CN109133653A - A kind of anti-corrosion and high strength glass fiber material - Google Patents
A kind of anti-corrosion and high strength glass fiber material Download PDFInfo
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- CN109133653A CN109133653A CN201811257588.3A CN201811257588A CN109133653A CN 109133653 A CN109133653 A CN 109133653A CN 201811257588 A CN201811257588 A CN 201811257588A CN 109133653 A CN109133653 A CN 109133653A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C13/00—Fibre or filament compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B37/00—Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
- C03B37/01—Manufacture of glass fibres or filaments
- C03B37/02—Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor
- C03B37/022—Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor from molten glass in which the resultant product consists of different sorts of glass or is characterised by shape, e.g. hollow fibres, undulated fibres, fibres presenting a rough surface
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/465—Coatings containing composite materials
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- Life Sciences & Earth Sciences (AREA)
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- General Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
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- Reinforced Plastic Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention provides a kind of anti-corrosion and high strength glass fiber material, the glass fiber material is by including that the raw material of following parts by weight is made: 36~42 parts of glass fibre mineral powder, 40~60 parts of aluminum oxide, 10~30 parts of diboron trioxide, 20~40 parts of cerium oxide, 28~50 parts of ferroso-ferric oxide powder, 23~30 parts of Zirconia particles, 50-80 parts of zinc oxide, 28~50 parts of nickel sulfate, 20~50 parts of polyethylene powder, 14~18 parts of sodium tripolyphosphate, 18~24 parts of ethyl trimethoxy silane, 18~26 parts of epoxy resin.Anti-corrosion and high strength glass fiber material of the present invention is a kind of inorganic non-metallic material haveing excellent performance, a certain amount of aluminum oxide and ferroso-ferric oxide powder are added inside it, effectively raise the tensile strength and corrosion resistance of glass fibre, and then its whole service performance is improved, expand use scope.
Description
Technical field
The invention belongs to glass fiber material technical fields, more particularly, to a kind of anti-corrosion and high strength glass fibre material
Material.
Background technique
Glass fibre is a kind of has excellent performanceInorganic non-metallic material, it is many kinds of, haveInsulating propertiesGood,Heat resistance
By force, the advantages that high mechanical strength, it is to be by seven kinds of pyrophillite, quartz sand, lime stone, dolomite, bechilite, boromagnesite ores
Raw material through high temperature melting, usingWire drawing, doff, the techniques such as woven fabric be fabricated, the diameter of monofilament is several microns to two
More than tenMicron, it is equivalent to the 1/20~1/5 of a hairline, every bundle fiber precursor is all by hundreds of even thousands of monofilament groups
At glass fibre is typically used as the reinforcing material in composite material, electrically insulating material and heat-insulating material, the states such as circuit substrate
The economic every field of the people, but existing glass fiber material during use due to its tensile strength and corrosion resistance not
The disadvantages of high, has in use process significant limitation to be badly in need of a kind of tool especially in fields such as aerospace, military chemical industry
There is the glass fiber material of high-tensile, highly corrosion resistant to solve these problems.
Summary of the invention
In view of this, the present invention is directed to propose a kind of anti-corrosion and high strength glass fiber material, pull resistance with higher
It can be with that stronger corrosivity.
In order to achieve the above objectives, the technical scheme of the present invention is realized as follows:
A kind of anti-corrosion and high strength glass fiber material, the glass fiber material is by including that the raw material of following parts by weight is made: glass
36~42 parts of glass fibrous mineral powder, 40~60 parts of aluminum oxide, 10~30 parts of diboron trioxide, 20~40 parts of cerium oxide, four
28~50 parts of Fe 3 O powder, 23~30 parts of Zirconia particles, 50-80 parts of zinc oxide, 28~50 parts of nickel sulfate, polyethylene powder 20
~50 parts, 14~18 parts of sodium tripolyphosphate, 18~24 parts of ethyl trimethoxy silane, 18~26 parts of epoxy resin, hexa metaphosphoric acid
16~22 parts and 14~20 parts of hydrochloric acid solution of sodium.
