A kind of no-solvent type double-composition polyurethane waterproof paint with flame-retardant smoke inhibition effect
Technical field
The present invention relates to a kind of polyurethane water-proof paint, in particular to a kind of no-solvent type with flame-retardant smoke inhibition effect is double
Component polyurethane waterproof coating.
Background technique
In polyurethane coating be usually polyether polyol reacted with polyisocyanates synthesize polymer, mostly by carbon, hydrogen,
The elements such as oxygen composition, there are flame when inflammable, burning is big, dense smoke, serious drippage have the problems such as toxic gas generation, and are drop
It glues and guarantees application property and additional solvent pollutes the environment in volatilization process after film, be detrimental to health, in use
There are biggish safety and environmental protection hidden danger.With people's awareness of safety be gradually increased and the change of social development demand, have resistance
The research and development for firing the no-solvent type coating of smoke suppressing effect are also increasingly taken seriously.Mechanism is the study found that in each conflagration according to investigations
Scene, the death rate of fire incident Field Force probably in ten a ten thousandths, and among these seventy percent or more the cause of death be by
It makes one to generate poisoning even asphyxia phenomenon in the toxic fumes that scene of fire diffuses, it is most of so as to cause the generation of tragedy
High molecular material can not only decompose in the case of a high temperature, generate toxic gas, while undecomposed solid residue meeting
Flue dust is formed, is diffused in air, is hindered escape, caused great harm to the life security of people.It is hidden in face of these safety
Suffer from, nowadays more effective and widely used fire prevention measure is that have the use of the coating of flame-retardant smoke inhibition.This kind of material it is extensive
It uses, to the injures and deaths for reducing scene of fire personnel, improves the fire safety grade of related places, with particularly important reality meaning
Justice.
Combustion reaction must have 3 conditions: combustible, oxygen and heat source as a kind of chemical reaction, its generation.Only
There are this 3 conditions while setting up and contacting with each other, combustion reaction could occur, and otherwise, burning just cannot occur.Polyurethane coating
In be usually polyether polyol reacted with polyisocyanates synthesize polymer, be made of mostly elements such as carbon, hydrogen, oxygen, it is inflammable.
Therefore three conditions of above-mentioned burning, oxygen and heat source are only fallen, just can reach flameproof effect.The present invention is halogenated using having
The flame-retardant smoke inhibition system of the flame-retardant smoke inhibitions synergist such as phosphorus liquid plasticizing flame retardant and inorganic salts compounding.Halogenated phosphorus flame retardant is
Novel efficient flame-retarding agent plays huge effect in many industries, halogenated phosphorus system and inorganic fire-retarded suppression known to inspection information
Cigarette synergist compositional flame-retardant smoke suppressing effect is excellent.The present invention mainly reaches solvent-free, flame-retardant smoke inhibition effect by the following method: 1.
The fire retardant of addition is colorless and transparent fire retardant liquid, can inhibit the generation of smog, effectively in pyrolytic burning so as to have
Effect reduces smoke density;2. smoke suppressant promotes being cross-linked with each other between polymer molecule to a certain extent, so that porous layer of charcoal is quick
It is formed, reduces the generation of combustible to achieve the purpose that press down cigarette.
Summary of the invention
Existing water-repellent paint is inflammable, shortcoming containing toxic solvent flashing it is an object of the invention to overcoming, and provides one
Kind has the no-solvent type double-composition polyurethane waterproof paint of flame-retardant smoke inhibition effect.Key of the invention is halogenated phosphorus system liquid
The flame-retardant smoke inhibition system of body plasticizing flame retardant and inorganic fire-retarded suppression cigarette synergist compounding introduces double-composition polyurethane waterproof paint
Component B system.Halogenated phosphorus system liquid plasticizing flame retardant can reduce coating system viscosity, avoid additional organic solvent, and its with
Inorganic fire-retarded suppression cigarette synergist compounding, so that coating in the case of a high temperature can substantially without obvious volume change when the coating meets fire
It is flame retardancy gas that a series of physical reaction, which occurs, to absorb a large amount of heat, and decompose the gas generated, can be in air
Imflammable gas generate dilution, while inorganic enamel-like protective layer can be formed on surface after material molten, completely cut off air, make oxygen
It cannot be contacted with by protection substrate, to play fire-retardant effect, and promote the mutual friendship between polymer molecule to a certain extent
Connection reduces the generation of combustible so that porous layer of charcoal is quickly formed to achieve the purpose that press down cigarette.
