CN109134911A - A kind of nano-far-infrared sponge - Google Patents
A kind of nano-far-infrared sponge Download PDFInfo
- Publication number
- CN109134911A CN109134911A CN201811145289.0A CN201811145289A CN109134911A CN 109134911 A CN109134911 A CN 109134911A CN 201811145289 A CN201811145289 A CN 201811145289A CN 109134911 A CN109134911 A CN 109134911A
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- China
- Prior art keywords
- nano
- far
- infrared
- sponge
- polyol
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- Pending
Links
- 150000003077 polyols Chemical class 0.000 claims abstract description 25
- 229920005862 polyol Polymers 0.000 claims abstract description 23
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 14
- 229920000570 polyether Polymers 0.000 claims abstract description 14
- 230000000694 effects Effects 0.000 claims abstract description 12
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- 239000000919 ceramic Substances 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 230000000704 physical effect Effects 0.000 claims abstract description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- 239000012948 isocyanate Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- 239000006260 foam Substances 0.000 claims description 10
- 150000002513 isocyanates Chemical class 0.000 claims description 8
- 239000003381 stabilizer Substances 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 4
- 239000003431 cross linking reagent Substances 0.000 claims description 4
- 125000005442 diisocyanate group Chemical group 0.000 claims description 4
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 claims description 4
- 239000004088 foaming agent Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 230000017531 blood circulation Effects 0.000 abstract description 5
- 230000004060 metabolic process Effects 0.000 abstract description 5
- 230000003110 anti-inflammatory effect Effects 0.000 abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 3
- 230000002708 enhancing effect Effects 0.000 abstract description 3
- 238000005187 foaming Methods 0.000 abstract description 3
- 229910021389 graphene Inorganic materials 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 230000036737 immune function Effects 0.000 abstract 1
- 238000010586 diagram Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000011344 liquid material Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 235000011203 Origanum Nutrition 0.000 description 1
- 240000000783 Origanum majorana Species 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000036592 analgesia Effects 0.000 description 1
- 210000000476 body water Anatomy 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000001595 contractor effect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007920 subcutaneous administration Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7607—Compounds of C08G18/7614 and of C08G18/7657
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/042—Graphene or derivatives, e.g. graphene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
The invention discloses a kind of nano-far-infrared sponges, mainly addition nano far infrared ceramic powder is mixed in sponge foaming process, it is using polyether polyol with high activity, the graphene of the pure and mild outer addition of CASE polyether polyols, including raw material supply layer, mixing, foamable reaction, the combination of physical property and a variety of polyalcohols, the activity of large biological molecule can be had activated, so that the molecule of organism is excited and is in compared with high vibration state, it can promote and improve simultaneously blood circulation, enhancing metabolism, improve immune function of human body, and there is anti-inflammatory, the auxiliary of detumescence, the effect for auxiliary of easing pain.
Description
Technical field
The present invention relates to sponge field more particularly to a kind of nano-far-infrared sponges.
Background technique
Releasable wavelength 4-16 microns of the far red light of nano far infrared ceramic powder, can penetrate human skin depth 0.05-
1.5 millimeters, the friction of body water sub-resonance can be caused and generate thermal response, Subcutaneous Temperature rises, and thermal expansion and cold contraction effect promotes skin
Lower Marjoram Extract reaches acceleration blood circulation, and enhancing metabolism removes internal harmful substance, generates ferment activating cell,
Enhance cell tissue power of regeneration, with the rapid development of science and technology, sponge also obtains technological improvement, but existing sponge
The activity of large biological molecule can not be had activated, can not promote and improve blood circulation, and metabolism is slow, not have anti-inflammatory, disappear
Swollen booster action.
Summary of the invention
In view of the above-mentioned problems, can not be had activated by solving by biological big point the present invention provides a kind of nano-far-infrared sponge
The activity of son can not promote and improve blood circulation, and metabolism is slow, does not have the problem of anti-inflammatory, the booster action of detumescence.
