CN109135456A - A kind of water mildow-proof coating - Google Patents
A kind of water mildow-proof coating Download PDFInfo
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- CN109135456A CN109135456A CN201810936616.8A CN201810936616A CN109135456A CN 109135456 A CN109135456 A CN 109135456A CN 201810936616 A CN201810936616 A CN 201810936616A CN 109135456 A CN109135456 A CN 109135456A
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- Prior art keywords
- proof coating
- parts
- water
- mould
- mildow
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a kind of water mildow-proof coating, the water mildow-proof coating includes the component of following weight percentage: modified rhoplex 20-50%, titanium dioxide 5-10%, talcum powder 5-10%, powdered whiting 5-10%, composite microcapsule mould inhibitor 1-2%, dispersing agent 0.1-0.2%, wetting agent 1-2%, preservative 1-2%, thickener 1-2%, levelling agent 1-2%, surplus are deionized water.The composite microcapsule mould inhibitor of the embodiment of the present invention is used in combination with mould proof effective component and mould proof synergistic component, anti-mold effect enhancing, with floating mould mattress spore in long-acting inhibition air, reach long-acting mould-proof effect, the water mildow-proof coating of the embodiment of the present invention passes through composite microcapsule mould inhibitor and other additive compounds, the compatibility of each raw material is good, not only has excellent, lasting anti-mold effect, while gained film has good washability ability and adhesion performance.Production cost of the embodiment of the present invention is low, simple process, easy to industrialized production, has good market future.
Description
Technical field
The present invention relates to technical field of coatings, and in particular to a kind of water mildow-proof coating.
Background technique
In recent years, rapidly developed as the water paint of one of ornament materials, water paint refer to made with water it is molten
Agent or the coating for making decentralized medium, water paint also typically include polymeric dispersions, pigment, filler and various additives etc.
Ingredient causes water paint easily to grow mould before and after coating due to microorganism abundant in nature, and it is existing that mildew occurs
As destroying coating performance and structure, so that coating phenomena such as cracking, adherency is pitched, color spot, blistering, slabbing is occurred, seriously affect painting
The beauty of layer, makes it lose decoration and protective effect, reduces the service life of coating, also pollutes to environment bring.
Therefore, it is destroyed to efficiently reduce microorganism bring, mould inhibitor can be added in water paint, to reach
To the microorganism killed in water paint, breeding of the mould rotten quasi-microorganism in coating material production, storage and application is prevented, protection applies
Material is not destroyed.
Existing coating adds mould inhibitor, and the fungicidal properties of water paint can be improved to a certain extent, but exists anti-
The defect that mouldiness energy is bad, fungicidal properties is vulnerable.
In view of this, proposing the present invention.
Summary of the invention
Of the existing technology in order to solve the problems, such as, the embodiment of the present invention is designed to provide a kind of water mildow-proof painting
Material.
To achieve the above object, the embodiment of the present invention provides a kind of water mildow-proof coating, and the water mildow-proof coating includes
The component of following weight percentage: modified rhoplex 20-50%, titanium dioxide 5-10%, talcum powder 5-10%, heavy
Calcium carbonate 5-10%, composite microcapsule mould inhibitor 1-2%, dispersing agent 0.1-0.2%, wetting agent 1-2%, preservative 1-2%,
Thickener 1-2%, levelling agent 1-2%, surplus are deionized water.
Further, the composite microcapsule mould inhibitor is made of the component of following parts by weight: GNCE5700-JS is anti-
Mould dose 18-22 parts, 20-25 parts of WS-098 daconil M, 1.5-3 parts of metopycide, dimethoxy methyl benzyl ammonia it is phonetic
0.8-1.2 parts of pyridine, 4-7 parts of emulsifier, deacetylation 32-40 parts of 12-18 parts of chitin, pure water.
Further, the composite microcapsule mould inhibitor the preparation method comprises the following steps: weigh each component of corresponding parts by weight,
It is mixed and heated to 70-90 DEG C, the material after homogeneous is spray-dried by emulsifying homogeneous, obtains raw material powder, then by raw material
Powder is cooled to 30-35 DEG C, obtains the composite microcapsule mould inhibitor that partial size is 2-4 μm.
