CN109160523A - A kind of gas ammonia prepares the system and method for ammonium hydroxide - Google Patents

A kind of gas ammonia prepares the system and method for ammonium hydroxide Download PDF

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Publication number
CN109160523A
CN109160523A CN201811330403.7A CN201811330403A CN109160523A CN 109160523 A CN109160523 A CN 109160523A CN 201811330403 A CN201811330403 A CN 201811330403A CN 109160523 A CN109160523 A CN 109160523A
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CN
China
Prior art keywords
ammonia
ammonium hydroxide
gas
liquefied
pipeline
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811330403.7A
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Chinese (zh)
Inventor
李伟平
张中帅
柯永红
郑润锁
杨海波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shaanxi Black Cat Coking Co Ltd
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Shaanxi Black Cat Coking Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shaanxi Black Cat Coking Co Ltd filed Critical Shaanxi Black Cat Coking Co Ltd
Priority to CN201811330403.7A priority Critical patent/CN109160523A/en
Publication of CN109160523A publication Critical patent/CN109160523A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01CAMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00Ammonia; Compounds thereof
    • C01C1/02Preparation, purification or separation of ammonia
    • C01C1/022Preparation of aqueous ammonia solutions, i.e. ammonia water

Abstract

The present invention relates to the system and methods that a kind of gas ammonia prepares ammonium hydroxide, including synthesis ammonia system, ammonia cooler, refrigeration system, freezing liquefied ammonia sulculus and ammonium hydroxide system processed, the process gas of the synthesis ammonia system enters ammonia cooler, ammonia cooler is connected to refrigeration system by gas ammonia pipeline, and the refrigeration system generates liquefied ammonia and is stored in freezing liquefied ammonia sulculus;It freezes liquefied ammonia sulculus and provides condensing agent to ammonia cooler by liquefied ammonia pipeline;It further include gas ammonia ammonia water pipeline, the ammonium hydroxide system processed includes super ammonia absorber, and on gas ammonia pipeline, outlet is connected to the entrance of the gas ammonia ammonia water pipeline with an entrance of super ammonia absorber.The present invention solves the technical issues of high existing ammonium hydroxide system power dissipation processed, low efficiency, and the present invention mainly directly prepares ammonium hydroxide with the gas ammonia that ammonia cooler comes out, and reduces the power consumption of ice maker, while improving the efficiency of ammonium hydroxide processed.

