CN109135947A - A kind of cleaning solution and preparation method thereof for books cleaning - Google Patents
A kind of cleaning solution and preparation method thereof for books cleaning Download PDFInfo
- Publication number
- CN109135947A CN109135947A CN201811233877.XA CN201811233877A CN109135947A CN 109135947 A CN109135947 A CN 109135947A CN 201811233877 A CN201811233877 A CN 201811233877A CN 109135947 A CN109135947 A CN 109135947A
- Authority
- CN
- China
- Prior art keywords
- parts
- cleaning
- keratin
- distilled water
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of cleaning solutions and preparation method thereof for books cleaning, raw material is as follows: surfactant, chitosan graft keratin/vinal powder, polyvinylpyrrolidone, carboxymethyl cellulose, sodium citrate, defoaming agent, Rosemary Oil, distilled water, steps are as follows: 1) pretreatment steaming distilled water is made through handling in distilled water；2 will be added in pretreatment steaming distilled water after polyvinylpyrrolidone, carboxymethyl cellulose, sodium citrate, surfactant mixing, obtained solution A after heating stirring dissolution；3) it is added in solution A after mixing defoaming agent, Rosemary Oil and chitosan graft keratin/vinal powder, high-speed stirred is carried out after heating, can be prepared by after cooling.Cleaning solution prepared by the present invention, preparation process is simple, easy to operate, selected raw material no pollution to the environment, and the waste liquid after cleaning can satisfy environment protection emission requirement, and cleaning ability is strong, cleaning speed is fast, validity period is long convenient for processing.
Description
Technical field
The invention belongs to books cleaning technique fields, and in particular to a kind of cleaning solution and its preparation side for books cleaning
Method.
Background technique
Before more than 2000 years after papermaking technology invention, human civilization produces major transformation, paper as write, printing
Carrier plays always log history, transmitting message, the key player for continuing cultural essence.However, books had been used for a long time
Cheng Zhong leads to paper jaundice mildew, damaged, dirt due to factors such as mould growth, gas pickling, mechanical wear, dust coverings
Mark is had one's face covered with, the strong influence use of books.With the increasing pair of books access times, regularly guarantor of the maintenance washes to books
Shield is particularly important.Existing cleaning solution purity is lower, impurity content is high, the pollutant and fiber ageing products to paper
Elimination effect is poor, and certain damage can be caused to paper, to be unfavorable for the protection of books.Therefore, to cleaning solution into
Row in-depth study improves the protection to paper while improving its cleaning ability, is a urgent problem to be solved.
Summary of the invention
The purpose of the present invention is be directed to existing problem, provide it is a kind of for books cleaning cleaning solution and its preparation side
Method.
The present invention is achieved by the following technical solutions:
A kind of cleaning solution for books cleaning, by weight component are as follows: 2-4 parts of surfactant, chitosan graft angle egg
White/3-5 parts of vinal powder, 3-4 parts of polyvinylpyrrolidone, 2-3 parts of carboxymethyl cellulose, 1-3 parts of sodium citrate,
1-2 parts of defoaming agent, 1-2 parts of Rosemary Oil, 150-200 parts of distilled water.
Preferably, a kind of cleaning solution for books cleaning, wherein the surfactant is non-ionic surface active
Agent is selected from one or both of fatty glyceride, fatty acid sorbitan, polysorbate.
Preferably, a kind of cleaning solution for books cleaning, wherein the defoaming agent is organic silicon defoaming agent, is selected from
One or both of dimethyl silicone polymer, silicone emulsion, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether.