Further, the spray drying carries out in spray dryer, and the inlet air temperature of spray dryer is 120-140
DEG C, leaving air temp is 70-80 DEG C.
Further, the dispersing agent is selected from any one of calcium phosphate, lauryl sodium sulfate, methyl anyl alcohol.
Further, the wetting agent is selected from any one of propylene glycol, ethyl alcohol, glycerol.
Further, the preservative is selected from isothiazolinone derivatives, benzimidazole esters, Dao Weixier -75,1,2-
Any one of benzisothiazole-3-ketone.
Further, the thickener is selected from any one of organobentonite, metallic soap, hydrogenated castor oil.
Further, the levelling agent appointing in fluorine-containing surfactant, acrylate and polyvinyl butyral
It is a kind of.
Further, the water mildow-proof coating preparation method the following steps are included:
1) each component is weighed according to the weight ratio, it is spare;
2) be added deionized water in agitator tank, under stirring condition, sequentially add modified rhoplex, titanium dioxide,
Talcum powder, powdered whiting, composite microcapsule mould inhibitor, dispersing agent, wetting agent, preservative, thickener, levelling agent, until
The uniform soilless sticking of system is to get water mildow-proof coating.
The embodiment of the present invention has the advantages that
1, the composite microcapsule mould inhibitor of the embodiment of the present invention is with GNCE5700-JS mould inhibitor and WS-098 tetrachloro isophthalic
Dintrile is mould proof effective component, with metopycide and dimethoxy methyl benzyl Aminometradine for mould proof synergistic component, the two connection
It closes and uses, the composite microcapsule robust consistent with fine and close film forming layer, tool is made by spray reactor in anti-mold effect enhancing
Have in long-acting inhibition air and float mould mattress spore, reach long-acting mould-proof effect, oneself tried out in food industry workshop, up to 5 years or more
It is not mouldy.
2, the water mildow-proof coating of the embodiment of the present invention passes through composite microcapsule mould inhibitor and other additive compounds, each original
The compatibility of material is good, not only have excellent, lasting anti-mold effect, while gained film have good washability ability and
Adhesion performance.
3, production cost of the embodiment of the present invention is low, simple process, easy to industrialized production, has good market future.
Specific embodiment
The following examples are used to illustrate the present invention, but are not intended to limit the scope of the present invention..It is not specified in embodiment specific
Condition person carries out according to conventional conditions or manufacturer's recommended conditions.Production firm person is not specified in all reagents or instrument, is
The conventional products that can be obtained by commercially available purchase.
Embodiment 1
The water mildow-proof coating of the present embodiment includes: modified rhoplex 42kg, titanium dioxide 6.3kg, talcum powder
7.5kg, powdered whiting 8.2kg, composite microcapsule mould inhibitor 1.1kg, dispersing agent 0.1kg, wetting agent 1.8kg, preservative
1.2kg, thickener 1kg, levelling agent 1.5kg, deionized water 29.3kg.
Wherein, composite microcapsule mould inhibitor the preparation method comprises the following steps: weighing 20 parts of GNCE5700-JS mould inhibitor, WS-098
22 parts of daconil M, 2 parts of metopycide, 1 part of dimethoxy methyl benzyl Aminometradine, 5 parts of emulsifier, deacetylation
15 parts of chitin, 35 parts of pure water;80 DEG C are mixed and heated to, emulsifying homogeneous, by the material after homogeneous in spray dryer
It is spray-dried, the inlet air temperature of spray dryer is 120 DEG C, and leaving air temp is 70 DEG C, obtains raw material powder, then by raw material
Powder is cooled to 30 DEG C, obtains the composite microcapsule mould inhibitor that partial size is 2 μm.
Dispersing agent is calcium phosphate;Wetting agent is propylene glycol;Preservative is isothiazolinone derivatives;Thickener is to add hydrogen castor
Sesame oil;Levelling agent is acrylate.