Description

A kind of gas ammonia prepares the system and method for ammonium hydroxide
Technical field
The invention belongs to ammonium hydroxide preparation fields, and in particular to a kind of gas ammonia prepares the system and method for ammonium hydroxide.
Background technique
In ammonia synthesis process, having an auxiliary system is exactly the refrigeration system of ammonia synthesis, for ammonia synthesis system Process gas cooling, has reached the mesh of separation liquefied ammonia.The liquefaction of gas ammonia include compression and condensation, gas ammonia after ice maker compresses, into Enter evaporative condenser, gas ammonia is condensed into liquefied ammonia by cooling water, is finally sent into freezing liquefied ammonia sulculus.It will by freezing liquefied ammonia sulculus Liquefied ammonia gives in ammonia cooler or other desired workshop section.With the development of environmental protection technology, many enterprises require ammonium hydroxide come into Row desulfurization is out of stock, and ammonium hydroxide market demand is very big, freezes liquefied ammonia sulculus for liquefied ammonia and is routed directly to ammonium hydroxide system processed.
In view of this refrigeration system in ammonia synthesis process is a relatively important system, directly restricts Hydrazine yield is synthesized, but existing refrigeration system has the following deficiencies:
1, the refrigeration system of ammonia synthesis process needs powerful ice maker to compress gas ammonia, reduces gas ammonia with evaporative condenser Temperature is allowed to become liquefied ammonia, is recycled.Cryogenic temperature is lower, and the effect for separating liquefied ammonia is better;The production of synthesis ammonia system is negative Lotus is bigger, and the load of refrigeration system is also bigger.This there is ice maker, and energy consumption is high, especially in summer, hot weather when It waits, refrigeration system temperature is high, and ice maker load is heavier;And plant maintenance amount is big, and equipment investment is big;With the production of synthesis ammonia system Load is corresponding, and the water that evaporative condenser needs to consume is big.
2, ammonium hydroxide system processed liquefied ammonia ammonium hydroxide, needs to first pass through liquid ammonia evaporator, prepares ammonium hydroxide with the gas ammonia of generation, and one Aspect needs to lose many energy;Another party's wheat flour ammonium hydroxide low efficiency, ammonium hydroxide processed it is at high cost.
Summary of the invention
The technical issues of in order to solve high existing ammonium hydroxide system power dissipation processed, low efficiency, the present invention provide a kind of freezing system System gas ammonia prepares the system and method for ammonium hydroxide.Tap installs threeway to the present invention mainly on refrigeration system ice maker intake header, It is piped ammonium hydroxide system processed, directly prepares ammonium hydroxide with the gas ammonia that ammonia cooler comes out, reduces the power consumption of ice maker, while improving ammonium hydroxide processed Efficiency.
Technical solution of the invention:
A kind of system that gas ammonia prepares ammonium hydroxide, including synthesis ammonia system, ammonia cooler, refrigeration system, freezing liquefied ammonia sulculus and Ammonium hydroxide system processed, the process gas of the synthesis ammonia system enter ammonia cooler, and ammonia cooler is connected to refrigeration system by gas ammonia pipeline, The refrigeration system generates liquefied ammonia and is stored in freezing liquefied ammonia sulculus;It freezes liquefied ammonia sulculus and is provided by liquefied ammonia pipeline to ammonia cooler Condensing agent;It is characterized in that further include gas ammonia ammonia water pipeline, and the ammonium hydroxide system processed includes super ammonia absorber, described On gas ammonia pipeline, outlet is connected to the entrance of gas ammonia ammonia water pipeline with an entrance of super ammonia absorber.
Further, the ammonium hydroxide system processed further includes liquid ammonia evaporator and Ammonia vessel, the liquid ammonia evaporator Entrance connects liquid ammonia ball tank, and the outlet of the liquid ammonia evaporator connects another entrance of super ammonia absorber, the outlet of super ammonia absorber Connect Ammonia vessel.
Further, the refrigeration system includes sequentially connected ice maker and evaporative condenser, the ice maker entrance ammonia The outlet of cooler connection, the vaporation-type cold air device is connect with freezing liquefied ammonia sulculus, evaporative condenser and freezing liquefied ammonia sulculus Temperature sensor is provided on the pipeline of connection;The first regulating valve is provided on the liquefied ammonia pipeline.
Further, the gas ammonia ammonia water pipeline is provided with the second regulating valve, is provided with cut-off on the gas ammonia pipeline Valve.
Further, the liquid ammonia ball tank feeds pipeline by liquefied ammonia and supplements liquefied ammonia, the liquefied ammonia to freezing liquefied ammonia sulculus It is provided with liquidometer in sulculus supplement liquefied ammonia, is provided with third regulating valve on the supply pipeline.