Preferably, a kind of cleaning solution for books cleaning, wherein the chitosan graft keratin/polyvinyl alcohol is fine
Tie up powder the preparation method is as follows:
1) it takes 4-8 parts of formic acid to be added in the distilled water that 3-5 times is measured, formic acid solution is made, then takes 3-5 parts of keratin to be added to
In formic acid solution, keratin formic acid solution is made after stirring and dissolving；
2) 2-3 parts of chitosan are taken, is added in keratin formic acid solution, stirring is heated to 60-65 DEG C after its dissolution, adds
Enter 1-2 parts of ammonium persulfate and isothermal holding 10-15min, then cool the temperature to 40-45 DEG C, polyvinyl alcohol 2-4 parts and mistake is added
Diisopropylbenzene (DIPB) 1-2 parts of oxidation stirs 10-15min in the case where revolving speed is 50-70r/min, then heats to 70-90 DEG C, isothermal reaction
2-3h；
3) to after reaction, nanofiber is made through electrostatic spinning machine in product, is then pulverized, obtained keratin/
Vinal powder, partial size are 10-15 μm.
A kind of preparation method of the cleaning solution for books cleaning, the specific steps are as follows:
1) distilled water is cut with the flow velocity of 2.5-3.0m/s along the vertical direction of the magnetic line of force after ion-exchange treatment, is made
Pretreatment steaming distilled water, wherein magnetic induction intensity is 4000-6000GS's；
2 will be added to pretreatment distillation after polyvinylpyrrolidone, carboxymethyl cellulose, sodium citrate, surfactant mixing
In water, it is heated to 60-65 DEG C, stirring is to being completely dissolved, obtained solution A；
3) solution A is added to after mixing defoaming agent, Rosemary Oil and chitosan graft keratin/vinal powder
In, it is heated to 70-80 DEG C, 4-8min is stirred in the case where revolving speed is 2000-4000r/min, can be prepared by after being cooled to room temperature.
Preferably, a kind of preparation method of the cleaning solution for books cleaning, wherein in step 1), the ion exchange
Processing is that distilled water is passed through to anion and cation exchange resin respectively to carry out replacement Treatment to the various anions and canons in water.
The present invention has the advantage that compared with prior art
1. cleaning solution prepared by the present invention, preparation process is simple, easy to operate, selected raw material no pollution to the environment, cleaning
Waste liquid afterwards can satisfy environment protection emission requirement convenient for processing, and the cleaning solution cleaning ability is strong, cleaning speed is fast, validity period is long,
It is wet to make paper surface, and can effectively change the boundary between spot and paper for the surface tension that water can be significantly reduced
Planar condition makes spot emulsification, dispersion, is easily removed, meanwhile, bacteriostatic film can be formed in paper surface, can not only inhibited
The growth of paper surface bacterium, prevents paper from going mouldy, but also paper can be prevented to turn to be yellow because of oxidation.
2. cleaning solution prepared by the present invention, firstly, the pure of distilled water can be improved through ion-exchange treatment in distilled water
Degree reduces ion concentration, so that the ability for dissolving other ions is received in enhancing, cleaning ability is improved, then by distilled water through magnetic
Change processing can make the macromolecular of association chain originally fragment into single small molecule, the dipole moment of hydrone is made to deflect, increase
The dipole moment of big hydrone increases the attraction of itself and other ions, to further increase cleaning ability；Secondly, shell is poly-
Sugar grafting keratin/vinal powder is the effect in initiator ammonium persulfate and crosslinking agent cumyl peroxide
Under, graft reaction occurs for chitosan and keratin, the compound then formed with polyvinyl alcohol the, due to-NH in chitosan3 +With
There is strong interaction between bacterium, there is very strong antibiotic property can increase-NH on keratin by graft reaction3 +Base
Group's quantity, thus assign keratin excellent antibiotic property, meanwhile, the compound formed after reacted with polyvinyl alcohol is in carboxymethyl
Chitosan graft keratin/vinal film can be formed under the action of cellulose, being covered on paper surface can mention
The flexibility and intensity of high paper, to help to enhance the protection to paper；Finally, defoaming agent can effectively reduce cleaning
The appearance of foam in the process, the fragranced of cleaning agent then can be improved in Rosemary Oil, while can also make the paper through over cleaning
It opens and distributes cool smell, facilitate the brain cell for activating reader, keep reader clearheaded, have the function of restoring consciouness.
Specific embodiment
Below with reference to specific implementation method, the present invention is described further.