In order to achieve the above objectives, the technical solution adopted by the present invention is that:
A kind of no-solvent type double-composition polyurethane waterproof paint with flame-retardant smoke inhibition effect, including first, second two-component.Its
Middle component A is mainly the base polyurethane prepolymer for use as prepared by polyether polyol, aliphatic diisocyanate, liquid filler, the invention
Mainly for component B, it is characterised in that its composition and ratio includes: 80~100 parts of polyether polyol by mass parts, and liquid is filled out
70~90 parts of material, 30~50 parts of auxiliary liquid filler, 30~40 parts of vulcanizer, 3.5~4.5 parts of dispersing agent, heavy carbonic acid
140~160 parts of calcium, 100~120 parts of precipitated calcium carbonate, 80~100 parts of fire retardant, 8~11 parts of iron oxide red, flame-retardant smoke inhibition association
40~60 parts of agent, 1.8~2.6 parts of defoaming agent, 0.8~4 part of rheology control auxiliary agent, 1.5~2.4 parts of catalyst of effect.
Described being prepared with the flame-retardant smoke inhibitions synergists such as halogenated phosphorus liquid plasticizing flame retardant and inorganic salts compounding is solvent-free
Type double-composition polyurethane waterproof paint component B process is as follows: by polyether polyol, liquid filler, auxiliary liquid filler, dispersion
After stirring is warming up to 80 ± 5 DEG C in agent addition reaction vessel, vulcanizer, coarse whiting, light calcium, iron oxide red, liter is added in stirring
Temperature keeps being dehydrated 3h under vacuum degree -0.08~-0.09MPa to 115 ± 5 DEG C, and water smoking temperature is controlled at 115 ± 5 DEG C, is taken off
Stop heating after water to start to cool down, when temperature is down to 70 ± 5 DEG C, after fire retardant and flame-retardant smoke inhibition synergist is added, point
After dissipating stirring 40min, defoaming agent, rheology control auxiliary agent, catalyst is added, stops heating, continues to discharge after stirring 0.5h
Obtain the no-solvent type two-component that preparation is compounded with flame-retardant smoke inhibitions synergists such as halogenated phosphorus liquid plasticizing flame retardant and inorganic salts
Polyurethane water-proof paint.
The liquid filler is one or more of chlorinated paraffin 52, naphthenic oil, epoxidized soybean oil.
The auxiliary liquid filler is one or more of rubber filling oil, aromatic naphtha.
The dispersing agent be solution flocculation-type dispersing agent, the trade mark be BYK company of Germany produce DISPERBYK107,
One of DISPERBYK108, DISPERBYK111.
The defoaming agent is one of BYK065, BYK066N, BYK8800 of BYK company of Germany production.
The fire retardant is liquid plasticizing flame retardant, can not plus solvent and reduce system viscosity, specially tricresyl phosphate
One or more of (2- chloroethyl) ester, tricresyl phosphate (bis- chloropropyl of 1,3-) ester.
The flame-retardant smoke inhibition synergist is one or more of zinc borate, molybdenum oxide, zinc aluminate, fire retardant and fire-retardant suppression
Cigarette synergist is introduced into system by mechanical mix techniques.
The rheology control auxiliary agent is one of BYK410, BYK430 of BYK company of Germany production.
Solvent-free, the fire-retardant and smoke-inhibiting type water-repellent paint be by select liquid plasticizing flame retardant, not plus solvent and
So that system is reached suitable and obtain working viscosity, then be aided with flame-retardant smoke inhibition synergist, reaches flame-retardant smoke inhibition effect by the following method: 1.
The fire retardant of addition is colorless and transparent fire retardant liquid, can inhibit the generation of smog, effectively in pyrolytic burning so as to have
Effect reduces smoke density;2. smoke suppressant promotes being cross-linked with each other between polymer molecule to a certain extent, so that porous layer of charcoal is quick
It is formed, reduces the generation of combustible to achieve the purpose that press down cigarette.