Further, the 4th regulating valve is provided in the connecting pipe with liquid ammonia ball tank of the liquid ammonia evaporator.
The present invention provides a kind of method that gas ammonia prepares ammonium hydroxide, comprising the following steps:
1) process gas by ammonia cooler carries out gas-liquid separation in synthesis ammonia system;
2) gas ammonia isolated enters ammonium hydroxide system processed, and extra gas ammonia enters refrigeration system.
Further, step 2) isolates the super ammonia absorber that gas ammonia enters ammonium hydroxide system processed.
Further, when ammonium hydroxide demand is big, liquid ammonia ball tank feeds liquefied ammonia to the liquid ammonia evaporator of ammonium hydroxide system processed;Together When turn off the access that extra gas ammonia enters refrigeration system.
Advantage for present invention:
The liquefied ammonia evaporation that is utilized of high degree of the present invention is to absorb a large amount of thermal properties, refrigeration system and ammonium hydroxide system processed System connects well, has achieved the purpose that energy-saving.It has the advantage that
1, the gas ammonia of refrigeration system directly goes ammonium hydroxide system processed, reduces ice maker load, it might even be possible to ice maker be cut off, dropped Low power consumption reduces cost of equipment maintenance.
2, the characteristic of liquefied ammonia evaporation endothermic is greatly utilized, liquefied ammonia can be supplemented, in ammonia synthesis according to refrigeration system temperature When system loading is big or when hot weather, control cryogenic temperature can be very good, without worrying the big problem of ice maker load.
3, ammonium hydroxide system processed eliminates the link of liquefied ammonia evaporation, improves the efficiency of ammonium hydroxide processed directly with gas ammonia ammonium hydroxide, Reduce the cost of ammonium hydroxide processed.
4, in ammonium hydroxide preparation method of the invention, while two kinds of techniques being had both, gas ammonia prepares ammonium hydroxide, and liquefied ammonia prepares ammonium hydroxide, It mutually compensates, improves the efficiency of the preparation of ammonium hydroxide.
Detailed description of the invention
Fig. 1 is the system schematic that the present invention prepares ammonium hydroxide.
Specific embodiment
Embodiment 1: a kind of system that gas ammonia prepares ammonium hydroxide, including synthesis ammonia system, ammonia cooler, refrigeration system, freezing liquid Ammonia sulculus, ammonium hydroxide system processed and gas ammonia ammonia water pipeline, the process gas of synthesis ammonia system enter ammonia cooler, and ammonia cooler and freezing are System is connected to by gas ammonia pipeline, and refrigeration system generates liquefied ammonia and is stored in freezing liquefied ammonia sulculus;Freezing liquefied ammonia sulculus passes through liquefied ammonia Pipeline provides condensing agent to ammonia cooler;Ammonium hydroxide system processed includes super ammonia absorber, and the entrance of gas ammonia ammonia water pipeline is in gas ammonia pipe On road, outlet is connected to an entrance of super ammonia absorber.Tap increases on the ammonia pipeline of ammonia cooler gas ammonia to ice maker import Aerating ammonia ammonia water pipeline, gas ammonia is sent back in super ammonia absorber, and super ammonia absorber is prepared with the gas ammonia that refrigeration system is sent Ammonium hydroxide.Liquefied ammonia is persistently added in the liquefied ammonia sulculus of refrigeration system, reduces refrigeration system temperature with the characteristic of liquefied ammonia evaporation endothermic Degree, and the gas ammonia of liquefied ammonia evaporation is directly sent to ammonium hydroxide system and ammonium hydroxide is made, and does not need ice maker compression gas ammonia circulation, reduces the energy and disappears Consumption.And ammonium hydroxide efficiency processed can also be improved with gas ammonia ammonium hydroxide, reduce consumption.
Embodiment 2: the preparation efficiency in order to improve ammonium hydroxide, ammonium hydroxide system processed include liquid ammonia evaporator and Ammonia vessel, The entrance of liquid ammonia evaporator is connect into liquid ammonia ball tank, the outlet of liquid ammonia evaporator connects another entrance of super ammonia absorber, super suction The outlet of ammonia device connects Ammonia vessel.The 4th regulating valve is provided in the connecting pipe with liquid ammonia ball tank of liquid ammonia evaporator.The reality It applies example and gas ammonia prepared into ammonium hydroxide prepares ammonium hydroxide with liquefied ammonia and combine.
When ammonium hydroxide demand is big, all gas ammonias of ammonia cooler are all sent to super ammonia absorber ammonium hydroxide, if at this time can't Meet and use, opens supplement liquefied ammonia ammonium hydroxide.So the ice maker of refrigeration system and evaporative condenser are all cut off, and are continuously ammonia Cooler supplements liquefied ammonia, and gas ammonia all goes super ammonia absorber to prepare ammonium hydroxide.Ice maker power consumption can be saved in this way and evaporates cold power consumption, ammonia Cooler temperature can also control well.