Embodiment 1
A kind of cleaning solution for books cleaning, by weight component are as follows: 2 parts of surfactant, chitosan graft keratin/
3 parts of vinal powder, 3 parts of polyvinylpyrrolidone, 2 parts of carboxymethyl cellulose, 1 part of sodium citrate, 1 part of defoaming agent,
1 part of Rosemary Oil, 150 parts of distilled water.
Preferably, wherein, the surfactant is nonionic surfactant, it is selected from fatty glyceride, fat
Sour sorb is smooth, one or both of polysorbate.
Preferably, wherein, the defoaming agent is organic silicon defoaming agent, selected from dimethyl silicone polymer, silicone emulsion,
One or both of polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether.
Preferably, wherein, the chitosan graft keratin/vinal powder the preparation method is as follows:
1) it takes in 4 parts of the formic acid distilled water for being added to 3 times of amounts, formic acid solution is made, then taking 3 parts of keratin, to be added to formic acid molten
In liquid, keratin formic acid solution is made after stirring and dissolving；
2) 2 parts of chitosan are taken, is added in keratin formic acid solution, stirring is heated to 60 DEG C after its dissolution, is added
Then 1-2 parts of ammonium sulfate and isothermal holding 15min cool the temperature to 40 DEG C, 2 parts of polyvinyl alcohol and cumyl peroxide is added
1 part, 15min is stirred in the case where revolving speed is 50r/min, then heats to 70 DEG C, isothermal reaction 3h；
3) to after reaction, nanofiber is made through electrostatic spinning machine in product, is then pulverized, obtained keratin/
Vinal powder, partial size are 10 μm.
A kind of preparation method of the cleaning solution for books cleaning, the specific steps are as follows:
1) distilled water is cut with the flow velocity of 2.5m/s along the vertical direction of the magnetic line of force after ion-exchange treatment, pre- place is made
Distilled water is managed, wherein magnetic induction intensity is 4000GS's；
2 will be added to pretreatment distillation after polyvinylpyrrolidone, carboxymethyl cellulose, sodium citrate, surfactant mixing
In water, it is heated to 60 DEG C, stirring is to being completely dissolved, obtained solution A；
3) solution A is added to after mixing defoaming agent, Rosemary Oil and chitosan graft keratin/vinal powder
In, 70 DEG C are heated to, 8min is stirred in the case where revolving speed is 2000r/min, can be prepared by after being cooled to room temperature.
Preferably, wherein, in step 1), the ion-exchange treatment is to hand over distilled water by anions and canons respectively
It changes resin and replacement Treatment is carried out to the various anions and canons in water.
Embodiment 2
A kind of cleaning solution for books cleaning, by weight component are as follows: 3 parts of surfactant, chitosan graft keratin/
4 parts of vinal powder, 3.5 parts of polyvinylpyrrolidone, 2.5 parts of carboxymethyl cellulose, 2 parts of sodium citrate, defoaming agent
1.5 parts, 1.5 parts of Rosemary Oil, 170 parts of distilled water.
Preferably, wherein, the surfactant is nonionic surfactant, it is selected from fatty glyceride, fat
Sour sorb is smooth, one or both of polysorbate.
Preferably, wherein, the defoaming agent is organic silicon defoaming agent, selected from dimethyl silicone polymer, silicone emulsion,
One or both of polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether.
Preferably, wherein, the chitosan graft keratin/vinal powder the preparation method is as follows:
1) it takes in 6 parts of the formic acid distilled water for being added to 4 times of amounts, formic acid solution is made, then taking 4 parts of keratin, to be added to formic acid molten
In liquid, keratin formic acid solution is made after stirring and dissolving；
2) 2.5 parts of chitosan are taken, is added in keratin formic acid solution, stirring is heated to 63 DEG C after its dissolution, is added
Then 1.5 parts of ammonium persulfate and isothermal holding 13min cool the temperature to 43 DEG C, 3 parts of polyvinyl alcohol and peroxidating diisopropyl is added
1.5 parts of benzene, 13min is stirred in the case where revolving speed is 60r/min, then heats to 80 DEG C, isothermal reaction 2.5h；
3) to after reaction, nanofiber is made through electrostatic spinning machine in product, is then pulverized, obtained keratin/
Vinal powder, partial size are 12 μm.
