CN109136747A - The quenched thin plate of 8mm thickness Q690 intensity rank low yield strength ratio and production method - Google Patents
The quenched thin plate of 8mm thickness Q690 intensity rank low yield strength ratio and production method Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/002—Heat treatment of ferrous alloys containing Cr
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/04—Making ferrous alloys by melting
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
Abstract
The invention discloses a kind of quenched thin plate of 8mm thickness Q690 intensity rank low yield strength ratio and production methods, the thin plate chemical component composition and its mass percentage are as follows: C:0.16~0.18%, Si:0.20~0.40%, Mn:1.15~1.25%, P≤0.015%, S≤0.005%, Cr:0.20~0.30%, Mo:0.15~0.25%, V:0.035~0.045%, Ti:0.010~0.015%, B:0.0008~0.0018%, surplus are Fe and inevitable impurity;The production method includes smelting ingredient, the refining of LF furnace, VD vacuum refining, heating, heat treatment procedure.The present invention is designed using the ingredient of the humble alloying element of high C, is aided with medium temperature Quenching plus tempering process, is realized the product quality requirement of≤0.95 yield tensile ratio, is met the market demand.
Description
Technical field
The invention belongs to metallurgical technology fields, and in particular to a kind of quenched thin plate of 8mm thickness Q690 intensity rank low yield strength ratio
And production method.
Background technique
Popularization with low yield strength ratio steel in regular tenacity level structures rings domain, market are bent for quenched and tempered state high-strength steel
There has also been limitations to require for strong ratio, mainstream kind of the quenched and tempered steel of Q690 intensity rank as quenched and tempered steel, aobvious to the control of yield tensile ratio
It is more urgent.
In terms of steel grade controls difficulty: the different conditions of delivery with regular tenacity rank steel grade, quenched and tempered state than controlled rolling state, just
The control difficulty of fiery state is bigger, and with the reduction of steel plate thickness, the control difficulty of yield tensile ratio also significantly increases.It is logical
In normal situation, the yield tensile ratio controlled level of 8mm thick quenched and tempered steel is generally >=0.98.
At the scene in terms of technology controlling and process: thin plate quenched for 8mm already belongs to the very thin steel of Heavy Plate Plant on rolling specs
Plate, it is contemplated that the needs rolled into cannot achieve technological measure in rolling sequence, and in heat treatment stages, steel plate has also been not present
The problem of through hardening, needs to make great innovation in terms of technique thinking.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of quenched thin plate of 8mm thickness Q690 intensity rank low yield strength ratio and lifes
Production method.
In order to solve the above technical problems, the technical solution adopted by the present invention is that: a kind of 8mm thickness Q690 intensity rank is low to bend by force
Than quenched thin plate, the thin plate chemical component composition and its mass percentage are as follows: C:0.16~0.18%, Si:0.20~
0.40%, Mn:1.15~1.25%, P≤0.015%, S≤0.005%, Cr:0.20~0.30%, Mo:0.15~0.25%, V:
0.035~0.045%, Ti:0.010~0.015%, B:0.0008~0.0018%, surplus are Fe and inevitable impurity.
Thin plate Ceq:0.43~0.50% of the present invention.
Lamella thickness specification of the present invention is 8mm.
Thin plate yield tensile ratio≤0.95 of the present invention.
The present invention also provides a kind of production method of the quenched thin plate of 8mm thickness Q690 intensity rank low yield strength ratio, the lifes
Production method includes smelting ingredient, the refining of LF furnace, VD vacuum refining, heating, heat treatment procedure;The heat treatment procedure, in
Warm quenching+tempering technique, 875~885 DEG C of hardening heat.
Heat treatment procedure of the present invention, 875~885 DEG C of hardening heat, the cool time: 40~42min;Tempering temperature
620~630 DEG C, 50~55min of tempering time.
