CN1091434C - Solid concrete water reducing agent and its preparation - Google Patents
Solid concrete water reducing agent and its preparation Download PDFInfo
- Publication number
- CN1091434C CN1091434C CN99114871A CN99114871A CN1091434C CN 1091434 C CN1091434 C CN 1091434C CN 99114871 A CN99114871 A CN 99114871A CN 99114871 A CN99114871 A CN 99114871A CN 1091434 C CN1091434 C CN 1091434C
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- Prior art keywords
- reducing agent
- water reducing
- concrete
- acid
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/16—Sulfur-containing compounds
- C04B24/20—Sulfonated aromatic compounds
- C04B24/22—Condensation or polymerisation products thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/30—Water reducers, plasticisers, air-entrainers, flow improvers
- C04B2103/302—Water reducers
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The present invention relates to a solid state water reducing agent for concrete and a manufacturing method thereof. The solid state water reducing agent is characterized in that a crosslinking inhibition agent is introduced in a high-strength and high-efficiency water reducing agent for concrete and a manufacturing method thereof, and the water reducing agent for the concrete in a liquid state is manufactured into the water reducing agent for the concrete in a solid state by a spray drying method at the temperature of 160 to 250 DEG C after a molecule substance is pulled out in a vacuum way. The manufactured water reducing agent for the concrete in the solid state has the advantages of good liquidity, concrete slump constant increase and smaller reduction of slump constant variation along with time when incorporated into a concrete composition or cement net paste; furthermore, the effects of the water reducing agent for the concrete in the solid state approach to or exceed that of the water reducing agent for the concrete in the liquid state, and the present invention can be widely used nationally and has obvious economical and social benefits.
Description
The present invention relates to a kind of solid concrete water reducing agent and manufacture method thereof, it is applicable to concrete, mortar, the processing and manufacturing of grout and aqueous slurry goods.
The existing abroad report of phenol series concrete high-efficiency water reducing agent, domestic report is very few, but all be to adopt liquid water reducer directly to mix in the processing and manufacturing of concrete and grout goods thereof, as Chinese patent CN1032445A, the Chinese patent 98121803.2 that is entitled as " aminophenyl sulfonic acid-phenol-formaldehyde condensation products and contain the concrete admixture of this condenses " and present inventor's application is entitled as " efficient water-reducing agent for high-strength concrete and manufacture method thereof and purposes " and is liquid water reducer product, as liquid product use nearby or in the short-range all right, packing and trucking costs have just been increased in the distant location use, having relatively high expectations of transport container particularly is because water content is up to 60～70% in the liquid water reducer.So people wish to develop the solid concrete water reducing agent product.Solve to make the key technology of solid concrete water reducing agent product: the one, solid product joins in concrete or the grout goods will very fast dissolving, dispersion, and its water-reducing effect should be consistent with liquid product down for same incorporation (solid content), even better; The 2nd, during from liquid product manufacturing solid product, condenses does not produce crosslinked, therefore selects suitable cross-linked inhibitor just very important.
The objective of the invention is provides a kind of solid concrete water reducing agent and manufacture method thereof at the deficiencies in the prior art, be characterized in efficient water-reducing agent for high-strength concrete and manufacture method thereof, introducing cross-linked inhibitor, and adopt spray-dired method to make solid concrete water reducing agent, the solid-state water reducer that makes is incorporated into good fluidity in concrete or the cement paste, concrete slump increases, the slump reduce over time very little, effect near or surpass liquid water reducer product.