A kind of preparation method of the cleaning solution for books cleaning, the specific steps are as follows:
1) distilled water is cut with the flow velocity of 2.7m/s along the vertical direction of the magnetic line of force after ion-exchange treatment, pre- place is made
Distilled water is managed, wherein magnetic induction intensity is 5000GS's；
2 will be added to pretreatment distillation after polyvinylpyrrolidone, carboxymethyl cellulose, sodium citrate, surfactant mixing
In water, it is heated to 63 DEG C, stirring is to being completely dissolved, obtained solution A；
3) solution A is added to after mixing defoaming agent, Rosemary Oil and chitosan graft keratin/vinal powder
In, 75 DEG C are heated to, 5min is stirred in the case where revolving speed is 3000r/min, can be prepared by after being cooled to room temperature.
Preferably, wherein, in step 1), the ion-exchange treatment is to hand over distilled water by anions and canons respectively
It changes resin and replacement Treatment is carried out to the various anions and canons in water.
Embodiment 3
A kind of cleaning solution for books cleaning, by weight component are as follows: 4 parts of surfactant, chitosan graft keratin/
5 parts of vinal powder, 4 parts of polyvinylpyrrolidone, 3 parts of carboxymethyl cellulose, 3 parts of sodium citrate, 2 parts of defoaming agent,
2 parts of Rosemary Oil, 200 parts of distilled water.
Preferably, wherein, the surfactant is nonionic surfactant, it is selected from fatty glyceride, fat
Sour sorb is smooth, one or both of polysorbate.
Preferably, wherein, the defoaming agent is organic silicon defoaming agent, selected from dimethyl silicone polymer, silicone emulsion,
One or both of polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether.
Preferably, wherein, the chitosan graft keratin/vinal powder the preparation method is as follows:
1) it takes in 8 parts of the formic acid distilled water for being added to 5 times of amounts, formic acid solution is made, then takes keratin 5 part to be added to formic acid molten
In liquid, keratin formic acid solution is made after stirring and dissolving；
2) 3 parts of chitosan are taken, is added in keratin formic acid solution, stirring is heated to 65 DEG C after its dissolution, is added
Then 2 parts of ammonium sulfate and isothermal holding 10min cool the temperature to 45 DEG C, 4 parts of polyvinyl alcohol and cumyl peroxide 2 is added
Part, 10min is stirred in the case where revolving speed is 70r/min, then heats to 90 DEG C, isothermal reaction 2h；
3) to after reaction, nanofiber is made through electrostatic spinning machine in product, is then pulverized, obtained keratin/
Vinal powder, partial size are 15 μm.
A kind of preparation method of the cleaning solution for books cleaning, the specific steps are as follows:
1) distilled water is cut with the flow velocity of 3.0m/s along the vertical direction of the magnetic line of force after ion-exchange treatment, pre- place is made
Distilled water is managed, wherein magnetic induction intensity is 6000GS's；
2 will be added to pretreatment distillation after polyvinylpyrrolidone, carboxymethyl cellulose, sodium citrate, surfactant mixing
In water, it is heated to 65 DEG C, stirring is to being completely dissolved, obtained solution A；
3) solution A is added to after mixing defoaming agent, Rosemary Oil and chitosan graft keratin/vinal powder
In, 80 DEG C are heated to, 4min is stirred in the case where revolving speed is 4000r/min, can be prepared by after being cooled to room temperature.
Preferably, wherein, in step 1), the ion-exchange treatment is to hand over distilled water by anions and canons respectively
It changes resin and replacement Treatment is carried out to the various anions and canons in water.
Comparative example 1: the ion-exchange treatment step in removal step 1), remaining is same as Example 1.
Comparative example 2: the magnetization treatment step in removal step 1), remaining is same as Example 1.
Comparative example 3: the surfactant in removal step 2, remaining is same as Example 1.