Smelting burden process of the present invention, ladle baking is good, baking temperature >=900 DEG C;Tapping cannot be shown in slag, tap
1600 DEG C of temperature >, C≤0.10% in molten steel;Using the fine fodder that must not be incorporated briquetting, slag steel, packet bottom, useless ingot mould, Xin Bao, big benefit
When furnace and the abnormal working of a furnace, this steel grade must not be smelted.
LF furnace refining procedure of the present invention, whole process guarantees that Argon is good, refines white slag retention time >=30min, and LF is total
Refining time >=55min, aluminum steel dosage >=1.8kg/t steel, lime consumption >=17kg/t steel, ferrosilicon deoxidier dosage >=2kg/t
Steel, process aluminium content >=0.015%, aluminium >=0.020% of skimming, refining terminate S≤0.005%.
Ca-Si is added before vacuum in vacuum refining process of the present invention, 55~62Pa of vacuum degree, retention time >=20min
Block >=1.5kg/t steel, argon gas soft blow time >=5min when vacuumizing are turned over so that the top of the slag is micro-, subject to molten steel is not exposed, are not permitted after vacuum
Perhaps it mends and feeds Al line.
Heating process of the present invention, 1250 DEG C of maximum heating temperature, 1220~1240 DEG C of soaking section temperature, soaking zone is protected
Warm time >=60min, heating time coefficient >=10min/mm guarantee that steel billet is grilled thoroughly, uniformly.
The quenched light sheet products canonical reference GB/T16270-2009 of 8mm thickness Q690 intensity rank low yield strength ratio of the present invention;It produces
Product examine surveys method standard and refers to GB/T228.
The beneficial effects of adopting the technical scheme are that the present invention is for the thick ultra-thin quenched Q690 rank of 8mm
Steel plate is designed using the ingredient of the humble alloying element of high C, is aided with medium temperature Quenching plus tempering process, is realized≤0.95 and is bent
The product quality requirement of strong ratio, meets the demand in market, realizes the upgrading of traditional product.
Specific embodiment
The present invention will be further described in detail combined with specific embodiments below.
Embodiment 1
The quenched thin plate heat (batch) number of the present embodiment Q690 intensity rank low yield strength ratio is 17409234N2, thickness specification 8mm, chemistry
At being grouped as and mass percentage are as follows: C:0.18%, Si:0.27%, Mn:1.18%, P:0.014%, S:0.0023%, Cr:
0.20%, Mo:0.19%, V:0.038%, Ti:0.012%, B:0.0011%, Ceq:0.46%, surplus be Fe and inevitably it is miscellaneous
Matter.
The quenched thin plate production method of the present embodiment Q690 intensity rank low yield strength ratio includes smelting ingredient, the refining of LF furnace, VD
Vacuum refining, heating, heat treatment procedure, specific process step are as described below:
(1) burden process is smelted: using the fine fodder that must not be incorporated briquetting, slag steel, packet bottom, useless ingot mould, Xin Bao, big fettling and the working of a furnace
When abnormal, this steel grade must not be smelted;Ladle baking is good, and 900 DEG C of baking temperature;Tapping cannot be shown in slag, tapping temperature
1610 DEG C, C:0.10% in molten steel;
(2) LF furnace refining procedure: whole process guarantees that Argon is good, refines the total refining time 55min of white slag retention time 30min, LF,
Aluminum steel dosage 1.8kg/t steel, lime consumption >=17kg/t steel, ferrosilicon deoxidier dosage 2kg/t steel, process aluminium content 0.015%,
It skims aluminium 0.020%, refining terminates S:0.005%;
(3) VD vacuum refining process: Ca-Si block 1.60kg/t steel is added before vacuum by vacuum degree 60Pa, retention time 20min, takes out
Argon soft blow time 6min when vacuum is not mended after vacuum and is fed Al line;
(4) heating process: 1250 DEG C of maximum heating temperature, 1220 DEG C of soaking section temperature, soaking zone soaking time 60min, heating
Time coefficient 10min/mm;
(5) heat treatment procedure: 880 DEG C of hardening heat, the cool time: 40min;625 DEG C of tempering temperature, tempering time 50min.
