CN109134105A - A kind of attapulgite modified compound fertilizer - Google Patents

A kind of attapulgite modified compound fertilizer Download PDF

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Publication number
CN109134105A
CN109134105A CN201811322651.7A CN201811322651A CN109134105A CN 109134105 A CN109134105 A CN 109134105A CN 201811322651 A CN201811322651 A CN 201811322651A CN 109134105 A CN109134105 A CN 109134105A
Authority
CN
China
Prior art keywords
urea
sulfuric acid
attapulgite
powder
modified compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811322651.7A
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Chinese (zh)
Inventor
魏玉祥
王晨晖
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Silver Rich Agrochemical Technology Co Ltd
Original Assignee
Silver Rich Agrochemical Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Silver Rich Agrochemical Technology Co Ltd filed Critical Silver Rich Agrochemical Technology Co Ltd
Priority to CN201811322651.7A priority Critical patent/CN109134105A/en
Publication of CN109134105A publication Critical patent/CN109134105A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/30Layered or coated, e.g. dust-preventing coatings
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/10Solid or semi-solid fertilisers, e.g. powders
    • C05G5/12Granules or flakes

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Soil Sciences (AREA)
  • Fertilizers (AREA)

Abstract

The present invention relates to a kind of attapulgite modified compound fertilizers, it is characterised in that is mixed with by weight percentage by following ingredients;Attapulgite powder 10-20%, urea 10-20%, ammonium sulfate 15-20%, potassium sulfate 20-30%, monoammonium phosphate 25-35%, ammonium hydrogen carbonate 3-5%, sulfuric acid urea solution 5-8%.The reaction heat of sulfuric acid and water, urea and sulfuric acid is rationally utilized, steam consumption is also greatly reduced because sulfuric acid urea solution has high viscosity in pelletizer, and energy-saving effect is obvious.Continuous production can be achieved, improve production efficiency.

Description

A kind of attapulgite modified compound fertilizer
Technical field
The present invention relates to technical field of fertilizer production, especially a kind of attapulgite modified compound fertilizer.
Background technique
Compound fertilizer's appearance is generally graininess, and primary raw material has ammonium sulfate, ammonium nitrate, urea, potassium sulfate, potassium chloride etc.. Have many advantages, such as that high, the secondary composition of nutrient content is few and physical behavior is good, for balance fertilizing, improves utilization rate of fertilizer, promote to make Object stable high yield has a very important role.Concave convex rod mine modified compound fertilizer has nanoporous road column structure, distinctive The loss of the adsorbable nitrogen of absorption property;It is also beneficial to save the nutrients such as phosphorus potassium, improves the utilization rate of fertilizer, reduce effectively The loss of nutrient.The prior art produces concave convex rod compound fertilizer, attapulgite powder is usually first acidified, by attapulgite powder and sulphur Acid-mixed is stacked after closing.It is big that this mode stacks place, also needs ceaselessly to stir, and mixing is uneven, cannot achieve serialization Production.
Summary of the invention
It is an object of the invention to avoid the deficiencies in the prior art, a kind of attapulgite modified compound fertilizer is provided.
To achieve the above object, the technical scheme adopted by the invention is as follows: a kind of attapulgite modified compound fertilizer, feature exist In being mixed with by weight percentage by following ingredients;
Attapulgite powder 10%-20%, urea 10-20%, ammonium sulfate 15-20%, potassium sulfate 20-30%, monoammonium phosphate 25- 35%, ammonium hydrogen carbonate 3-5%, sulfuric acid urea solution 5-8%;
Preparation method includes the following steps:
A. it prepares attapulgite fine powder: by attapulgite clay mineral through picking → drying → broken → ore grinding → classification, being made - 150 targeted fine powder of 100 mesh, water content≤15%, color are canescence or red;
B. sulfuric acid urea solution is prepared: by being mixed evenly for 93% sulfuric acid, urea, water 1:2:0.1 in mass ratio, temperature control 40-60 DEG C processed;
C. be granulated: by attapulgite powder, urea, ammonium sulfate, potassium sulfate, monoammonium phosphate, ammonium hydrogen carbonate is proportionally added into granulation Machine, then ureasulfuric acid solution atomization is sprayed onto pelletizer material bed surface, flow is controlled with flowmeter;
D. packaging will be carried out after the particle drying made, cooling, screening, coating, metering forms complex fertilizer product.
The beneficial effects of the present invention are:
1, the reaction heat of sulfuric acid and water, urea and sulfuric acid is rationally utilized, dissolved urea forms sulfuric acid urea solution and do not have to steam, complete Reaction heat is relied on entirely, and steam consumption is also greatly reduced because sulfuric acid urea solution has high viscosity in pelletizer, and energy-saving effect is obvious.
2, due to the porous crystal structure of concave convex rod, good improvement soil effect is made it have;Simultaneously again using concave-convex The colloidality and adsorptivity of stick add sulfuric acid urea solution caking property, and granulation is strong, and pelletizer outlet granulating rate reaches 95%, Particle surface roundness degree increases, and compression strength improves, and grain color bleaches, and commodity is good;
3, due to ureasulfuric acid inhibition, make efficiency slow release, extend fertilizer efficiency.
4, attapulgite powder is acidified using dynamic, the method for serialization, is acidified, is uniformly mixed, feeds intake stabilization, can It realizes continuous production, improves production efficiency.
Specific embodiment
The principles and features of the present invention are described below, and the given examples are served only to explain the present invention, is not intended to limit Determine the scope of the present invention.
Embodiment 1, a kind of attapulgite modified compound fertilizer, it is characterised in that mixed by weight percentage by following ingredients Preparation;
Attapulgite powder 20%, urea 10%, ammonium sulfate 15%, potassium sulfate 22%, monoammonium phosphate 25%, ammonium hydrogen carbonate 3%, sulphur Sour urea solution 5%
Preparation method includes the following steps:
A. it prepares attapulgite fine powder: by attapulgite clay mineral through picking → drying → broken → ore grinding → classification, being made - 150 targeted fine powder of 100 mesh, water content≤15%, color are canescence or red;
B. sulfuric acid urea solution is prepared: by being mixed evenly for 93% sulfuric acid, urea, water 1:2:0.1 in mass ratio, temperature control 40-60 DEG C processed;
C. be granulated: by attapulgite powder, urea, ammonium sulfate, potassium sulfate, monoammonium phosphate, ammonium hydrogen carbonate is proportionally added into granulation Machine, then ureasulfuric acid solution atomization is sprayed onto pelletizer material bed surface, flow is controlled with flowmeter;
D. packaging will be carried out after the particle drying made, cooling, screening, coating, metering forms complex fertilizer product.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, it is all in spirit of the invention and Any modification, equivalent replacement, improvement and so within principle, should all be included in the protection scope of the present invention.

