CN109161333A - A kind of antifouling car paint of high stability and preparation method thereof - Google Patents
A kind of antifouling car paint of high stability and preparation method thereof Download PDFInfo
- Publication number
- CN109161333A CN109161333A CN201810770772.1A CN201810770772A CN109161333A CN 109161333 A CN109161333 A CN 109161333A CN 201810770772 A CN201810770772 A CN 201810770772A CN 109161333 A CN109161333 A CN 109161333A
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- China
- Prior art keywords
- bismuth
- high stability
- car paint
- quality
- azo polyether
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/06—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
Abstract
The present invention provides antifouling car paints of a kind of high stability and preparation method thereof, belong to paint field.The present invention is prepared by azo polyether polyeste, the metallate salt of bismuth and amine curing agent, wherein organosiloxane is prepared by modifying agent and polymethyl hydrogen siloxane, modifying agent is selected from two acrylic ester of two acrylic ester of dioctyl phthalate, diallyl phthalate or terephthalic acid (TPA), amine curing agent is selected from N, N- diethyl cyclopentane-1,2- diamines ,-2 amino of 1-N- morpholino-pentamethylene or 2- (4- methyl-1-piperazine) cyclopentamine.Car paint provided by the invention tool has good corrosion resistance, resistance to ag(e)ing and antibiotic property.
Description
Technical field
The invention belongs to paint field, especially a kind of antifouling car paint of high stability and preparation method thereof.
Background technique
In recent years, acrylic polysiloxane coating had obtained widely answering as long-acting heavy duty system finishing coat
With such coating combines the dual characteristics of acrylic acid and polysiloxanes, has hybrid inorganic-organic structure, shows excellent
Long-effective corrosion weather resistance, and have the characteristics that highly filled, low-viscosity, easy construction, VOC content is extremely low, meets new
The requirement of environmental regulation.
Acrylic polysiloxane resin mainly has following two major classes type as base-material, according to curing mechanism, and one kind is to use
Double bond containing acrylic resin or oligomer modified polyorganosiloxane intermediate, double bond can occur to step with the amino in curing agent component
With silicone intermediates hydrolytic condensation can occur for Ke Er addition reaction, curing agent again.Another kind of is to use to contain functionality side
The low acrylic resin modified polyorganosiloxane intermediate of the relative molecular mass of base, side group mainly have hydroxyl, glycidol ester group
Deng, in acrylic resin functionality side group under the action of catalyst with alkylamino siloxane curing agents and silicone intermediates
Crosslink reaction.The Michael addition reaction of acrylic resin and amino silane containing unsaturated double bond is utilized herein, with
And the hydrolysis condensation reaction of polysiloxanes and amino silane, a kind of acrylic polysiloxane resin is developed, with excellent comprehensive
Close performance and extremely low VOC content.
In the prior art, there is many research to acrylic polysiloxane coating, the method including being modified to it
And the use of modifying agent.But modifying agent still is limited to acrylic acid or derivatives thereof, does not get rid of the yoke of traditional thought.It is existing
Although some acrylic polysiloxane coating mechanical properties, antiseptic property are greatly improved, still anti-pollution still has scarce
It falls into.
Automobile is often subject to the variation of various environment as a kind of vehicles, this inevitably comes to automobile belt
A large amount of spot, these spots can bring a large amount of microorganism, it is obvious that microbes come some irreversible to automobile belt
Destroy, such as accelerated corrosion etc., thus sterilization ability be also car paint there is an urgent need to a performance, still lack in the prior art
The weary car paint with the performance.
Summary of the invention
The present invention provides antifouling car paints of a kind of high stability and preparation method thereof.The present invention uses modified organic silicon
Oxygen alkane, the metallate salt of bismuth and amine curing agent are prepared for a kind of antifouling car paint of high stability.Wherein, modified organic silicon
The modifying agent of oxygen alkane is disubstituted acrylic ester on phenyl ring, and simultaneous selection ring pentanediamine derivative is as amine curing agent.Pass through
The car paint of this method preparation has and its excellent corrosion resistance, resistance to ag(e)ing and antibiotic property.
Specifically, the present invention is achieved through the following technical solutions:
A kind of antifouling car paint of high stability, by azo polyether polyeste, the metallate salt and amine curing agent of bismuth
It is prepared, which is characterized in that the azo polyether polyeste is prepared by modifying agent and polymethyl hydrogen siloxane；
The molal weight ratio of the ester group of the molal weight and azo polyether polyeste of the amino of the amine curing agent is (1-
1.5): (1-1.5)；
The metallate salt quality of the bismuth is the 4%-10% of azo polyether polyeste quality.