The preparation method of the water mildow-proof coating of the present embodiment the following steps are included:
1) each component is weighed according to the weight ratio, it is spare;
2) be added deionized water in agitator tank, under stirring condition, sequentially add modified rhoplex, titanium dioxide,
Talcum powder, powdered whiting, composite microcapsule mould inhibitor, dispersing agent, wetting agent, preservative, thickener, levelling agent, until
The uniform soilless sticking of system is to get water mildow-proof coating.
Performance test: abrasion resistance 7250 times (GB/T 9266-1988);1 grade of (GB/T 9286- of adhesive force grade
1998)。
Embodiment 2
The water mildow-proof coating of the present embodiment includes: modified rhoplex 28kg, titanium dioxide 9.2kg, talcum powder
10kg, powdered whiting 5.2kg, composite microcapsule mould inhibitor 1.8kg, dispersing agent 0.15kg, wetting agent 1kg, preservative
2kg, thickener 1.1kg, levelling agent 1kg, deionized water 40.55kg.
Wherein, composite microcapsule mould inhibitor the preparation method comprises the following steps: weighing 18 parts of GNCE5700-JS mould inhibitor, WS-098
24 parts of daconil M, 3 parts of metopycide, 0.8 part of dimethoxy methyl benzyl Aminometradine, 4 parts of emulsifier, deacetylation
16 parts of chitin, 38 parts of pure water;70 DEG C are mixed and heated to, emulsifying homogeneous, by the material after homogeneous in spray dryer
In be spray-dried, the inlet air temperature of spray dryer is 140 DEG C, and leaving air temp is 70 DEG C, obtains raw material powder, then will be former
Feed powder end is cooled to 35 DEG C, obtains the composite microcapsule mould inhibitor that partial size is 2.5 μm.
Dispersing agent is lauryl sodium sulfate;Wetting agent is ethyl alcohol;Preservative is benzimidazole esters;Thickener is organic
Bentonite;Levelling agent is fluorine-containing surfactant.
The preparation method is the same as that of Example 1 for the water mildow-proof coating of the present embodiment.
Performance test: abrasion resistance 6820 times (GB/T 9266-1988);1 grade of (GB/T 9286- of adhesive force grade
1998)。
Embodiment 3
The water mildow-proof coating of the present embodiment include: modified rhoplex 21kg, titanium dioxide 10kg, talcum powder 9kg,
Powdered whiting 10kg, composite microcapsule mould inhibitor 2kg, dispersing agent 0.18kg, wetting agent 1.5kg, preservative 1.5kg, increase
Thick dose of 2kg, levelling agent 2kg, deionized water 40.82kg.
Wherein, composite microcapsule mould inhibitor the preparation method comprises the following steps: weighing 21 parts of GNCE5700-JS mould inhibitor, WS-098
20 parts of daconil M, 3 parts of metopycide, 1.2 parts of dimethoxy methyl benzyl Aminometradine, 7 parts of emulsifier, deacetylation
12 parts of chitin, 32 parts of pure water;90 DEG C are mixed and heated to, emulsifying homogeneous, by the material after homogeneous in spray dryer
In be spray-dried, the inlet air temperature of spray dryer is 140 DEG C, and leaving air temp is 80 DEG C, obtains raw material powder, then will be former
Feed powder end is cooled to 35 DEG C, obtains the composite microcapsule mould inhibitor that partial size is 4 μm.
Dispersing agent is methyl anyl alcohol;Wetting agent is glycerol;Preservative is isothiazolinone derivatives;Thickener is metal
Soap;Levelling agent is polyvinyl butyral.
The preparation method is the same as that of Example 1 for the water mildow-proof coating of the present embodiment.
Performance test: abrasion resistance 6627 times (GB/T 9266-1988);1 grade of (GB/T 9286- of adhesive force grade
1998)。
Embodiment 4
The water mildow-proof coating of the present embodiment includes: modified rhoplex 49kg, titanium dioxide 5kg, talcum powder
5.2kg, powdered whiting 5.5kg, composite microcapsule mould inhibitor 1kg, dispersing agent 0.1kg, wetting agent 2kg, preservative 1kg,
Thickener 1kg, levelling agent 1kg, deionized water 29.2kg.