Preferably, the glass fiber material is by including that the raw material of following parts by weight is made: glass fibre mineral powder 36
~40 parts, 40~50 parts of aluminum oxide, 10~20 parts of diboron trioxide, 20~30 parts of cerium oxide, ferroso-ferric oxide powder 28~
40 parts, 23~25 parts of Zirconia particles, 50-65 parts of zinc oxide, 28~40 parts of nickel sulfate, 20~36 parts of polyethylene powder, trimerization phosphorus
14~15 parts of sour sodium, 18~20 parts of ethyl trimethoxy silane, 18~24 parts of epoxy resin, 16~20 parts of calgon and salt
14~17 parts of acid solution.
Preferably, the glass fiber material is by including that the raw material of following parts by weight is made: glass fibre mineral powder 38
~42 parts, 45~55 parts of aluminum oxide, 20~30 parts of diboron trioxide, 30~40 parts of cerium oxide, ferroso-ferric oxide powder 35~
45 parts, 25~28 parts of Zirconia particles, 60-70 parts of zinc oxide, 35~45 parts of nickel sulfate, 25~45 parts of polyethylene powder, trimerization phosphorus
16~17 parts of sour sodium, 20~22 parts of ethyl trimethoxy silane, 20~24 parts of epoxy resin, 18~21 parts of calgon and salt
15~18 parts of acid solution.
Preferably, the glass fiber material is by including that the raw material of following parts by weight is made: glass fibre mineral powder 40
~42 parts, 50~60 parts of aluminum oxide, 15~25 parts of diboron trioxide, 25~35 parts of cerium oxide, ferroso-ferric oxide powder 40~
50 parts, 27~30 parts of Zirconia particles, 65-80 parts of zinc oxide, 40~50 parts of nickel sulfate, 40~50 parts of polyethylene powder, trimerization phosphorus
16~18 parts of sour sodium, 20~24 parts of ethyl trimethoxy silane, 22~26 parts of epoxy resin, 20~22 parts of calgon and salt
19~20 parts of acid solution.
The preparation method of the anti-corrosion and high strength glass fiber material, includes the following steps:
(1) by glass fibre mineral powder, aluminum oxide, diboron trioxide, cerium oxide, ferroso-ferric oxide powder, Zirconia particles,
Zinc oxide, nickel sulfate, polyethylene powder, sodium tripolyphosphate and ethyl trimethoxy silane mixing, are then placed within high-speed mixer
Middle progress 40~60min of high-speed stirred, mixing speed are 500~650r/min, obtain material one；
(2) material one is placed in dryer after being dried to water content below 2.5%, then carries out wire drawing, obtains material
Two, the diameter of material two is in 4~6um；
(3) epoxy resin and calgon are placed in blender and stir and heats, heating temperature is 70~90 DEG C, is added
The hydrochloric acid solution that weight fraction is 14~20, reaction time are 30~40min, obtain material three；
(4) material two is mixed with material three and is placed on melting in smelting furnace, the revolving speed of smelting furnace is 300~360r/min, so
It is stirred in blender afterwards, the revolving speed of blender is 250~320r/min, and mixing time is 60~80min, obtains material
Four；
(5) material four is placed in dryer and is dried, drying time is 20~30min, and drying temperature is 150~180 DEG C, then
It is rapidly cooled to room temperature with cooler, then is placed in organic solvent and impregnates, soaking time is 4~5h, be can be obtained into after drying
Product；
Further, the time being mixed in the step (1) is 50min, mixing speed 600r/min；The step
(2) diameter of material two is in 5um in；
Further, the heating temperature in the step (3) is 80 DEG C,
Further, the smelting time of the step (4) is 3.5h, and the revolving speed of smelting furnace is 350r/min, the revolving speed of blender
For 300r/min, mixing time 70min；
Further, the material four in the step (5) carries out plasma-assisted chemical vapour deposition method in material before baking
Four surfaces deposit adhesive layer, and the source substance of sedimentary condition is the mixture of ethylene and silicon tetrachloride, and depositing temperature is 500 DEG C, argon
Gas be carrier gas and carrier gas, sedimentation time 50min,
Further, the drying time of material four is 25min in the step (5), and drying temperature is 165 DEG C；
Further, the organic solvent of the step (5) is the mixing of any one in toluene and acetone or both, when immersion
Between be 4.5h.