Preferably, the modifying agent is two acrylic ester of M-phthalic acid, diallyl phthalate or terephthaldehyde
Sour two acrylic esters.
Preferably, the metallate salt of the bismuth is any one in bismuth tungstate, bismuth molybdate and bismuth aluminate or two kinds
With the mixture of arbitrary proportion.
Preferably, the amine curing agent is N, N- diethyl cyclopentane -1,2- diamines, -2 amino of 1-N- morpholino -
Pentamethylene or 2- (4- methyl-1-piperazine) cyclopentamine.
Preferably, the azo polyether polyeste the preparation method is as follows:
The chloroplatinic acid t-butanol solution of modifying agent, the tert-butyl alcohol and 1-5wt% are mixed, are warming up under inert gas protection
50-70 DEG C, polymethyl hydrogen siloxane is added, is warming up to 80-90 DEG C, react 7-12 hour, vacuum distillation removing solvent to get；
The mole of the alkenyl of the modifying agent is the 100%- of the mole of the active hydrogen of polymethyl hydrogen siloxane
120%；
The chloroplatinic acid mole of the chloroplatinic acid t-butanol solution of the 1-5wt% is the 2-5% of modifier molar amount；
The quality of the tert-butyl alcohol is the 100%-150% of modifying agent quality.
The preparation step for preparing the antifouling car paint of high stability described in claim 1-5 any one is as follows:
Azo polyether polyeste is added in 3-5 times of quality water, the metallate of amine curing agent and bismuth is sequentially added
Salt, stir evenly to get.
Beneficial effects of the present invention are as follows: although still using propylene ester type compound as modifying agent, using benzene
Disubstituted propylene ester type compound, has been greatly improved the performance of coating on ring, has also selected cyclopentamine mono amino substituted
For derivative as amine curing agent, this is also the big key that paint stability is promoted.Bismuth salt is finally also added in coating,
Bismuth salt can not only be adapted with coating well in coating, and also unexpectedly embodying makes coating embody excellent kill
Bacterium performance.
Specific embodiment
Below with reference to embodiment, the present invention is described in further detail, and following embodiment is merely illustrative this
Invention, is not intended to limit the present invention.
Specifically, the raw material and instrument source used in the following embodiments is as follows:
Polymethyl hydrogen siloxane, No. CAS: 63148-57-2, it is purchased from Wuhan Tian Ze Xin Science and Technology Ltd..
Bismuth tungstate, No. CAS: 13595-87-4.
Bismuth aluminate, No. CAS: 12284-76-3.
Bismuth molybdate, No. CAS: 13565-96-3.
- 2 amino of 1-N- morpholino-pentamethylene, No. CAS: 88807-08-3.
2- (4- methyl-1-piperazine) cyclopentamine, No. CAS: 953895-57-3.
N, N- diethyl cyclopentane -1,2- diamines, No. CAS: 90796-40-0.
Two acrylic ester of terephthalic acid (TPA), No. CAS: 1026-92-2.
The tert-butyl alcohol, No. CAS: 76-65-0.
Chloroplatinic acid, No. CAS: 16941-12-1.
Embodiment 1
A kind of antifouling car paint of high stability, by azo polyether polyeste, bismuth tungstate and N, N- diethyl cyclopentane -1,
2- diamines is prepared, which is characterized in that the azo polyether polyeste is by two acrylic ester of terephthalic acid (TPA) and poly- methyl hydrogen
Siloxanes is prepared；
The ester group of the molal weight and azo polyether polyeste of the amino of the N, N- diethyl cyclopentane -1,2- diamines
Molal weight ratio is 1:1；
The bismuth tungstate quality is the 5% of azo polyether polyeste quality.
Azo polyether polyeste the preparation method is as follows:
The chloroplatinic acid t-butanol solution of two acrylic ester of terephthalic acid (TPA), the tert-butyl alcohol and 3wt% are mixed, under nitrogen protection
60 DEG C are warming up to, polymethyl hydrogen siloxane is added, is warming up to 85 DEG C, is reacted 10 hours, depressurizes and steams under conditions of 60 DEG C/10mmHg
Distillation go solvent to get；
The mole of the alkenyl of two acrylic ester of terephthalic acid (TPA) is the mole of the active hydrogen of polymethyl hydrogen siloxane
120%；
The chloroplatinic acid mole of the chloroplatinic acid t-butanol solution of the 3wt% is the 5% of modifier molar amount；
The quality of the tert-butyl alcohol is the 120% of modifying agent quality.