The present invention prepares no-solvent type pair with flame-retardant smoke inhibitions synergists such as halogenated phosphorus liquid plasticizing flame retardant and inorganic salts
Component polyurethane waterproof coating component B, is aided with the dispersion haveing excellent performance and antifoaming system is prepared, except with general poly- ammonia
Outside the excellent properties of ester water-repellent paint, also imparting application property is excellent, and without additional organic solvent, flame-retardant smoke inhibition is environmental-friendly etc. excellent
Point.
Specific embodiment
The following examples are intended to illustrate the invention, to facilitate those skilled in the art to can reach experimental result referring to specification
It reappears, but is not intended to limit the scope of the invention.
There is phosphorus halogen glutamate class I liquid I fire retardant fire-retardant and plasticising double action, phosphorus compound can decompose when burning, and generate
The free groups such as PO can inhibit flame in conjunction with the H in flame region, meanwhile, it can be in a thin layer of vitreous in surface
Or the protective layer of liquid, therefore oxygen diffusion and heat and mass transfer between gas phase and solid phase are reduced, especially phosphorus halogen is first
Element and used time can become apparent from the flame retardant effect for improving flame-retardant system, using phosphorus halogen glutamate class I liquid I fire retardant and flame-retardant smoke inhibition synergistic
When agent is used in compounding, so that product has apparent flame-retardant smoke inhibition effect.
The effect of flame-retardant smoke inhibition synergist is can to effectively improve flame retardant property, the generation of smog when reducing burning.
According to the present invention, in the no-solvent type double-composition polyurethane waterproof paint component B with flame-retardant smoke inhibition effect
It is also added into rheology control auxiliary agent, mainly for improving the rheological characteristic of system, the flowing of coating system pseudoplastic behavior is assigned and brushes and apply
Work, and the ideal anti-settling of system and long term storage stability are provided.
Embodiment 1:
The component A of the present embodiment 1 prepares as follows (by mass parts): 63 parts of polyethers N220,18 parts of polyethers N330 being mixed equal
Even, warming while stirring keeps being dehydrated 1h under vacuum degree -0.08~-0.09MPa, be surveyed with karl Fischer moisture to 90~100 DEG C
70~75 DEG C, which are cooled to, after determining instrument detection moisture content less than 0.05% (if moisture content is not less than 0.05%, it is straight to continue dehydration
To moisture content less than 0.05% after carry out in next step), be slowly added to 24 parts of TDI-80, at 80~85 DEG C react 2~3h after,
20 parts of addition stirs 0.5h after having detected chlorinated paraffin 52 of the moisture content less than 0.05% in advance, discharges i.e. after being cooled to 60 DEG C
Obtain component A;
The second component of the present embodiment 1 prepares as follows (by mass parts): by 90 parts of polyethers 330N, 80 parts of chlorinated paraffins 52,45
After stirring is warming up to 80 ± 5 DEG C in part rubber filling oil, 3.8 parts of DISPERBYK108 addition multifunctional powerful dispersators,
35 parts of chloro- 4,4'- diaminodiphenyl-methanes of vulcanizer 3,3'- bis-, 150 parts of coarse whitings, 110 parts of light calciums, 10 are added in stirring
Part iron oxide red, is warming up to 115 ± 5 DEG C, keeps being dehydrated 3h under vacuum degree -0.08~-0.09MPa, the control of water smoking temperature
Stop heating at 115 ± 5 DEG C, after dehydration to start to cool down, when temperature is down to 70 ± 5 DEG C, 80 parts of tricresyl phosphate (2- chlorine are added
Ethyl) after ester and 55 parts of zinc borates, after dispersion stirring 40min, 2.0 parts of BYK065,2.5 parts of BYK410,1.8 part of two laurel is added
Sour dibutyl tin stops heating, continues to discharge after stirring 0.5h.