Compared with the existing technology, anti-corrosion and high strength glass fiber material of the present invention has the advantage that
1, a certain amount of aluminum oxide is added in anti-corrosion and high strength glass fiber material of the present invention, makes it have very high anti-
Tensile strength may be used as the supporting material of reinforced plastics, while high tensile strength can greatly prolong the use of glass fibre
Service life；
2, the ferroso-ferric oxide being added in anti-corrosion and high strength glass fiber material of the present invention, can be such that its corrosion resistance obtains
It is promoted, it can be made to be applied to Chemical Manufacture, the fields such as cement preparation effectively expand its scope of application；
3, the raw material sources of anti-corrosion and high strength glass fiber material of the present invention are extensive, and are easy to get, while the present invention
Preparation process it is easy to operate, preparation flow is relatively short, thus be suitble to industrialization large-scale production manufacture.
Specific embodiment
In addition to being defined, technical term used in following embodiment has universal with those skilled in the art of the invention
The identical meanings of understanding.Organic solvent used in following embodiment or reagent are unless otherwise specified routine biochemistry examination
Agent；The experimental method is unless otherwise specified conventional method.
Below with reference to embodiment, the present invention will be described in detail.
Embodiment 1
A kind of anti-corrosion and high strength glass fiber material, the glass fiber material is by including that the raw material of following parts by weight is made: glass
38 parts of glass fibrous mineral powder, 55 parts of aluminum oxide, 15 parts of diboron trioxide, 25 parts of cerium oxide, 34 parts of ferroso-ferric oxide powder, oxygen
Change 24 parts of zirconium particle, 60 parts of zinc oxide, 35 parts of nickel sulfate, 28 parts of polyethylene powder, 15 parts of sodium tripolyphosphate, ethyl trimethoxy silicon
19 parts of alkane, 22 parts of epoxy resin, 28 parts of calgon and 16 parts of hydrochloric acid solution.
The preparation method of the anti-corrosion and high strength glass fiber material, includes the following steps:
(1) by glass fibre mineral powder, aluminum oxide, diboron trioxide, cerium oxide, ferroso-ferric oxide powder, zirconium oxide grain
Son, zinc oxide, nickel sulfate, polyethylene powder, sodium tripolyphosphate and ethyl trimethoxy silane mixing, are then placed within high-speed stirred
High-speed stirred 50min is carried out in machine, mixing speed 600r/min obtains material one；
(2) material one is placed in dryer after being dried to water content below 2.5%, then carries out wire drawing, obtains material
Two, the diameter of material two is in 5um；
(3) epoxy resin and calgon are placed in blender and stir and heats, heating temperature is 80 DEG C, adds weight
The hydrochloric acid solution that score is 18, reaction time 35min obtain material three；
(4) material two is mixed with material three and is placed on melting in smelting furnace, the revolving speed of smelting furnace is 350r/min, is then being stirred
It mixes in machine and is stirred, the revolving speed of blender is 300r/min, and mixing time 70min obtains material four；
(5) material four is subjected to plasma-assisted chemical vapour deposition method and deposits adhesive layer on four surface of material, sedimentary condition
Source substance is the mixture of ethylene and silicon tetrachloride, and depositing temperature is 500 DEG C, and argon gas is carrier gas and carrier gas, and sedimentation time is
Then material four is placed in dryer and dries by 50min, drying time 25min, and drying temperature is 165 DEG C, then with cooling
Machine is rapidly cooled to room temperature, then is placed in organic solvent and impregnates, and finished product can be obtained after drying in soaking time 4.5h；
Embodiment 2
A kind of anti-corrosion and high strength glass fiber material, the glass fiber material is by including that the raw material of following parts by weight is made: glass
40 parts of glass fibrous mineral powder, 50 parts of aluminum oxide, 25 parts of diboron trioxide, 35 parts of cerium oxide, 40 parts of ferroso-ferric oxide powder, oxygen
Change 26 parts of zirconium particle, 65 parts of zinc oxide, 40 parts of nickel sulfate, 35 parts of polyethylene powder, 17 parts of sodium tripolyphosphate, ethyl trimethoxy silicon
21 parts of alkane, 22 parts of epoxy resin, 20 parts of calgon and 17 parts of hydrochloric acid solution.