The preparation step of the antifouling car paint of high stability is as follows:
Azo polyether polyeste is added in 3 times of quality water, sequentially adds N, N- diethyl cyclopentane -1,2- diamines and
Bismuth tungstate, stir evenly to get.
Embodiment 2
A kind of antifouling car paint of high stability, by azo polyether polyeste, bismuth tungstate and 1-N- morpholino -2 amino-ring
Pentane is prepared, which is characterized in that the azo polyether polyeste is by two acrylic ester of terephthalic acid (TPA) and poly- methyl hydrogen silicon
Oxygen alkane is prepared；
The ester group of the molal weight and azo polyether polyeste of -2 amino of the 1-N- morpholino-pentamethylene amino rubs
Your mass ratio is 1:1；
The bismuth tungstate quality is the 5% of azo polyether polyeste quality.
Azo polyether polyeste the preparation method is as follows:
The chloroplatinic acid t-butanol solution of two acrylic ester of terephthalic acid (TPA), the tert-butyl alcohol and 3wt% are mixed, under nitrogen protection
60 DEG C are warming up to, polymethyl hydrogen siloxane is added, is warming up to 85 DEG C, is reacted 10 hours, depressurizes and steams under conditions of 60 DEG C/10mmHg
Distillation go solvent to get；
The mole of the alkenyl of two acrylic ester of terephthalic acid (TPA) is the mole of the active hydrogen of polymethyl hydrogen siloxane
120%；
The chloroplatinic acid mole of the chloroplatinic acid t-butanol solution of the 3wt% is the 5% of modifier molar amount；
The quality of the tert-butyl alcohol is the 120% of modifying agent quality.
The preparation step of the antifouling car paint of high stability is as follows:
Azo polyether polyeste is added in 3 times of quality water, -2 amino of 1-N- morpholino-pentamethylene and tungsten are sequentially added
Sour bismuth, stir evenly to get.
Embodiment 3
A kind of antifouling car paint of high stability, by azo polyether polyeste, bismuth tungstate and 2- (4- methyl-1-piperazine) ring
Amylamine is prepared, which is characterized in that the azo polyether polyeste is by two acrylic ester of terephthalic acid (TPA) and poly- methyl hydrogen silicon
Oxygen alkane is prepared；
The ester group of the molal weight and azo polyether polyeste of the amino of 2- (4- methyl-1-piperazine) cyclopentamine rubs
Your mass ratio is 1:1；
The bismuth tungstate quality is the 5% of azo polyether polyeste quality.
Azo polyether polyeste the preparation method is as follows:
The chloroplatinic acid t-butanol solution of two acrylic ester of terephthalic acid (TPA), the tert-butyl alcohol and 3wt% are mixed, under nitrogen protection
60 DEG C are warming up to, polymethyl hydrogen siloxane is added, is warming up to 85 DEG C, is reacted 10 hours, depressurizes and steams under conditions of 60 DEG C/10mmHg
Distillation go solvent to get；
The mole of the alkenyl of two acrylic ester of terephthalic acid (TPA) is the mole of the active hydrogen of polymethyl hydrogen siloxane
120%；
The chloroplatinic acid mole of the chloroplatinic acid t-butanol solution of the 3wt% is the 5% of modifier molar amount；
The quality of the tert-butyl alcohol is the 120% of modifying agent quality.
The preparation step of the antifouling car paint of high stability is as follows:
Azo polyether polyeste is added in 3 times of quality water, 2- (4- methyl-1-piperazine) cyclopentamine and tungsten are sequentially added
Sour bismuth, stir evenly to get.
Embodiment 4
A kind of antifouling car paint of high stability, by azo polyether polyeste, bismuth aluminate and 1-N- morpholino -2 amino-ring
Pentane is prepared, which is characterized in that the azo polyether polyeste is by two acrylic ester of terephthalic acid (TPA) and poly- methyl hydrogen silicon
Oxygen alkane is prepared；
The ester group of the molal weight and azo polyether polyeste of -2 amino of the 1-N- morpholino-pentamethylene amino rubs
Your mass ratio is 1:1；
The bismuth aluminate quality is the 5% of azo polyether polyeste quality.