Wherein, composite microcapsule mould inhibitor the preparation method comprises the following steps: weighing 22 parts of GNCE5700-JS mould inhibitor, WS-098
It is 25 parts of daconil M, 1.5 parts of metopycide, 1.5 parts of dimethoxy methyl benzyl Aminometradine, 6 parts of emulsifier, deacetylated
40 parts of 15 parts of chitin, the pure water of degree;70 DEG C are mixed and heated to, the material after homogeneous is being spray-dried by emulsifying homogeneous
It is spray-dried in device, the inlet air temperature of spray dryer is 120 DEG C, and leaving air temp is 80 DEG C, obtains raw material powder, then will
Raw material powder is cooled to 30 DEG C, obtains the composite microcapsule mould inhibitor that partial size is 3 μm.
Dispersing agent is lauryl sodium sulfate;Wetting agent is propylene glycol;Preservative is 1,2-benzisothiazolin-3-one;
Thickener is hydrogenated castor oil;Levelling agent is fluorine-containing surfactant.
The preparation method is the same as that of Example 1 for the water mildow-proof coating of the present embodiment.
Performance test: abrasion resistance 7028 times (GB/T 9266-1988);1 grade of (GB/T 9286- of adhesive force grade
1998)。
Embodiment 5
The water mildow-proof coating of the present embodiment includes: modified rhoplex 36kg, titanium dioxide 7.2kg, talcum powder
6kg, powdered whiting 7.8kg, composite microcapsule mould inhibitor 1.5kg, dispersing agent 0.2kg, wetting agent 1.1kg, preservative
1.8kg, thickener 1.5kg, levelling agent 1.8kg, deionized water 35.1kg.
Wherein, composite microcapsule mould inhibitor the preparation method comprises the following steps: weighing 20 parts of GNCE5700-JS mould inhibitor, WS-098
21 parts of daconil M, 3 parts of metopycide, 1.2 parts of dimethoxy methyl benzyl Aminometradine, 7 parts of emulsifier, deacetylation
18 parts of chitin, 36 parts of pure water;90 DEG C are mixed and heated to, emulsifying homogeneous, by the material after homogeneous in spray dryer
In be spray-dried, the inlet air temperature of spray dryer is 130 DEG C, and leaving air temp is 70 DEG C, obtains raw material powder, then will be former
Feed powder end is cooled to 30 DEG C, obtains the composite microcapsule mould inhibitor that partial size is 2 μm.
Dispersing agent is methyl anyl alcohol;Wetting agent is glycerol;Preservative is Dao Weixier -75;Thickener is metallic soap;Levelling
Agent is acrylate.
The preparation method is the same as that of Example 1 for the water mildow-proof coating of the present embodiment.
Performance test: abrasion resistance 6940 times (GB/T 9266-1988);1 grade of (GB/T 9286- of adhesive force grade
1998)。
Comparative example 1
The composite microcapsule that the water mildow-proof coating of this comparative example is different from that of the embodiment 1 only in the following aspects: this comparative example is mould
Bacteria inhibitor is made of each component of following parts by weight: 24 parts of GNCE5700-JS mould inhibitor, WS-098 daconil M 6
Part, 5 parts of emulsifier, deacetylation 35 parts of 15 parts of chitin, pure water.
Performance test: abrasion resistance 5280 times (GB/T 9266-1988);1 grade of (GB/T 9286- of adhesive force grade
1998)。
Comparative example 2
The water mildow-proof coating of this comparative example is different from that of the embodiment 1 only in the following aspects: the composite microcapsule of this comparative example
Mould inhibitor is made of each component of following parts by weight: 16 parts of GNCE5700-JS mould inhibitor, WS-098 daconil M
18 parts, 4 parts of metopycide, 2 parts of dimethoxy methyl benzyl Aminometradine, 5 parts of emulsifier, deacetylation 15 parts of chitin,
35 parts of pure water.