The preparation method of the anti-corrosion and high strength glass fiber material, includes the following steps:
(1) by glass fibre mineral powder, aluminum oxide, diboron trioxide, cerium oxide, ferroso-ferric oxide powder, Zirconia particles,
Zinc oxide, nickel sulfate, polyethylene powder, sodium tripolyphosphate and ethyl trimethoxy silane mixing, are then placed within high-speed mixer
Middle progress high-speed stirred 50min, mixing speed 600r/min obtain material one；
(2) material one is placed in dryer after being dried to water content below 2.5%, then carries out wire drawing, obtains material
Two, the diameter of material two is in 5um；
(3) epoxy resin and calgon are placed in blender and stir and heats, heating temperature is 80 DEG C, adds weight
The hydrochloric acid solution that score is 18, reaction time 35min obtain material three；
(4) material two is mixed with material three and is placed on melting in smelting furnace, the revolving speed of smelting furnace is 350r/min, is then being stirred
It mixes in machine and is stirred, the revolving speed of blender is 300r/min, and mixing time 70min obtains material four；
(5) material four is subjected to plasma-assisted chemical vapour deposition method and deposits adhesive layer on four surface of material, sedimentary condition
Source substance is the mixture of ethylene and silicon tetrachloride, and depositing temperature is 500 DEG C, and argon gas is carrier gas and carrier gas, and sedimentation time is
Then material four is placed in dryer and dries by 50min, drying time 25min, and drying temperature is 165 DEG C, then with cooling
Machine is rapidly cooled to room temperature, then is placed in organic solvent and impregnates, and finished product can be obtained after drying in soaking time 4.5h；
Embodiment 3
A kind of anti-corrosion and high strength glass fiber material, the glass fiber material is by including that the raw material of following parts by weight is made: glass
42 parts of glass fibrous mineral powder, 55 parts of aluminum oxide, 20 parts of diboron trioxide, 30 parts of cerium oxide, 45 parts of ferroso-ferric oxide powder, oxygen
Change 29 parts of zirconium particle, 75 parts of zinc oxide, 45 parts of nickel sulfate, 45 parts of polyethylene powder, 17 parts of sodium tripolyphosphate, ethyl trimethoxy silicon
22 parts of alkane, 24 parts of epoxy resin, 21 parts of calgon and 20 parts of hydrochloric acid solution.