Azo polyether polyeste the preparation method is as follows:
The chloroplatinic acid t-butanol solution of two acrylic ester of terephthalic acid (TPA), the tert-butyl alcohol and 3wt% are mixed, under nitrogen protection
60 DEG C are warming up to, polymethyl hydrogen siloxane is added, is warming up to 85 DEG C, is reacted 10 hours, depressurizes and steams under conditions of 60 DEG C/10mmHg
Distillation go solvent to get；
The mole of the alkenyl of two acrylic ester of terephthalic acid (TPA) is the mole of the active hydrogen of polymethyl hydrogen siloxane
120%；
The chloroplatinic acid mole of the chloroplatinic acid t-butanol solution of the 3wt% is the 5% of modifier molar amount；
The quality of the tert-butyl alcohol is the 120% of modifying agent quality.
The preparation step of the antifouling car paint of high stability is as follows:
Azo polyether polyeste is added in 3 times of quality water, -2 amino of 1-N- morpholino-pentamethylene and aluminium are sequentially added
Sour bismuth, stir evenly to get.
Embodiment 5
A kind of antifouling car paint of high stability, by azo polyether polyeste, bismuth molybdate and 1-N- morpholino -2 amino-ring
Pentane is prepared, which is characterized in that the azo polyether polyeste is by two acrylic ester of terephthalic acid (TPA) and poly- methyl hydrogen silicon
Oxygen alkane is prepared；
The ester group of the molal weight and azo polyether polyeste of -2 amino of the 1-N- morpholino-pentamethylene amino rubs
Your mass ratio is 1:1；
The bismuth molybdate quality is the 5% of azo polyether polyeste quality.
Azo polyether polyeste the preparation method is as follows:
The chloroplatinic acid t-butanol solution of two acrylic ester of terephthalic acid (TPA), the tert-butyl alcohol and 3wt% are mixed, under nitrogen protection
60 DEG C are warming up to, polymethyl hydrogen siloxane is added, is warming up to 85 DEG C, is reacted 10 hours, depressurizes and steams under conditions of 60 DEG C/10mmHg
Distillation go solvent to get；
The mole of the alkenyl of two acrylic ester of terephthalic acid (TPA) is the mole of the active hydrogen of polymethyl hydrogen siloxane
120%；
The chloroplatinic acid mole of the chloroplatinic acid t-butanol solution of the 3wt% is the 5% of modifier molar amount；
The quality of the tert-butyl alcohol is the 120% of modifying agent quality.
The preparation step of the antifouling car paint of high stability is as follows:
Azo polyether polyeste is added in 3 times of quality water, -2 amino of 1-N- morpholino-pentamethylene and molybdenum are sequentially added
Sour bismuth, stir evenly to get.
Test case 1
Resistance to dissolubility and ageing-resistant performance test
Will be according to the prepared water paint spraying of embodiment 1-5 on standard tinplate, 50 μm of coating thickness, 120 DEG C
Lower baking 360 minutes, is then tested for the property.
Resistance to dissolubility is measured according to GB/T 1733-1993 (water resistance) and GB/T 10834-1989 (resistance to salt water), resistance to old
The property changed is measured according to GB/T 1766-1995.
Test result is as follows shown in table:
As seen from the above table, the present invention provides a kind of car paint with high stability, the coating by and its it is outstanding
Water resistance, resistance to salt water and resistance to UV aging.Especially have when curing agent is selected as -2 amino of 1-N- morpholino-pentamethylene
Optimal stability.
Test case 2
Antibacterial experiment
Select bacillus coli DH 5 alpha as strain, elder generation preculture 18 hours in 5mLL-B culture dish at 37 DEG C.Select 6
A culture dish, high pressure sterilization 15 minutes at 120 DEG C, the coating that wherein prepared by 1-5 culture dish spraying embodiment 1-5, No. 6 trainings
Ware is supported as reference examples.It will be toasted 360 minutes at 120 DEG C of 1-6 culture dish, each bacillus coli DH 5 that 100 μ L precultures are added
α is uninterruptedly irradiated experiment culture dish with the visible light emitting diode of 33w during experiment, every 1 hour using ultraviolet
Visible spectrophotometer measures the OD of 1 each culture dish600Value adds up test 12 hours, calculates average minute clock OD600Value
Growth rate.
As a result as shown in the table:
As seen from the above table, the antifouling car paint of high stability provided by the invention has good antibacterial property, especially works as selection
There is best antimicrobial effect when -2 amino of 1-N- morpholino-pentamethylene and bismuth molybdate are as coating composition.
Claims (6)
1. a kind of antifouling car paint of high stability, by azo polyether polyeste, the metallate salt of bismuth and amine curing agent system
It is standby to form, which is characterized in that the azo polyether polyeste is prepared by modifying agent and polymethyl hydrogen siloxane；
The molal weight ratio of the ester group of the molal weight and azo polyether polyeste of the amino of the amine curing agent is (1-
1.5): (1-1.5)；
The metallate salt quality of the bismuth is the 4%-10% of azo polyether polyeste quality.
