 1
A kind of high-power glass optical fiber, including fibre core and the surrounding layer being placed in outside fibre core, the fibre core and the surrounding layer are equal For glass material, the core diameter is 80 μm, and for the surrounding layer with a thickness of 100 μm, the fibre core is based on phosphate Glass material, the surrounding layer is glass material based on silicate.
The fibre core includes the component of following mass fraction:
40 parts of phosphorous oxide
10 parts of magnesia
20 parts of potassium oxide
15 parts of aluminium oxide
25 parts of lanthana
3 parts of dispersing agent.
The surrounding layer includes the component of following mass fraction:
60 parts of silica;
20 parts of lithia;
30 parts of sodium oxide molybdena;
20 parts of magnesia;
8 parts of dispersing agent.
Embodiment 2
A kind of high-power glass optical fiber, including fibre core and the surrounding layer being placed in outside fibre core, the fibre core and the surrounding layer are equal For glass material, the core diameter is 90 μm, and for the surrounding layer with a thickness of 180 μm, the fibre core is based on phosphate Glass material, the surrounding layer is glass material based on silicate.
The fibre core includes the component of following mass fraction:
80 parts of phosphorous oxide
30 parts of magnesia
10 parts of potassium oxide
10 parts of aluminium oxide
20 parts of lanthana
2 parts of dispersing agent.
The surrounding layer includes the component of following mass fraction:
80 parts of silica;
30 parts of lithia;
10 parts of sodium oxide molybdena;
10 parts of magnesia;
5 parts of dispersing agent.
Embodiment 3
A kind of high-power glass optical fiber, including fibre core and the surrounding layer being placed in outside fibre core, the fibre core and the surrounding layer are equal For glass material, the core diameter is 85 μm, and for the surrounding layer with a thickness of 110 μm, the fibre core is based on phosphate Glass material, the surrounding layer is glass material based on silicate.
The fibre core includes the component of following mass fraction:
60 parts of phosphorous oxide
20 parts of magnesia
15 parts of potassium oxide
13 parts of aluminium oxide
23 parts of lanthana
2.5 parts of dispersing agent.
The surrounding layer includes the component of following mass fraction:
70 parts of silica;
25 parts of lithia;
15 parts of sodium oxide molybdena;
15 parts of magnesia;
7 parts of dispersing agent.
The above is only a preferred embodiment of the present invention, and the present invention is not limited in the content of embodiment.For in this field Technical staff for, can have various change and change within the scope of technical solution of the present invention, made any variation and Change, within that scope of the present invention.

Claims (6)

1. a kind of high-power glass optical fiber, including fibre core and the surrounding layer being placed in outside fibre core, it is characterised in that: the fibre core and The surrounding layer is glass material, the core diameter be 80~90 μm, the surrounding layer with a thickness of 100~180 μm, The fibre core is the glass material based on phosphate, and the surrounding layer is the glass material based on silicate.
2. high power glass optical fiber according to claim 1, it is characterised in that: the fibre core includes following mass fraction Component:
40 ~ 80 parts of phosphorous oxide
10 ~ 30 parts of magnesia
10 ~ 20 parts of potassium oxide
10 ~ 15 parts of aluminium oxide
20 ~ 25 parts of lanthana
2 ~ 3 parts of dispersing agent.
3. high power glass optical fiber according to claim 1, it is characterised in that: the core diameter and the surrounding layer Thickness proportion is 1:1 ~ 2.
4. high power glass optical fiber according to claim 1, it is characterised in that: the core diameter and the surrounding layer Thickness proportion is 1:1.5.
5. high power glass optical fiber according to claim 1, it is characterised in that: the surrounding layer includes following mass fraction Component:
60 ~ 80 parts of silica;
20 ~ 30 parts of lithia;
10 ~ 30 parts of sodium oxide molybdena;
10 ~ 20 parts of magnesia;
5 ~ 8 parts of dispersing agent.
6. high power glass optical fiber according to claim 1, it is characterised in that: the surrounding layer includes following mass fraction Component:
65 ~ 76 parts of silica;
20 ~ 25 parts of lithia;
15 ~ 30 parts of sodium oxide molybdena;
15 ~ 20 parts of magnesia;
5 ~ 7 parts of dispersing agent.
CN201811145804.5A 2018-09-29 2018-09-29 A kind of high-power glass optical fiber Pending CN109164535A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811145804.5A CN109164535A (en) 2018-09-29 2018-09-29 A kind of high-power glass optical fiber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811145804.5A CN109164535A (en) 2018-09-29 2018-09-29 A kind of high-power glass optical fiber

Publications (1)

Publication Number Publication Date
CN109164535A true CN109164535A (en) 2019-01-08

Family

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Family Applications (1)

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Country Status (1)

Country Link
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110040969A (en) * 2019-04-10 2019-07-23 长春理工大学 A kind of flexible optical fiber image transmitting beam inner cladding glass and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4871230A (en) * 1987-06-24 1989-10-03 Hoya Corporation Single mode phosphate laser glass fiber
CN1402028A (en) * 2002-09-06 2003-03-12 中国科学院上海光学精密机械研究所 Rare-earth element doped glass double-clad optic fibre and mfg. method thereof
CN102023318A (en) * 2009-09-11 2011-04-20 中国科学院西安光学精密机械研究所 Composition of super large mode area silicate fiber and method of producing the same
CN103964696A (en) * 2014-05-26 2014-08-06 山东海富光子科技股份有限公司 Phosphate-silicate all glass hybrid optical fiber for high-power optical fiber laser

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4871230A (en) * 1987-06-24 1989-10-03 Hoya Corporation Single mode phosphate laser glass fiber
CN1402028A (en) * 2002-09-06 2003-03-12 中国科学院上海光学精密机械研究所 Rare-earth element doped glass double-clad optic fibre and mfg. method thereof
CN102023318A (en) * 2009-09-11 2011-04-20 中国科学院西安光学精密机械研究所 Composition of super large mode area silicate fiber and method of producing the same
CN103964696A (en) * 2014-05-26 2014-08-06 山东海富光子科技股份有限公司 Phosphate-silicate all glass hybrid optical fiber for high-power optical fiber laser

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110040969A (en) * 2019-04-10 2019-07-23 长春理工大学 A kind of flexible optical fiber image transmitting beam inner cladding glass and preparation method thereof

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Application publication date: 20190108

RJ01 Rejection of invention patent application after publication