Performance test: abrasion resistance 5650 times (GB/T 9266-1988);1 grade of (GB/T 9286- of adhesive force grade
1998)。
Comparative example 3
The water mildow-proof coating of this comparative example is different from that of the embodiment 1 only in the following aspects: the water mildow-proof of this comparative example
Coating includes the component of following weight percentage: modified rhoplex 55kg, titanium dioxide 6.3kg, talcum powder 7.5kg,
Powdered whiting 8.2kg, composite microcapsule mould inhibitor 1.1kg, dispersing agent 0.1kg, wetting agent 1.8kg, preservative 1.2kg,
Thickener 1kg, levelling agent 1.5kg, deionized water 16.3kg.
Performance test: abrasion resistance 3620 times (GB/T 9266-1988);2 grades of (GB/T 9286- of adhesive force grade
1998)。
Test case
The fungicidal properties of coating made from 1-5 of the embodiment of the present invention and comparative example 1-3 is tested.
Fungicide effectiveness test: such as coating or be sprayed at surface of glass slide according to this field usual manner for coating obtained, does
× the coating sample of (0.2-0.3mm) is formed having a size of 50mm × 50mm after dry.Culture includes Escherichia coli, black-koji mould, Huang
Aspergillus, discoloration mould, Penicillium citrinum, Trichoderma viride mould mix spore suspension, by mould mix spore suspension uniformly spray
On coating sample, the mildew size of sample is checked after temperature is 28 ± 2 DEG C, cultivates 14 days in the incubator of humidity >=90%
With mould area coverage, the mildew grade of sample is evaluated.
It tests to obtain the mildew grade of sample in 0 month, 3 months, 6 months, 12 months progress fungicide effectiveness respectively, test
It the results are shown in Table 1.
Table 1
Sample | 0 month | 1 month | 3 months | 6 months |
Embodiment 1 | 0 grade | 0 grade | 0 grade | 0 grade |
Embodiment 2 | 0 grade | 0 grade | 0 grade | 0 grade |
Embodiment 3 | 0 grade | 0 grade | 0 grade | 0 grade |
Embodiment 4 | 0 grade | 0 grade | 0 grade | 0 grade |
Embodiment 5 | 0 grade | 0 grade | 0 grade | 0 grade |
Comparative example 1 | 0 grade | 1 grade | 2 grades | 4 grades |
Comparative example 2 | 0 grade | 1 grade | 2 grades | 3 grades |
Comparative example 3 | 0 grade | 0 grade | 0 grade | 1 grade |
The result shows that: for the coating of the embodiment of the present invention compared to the coating of comparative example, fungus and mildew resistance performance is more excellent, holds
Long.
Although above having used general explanation and specific embodiment, the present invention is described in detail, at this
On the basis of invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Therefore,
These modifications or improvements without departing from theon the basis of the spirit of the present invention are fallen within the scope of the claimed invention.
Claims (10)
1. a kind of water mildow-proof coating, which is characterized in that the water mildow-proof coating includes the component of following weight percentage:
Modified rhoplex 20-50%, titanium dioxide 5-10%, talcum powder 5-10%, powdered whiting 5-10%, composite microcapsule are mould
Bacteria inhibitor 1-2%, dispersing agent 0.1-0.2%, wetting agent 1-2%, preservative 1-2%, thickener 1-2%, levelling agent 1-
2%, surplus is deionized water.
2. water mildow-proof coating according to claim 1, which is characterized in that the composite microcapsule mould inhibitor is by following
The component of parts by weight is made: 18-22 parts of GNCE5700-JS mould inhibitor, 20-25 parts of WS-098 daconil M, trimethoxy
1.5-3 parts of benzyl Aminometradine, 0.8-1.2 parts of dimethoxy methyl benzyl Aminometradine, 4-7 parts of emulsifier, deacetylation chitin 12-18
Part, 32-40 parts of pure water.