Embodiment 2:
The component A of the present embodiment 2 prepares as follows (by mass parts): 63 parts of polyethers N220,18 parts of polyethers N330 being mixed equal
Even, warming while stirring keeps being dehydrated 1h under vacuum degree -0.08~-0.09MPa, be surveyed with karl Fischer moisture to 90~100 DEG C
70~75 DEG C, which are cooled to, after determining instrument detection moisture content less than 0.05% (if moisture content is not less than 0.05%, it is straight to continue dehydration
To moisture content less than 0.05% after carry out in next step), be slowly added to 24 parts of TDI-80, at 80~85 DEG C react 2~3h after,
20 parts of addition stirs 0.5h after having detected chlorinated paraffin 52 of the moisture content less than 0.05% in advance, discharges i.e. after being cooled to 60 DEG C
Obtain component A;
The second component of the present embodiment 2 prepares as follows (by mass parts): by 90 parts of polyethers 330N, 90 parts of naphthenic oils, 50 parts of virtues
After stirring is warming up to 80 ± 5 DEG C in hydrocarbon ils, 4.5 parts of DISPERBYK107 addition multifunctional powerful dispersators, stirring is added
35 parts of chloro- 4,4'- diaminodiphenyl-methanes of vulcanizer 3,3'- bis-, 150 parts of coarse whitings, 110 parts of light calciums, 10 parts of iron oxide
It is red, 115 ± 5 DEG C are warming up to, keeps being dehydrated 3h under vacuum degree -0.08~-0.09MPa, water smoking temperature is controlled 115 ± 5
DEG C, stop heating after dehydration and start to cool down, when temperature is down to 70 ± 5 DEG C, 80 parts of tricresyl phosphates (1,3- dichloro third is added
Base) after ester and 45 parts of molybdenum oxides, after dispersion stirring 40min, 2.4 parts of BYK066N, 3 parts of BYK430,1.8 parts of tin dilaurates are added
Dibutyl tin stops heating, continues to discharge after stirring 0.5h.
Embodiment 3:
The component A of the present embodiment 3 prepares as follows (by mass parts): 63 parts of polyethers N220,18 parts of polyethers N330 being mixed equal
Even, warming while stirring keeps being dehydrated 1h under vacuum degree -0.08~-0.09MPa, be surveyed with karl Fischer moisture to 90~100 DEG C
70~75 DEG C, which are cooled to, after determining instrument detection moisture content less than 0.05% (if moisture content is not less than 0.05%, it is straight to continue dehydration
To moisture content less than 0.05% after carry out in next step), be slowly added to 24 parts of TDI-80, at 80~85 DEG C react 2~3h after,
20 parts of addition stirs 0.5h after having detected chlorinated paraffin 52 of the moisture content less than 0.05% in advance, discharges i.e. after being cooled to 60 DEG C
Obtain component A;
The second component of the present embodiment 3 prepares as follows (by mass parts): by 90 parts of polyethers 330N, 85 parts of epoxidized soybean oils, 50
After stirring is warming up to 80 ± 5 DEG C in part rubber filling oil, 4.3 parts of DISPERBYK111 addition multifunctional powerful dispersators,
35 parts of chloro- 4,4'- diaminodiphenyl-methanes of vulcanizer 3,3'- bis-, 150 parts of coarse whitings, 110 parts of light calciums, 10 are added in stirring
Part iron oxide red, is warming up to 115 ± 5 DEG C, keeps being dehydrated 3h under vacuum degree -0.08~-0.09MPa, the control of water smoking temperature
Stop heating at 115 ± 5 DEG C, after dehydration to start to cool down, when temperature is down to 70 ± 5 DEG C, 95 parts of tricresyl phosphate (2- chlorine are added
Ethyl) after ester and 60 parts of zinc aluminates, after dispersion stirring 40min, 2.6 parts of BYK8800,2.8 parts of BYK410,1.8 parts of February are added
Dilaurylate stops heating, continues to discharge after stirring 0.5h.
Embodiment 4:
The component A of the present embodiment 4 prepares as follows (by mass parts): 63 parts of polyethers N220,18 parts of polyethers N330 being mixed equal
Even, warming while stirring keeps being dehydrated 1h under vacuum degree -0.08~-0.09MPa, be surveyed with karl Fischer moisture to 90~100 DEG C
70~75 DEG C, which are cooled to, after determining instrument detection moisture content less than 0.05% (if moisture content is not less than 0.05%, it is straight to continue dehydration
To moisture content less than 0.05% after carry out in next step), be slowly added to 24 parts of TDI-80, at 80~85 DEG C react 2~3h after,
20 parts of addition stirs 0.5h after having detected chlorinated paraffin 52 of the moisture content less than 0.05% in advance, discharges i.e. after being cooled to 60 DEG C
Obtain component A;
The second component of the present embodiment 4 prepares as follows (by mass parts): by 90 parts of polyethers 330N, 70 parts of chlorinated paraffins 52,35
After stirring is warming up to 80 ± 5 DEG C in part aromatic naphtha, 4.0 parts of DISPERBYK108 addition multifunctional powerful dispersators, stirring
The chloro- 4,4'- diaminodiphenyl-methane of 35 parts of vulcanizer 3,3'- bis-, 150 parts of coarse whitings, 110 parts of light calciums, 10 parts of oxygen are added
Change iron oxide red, be warming up to 115 ± 5 DEG C, keeps being dehydrated 3h under vacuum degree -0.08~-0.09MPa, water smoking temperature is controlled 115
± 5 DEG C, stops heating after dehydration and start to cool down, when temperature is down to 70 ± 5 DEG C, 100 parts of tricresyl phosphate (1,3- dichloros are added
Propyl) after ester and 45 parts of zinc borates, after dispersion stirring 40min, 2.4 parts of BYK065,1.8 parts of BYK430,1.8 part of two laurel is added
Sour dibutyl tin stops heating, continues to discharge after stirring 0.5h.