Ammonium hydroxide demand hour, the part gas ammonia of ammonia cooler remove ammonium hydroxide processed, and part gas ammonia still goes ice maker import through over-voltage Refrigeration system liquefied ammonia sulculus is returned to after contracting and evaporative condenser, liquid ammonia ball tank stops providing liquefied ammonia to liquid ammonia evaporator at this time.In this way Ice maker load can be reduced, while power consumption can also be reduced.
Embodiment 3: a kind of system that gas ammonia prepares ammonium hydroxide, refrigeration system include sequentially connected ice maker and evaporating type condensing The outlet of device, the connection of ice maker entrance ammonia cooler, vaporation-type cold air device is connect with freezing liquefied ammonia sulculus, evaporative condenser and freezing Temperature sensor is provided on the pipeline of liquefied ammonia sulculus connection;The first regulating valve is provided on liquefied ammonia pipeline, it can be according to freezing System temperature supplements liquefied ammonia.Liquefied ammonia is persistently added to ammonia cooler by freezing liquefied ammonia sulculus, is mended ammonia amount and is used according to the temperature of ammonia cooler Self-adjusting valve control;
Embodiment 5: a kind of system that gas ammonia prepares ammonium hydroxide, liquid ammonia ball tank feed pipeline to freezing liquefied ammonia sulculus by liquefied ammonia Liquefied ammonia is supplemented, liquidometer is provided in liquefied ammonia sulculus supplement liquefied ammonia, feeds and be provided with third regulating valve on pipeline.Liquid ammonia ball tank Liquefied ammonia persistently adds to freezing liquefied ammonia sulculus, mends ammonia amount and is controlled according to sulculus liquid level self-regulated.
Total system of the present invention increases self-adjusting valve and measure and control instrument, and all measuring and control datas are pooled to DCS system, realizes total system It is automatic controllable.According to payload adjusting process operational mode, to greatest extent energy conservation and optimization.
Embodiment 6: the structure, connection relationship and positional relationship of product is described in detail in integrated structure schematic diagram.
Diagram 1: the process gas of ammonia synthesis system exchanges heat into ammonia cooler and cools down;
Diagram 2: going out ammonia cooler after the process gas heat exchange of ammonia synthesis system is cooling, returns to ammonia synthesis system separation liquefied ammonia;
Diagram 3: after ammonia cooler heat exchange, liquefied ammonia is evaporated to gas ammonia, is sent to ice maker import;
Diagram 4: gas ammonia is sent to evaporative condenser after ice maker compresses;
Diagram 5: compressed gas ammonia becomes liquefied ammonia after evaporating type condensing, is sent to freezing liquefied ammonia sulculus;
Diagram 6: the liquefied ammonia of freezing liquefied ammonia sulculus adds to ammonia cooler;
Diagram 7: liquid ammonia ball tank is that freezing liquefied ammonia sulculus supplements liquefied ammonia;
Diagram 8: liquid ammonia ball tank is the liquid ammonia evaporator supplement liquefied ammonia of ammonium hydroxide system processed;
Diagram 9: the gas ammonia of the liquid ammonia evaporator evaporation of ammonium hydroxide system processed is sent to super ammonia absorber and prepares ammonium hydroxide;
Diagram 10: the ammonium hydroxide that super ammonia absorber prepares is sent to Ammonia vessel;
Diagram 11: ammonia cooler gas ammonia goes super ammonia absorber to prepare ammonium hydroxide;
The working principle of the invention or working method:
Diagram 1 and diagram 2 exchange heat for ammonia synthesis technology gas in ammonia cooler, reduce process gas temperature, separate liquefied ammonia.
Process flow of the invention are as follows: the liquefied ammonia of 7 liquid ammonia ball tanks of diagram persistently adds to freezing liquefied ammonia sulculus, mends ammonia amount root It is controlled according to sulculus liquid level self-regulated;Liquefied ammonia is persistently added to ammonia cooler by 6 freezing liquefied ammonia sulculus of diagram, mends ammonia amount according to ammonia cooler Temperature is controlled with self-adjusting valve;Diagram 11, gas ammonia is sent back to super suction by the tap on the pipeline of ammonia cooler gas ammonia to ice maker import The ammonia gas pipeline of ammonia device, super ammonia absorber prepare ammonium hydroxide with the gas ammonia that refrigeration system is sent.
When ammonium hydroxide demand is big, all gas ammonias of ammonia cooler are all sent to super ammonia absorber ammonium hydroxide, replenisher when inadequate Ammonia ammonium hydroxide.The ice maker and evaporative condenser of refrigeration system can all be cut off in this way, be continuously ammonia cooler supplement liquefied ammonia, Gas ammonia all goes super ammonia absorber to prepare ammonium hydroxide.Ice maker power consumption can be saved in this way and evaporates cold power consumption, and ammonia cooler temperature also can Control well.
Ammonium hydroxide demand hour, the part gas ammonia of ammonia cooler remove ammonium hydroxide processed, and part gas ammonia still goes ice maker import through over-voltage Refrigeration system liquefied ammonia sulculus is returned to after contracting and evaporative condenser.It thus can reduce ice maker load, reduce power consumption.