Comparative example 4: chitosan graft keratin/vinal powder in removal step 3), remaining and embodiment 1
It is identical.
Test example: padding a upper blotting paper in the paper for speckling with spot of the same race respectively below, so uses embodiment 1-3 respectively
Spot is soaked with the comparative example 1-4 cleaning agent provided, a blotting paper is then put on paper, observes paper after water stain disappearance
The cleaning situation opened in the environment of books are then put into 25 DEG C of temperature, humidity 75% again, observes the mildew feelings of books after a week
Condition is placed under daylight etc. after finally again spreading books out and is irradiated, intensity of illumination 1500lx, and paper is observed after three months
Jaundice situation, control group select commercially available general books cleaning agent, and record result is as shown in Table 1:
Table one
As can be seen from Table I, cleaning agent provided by the invention not only can effectively remove the spot on books, but also clean
Speed is fast, and books have good antibacterial property and inoxidizability after over cleaning.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
It transforms or replaces, should be covered by the scope of protection of the present invention without what creative work was expected.
Claims (6)
1. a kind of cleaning solution for books cleaning, which is characterized in that component is as follows by weight: 2-4 parts of surfactant, shell
Glycan is grafted keratin/3-5 parts of vinal powder, 3-4 parts of polyvinylpyrrolidone, 2-3 parts of carboxymethyl cellulose, lemon
1-3 parts of lemon acid sodium, 1-2 parts of defoaming agent, 1-2 parts of Rosemary Oil, 150-200 parts of distilled water.
2. a kind of cleaning solution for books cleaning as described in claim 1, which is characterized in that the surfactant is non-
Ionic surface active agent is selected from one or both of fatty glyceride, fatty acid sorbitan, polysorbate.
3. a kind of cleaning solution for books cleaning as described in claim 1, which is characterized in that the defoaming agent is organosilicon
Class defoaming agent, in dimethyl silicone polymer, silicone emulsion, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether
It is one or two kinds of.
4. a kind of cleaning solution for books cleaning as described in claim 1, which is characterized in that chitosan graft angle egg
White/vinal powder the preparation method is as follows:
1) it takes 4-8 parts of formic acid to be added in the distilled water that 3-5 times is measured, formic acid solution is made, then takes 3-5 parts of keratin to be added to
In formic acid solution, keratin formic acid solution is made after stirring and dissolving；
2) 2-3 parts of chitosan are taken, is added in keratin formic acid solution, stirring is heated to 60-65 DEG C after its dissolution, adds
Enter 1-2 parts of ammonium persulfate and isothermal holding 10-15min, then cool the temperature to 40-45 DEG C, polyvinyl alcohol 2-4 parts and mistake is added
Diisopropylbenzene (DIPB) 1-2 parts of oxidation stirs 10-15min in the case where revolving speed is 50-70r/min, then heats to 70-90 DEG C, isothermal reaction
2-3h；
3) to after reaction, fiber is made through electrostatic spinning machine in product, is then pulverized, be can be prepared by chitosan grafted
Branch keratin/vinal powder, partial size are 10-15 μm.
5. a kind of preparation method for the cleaning solution of books cleaning as described in claim 1, which is characterized in that specific steps
It is as follows:
1) distilled water is cut with the flow velocity of 2.5-3.0m/s along the vertical direction of the magnetic line of force after ion-exchange treatment, is made
Pretreatment steaming distilled water, wherein magnetic induction intensity is 4000-6000GS's；
2 will be added to pretreatment distillation after polyvinylpyrrolidone, carboxymethyl cellulose, sodium citrate, surfactant mixing
In water, it is heated to 60-65 DEG C, stirring is to being completely dissolved, obtained solution A；
3) solution A is added to after mixing defoaming agent, Rosemary Oil and chitosan graft keratin/vinal powder
In, it is heated to 70-80 DEG C, 4-8min is stirred in the case where revolving speed is 2000-4000r/min, can be prepared by after being cooled to room temperature.