Embodiment 5:
The component A of the present embodiment 5 prepares as follows (by mass parts): 63 parts of polyethers N220,18 parts of polyethers N330 being mixed equal
Even, warming while stirring keeps being dehydrated 1h under vacuum degree -0.08~-0.09MPa, be surveyed with karl Fischer moisture to 90~100 DEG C
70~75 DEG C, which are cooled to, after determining instrument detection moisture content less than 0.05% (if moisture content is not less than 0.05%, it is straight to continue dehydration
To moisture content less than 0.05% after carry out in next step), be slowly added to 24 parts of TDI-80, at 80~85 DEG C react 2~3h after,
20 parts of addition stirs 0.5h after having detected chlorinated paraffin 52 of the moisture content less than 0.05% in advance, discharges i.e. after being cooled to 60 DEG C
Obtain component A;
The second component of the present embodiment 5 prepares as follows (by mass parts): by 90 parts of polyethers 330N, 85 parts of naphthenic oils, 40 portions of rubbers
After stirring is warming up to 80 ± 5 DEG C in glue filling oil, 4.0 parts of DISPERBYK111 addition multifunctional powerful dispersators, stirring
The chloro- 4,4'- diaminodiphenyl-methane of 35 parts of vulcanizer 3,3'- bis-, 150 parts of coarse whitings, 110 parts of light calciums, 10 parts of oxygen are added
Change iron oxide red, be warming up to 115 ± 5 DEG C, keeps being dehydrated 3h under vacuum degree -0.08~-0.09MPa, water smoking temperature is controlled 115
± 5 DEG C, stops heating after dehydration and start to cool down, when temperature is down to 70 ± 5 DEG C, 100 parts of tricresyl phosphate (2- chloroethenes are added
Base) after ester and 56 parts of molybdenum oxides, after dispersion stirring 40min, 2.6 parts of BYK066N, 2.0 parts of BYK410,1.8 part of two laurel is added
Sour dibutyl tin stops heating, continues to discharge after stirring 0.5h.
Embodiment 6:
The component A of the present embodiment 6 prepares as follows (by mass parts): 63 parts of polyethers N220,18 parts of polyethers N330 being mixed equal
Even, warming while stirring keeps being dehydrated 1h under vacuum degree -0.08~-0.09MPa, be surveyed with karl Fischer moisture to 90~100 DEG C
70~75 DEG C, which are cooled to, after determining instrument detection moisture content less than 0.05% (if moisture content is not less than 0.05%, it is straight to continue dehydration
To moisture content less than 0.05% after carry out in next step), be slowly added to 24 parts of TDI-80, at 80~85 DEG C react 2~3h after,
20 parts of addition stirs 0.5h after having detected chlorinated paraffin 52 of the moisture content less than 0.05% in advance, discharges i.e. after being cooled to 60 DEG C
Obtain component A;
The second component of the present embodiment 6 prepares as follows (by mass parts): by 90 parts of polyethers 330N, 90 parts of epoxidized soybean oils, 45
After stirring is warming up to 80 ± 5 DEG C in part aromatic naphtha, 3.6 parts of DISPERBYK107 addition multifunctional powerful dispersators, stirring
The chloro- 4,4'- diaminodiphenyl-methane of 35 parts of vulcanizer 3,3'- bis-, 150 parts of coarse whitings, 110 parts of light calciums, 10 parts of oxygen are added
Change iron oxide red, be warming up to 115 ± 5 DEG C, keeps being dehydrated 3h under vacuum degree -0.08~-0.09MPa, water smoking temperature is controlled 115
± 5 DEG C, stops heating after dehydration and start to cool down, when temperature is down to 70 ± 5 DEG C, 90 parts of tricresyl phosphate (1,3- dichloros are added
Propyl) after ester and 55 parts of zinc aluminates, after dispersion stirring 40min, 2.5 parts of BYK8800,3.2 parts of BYK430,1.8 parts of February are added
Dilaurylate stops heating, continues to discharge after stirring 0.5h.