The preparation method of the anti-corrosion and high strength glass fiber material, includes the following steps:
(1) by glass fibre mineral powder, aluminum oxide, diboron trioxide, cerium oxide, ferroso-ferric oxide powder, Zirconia particles,
Zinc oxide, nickel sulfate, polyethylene powder, sodium tripolyphosphate and ethyl trimethoxy silane mixing, are then placed within high-speed mixer
Middle progress high-speed stirred 50min, mixing speed 600r/min obtain material one；
(2) material one is placed in dryer after being dried to water content below 2.5%, then carries out wire drawing, obtains material
Two, the diameter of material two is in 5um；
(3) epoxy resin and calgon are placed in blender and stir and heats, heating temperature is 80 DEG C, adds weight
The hydrochloric acid solution that score is 18, reaction time 35min obtain material three；
(4) material two is mixed with material three and is placed on melting in smelting furnace, the revolving speed of smelting furnace is 350r/min, is then being stirred
It mixes in machine and is stirred, the revolving speed of blender is 300r/min, and mixing time 70min obtains material four；
(5) material four is subjected to plasma-assisted chemical vapour deposition method and deposits adhesive layer on four surface of material, sedimentary condition
Source substance is the mixture of ethylene and silicon tetrachloride, and depositing temperature is 500 DEG C, and argon gas is carrier gas and carrier gas, and sedimentation time is
Then material four is placed in dryer and dries by 50min, drying time 25min, and drying temperature is 165 DEG C, then with cooling
Machine is rapidly cooled to room temperature, then is placed in organic solvent and impregnates, and finished product can be obtained after drying in soaking time 4.5h；
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, it is all in spirit of the invention and
Within principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (5)
1. a kind of anti-corrosion and high strength glass fiber material, it is characterised in that: the glass fiber material is by including following parts by weight
Raw material be made: 36~42 parts of glass fibre mineral powder, 40~60 parts of aluminum oxide, 10~30 parts of diboron trioxide, oxidation
20~40 parts of cerium, 28~50 parts of ferroso-ferric oxide powder, 23~30 parts of Zirconia particles, 50-80 parts of zinc oxide, nickel sulfate 28~50
Part, 20~50 parts of polyethylene powder, 14~18 parts of sodium tripolyphosphate, 18~24 parts of ethyl trimethoxy silane, epoxy resin 18~
26 parts, 16~22 parts of calgon and 14~20 parts of hydrochloric acid solution.
2. a kind of anti-corrosion and high strength glass fiber material according to claim 1, it is characterised in that: the glass fibers
Dimension material is by including that the raw material of following parts by weight is made: 36~40 parts of glass fibre mineral powder, 40~50 parts of aluminum oxide, three
Aoxidize 10~20 parts of two boron, 20~30 parts of cerium oxide, 28~40 parts of ferroso-ferric oxide powder, 23~25 parts of Zirconia particles, oxidation
50-65 parts of zinc, 28~40 parts of nickel sulfate, 20~36 parts of polyethylene powder, 14~15 parts of sodium tripolyphosphate, ethyl trimethoxy silane
18~20 parts, 18~24 parts of epoxy resin, 16~20 parts of calgon and 14~17 parts of hydrochloric acid solution.
3. a kind of anti-corrosion and high strength glass fiber material according to claim 1, it is characterised in that: the glass fibers
Dimension material is by including that the raw material of following parts by weight is made: 38~42 parts of glass fibre mineral powder, 45~55 parts of aluminum oxide, three
Aoxidize 20~30 parts of two boron, 30~40 parts of cerium oxide, 35~45 parts of ferroso-ferric oxide powder, 25~28 parts of Zirconia particles, oxidation
60-70 parts of zinc, 35~45 parts of nickel sulfate, 25~45 parts of polyethylene powder, 16~17 parts of sodium tripolyphosphate, ethyl trimethoxy silane
20~22 parts, 20~24 parts of epoxy resin, 18~21 parts of calgon and 15~18 parts of hydrochloric acid solution.
4. a kind of anti-corrosion and high strength glass fiber material according to claim 1, it is characterised in that: the glass fibers
Dimension material is by including that the raw material of following parts by weight is made: 40~42 parts of glass fibre mineral powder, 50~60 parts of aluminum oxide, three
Aoxidize 15~25 parts of two boron, 25~35 parts of cerium oxide, 40~50 parts of ferroso-ferric oxide powder, 27~30 parts of Zirconia particles, oxidation
65-80 parts of zinc, 40~50 parts of nickel sulfate, 40~50 parts of polyethylene powder, 16~18 parts of sodium tripolyphosphate, ethyl trimethoxy silane
20~24 parts, 22~26 parts of epoxy resin, 20~22 parts of calgon and 19~20 parts of hydrochloric acid solution.