Claims (9)

1. the system that a kind of gas ammonia prepares ammonium hydroxide, including synthesis ammonia system, ammonia cooler, refrigeration system, freezing liquefied ammonia sulculus and system Ammonium hydroxide system, the process gas of the synthesis ammonia system enter ammonia cooler, and ammonia cooler is connected to refrigeration system by gas ammonia pipeline, institute Refrigeration system generation liquefied ammonia is stated to be stored in freezing liquefied ammonia sulculus;It is cold to ammonia cooler offer by liquefied ammonia pipeline to freeze liquefied ammonia sulculus Solidifying agent;It is characterized by also including gas ammonia ammonia water pipeline, the ammonium hydroxide system processed includes super ammonia absorber, the gas ammonia system On gas ammonia pipeline, outlet is connected to the entrance of ammonia water pipeline with an entrance of super ammonia absorber.
2. the system that gas ammonia according to claim 1 prepares ammonium hydroxide, it is characterised in that: the ammonium hydroxide system processed further includes liquid Ammonia evaporator and Ammonia vessel, the entrance of the liquid ammonia evaporator connect liquid ammonia ball tank, and the outlet of the liquid ammonia evaporator connects super Another entrance of grade ammonia absorber, the outlet of super ammonia absorber connects Ammonia vessel.
3. the system that gas ammonia according to claim 1 prepares ammonium hydroxide, it is characterised in that: the refrigeration system includes successively connecting The ice maker and evaporative condenser connect, the ice maker entrance ammonia cooler connection, the outlet of the vaporation-type cold air device and freezing liquid Ammonia sulculus connects, and is provided with temperature sensor on the pipeline that evaporative condenser is connect with freezing liquefied ammonia sulculus;The liquid ammonia tube The first regulating valve is provided on road.
4. the system that gas ammonia according to claim 1 prepares ammonium hydroxide, it is characterised in that: the gas ammonia ammonia water pipeline setting There is the second regulating valve, is provided with shut-off valve on the gas ammonia pipeline.
5. the system that gas ammonia according to claim 2 prepares ammonium hydroxide, it is characterised in that: the liquid ammonia ball tank is mended by liquefied ammonia Liquefied ammonia is supplemented to freezing liquefied ammonia sulculus to pipeline, is provided with liquidometer, the supply pipeline in the liquefied ammonia sulculus supplement liquefied ammonia On be provided with third regulating valve.
6. the system that gas ammonia according to claim 5 prepares ammonium hydroxide, it is characterised in that: the liquid ammonia evaporator and liquefied ammonia The 4th regulating valve is provided in the connecting pipe of spherical tank.
7. a kind of method that gas ammonia prepares ammonium hydroxide, it is characterised in that the following steps are included:
1) process gas by ammonia cooler carries out gas-liquid separation in synthesis ammonia system;
2) gas ammonia isolated enters ammonium hydroxide system processed, and extra gas ammonia enters refrigeration system.
8. the method that gas ammonia according to claim 7 prepares ammonium hydroxide, it is characterised in that: step 2) isolates gas ammonia and enters system The super ammonia absorber of ammonium hydroxide system.
9. the method that gas ammonia according to claim 7 or 8 prepares ammonium hydroxide, it is characterised in that: when ammonium hydroxide demand is big, liquid Ammonia spherical tank feeds liquefied ammonia to the liquid ammonia evaporator of ammonium hydroxide system processed;Simultaneously turn off the access that extra gas ammonia enters refrigeration system.
CN201811330403.7A 2018-11-09 2018-11-09 A kind of gas ammonia prepares the system and method for ammonium hydroxide Pending CN109160523A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1887707A (en) * 2006-07-12 2007-01-03 宋三奎 Process of producing ammonium nitrate with exhausted gas from synthetic ammonia freezing system
WO2009109036A1 (en) * 2008-03-04 2009-09-11 Thermalfrost Inc. Ammonia refrigeration system
CN202470617U (en) * 2012-03-26 2012-10-03 新疆宜化化工有限公司 Gas ammonia compressing and condensing system
CN203053107U (en) * 2012-12-20 2013-07-10 贵州开磷(集团)有限责任公司 Ammonia processed product cooling system
CN103285755A (en) * 2013-06-24 2013-09-11 天津市奥利达设备工程技术有限公司 Coiled pipe integrated machine used for preparation of ammoniacal liquor
CN204454614U (en) * 2015-03-19 2015-07-08 苏州晶瑞化学有限公司 A kind of high-purity ammonia water continuous production device
CN204574696U (en) * 2014-12-13 2015-08-19 重庆华强投资集团有限公司 Synthetic ammonia freezing system

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1887707A (en) * 2006-07-12 2007-01-03 宋三奎 Process of producing ammonium nitrate with exhausted gas from synthetic ammonia freezing system
WO2009109036A1 (en) * 2008-03-04 2009-09-11 Thermalfrost Inc. Ammonia refrigeration system
CN202470617U (en) * 2012-03-26 2012-10-03 新疆宜化化工有限公司 Gas ammonia compressing and condensing system
CN203053107U (en) * 2012-12-20 2013-07-10 贵州开磷(集团)有限责任公司 Ammonia processed product cooling system
CN103285755A (en) * 2013-06-24 2013-09-11 天津市奥利达设备工程技术有限公司 Coiled pipe integrated machine used for preparation of ammoniacal liquor
CN204574696U (en) * 2014-12-13 2015-08-19 重庆华强投资集团有限公司 Synthetic ammonia freezing system
CN204454614U (en) * 2015-03-19 2015-07-08 苏州晶瑞化学有限公司 A kind of high-purity ammonia water continuous production device

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Application publication date: 20190108