Comparative example 1
Anti-flammability is used in a kind of component B of the no-solvent type double-composition polyurethane waterproof paint with flame-retardant smoke inhibition effect
Plasticizer three butoxy ethyl ester of phosphoric acid equivalent replaces plasticizing flame retardant tricresyl phosphate (2- chloroethyl) ester, other are the same as embodiment 1.
With this condition, the coating viscosity reducing effect is good, coating initial viscosity 3250mpas, convenient construction, but bottom after 50 DEG C of storage 7d
There are a small amount of precipitating, and film poor fire, light a fire 15s, is 160mm from flame height after fiery 5s.
Comparative example 2
With controlled wadding in a kind of component B of the no-solvent type double-composition polyurethane waterproof paint with flame-retardant smoke inhibition effect
Solidifying wetting dispersing agent ANTI-TERRA-203 equivalent replacement solution flocculation-type dispersing agent DISPERBYK108, other are the same as embodiment 1.?
Under this condition, the viscosity of the coating is big, and coating initial viscosity 7230mpas, application property is poor, needs additional diluent that can meet construction
Property, bottom is without precipitating, excellent storage stability after 50 DEG C of storage 7d.
Comparative example 3
It is not added and becomes a mandarin in a kind of component B of the no-solvent type double-composition polyurethane waterproof paint with flame-retardant smoke inhibition effect
Become control auxiliary agent B YK410, other are the same as embodiment 1.With this condition, the coating storage stability is poor, bottom after 50 DEG C of storage 7d
There is more precipitating.
Comparative example 4
Resistance is added without in a kind of component B of the no-solvent type double-composition polyurethane waterproof paint with flame-retardant smoke inhibition effect
Combustion suppression cigarette synergist zinc borate, other are the same as embodiment 1.With this condition, coating film flame-retardant smoke inhibition effect is poor, and light a fire 15s, from
Flame height is 110mm after fiery 5s, there is a large amount of dense smokes and more dropping.
It can be seen that distinguish compared with comparative example 1 by embodiment 1 and choose plasticizing flame retardant and anti-flammability increasing
Agent is moulded, the difference of the two performance will affect the viscosity and flame retardant effect of coating.
Controlled type dispersing agent reconciliation flocculation-type dispersing agent be can be seen that compared with comparative example 2 by embodiment 1 to system
Viscosity is affected, to influence the application property of coating.
Can be seen that suitable rheology control auxiliary agent compared with comparative example 3 by embodiment 1 will affect the thixotroping of system
Property and improve long term storage stability, assign coating excellent workability.
It can be seen that the resistance that flame-retardant smoke inhibition synergist is remarkably improved fire retardant compared with comparative example 4 by embodiment 1
Fuel efficiency fruit, and smoke suppressing effect is played, and reduce drippage, to assign coating excellent flame-retardant smoke inhibition effect.
To sum up, a kind of no-solvent type double-composition polyurethane waterproof paint with flame-retardant smoke inhibition effect of the present invention, using general
The flame-retardant smoke inhibition system of halogenated phosphorus system liquid plasticizing flame retardant and inorganic fire-retarded suppression cigarette synergist compounding introduces coating system, choosing
With solution flocculation-type dispersing agent and liquid filler, and under the action of rheology control auxiliary agent, it is moderate to assign viscosity of the coating, without additional
Diluent can directly construct, and construction operable time is long, and excellent storage stability, and 50 DEG C of placement bottoms 10d are without precipitating, system
In be free of organic solvent, have no irritating odor, and can be effectively improved after double-component polyurethane coating is inflammable and burning generate it is a large amount of
Flue dust problem.
Table 1: embodiment composition and proportion (by weight):
Table 2: embodiment testing result