In order to solve the above technical problems, the technical scheme adopted by the invention is that: be using polyether polyol with high activity,
The graphene of the pure and mild outer addition of CASE polyether polyols, including raw material supply layer, mixing, foamable reaction and physical property layer, feature is also
It include: the combination of a variety of polyalcohols, a variety of polyalcohols include polyol, material component and isocyanate component, institute
Polyol is stated to be stablized by polyether polyol with high activity, CASE polyether polyol, crosslinking agent, foaming agent, catalyst and foam
Agent mixes, the isocyanate component by toluene di-isocyanate(TDI), diphenyl methane -4,4 ' and diisocyanate mix and
At.
Preferably, the material component adjusts nano-meter far infrared ceramic powder additive amount (3- according to density in normal recipe
20%).
Preferably, (total mixing revolving speed is 4800-5200 rpm/min, foam stabiliser revolving speed to the mixing revolving speed
In 4300rpm/min).
By the above-mentioned description of this invention it is found that compared to the prior art, the present invention has the advantage that
A kind of nano-far-infrared sponge of the present invention, can have activated the activity of large biological molecule, enable the molecule of organism by
It excites and is in compared with high vibration state, while can promote and improve blood circulation, enhancing metabolism improves human immunity function
Can, and have the function of anti-inflammatory, the auxiliary of detumescence, analgesia auxiliary.
Detailed description of the invention
Fig. 1 is schematic structural view of the invention；
Fig. 2 is a variety of polyol structure schematic diagrames of the present invention；
Fig. 3 is polyol structural schematic diagram of the present invention；
Fig. 4 is isocyanate component structural schematic diagram of the present invention.
Wherein: cavernous body -1, a variety of polyalcohols -2, polyol -21, material component -22, isocyanate component -23,
Polyether polyol with high activity -211, CASE polyether polyol -212, crosslinking agent -213, foaming agent -214, catalyst -215, foam
Stabilizer -216, toluene di-isocyanate(TDI) -231, diphenyl methane -4,4 ' -232, diisocyanate -233.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to the accompanying drawings and embodiments, right
The present invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, and
It is not used in the restriction present invention.
Embodiment 1
A kind of nano-far-infrared sponge, adds the production technology of the polyurethane sponge product of nano-meter far infrared ceramic powder are as follows: be
Use polyether polyol with high activity, the graphene of the pure and mild outer addition of CASE polyether polyols, including raw material supply layer, mixing, foaming
Reaction, the combination of physical property and a variety of polyalcohols 2, a variety of polyalcohols 2 include polyol 21, material component 22 and isocyanide
Acid esters component 23, the polyol 21 by polyether polyol with high activity 211, CASE polyether polyol 212, crosslinking agent 213,
Foaming agent 214, catalyst 215 and foam stabiliser 216 mix, and the isocyanate component 23 is by toluene diisocynate
Ester 231, diphenyl methane -4,4 ' 232 and diisocyanate 233 mix, and material component 22 is in normal recipe according to density
Nano-meter far infrared ceramic powder additive amount (3-20%) is adjusted, revolving speed is mixed, and (total mixing revolving speed is 4800-5200 rpm/
Min, foam stabiliser revolving speed is in 4300rpm/min).
Embodiment 2
Polyol 21, material component 22 and isocyanate component 23 etc. are taken out input by a kind of nano-far-infrared sponge respectively
Storage tank is produced, with temperature control system, regulation produces the temperature of raw material in storage tank, controls (± 1 within the scope of 21-25 DEG C
DEG C), mixing section (hybrid mode) is using as follows: material component 22 is pumped out of production storage tank through high-precision measuring, metering is taken out defeated
It send and is stirred mixing into foam mixing head, form liquid material after the raw materials used agitated mixing of component, material is continuously spat
Out, it is reacted；The mixing speed adopted is stirred in 4000-5200rpm/min, product can be divided to adjust (different densities object
Property adjust), foamable reaction section use following technique: by the liquid material mixed by connecting tube to yaw branch pipe, from mixing
Head is flowed into yaw branch pipe, reinjects inclination and falls on the lining paper of the rolling on plate, primary emulsifying on plate in falling for lengthening, instead
The 10% of total foam volume is reflected, then increases inclination and falls plate angle degree, makes the material and foam box side plate that viscosity improves in the reaction
(baffle) cooperation muti-piece inclination falls plate and moves down with lining paper, completes remaining foaming, when being moved on horizontal feed band, is completed
The expansion of reaction process forms cavernous body.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.