Purpose of the present invention is realized by following technical measures
The recipe ingredient of solid concrete water reducing agent (by weight) is:
Phenolic material (available phenol, dihydroxy-benzene, cresols and/or naphthols are at least a) 10-70 part
Aldehydes (available formaldehyde, acetaldehyde, oxalic dialdehyde, propionic aldehyde, mda, butyraldehyde, isobutyric aldehyde, glutaraldehyde and/or furfural at least a) 15-95 part
Sulfonated bodies (available sulphite, persulphate, thionamic acid, sulfamate, aniline sulfonic acid and/or amino phenyl sulfonyl hydrochlorate are at least a) 10-80 part
Viscosity modifier (available quadrol, diethylenetriamine, triethylene tetramine, Tetramethylammonium hydroxide, hexamethylenetetramine, ethanamide and/or acrylamide are at least a) 0.1-40 part
Cross-linked inhibitor (available formic acid, phenylformic acid, citric acid, urea, lewis' acid and/or Tetramethylammonium hydroxide are at least a) 0.1-30 part
The manufacture method of solid concrete water reducing agent: with 10～70 parts of phenolic materials, 15～95 parts of aldehydes and 0.1～40 part of adding of viscosity modifier have in the reactor of reflux exchanger, thermometer and agitator, under agitation add sodium hydroxide adjusting pH value and be 7-11, be warming up to the reflux temperature reaction after 2-3 hour, add 10～80 parts of sulfonated bodiess, reacted 1～3 hour, add 0.1～30 part of cross-linked inhibitor, continue reaction 1～5 hour, the viscosity that adopt vacuum to deviate from low-molecular material, to record liquid condenses is 25～35 seconds (4
#Cup), liquid condenses makes solid concrete water reducing agent in 160～250 ℃ of temperature by spraying drying.
Solid concrete water reducing agent is used in the processing and manufacturing of concrete, mortar, grout and grout goods thereof, and its incorporation is 0.3～1.0% of a cement consumption, reaches the requirement of pump concrete.Its flowing degree of net paste of cement and concrete performance see a table 1 and table 2 column data for details.
Table 1 is the flowing degree of net paste of cement test data
Table 2 is the testing concrete performance data
Test-results shows: mix the cement paste good fluidity of solid concrete water reducing agent, although water cement ratio (W/C) is 0.29, good flowability is arranged still, concrete slump increases, and slump-loss is little; Solid concrete water reducing agent directly mixes in the concrete and do not influence its performance, and this is that admixture was can't be obtained in the past.Simultaneous test shows that the cement paste that does not add water reducer can't flow at all.
The present invention compared with prior art has following advantage:
1. employing viscosity modifier can the better controlled molecular weight product, has satisfied the range of viscosities of processing requirement.
2. the employing cross-linked inhibitor has been controlled the crosslinking reaction of solid concrete water reducing agent in production process effectively, and crosslinked action does not particularly take place in spraying drying or takes place less.
3. do not have temperature-fall period in entire reaction, save energy has shortened the production cycle, and three-waste free discharge.
4. manufacture method is simple, be easy to grasp, and convenient transportation, performance is good, can be applicable in China, and remarkable economic efficiency and social benefit are arranged.
Embodiment
Below by embodiment the present invention is specifically described; be necessary to be pointed out that at this following examples only are used for the present invention is further detailed; can not be interpreted as limiting the scope of the invention, the person skilled in art can do some nonessential improvement and adjustment to the present invention by foregoing according to the present invention.
1. with 20 kilograms of phenol, 0.3 kilogram of 36 kilograms of 36.8% formalins and acrylamide, add and have reflux exchanger, in the reactor of thermometer and agitator, under agitation add sodium hydroxide adjusting pH value and be 7-11, be warming up to the reflux temperature reaction after 2～3 hours, add 39.8 kilograms of sodium sulfanilates, 200 kilograms in water in reflux temperature reaction 3 hours, adds 0.4 kilogram in phenylformic acid, be warming up to reflux temperature then, continue reaction 2-3 hour, the condenses of acquisition carries out vacuum and deviates from low-molecular material, and the viscosity that records liquid water reducer is 28 seconds (4
#The cup), again with liquid water reducer in 180～200 ℃ of temperature, make solid concrete water reducing agent by spraying drying.
2. with 33 kilograms in cresols, 4.5 kilograms of 45 kilograms of 40% glyoxal water solutions and six toluene tetramines, join and have agitator, in the reactor of reflux exchanger and thermometer, under agitation adding sodium hydroxide, to regulate pH value be 7-11, be warming up to reflux temperature reaction 2-3 hour, add 38 kilograms of sodium sulphite anhydrous 99.3s, 180 kilograms in water is in the temperature ℃ reaction 3 hours that refluxes, add 0.5 kilogram of lewis' acid, the working method by embodiment 1 makes solid concrete water reducing agent then.