3. water mildow-proof coating according to claim 2, which is characterized in that the preparation of the composite microcapsule mould inhibitor
Method are as follows: each component for weighing corresponding parts by weight is mixed and heated to 70-90 DEG C, emulsifying homogeneous, by the material after homogeneous into
Row spray drying, obtains raw material powder, then raw material powder is cooled to 30-35 DEG C, and it is mould to obtain the composite microcapsule that partial size is 2-4 μm
Bacteria inhibitor.
4. water mildow-proof coating according to claim 3, which is characterized in that it is described spray drying in spray dryer into
Row, the inlet air temperature of spray dryer are 120-140 DEG C, and leaving air temp is 70-80 DEG C.
5. water mildow-proof coating according to claim 1, which is characterized in that the dispersing agent is selected from calcium phosphate, dodecane
Any one of base sodium sulphate, methyl anyl alcohol.
6. water mildow-proof coating according to claim 1, which is characterized in that the wetting agent is selected from propylene glycol, ethyl alcohol, sweet
Any one of oil.
7. water mildow-proof coating according to claim 1, which is characterized in that the preservative is derivative selected from isothiazolinone
Any one of object, benzimidazole esters, Dao Weixier -75,1,2-benzisothiazolin-3-one.
8. water mildow-proof coating according to claim 1, which is characterized in that the thickener is selected from organobentonite, gold
Belong to any one of soap, hydrogenated castor oil.
9. water mildow-proof coating according to claim 1, which is characterized in that the levelling agent is selected from fluorine-containing surfactants
Any one of agent, acrylate and polyvinyl butyral.
10. water mildow-proof coating according to claim 1, which is characterized in that the preparation method of the water mildow-proof coating
The following steps are included:
1) each component is weighed according to the weight ratio, it is spare;
2) it is added deionized water in agitator tank, under stirring condition, sequentially adds modified rhoplex, titanium dioxide, talcum
Powder, powdered whiting, composite microcapsule mould inhibitor, dispersing agent, wetting agent, preservative, thickener, levelling agent, until system
Uniform soilless sticking is to get water mildow-proof coating.
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CN201810936616.8A CN109135456A (en) | 2018-08-16 | 2018-08-16 | A kind of water mildow-proof coating |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03146570A (en) * | 1989-10-31 | 1991-06-21 | Mitsubishi Cable Ind Ltd | Rodenticidal coating compound and its use |
CN1409596A (en) * | 1999-12-13 | 2003-04-09 | 拜尔公司 | Fungicidal combinations of active substances |
CN101210143A (en) * | 2006-12-31 | 2008-07-02 | 北京金源化学集团有限公司 | Environment-friendly type long-acting mildew-resisting paint and preparing method thereof |
CN103706311A (en) * | 2012-10-09 | 2014-04-09 | 陈敏 | Microcapsule preparation technology for obviously improving overall performances of product |
CN108299986A (en) * | 2018-02-06 | 2018-07-20 | 漳州三德利油漆涂料有限公司 | Plants essential oil microcapsules fungus and mildew resistance coating and its preparation method and application |
-
2018
- 2018-08-16 CN CN201810936616.8A patent/CN109135456A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03146570A (en) * | 1989-10-31 | 1991-06-21 | Mitsubishi Cable Ind Ltd | Rodenticidal coating compound and its use |
CN1409596A (en) * | 1999-12-13 | 2003-04-09 | 拜尔公司 | Fungicidal combinations of active substances |
CN101210143A (en) * | 2006-12-31 | 2008-07-02 | 北京金源化学集团有限公司 | Environment-friendly type long-acting mildew-resisting paint and preparing method thereof |
CN103706311A (en) * | 2012-10-09 | 2014-04-09 | 陈敏 | Microcapsule preparation technology for obviously improving overall performances of product |
CN108299986A (en) * | 2018-02-06 | 2018-07-20 | 漳州三德利油漆涂料有限公司 | Plants essential oil microcapsules fungus and mildew resistance coating and its preparation method and application |
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Application publication date: 20190104 |