Claims (3)
1. a kind of nano-far-infrared sponge, structure includes raw material supply layer, mixed layer, foamable reaction and physical property layer, feature
Be: a variety of polyalcohols (2), a variety of polyalcohols (2) include polyol (21), material component (22) and isocyanates
Component (23), the polyol (21) is by polyether polyol with high activity (211), CASE polyether polyol (212), crosslinking agent
(213), foaming agent (214), catalyst (215) and foam stabiliser (216) mix, the isocyanate component (23)
It is mixed by toluene di-isocyanate(TDI) (231), diphenyl methane -4,4 ' (232) and diisocyanate (233).
2. a kind of nano-far-infrared sponge according to claim 1, it is characterised in that: the material component (22) is normally being matched
Nano-meter far infrared ceramic powder additive amount (3-20%) is adjusted according to density in side.
3. a kind of nano-far-infrared sponge according to claim 1, it is characterised in that: mixing revolving speed (total mixing
Revolving speed is 4800-5200 rpm/min, and foam stabiliser revolving speed is in 4300rpm/min).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811145289.0A CN109134911A (en) | 2018-09-29 | 2018-09-29 | A kind of nano-far-infrared sponge |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811145289.0A CN109134911A (en) | 2018-09-29 | 2018-09-29 | A kind of nano-far-infrared sponge |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109134911A true CN109134911A (en) | 2019-01-04 |
Family
ID=64813490
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811145289.0A Pending CN109134911A (en) | 2018-09-29 | 2018-09-29 | A kind of nano-far-infrared sponge |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109134911A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109762126A (en) * | 2019-01-21 | 2019-05-17 | 深圳市德润明宇科技有限公司 | A kind of sponge and its foam process, a kind of VR glasses |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101353227A (en) * | 2007-07-23 | 2009-01-28 | 珠海天睿生物科技有限公司 | Far infrared composite powder |
| CN101463187A (en) * | 2007-12-19 | 2009-06-24 | 秦荣 | Tourmaline polyether type sponge material, and production method and use thereof |
| CN102453224A (en) * | 2011-07-15 | 2012-05-16 | 上海高裕海绵制品有限公司 | Technology for producing sponge from plant oil polyether |
| CN102649873A (en) * | 2011-02-24 | 2012-08-29 | 林国栋 | Far infrared sponge |
| CN108378434A (en) * | 2018-02-09 | 2018-08-10 | 杨彪 | A kind of underwear chest pad production method containing anion |
-
2018
- 2018-09-29 CN CN201811145289.0A patent/CN109134911A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101353227A (en) * | 2007-07-23 | 2009-01-28 | 珠海天睿生物科技有限公司 | Far infrared composite powder |
| CN101463187A (en) * | 2007-12-19 | 2009-06-24 | 秦荣 | Tourmaline polyether type sponge material, and production method and use thereof |
| CN102649873A (en) * | 2011-02-24 | 2012-08-29 | 林国栋 | Far infrared sponge |
| CN102453224A (en) * | 2011-07-15 | 2012-05-16 | 上海高裕海绵制品有限公司 | Technology for producing sponge from plant oil polyether |
| CN108378434A (en) * | 2018-02-09 | 2018-08-10 | 杨彪 | A kind of underwear chest pad production method containing anion |
Non-Patent Citations (1)
| Title |
|---|
| 谢圣英: "《塑料材料》", 31 January 2010, 中国轻工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109762126A (en) * | 2019-01-21 | 2019-05-17 | 深圳市德润明宇科技有限公司 | A kind of sponge and its foam process, a kind of VR glasses |
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| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 528000 No. 29 and 30, Changgang Road, Genghe Avenue, Genghe Town, Gaoming District, Foshan City, Guangdong Province (Plant 2) (application for residence) Applicant after: Guangdong dopda high tech materials Co.,Ltd. Address before: 529700 Building D, No. 326, Xianghe Road, Gonghe Town, Heshan City, Jiangmen City, Guangdong Province Applicant before: JIANGMEN DUOPUDA Co.,Ltd. |
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Application publication date: 20190104 |