The present embodiment Q690 intensity rank low yield strength ratio quenched thin plate yield strength 816MPa, tensile strength 862MPa are bent
Strong ratio 0.95, elongation percentage 16%;- 40 DEG C of impact of collision function 148,138,170J.
Embodiment 2
The quenched thin plate heat (batch) number of the present embodiment Q690 intensity rank low yield strength ratio is 17409104N2, thickness specification 8mm, chemistry
At being grouped as and mass percentage are as follows: C:0.16%, Si:0.23%, Mn:1.25%, P:0.013%, S:0.0019%, Cr:
0.22%, Mo:0.18%, V:0.040%, Ti:0.013%, B:0.0016%, Ceq:0.46%, surplus be Fe and inevitably it is miscellaneous
Matter.
The quenched thin plate production method of the present embodiment Q690 intensity rank low yield strength ratio includes smelting ingredient, the refining of LF furnace, VD
Vacuum refining, heating, heat treatment procedure, specific process step are as described below:
(1) burden process is smelted: using the fine fodder that must not be incorporated briquetting, slag steel, packet bottom, useless ingot mould, Xin Bao, big fettling and the working of a furnace
When abnormal, this steel grade must not be smelted;Ladle baking is good, and 920 DEG C of baking temperature;Tapping cannot be shown in slag, tapping temperature
1650 DEG C, C:0.08% in molten steel;
(2) LF furnace refining procedure: whole process guarantees that Argon is good, refines the total refining time 58min of white slag retention time 32min, LF,
Aluminum steel dosage 1.95kg/t steel, lime consumption 19kg/t steel, ferrosilicon deoxidier dosage 2.5kg/t steel, process aluminium content 0.017%,
It skims aluminium 0.025%, refining terminates S:0.003%;
(3) VD vacuum refining process: Ca-Si block 1.55kg/t steel is added before vacuum by vacuum degree 58Pa, retention time 25min, takes out
Argon soft blow time 7min when vacuum is not mended after vacuum and is fed Al line;
(4) heating process: 1250 DEG C of maximum heating temperature, 1240 DEG C of soaking section temperature, soaking zone soaking time 65min, heating
Time coefficient 12min/mm;
(5) heat treatment procedure: 880 DEG C of hardening heat, the cool time: 40min;625 DEG C of tempering temperature, tempering time 50min.
The present embodiment Q690 intensity rank low yield strength ratio quenched thin plate yield strength 824MPa, tensile strength 870MPa are bent
Strong ratio 0.95, elongation percentage 16.5%;- 40 DEG C of impact of collision function 190,195,182J.
Embodiment 3
The quenched thin plate heat (batch) number of the present embodiment Q690 intensity rank low yield strength ratio be 18401343, thickness specification 8mm, chemistry at
It is grouped as and mass percentage are as follows: C:0.16%, Si:0.20%, Mn:1.15%, P:0.015%, S:0.005%, Cr:0.20%,
Mo:0.15%, V:0.035%, Ti:0.010%, B:0.0008%, Ceq:0.43%, surplus are Fe and inevitable impurity.