5. the preparation method of anti-corrosion and high strength glass fiber material according to any one of claims 1 to 4, feature exist
In: include the following steps:
By glass fibre mineral powder, aluminum oxide, diboron trioxide, cerium oxide, ferroso-ferric oxide powder, Zirconia particles, oxygen
Change zinc, nickel sulfate, polyethylene powder, sodium tripolyphosphate and ethyl trimethoxy silane mixing, is then placed in high-speed mixer
40~60min of high-speed stirred is carried out, mixing speed is 500~650r/min, obtains material one；
Material one is placed in dryer after being dried to water content below 2.5%, then carries out wire drawing, obtains material two, material
The diameter of material two is in 4~6um；
Epoxy resin and calgon are placed in blender and stirs and heats, heating temperature is 70~90 DEG C, adds weight
The hydrochloric acid solution that score is 14~20 is measured, the reaction time is 30~40min, obtains material three；
Material two is mixed with material three and is placed on melting in smelting furnace, the revolving speed of smelting furnace is 300~360r/min, is then existed
It is stirred in blender, the revolving speed of blender is 250~320r/min, and mixing time is 60~80min, obtains material four；
Material four is placed in dryer and is dried, drying time is 20~30min, and drying temperature is 150~180 DEG C, is then used
Cooler is rapidly cooled to room temperature, then is placed in organic solvent and impregnates, and soaking time is 4~5h, and finished product can be obtained after drying；
The preparation method of anti-corrosion and high strength glass fiber material according to claim 5, it is characterised in that:
The time being mixed in the step (1) is 50min, mixing speed 600r/min；Material two in the step (2)
Diameter in 5um；
Heating temperature in the step (3) is 80 DEG C,
The smelting time of the step (4) is 3.5h, and the revolving speed of smelting furnace is 350r/min, and the revolving speed of blender is 300r/
Min, mixing time 70min；
Material four in the step (5) carries out plasma-assisted chemical vapour deposition method before baking and deposits on four surface of material
Adhesive layer, the source substance of sedimentary condition are the mixture of ethylene and silicon tetrachloride, and depositing temperature is 500 DEG C, and argon gas is carrier gas
And carrier gas, sedimentation time 50min,
The drying time of material four is 25min in the step (5), and drying temperature is 165 DEG C；
The organic solvent of the step (5) is the mixing of any one in toluene and acetone or both, soaking time 4.5h.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811257588.3A CN109133653A (en) | 2018-10-26 | 2018-10-26 | A kind of anti-corrosion and high strength glass fiber material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811257588.3A CN109133653A (en) | 2018-10-26 | 2018-10-26 | A kind of anti-corrosion and high strength glass fiber material |
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| CN109133653A true CN109133653A (en) | 2019-01-04 |
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ID=64810232
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110063639A (en) * | 2019-05-17 | 2019-07-30 | 永康市木辰子家居用品有限公司 | The production method of chopsticks |
| CN111546715A (en) * | 2020-06-02 | 2020-08-18 | 浙江精远膜结构工程有限公司 | High-strength PTFE glass fiber material suitable for environment-friendly building membrane structure |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102849958A (en) * | 2012-10-12 | 2013-01-02 | 重庆国际复合材料有限公司 | Glass fiber |
| CN107324661A (en) * | 2017-08-01 | 2017-11-07 | 合肥利裕泰玻璃制品有限公司 | A kind of preparation method of corrosion-resistant fiberglass material |
-
2018
- 2018-10-26 CN CN201811257588.3A patent/CN109133653A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102849958A (en) * | 2012-10-12 | 2013-01-02 | 重庆国际复合材料有限公司 | Glass fiber |
| CN107324661A (en) * | 2017-08-01 | 2017-11-07 | 合肥利裕泰玻璃制品有限公司 | A kind of preparation method of corrosion-resistant fiberglass material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110063639A (en) * | 2019-05-17 | 2019-07-30 | 永康市木辰子家居用品有限公司 | The production method of chopsticks |
| CN111546715A (en) * | 2020-06-02 | 2020-08-18 | 浙江精远膜结构工程有限公司 | High-strength PTFE glass fiber material suitable for environment-friendly building membrane structure |
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