Claims (1)

1. a kind of attapulgite modified compound fertilizer, it is characterised in that be mixed with by weight percentage by following ingredients;
Attapulgite powder 10-20%, urea 10-20%, ammonium sulfate 15-20%, potassium sulfate 20-30%, monoammonium phosphate 25- 35%, ammonium hydrogen carbonate 3-5%, sulfuric acid urea solution 5-8%;
Preparation method includes the following steps:
A. it prepares attapulgite fine powder: by attapulgite clay mineral through picking → drying → broken → ore grinding → classification, being made - 150 targeted fine powder of 100 mesh, water content≤15%, color are canescence or red;
B. sulfuric acid urea solution is prepared: by being mixed evenly for 93% sulfuric acid, urea, water 1:2:0.1 in mass ratio, temperature control 40-60 DEG C processed;
C. be granulated: by attapulgite powder, urea, ammonium sulfate, potassium sulfate, monoammonium phosphate, ammonium hydrogen carbonate is proportionally added into granulation Machine, then ureasulfuric acid solution atomization is sprayed onto pelletizer material bed surface, flow is controlled with flowmeter;
D. packaging will be carried out after the particle drying made, cooling, screening, coating, metering forms complex fertilizer product.
CN201811322651.7A 2018-11-08 2018-11-08 A kind of attapulgite modified compound fertilizer Pending CN109134105A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811322651.7A CN109134105A (en) 2018-11-08 2018-11-08 A kind of attapulgite modified compound fertilizer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811322651.7A CN109134105A (en) 2018-11-08 2018-11-08 A kind of attapulgite modified compound fertilizer

Publications (1)

Publication Number Publication Date
CN109134105A true CN109134105A (en) 2019-01-04

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811322651.7A Pending CN109134105A (en) 2018-11-08 2018-11-08 A kind of attapulgite modified compound fertilizer

Country Status (1)

Country Link
CN (1) CN109134105A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4116664A (en) * 1976-11-04 1978-09-26 Jones Leon R Fertilizer composition and method of making same
CN1651359A (en) * 2004-02-06 2005-08-10 河北天人化工股份有限公司 Production method of urocomposite fertilizer
CN102503622A (en) * 2011-09-17 2012-06-20 山东金山化肥有限公司 Process for producing urea sulfate ammoniated compound fertilizer
CN102992846A (en) * 2012-11-30 2013-03-27 江西开门子肥业股份有限公司 Ultra-high concentration sulfur-based compound fertilizer with total nutrient of 65 percent and production method of compound fertilizer
CN104108967A (en) * 2013-04-19 2014-10-22 云中英 Production process for preparing compound fertilizer through urea sulfate ammoniation method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4116664A (en) * 1976-11-04 1978-09-26 Jones Leon R Fertilizer composition and method of making same
CN1651359A (en) * 2004-02-06 2005-08-10 河北天人化工股份有限公司 Production method of urocomposite fertilizer
CN102503622A (en) * 2011-09-17 2012-06-20 山东金山化肥有限公司 Process for producing urea sulfate ammoniated compound fertilizer
CN102992846A (en) * 2012-11-30 2013-03-27 江西开门子肥业股份有限公司 Ultra-high concentration sulfur-based compound fertilizer with total nutrient of 65 percent and production method of compound fertilizer
CN104108967A (en) * 2013-04-19 2014-10-22 云中英 Production process for preparing compound fertilizer through urea sulfate ammoniation method

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
黄占斌: "《环境材料学》", 30 November 2017, 冶金工业出版社 *

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Application publication date: 20190104

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