The quenched thin plate production method of the present embodiment Q690 intensity rank low yield strength ratio includes smelting ingredient, the refining of LF furnace, VD
Vacuum refining, heating, heat treatment procedure, specific process step are as described below:
(1) burden process is smelted: using the fine fodder that must not be incorporated briquetting, slag steel, packet bottom, useless ingot mould, Xin Bao, big fettling and the working of a furnace
When abnormal, this steel grade must not be smelted;Ladle baking is good, and 905 DEG C of baking temperature;Tapping cannot be shown in slag, tapping temperature
1630 DEG C, C:0.06% in molten steel;
(2) LF furnace refining procedure: whole process guarantees that Argon is good, refines the total refining time 59min of white slag retention time 35min, LF,
Aluminum steel dosage 2.1kg/t steel, lime consumption 18kg/t steel, ferrosilicon deoxidier dosage 3kg/t steel, process aluminium content 0.020% are taken off
Slag aluminium 0.030%, refining terminate S:0.002%;
(3) VD vacuum refining process: Ca-Si block 1.65kg/t steel is added before vacuum by vacuum degree 55Pa, retention time 27min, takes out
Argon soft blow time 5min when vacuum is not mended after vacuum and is fed Al line;
(4) heating process: 1250 DEG C of maximum heating temperature, 1230 DEG C of soaking section temperature, soaking zone soaking time 68min, heating
Time coefficient 13min/mm;
(5) heat treatment procedure: 875 DEG C of hardening heat, the cool time: 41min;620 DEG C of tempering temperature, cool time 52min.
The present embodiment Q690 intensity rank low yield strength ratio quenched thin plate yield strength 783MPa, tensile strength 834MPa are bent
Strong ratio 0.94, elongation percentage 24%;- 40 DEG C of impact of collision function 90,112,131J.
Embodiment 4
The quenched thin plate heat (batch) number of the present embodiment Q690 intensity rank low yield strength ratio be 18401916, thickness specification 8mm, chemistry at
It is grouped as and mass percentage are as follows: C:0.17%, Si:0.40%, Mn:1.25%, P:0.010%, S:0.002%, Cr:0.30%,
Mo:0.25%, V:0.045%, Ti:0.015%, B:0.0018%, Ceq:0.50%, surplus are Fe and inevitable impurity.
The quenched thin plate production method of the present embodiment Q690 intensity rank low yield strength ratio includes smelting ingredient, the refining of LF furnace, VD
Vacuum refining, heating, heat treatment procedure, specific process step are as described below:
(1) burden process is smelted: using the fine fodder that must not be incorporated briquetting, slag steel, packet bottom, useless ingot mould, Xin Bao, big fettling and the working of a furnace
When abnormal, this steel grade must not be smelted;Ladle baking is good, and 950 DEG C of baking temperature;Tapping cannot be shown in slag, tapping temperature
1660 DEG C, C:0.07% in molten steel;
(2) LF furnace refining procedure: whole process guarantees that Argon is good, refines the total refining time 60min of white slag retention time 36min, LF,
Aluminum steel dosage 2.4kg/t steel, lime consumption 20kg/t steel, ferrosilicon deoxidier dosage 2.8kg/t steel, process aluminium content 0.022%,
It skims aluminium 0.028%, refining terminates S:0.004%;
(3) VD vacuum refining process: Ca-Si block 1.50kg/t steel is added before vacuum by vacuum degree 62Pa, retention time 30min, takes out
Argon soft blow time 8min when vacuum is not mended after vacuum and is fed Al line;
(4) heating process: 1250 DEG C of maximum heating temperature, 1225 DEG C of soaking section temperature, soaking zone soaking time 70min, heating
Time coefficient 11min/mm;
(5) heat treatment procedure: 885 DEG C of hardening heat, the cool time: 42min;630 DEG C of tempering temperature, cool time 55min.
The present embodiment Q690 intensity rank low yield strength ratio quenched thin plate yield strength 749MPa, tensile strength 803MPa are bent
Strong ratio 0.93, elongation percentage 19%;- 40 DEG C of impact of collision function 148,187,111J.
The above embodiments are only used to illustrate and not limit the technical solutions of the present invention, although referring to above-described embodiment to this hair
It is bright to be described in detail, those skilled in the art should understand that: still the present invention can be modified or be waited
With replacement, without departing from the spirit or scope of the invention, or any substitutions, should all cover in power of the invention
In sharp claimed range.