3. with 27.5 kilograms of dihydroxy-benzenes, 6.5 kilograms of 40.8 kilograms of 36.6% formalins and hexamethylenetetramines, join and have agitator, in the reactor of reflux exchanger and thermometer, under agitation adding sodium hydroxide, to regulate pH value be 7-11, be warming up to the reflux temperature reaction after 2-3 hour, add 26 kilograms of sodium sulfanilates, 140 kilograms in water was in reflux temperature reaction 2.5 hours, add 0.5 kilogram in urea, the working method according to embodiment 1 makes solid concrete water reducing agent then.
Table 1 flowing degree of net paste of cement test data
*
* testing cement is river oil span 525R cement, W/C=0.29, and 12 ℃ of probe temperatures, degree of mobilization are pressed GB/T80077-87 flowing degree of net paste of cement determination of test method.Table 2 testing concrete performance data
*
* testing concrete performance is a cement by GB8076-1997 prescriptive procedure mensuration C, and S is a sand, and G is a stone, and W is a water
| Sample | Incorporation (cement amount %) | Degree of mobilization (millimeter) | Remarks | |||
| Initially | 30 minutes | 60 minutes | 120 minutes | |||
| 1 | 0 | Do not flow | ||||
| 2 | 0.5 | 232 | 231 | 222 | In the solid-state direct adding cement | |
| 3 | 0.5 | 235 | 240 | 229 | Solid-state elder generation is water-soluble, adds in the cement again | |
| Sample | Volume (%) | Proportioning | Water-reducing rate (%) | Ultimate compression strength MPa | |||
| C∶S∶G∶W | 1 day | 3 days | 7 days | 28 days | |||
| Benchmark | 0 | 440∶755∶1045∶193.3 | 0 | 7.4/100 | 28.7/100 | 35.5/100 | 45.6/100 |
| 1 | 0.4 | 440∶755∶1045∶157.3 | 18.6 | 11.9/161 | 38.8/135 | 45.5/128 | 50.3/110 |
| 2 | 0.5 | 440∶755∶1045∶151.7 | 21.6 | 15.5/209 | 45.0/157 | 49.9/141 | 57.5/126 |
| 3 | 0.6 | 440∶755∶1045∶144.3 | 25.3 | 14.0/189 | 41.6/145 | 46.9/132 | 56.6/124 |
Claims (2)
1. solid concrete water reducing agent is characterized in that the recipe ingredient (by weight) of this water reducer is:
10～70 parts of phenolic materials
15～95 parts of aldehydes
10～80 parts of sulfonated bodiess
0.1～40 part of viscosity modifier
0.1～30 part of cross-linked inhibitor
Wherein phenolic material is that phenol, dihydroxy-benzene, cresols and/or naphthols are at least a; Aldehydes be formaldehyde, acetaldehyde, oxalic dialdehyde, propionic aldehyde, mda, butyraldehyde, isobutyric aldehyde, glutaraldehyde and/or furfural be at least a; Sulfonated bodies is a sulphite, persulphate, and thionamic acid, sulfamate, aniline sulfonic acid and/or amino phenyl sulfonyl hydrochlorate are at least a; Viscosity modifier is quadrol, diethylenetriamine, triethylene tetramine, Tetramethylammonium hydroxide, and hexamethylenetetramine, ethanamide and/or acrylamide are at least a; Crosslinked inhibition is that formic acid, phenylformic acid, citric acid, urea, lewis' acid and/or Tetramethylammonium hydroxide are at least a.