2. the antifouling car paint of high stability according to claim 1, which is characterized in that the modifying agent is isophthalic two
Two acrylic ester of two acrylic ester of formic acid, diallyl phthalate or terephthalic acid (TPA).
3. the antifouling car paint of high stability according to claim 1, which is characterized in that the metallate salt of the bismuth
For any one or the two kinds of mixtures with arbitrary proportion in bismuth tungstate, bismuth molybdate and bismuth aluminate.
4. the antifouling car paint of high stability according to claim 1, which is characterized in that the amine curing agent is N,
N- diethyl cyclopentane-1,2- diamines ,-2 amino of 1-N- morpholino-pentamethylene or 2- (4- methyl-1-piperazine) cyclopentamine.
5. the antifouling car paint of high stability according to claim 1, which is characterized in that the azo polyether polyeste
The preparation method is as follows:
The chloroplatinic acid t-butanol solution of modifying agent, the tert-butyl alcohol and 1-5wt% are mixed, are warming up to 50- under inert gas protection
70 DEG C, polymethyl hydrogen siloxane is added, is warming up to 80-90 DEG C, react 7-12 hour, vacuum distillation removing solvent to get；
The mole of the alkenyl of the modifying agent is the 100%-120% of the mole of the active hydrogen of polymethyl hydrogen siloxane；
The chloroplatinic acid mole of the chloroplatinic acid t-butanol solution of the 1-5wt% is the 2-5% of modifier molar amount；
The quality of the tert-butyl alcohol is the 100%-150% of modifying agent quality.
6. the method for preparing the antifouling car paint of high stability described in claim 1-5 any one, which is characterized in that preparation
Steps are as follows:
Azo polyether polyeste is added in 3-5 times of quality water, the metallate salt of amine curing agent and bismuth is sequentially added, stirs
Mix uniformly to get.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201810770772.1A CN109161333A (en) | 2018-07-13 | 2018-07-13 | A kind of antifouling car paint of high stability and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810770772.1A CN109161333A (en) | 2018-07-13 | 2018-07-13 | A kind of antifouling car paint of high stability and preparation method thereof |
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| CN201810770772.1A Pending CN109161333A (en) | 2018-07-13 | 2018-07-13 | A kind of antifouling car paint of high stability and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111282790A (en) * | 2020-03-24 | 2020-06-16 | 同曦集团有限公司 | Antibacterial and antiviral aluminum alloy fluorocarbon roller coating process |
| CN113698609A (en) * | 2021-10-14 | 2021-11-26 | 佛山金戈新材料股份有限公司 | Polysiloxane alkenyl terephthalate compound as anti-settling agent |
| CN117624609A (en) * | 2023-12-14 | 2024-03-01 | 广州波粒新材料科技有限公司 | Resin for automobile spraying vehicle coating, preparation method and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101155647A (en) * | 2005-04-05 | 2008-04-02 | 中国涂料株式会社 | Tie coat for organopolysiloxane antifouling coat, composite coats, and ships and underwater structures covered with the composite coats |
-
2018
- 2018-07-13 CN CN201810770772.1A patent/CN109161333A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101155647A (en) * | 2005-04-05 | 2008-04-02 | 中国涂料株式会社 | Tie coat for organopolysiloxane antifouling coat, composite coats, and ships and underwater structures covered with the composite coats |
Non-Patent Citations (1)
| Title |
|---|
| 刘文忠等: "《幽门螺杆菌研究进展》", 31 October 2001, 上海科学技术文献出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111282790A (en) * | 2020-03-24 | 2020-06-16 | 同曦集团有限公司 | Antibacterial and antiviral aluminum alloy fluorocarbon roller coating process |
| CN113698609A (en) * | 2021-10-14 | 2021-11-26 | 佛山金戈新材料股份有限公司 | Polysiloxane alkenyl terephthalate compound as anti-settling agent |
| CN113698609B (en) * | 2021-10-14 | 2022-08-26 | 佛山金戈新材料股份有限公司 | Polysiloxane alkenyl terephthalate compound as anti-settling agent |
| CN117624609A (en) * | 2023-12-14 | 2024-03-01 | 广州波粒新材料科技有限公司 | Resin for automobile spraying vehicle coating, preparation method and application thereof |
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Application publication date: 20190108 |