6. a kind of preparation method of cleaning solution for books cleaning as claimed in claim 5, which is characterized in that step 1)
In, the ion-exchange treatment be distilled water is passed through respectively anion and cation exchange resin to the various anions and canons in water into
Line replacement processing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811233877.XA CN109135947A (en) | 2018-10-23 | 2018-10-23 | A kind of cleaning solution and preparation method thereof for books cleaning |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811233877.XA CN109135947A (en) | 2018-10-23 | 2018-10-23 | A kind of cleaning solution and preparation method thereof for books cleaning |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109135947A true CN109135947A (en) | 2019-01-04 |
Family
ID=64809424
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811233877.XA Withdrawn CN109135947A (en) | 2018-10-23 | 2018-10-23 | A kind of cleaning solution and preparation method thereof for books cleaning |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109135947A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109735948A (en) * | 2019-01-07 | 2019-05-10 | 合肥必更赢科技有限公司 | Preparation, the application of a kind of casein-chitosan composite fiber and its fabric |
| CN113930857A (en) * | 2021-11-08 | 2022-01-14 | 天津科技大学 | Slow-release antibacterial electrostatic spinning nanofiber and preparation method thereof |
-
2018
- 2018-10-23 CN CN201811233877.XA patent/CN109135947A/en not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109735948A (en) * | 2019-01-07 | 2019-05-10 | 合肥必更赢科技有限公司 | Preparation, the application of a kind of casein-chitosan composite fiber and its fabric |
| CN109735948B (en) * | 2019-01-07 | 2021-04-06 | 山东安琪尔生活科技有限公司 | Preparation and application of casein-chitosan composite fiber and fabric thereof |
| CN113930857A (en) * | 2021-11-08 | 2022-01-14 | 天津科技大学 | Slow-release antibacterial electrostatic spinning nanofiber and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109135947A (en) | A kind of cleaning solution and preparation method thereof for books cleaning | |
| US2957785A (en) | Aqueous metastable dispersion of tetravalent organo-tin compounds treating process | |
| Pereira et al. | Environmentally friendly bleaching of cotton using laccases | |
| JPS6391106A (en) | Defoaming agent for aqueous system and its use | |
| WO2002095122A1 (en) | Hydrophobically modified polyethylenimines and polyvinylamines for wrinkle-resistant finishing of textiles containing cellulose | |
| US10094049B2 (en) | Fabricating method for spunbond nonwoven from natural cellulose fiber blended with nano silver | |
| PT88507B (en) | PROCESS FOR INTRODUCING VARIACS OF COLOR INTENSITY IN CELLULOSE FABRICS, ESPECIALLY IN TINGIDA GANGA WITH INDIGO | |
| CN1973027A (en) | Cleanser for organiac/inorganic complex stains and method of cleaning artificial dialyzer | |
| GB2095285A (en) | Drying textiles skins pelts or leather | |
| JPH0325549B2 (en) | ||
| CN100510064C (en) | Novel laccase enzyme and gene encoding the enzyme | |
| CN103025951A (en) | Method for producing antibacterial fibers, antibacterial fibers and antibacterial processing agent for fibers | |
| CN102471995A (en) | Method for producing dyed polyester fibers and scouring/dyeing assistant | |
| CN106638054A (en) | Terylene reduction cleaning agent and preparation method thereof | |
| CN108774891A (en) | A kind of cotton environment-friendly high-efficiency scouring agent and preparation method thereof | |
| AU663913B2 (en) | A method for the treatment of wool | |
| US4118324A (en) | Fabric softeners | |
| JP2017114967A (en) | Liquid detergent composition for clothing | |
| JP2017031532A (en) | Liquid softener composition | |
| JP5281257B2 (en) | Washing method | |
| US20130111674A1 (en) | Treatment of keratinous fibers with an enzyme having perhydrolase activity | |
| US5855622A (en) | Hydrogen peroxide-containing bleach liquor and bleaching method thereby | |
| CN110257182A (en) | A kind of hyperconcetration fabric washing coagulates pearl and preparation method | |
| EP1593774A2 (en) | Ironing aid composition with nanoparticles | |
| US2730503A (en) | Detergent and brightening composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190104 |