Claims (10)
1. a kind of quenched thin plate of 8mm thickness Q690 intensity rank low yield strength ratio, which is characterized in that thin plate chemical component composition and
Its mass percentage are as follows: C:0.16~0.18%, Si:0.20~0.40%, Mn:1.15~1.25%, P≤0.015%, S≤
0.005%, Cr:0.20~0.30%, Mo:0.15~0.25%, V:0.035~0.045%, Ti:0.010~0.015%, B:
0.0008~0.0018%, surplus is Fe and inevitable impurity.
2. a kind of quenched thin plate of 8mm thickness Q690 intensity rank low yield strength ratio according to claim 1, which is characterized in that institute
State thin plate Ceq:0.43~0.50%.
3. a kind of quenched thin plate of 8mm thickness Q690 intensity rank low yield strength ratio according to claim 1, which is characterized in that institute
Stating lamella thickness specification is 8mm.
4. a kind of quenched thin plate of 8mm thickness Q690 intensity rank low yield strength ratio according to claim 1, which is characterized in that institute
State thin plate yield tensile ratio≤0.95.
5. a kind of life of the quenched thin plate of 8mm thickness Q690 intensity rank low yield strength ratio according to any one of claims 1-4
Production method, which is characterized in that the production method includes smelting ingredient, the refining of LF furnace, VD vacuum refining, heating, heat treatment work
Sequence;The heat treatment procedure, using medium temperature quenching+tempering technique, 875~885 DEG C of hardening heat.
6. a kind of production method of the quenched thin plate of 8mm thickness Q690 intensity rank low yield strength ratio according to claim 5, special
Sign is, the heat treatment procedure, 875~885 DEG C of hardening heat, the cool time: 40~42min;Tempering temperature 620~630
DEG C, 50~55min of tempering time.
7. a kind of production method of the quenched thin plate of 8mm thickness Q690 intensity rank low yield strength ratio according to claim 5, special
Sign is, the smelting burden process, baking temperature of steel ladle >=900 DEG C;Slag cannot be seen by tapping, 1600 DEG C of tapping temperature >, steel
C≤0.10% in water.
8. the life of the quenched thin plate of a kind of 8mm thickness Q690 intensity rank low yield strength ratio according to claim 5-7 any one
Production method, which is characterized in that the LF furnace refining procedure, whole process guarantee that Argon is good, refining white slag retention time >=30min,
Total refining time >=the 55min of LF, aluminum steel dosage >=1.8kg/t steel, lime consumption >=17kg/t steel, ferrosilicon deoxidier dosage >=
2kg/t steel, process aluminium content >=0.015%, aluminium >=0.020% of skimming, refining terminate S≤0.005%.
9. the life of the quenched thin plate of a kind of 8mm thickness Q690 intensity rank low yield strength ratio according to claim 5-7 any one
Production method, which is characterized in that the vacuum refining process, 55~62Pa of vacuum degree, retention time >=20min are added before vacuum
Ca-Si block >=1.5kg/t steel, argon gas soft blow time >=5min when vacuumizing are turned over so that the top of the slag is micro-, subject to molten steel is not exposed, vacuum
Do not allow to mend afterwards and feeds Al line.
10. the life of the quenched thin plate of a kind of 8mm thickness Q690 intensity rank low yield strength ratio according to claim 5-7 any one
Production method, which is characterized in that the heating process, 1250 DEG C of maximum heating temperature, 1220~1240 DEG C of soaking section temperature, soaking
Section soaking time >=60min, heating time coefficient >=10min/mm.
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CN111020399A (en) * | 2019-12-12 | 2020-04-17 | 舞阳钢铁有限责任公司 | Normalized air-cooled steel plate with long-time die welding performance and production method thereof |
CN111020351A (en) * | 2019-12-12 | 2020-04-17 | 舞阳钢铁有限责任公司 | Low-carbon steel plate with excellent low-temperature impact toughness and welding performance and production method thereof |
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