2. according to the manufacture method of claims 1 described solid concrete water reducing agent, it is characterized in that:
With phenolic material phenol, dihydroxy-benzene, 10～70 parts of cresols or naphthols, aldehydes formaldehyde, acetaldehyde, oxalic dialdehyde, propionic aldehyde, mda, butyraldehyde, isobutyric aldehyde, 15～95 parts in glutaraldehyde or furfural and viscosity modifier quadrol, diethylenetriamine, triethylene tetramine, Tetramethylammonium hydroxide, hexamethylenetetramine, 0.1～40 part of adding of ethanamide or acrylamide has reflux exchanger, in the reactor of thermometer and agitator, under agitation adding sodium hydroxide adjusting pH value is 7～11, be warming up to the reflux temperature reaction after 2～3 hours, add sulfonated bodies sulphite, persulphate, thionamic acid, sulfamate, 10～80 parts of aniline sulfonic acid or amino phenyl sulfonyl hydrochlorates, reacted 1～3 hour, add cross-linked inhibitor formic acid, phenylformic acid, citric acid, urea, 0.1～30 part of lewis' acid or Tetramethylammonium hydroxide, continue reaction 1～5 hour, adopt vacuum to deviate from low-molecular material, the viscosity that records liquid condenses is 25～35 seconds (4
#Cup), liquid condenses makes solid concrete water reducing agent in 160～250 ℃ of temperature by spraying drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99114871A CN1091434C (en) | 1999-05-19 | 1999-05-19 | Solid concrete water reducing agent and its preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99114871A CN1091434C (en) | 1999-05-19 | 1999-05-19 | Solid concrete water reducing agent and its preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1274696A CN1274696A (en) | 2000-11-29 |
| CN1091434C true CN1091434C (en) | 2002-09-25 |
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ID=5277906
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN99114871A Expired - Fee Related CN1091434C (en) | 1999-05-19 | 1999-05-19 | Solid concrete water reducing agent and its preparation |
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| Country | Link |
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| CN (1) | CN1091434C (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102092979B (en) * | 2010-12-10 | 2012-11-14 | 马清浩 | Sulfamate water-reducing agent and preparation method thereof |
| CN103113036B (en) * | 2013-03-12 | 2014-12-10 | 南京瑞迪高新技术有限公司 | Modified aliphatic superplasticizer and preparation method thereof |
| CN103570270A (en) * | 2013-10-29 | 2014-02-12 | 大连创达技术交易市场有限公司 | Water reducing agent |
| CN107746220A (en) * | 2017-09-21 | 2018-03-02 | 镇江市太浪新材料科技有限公司 | A kind of novel architecture concrete |
| CN107572960A (en) * | 2017-09-21 | 2018-01-12 | 镇江市太浪新材料科技有限公司 | A kind of preparation method of efficiently build concrete |
| CN107746201A (en) * | 2017-09-21 | 2018-03-02 | 镇江市太浪新材料科技有限公司 | A kind of efficient preparation technology of the special water reducer of concrete |
| CN107793064A (en) * | 2017-09-21 | 2018-03-13 | 镇江市太浪新材料科技有限公司 | A kind of special water reducer of concrete |
| CN108706898A (en) * | 2018-06-17 | 2018-10-26 | 李达峰 | A kind of Concrete synergist and preparation method thereof containing sulfonic acid group |
| CN109853315A (en) * | 2019-03-25 | 2019-06-07 | 广州市诚利建设工程有限公司 | A kind of road construction method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1120030A (en) * | 1994-05-13 | 1996-04-10 | 武汉化工学院 | Synthesizing efficient cement water reducing agent by using waste phenol dregs oil refinery |
| CN1176946A (en) * | 1996-09-17 | 1998-03-25 | 北京城建集团总公司构件厂 | Self-compactable concrete blend needing vibrating |
-
1999
- 1999-05-19 CN CN99114871A patent/CN1091434C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1120030A (en) * | 1994-05-13 | 1996-04-10 | 武汉化工学院 | Synthesizing efficient cement water reducing agent by using waste phenol dregs oil refinery |
| CN1176946A (en) * | 1996-09-17 | 1998-03-25 | 北京城建集团总公司构件厂 | Self-compactable concrete blend needing vibrating |
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| Publication number | Publication date |
|---|---|
| CN1274696A (en) | 2000-11-29 |
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