CN109133132A - A kind of aluminium polychloride - Google Patents
A kind of aluminium polychloride Download PDFInfo
- Publication number
- CN109133132A CN109133132A CN201710502130.9A CN201710502130A CN109133132A CN 109133132 A CN109133132 A CN 109133132A CN 201710502130 A CN201710502130 A CN 201710502130A CN 109133132 A CN109133132 A CN 109133132A
- Authority
- CN
- China
- Prior art keywords
- gibbsite
- tap water
- stirring
- aluminium
- aluminium polychloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/48—Halides, with or without other cations besides aluminium
- C01F7/56—Chlorides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/66—Salts, e.g. alums
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Geology (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
The invention discloses a kind of aluminium polychloride and its production method, which belongs to chemical industry field of papermaking, and producing the raw material that the product uses includes: gibbsite, technical-grade hydrochloric acid, tap water, calcium aluminate powder.The preparation method simple process, product is mainly used for water purification and papermaking, inorganic retention agent, sizing agent are mainly used as in papermaking, it is glued using aluminium polychloride, the retention of slurry, filtrating aid function significantly improve, it can be effectively facilitated flocculation, sizing, in addition to fracture length, all other indexs improve paper performance to some extent.
Description
Technical field:
Product of the present invention belongs to chemical field more particularly to a kind of aluminium polychloride.
Background technique:
Aluminium polychloride is the biggish flocculant of market sales volume, has the trend for gradually replacing traditional flocculant, production polymerization chlorine
The raw material for changing aluminium mainly has two major classes: one kind is aluminum-containing mineral, including bauxite (gibbsite, boehmite, a hydraulic aluminium
Stone), clay, kaolin, alunite etc.；Another kind of is other aluminum-containing raw materials, including metallic aluminium, aluminium scrap bits, grey aluminium, hydroxide
Aluminium, alchlor, gangue, flyash etc..Only using aluminium ingot, aluminium skimmings, aluminium hydroxide as raw material and with aluminum sulfate, al dichloride
Purer aluminium polychloride product can be just produced for raw material, but production cost will be higher by several times.When requiring less high,
Production aluminium polychloride mainly uses clay pit, kaolin ore and bauxite for raw material, produces aluminium polychloride product.It polymerize chlorine
That changes aluminium is mainly used for water purification and papermaking, and inorganic retention agent, sizing agent are mainly used as in papermaking, is applied using aluminium polychloride
Glue, the retention of slurry, filtrating aid function significantly improve, and can be effectively facilitated flocculation, sizing, and paper performance is other in addition to fracture length
Indices improve to some extent.
Summary of the invention:
The present invention relates to a kind of methods using kaolin production typical zolymerization aluminium chloride, produce the raw material packet that the product uses
It includes: gibbsite, technical-grade hydrochloric acid, tap water, calcium aluminate powder.
The present invention can be achieved through the following technical solutions:
(1) reaction tank is sent into after being sent into formula ratio gibbsite roaster calcination activation 2-2.5 hours；
(2) tap water and technical-grade hydrochloric acid are added in reaction tank, gibbsite: tap water: technical-grade hydrochloric acid=1.6-1.8:
2.5-2.7:4-4.2, turn on agitator stirring, warming while stirring no longer heat up when reaching 80-85 DEG C, react 1.5-
1.7 hour；
(3) temperature is dropped to 65-70 DEG C, puts into calcium aluminate powder, the weight of calcium aluminate powder and the weight of gibbsite while stirring
Than after being stirred to react 2.5-3.0 hours, suitable tap water is added for 0.8:1, polyaluminium aluminium content is adjusted at 20%,
Stop stirring, cooling down is got product.
Preferably, the aluminum content of the gibbsite is 35%.
Preferably, the purity of the calcium aluminate powder is 60%.
The beneficial effects of the present invention are: a kind of aluminium polychloride and its production method are provided, preparation method technique letter
Single, product is mainly used for water purification and papermaking, inorganic retention agent, sizing agent is mainly used as in papermaking, uses polyaluminium
Aluminium sizing, the retention of slurry, filtrating aid function significantly improve, and can be effectively facilitated flocculation, sizing, paper performance in addition to fracture length,
All other indexs improve to some extent.
Specific embodiment
Embodiment 1
Reaction tank is sent into after formula ratio gibbsite is sent into roaster calcination activation 2- hours；Tap water is added in reaction tank
And technical-grade hydrochloric acid, gibbsite: tap water: technical-grade hydrochloric acid=1.6:2.5:4, turn on agitator stirring, warming while stirring
It no longer heats up, reacts 1.7 hours when reaching 80 DEG C；Temperature is dropped to 65 DEG C, puts into calcium aluminate powder, calcium aluminate while stirring
The weight of powder and the weight ratio of gibbsite are 0.8:1, and after being stirred to react 3.0 hours, suitable tap water is added, adjusts polymerization
Chlorination aluminium content stops stirring at 20%, and cooling down is got product.
Embodiment 2
Reaction tank is sent into after formula ratio gibbsite is sent into roaster calcination activation 2.25 hours；It is added originally in reaction tank
Water and technical-grade hydrochloric acid, gibbsite: tap water: technical-grade hydrochloric acid=1.7:2.6:4.1, turn on agitator stirring, while stirring
Heating no longer heats up when reaching 82.5 DEG C, reacts 1.6 hours；Temperature is dropped to 67.5 DEG C, puts into calcium aluminate while stirring
Powder, the weight of calcium aluminate powder and the weight ratio of gibbsite are 0.8:1, and after being stirred to react 2.75 hours, addition is suitable originally
Water adjusts polyaluminium aluminium content at 20%, stops stirring, and cooling down is got product.
Embodiment 3
Reaction tank is sent into after formula ratio gibbsite is sent into roaster calcination activation 2.5 hours；It is added originally in reaction tank
Water and technical-grade hydrochloric acid, gibbsite: tap water: technical-grade hydrochloric acid=1.8:2.7:4.2, turn on agitator stirring, side stirring
Side heating no longer heats up when reaching 85 DEG C, reacts 1.5 hours；Temperature is dropped to 70 DEG C, puts into calcium aluminate powder while stirring,
The weight of calcium aluminate powder and the weight ratio of gibbsite are 0.8:1, and after being stirred to react 2.5 hours, suitable tap water is added, adjusts
Polyaluminium aluminium content is saved at 20%, stops stirring, cooling down is got product.
Claims (3)
1. a kind of aluminium polychloride, producing the raw material that the product uses includes: gibbsite, technical-grade hydrochloric acid, tap water, aluminic acid
Calcium powder；It is characterized in that:
(1) reaction tank is sent into after being sent into formula ratio gibbsite roaster calcination activation 2-2.5 hours；
(2) tap water and technical-grade hydrochloric acid are added in reaction tank, gibbsite: tap water: technical-grade hydrochloric acid=1.6-1.8:
2.5-2.7:4-4.2, turn on agitator stirring, warming while stirring no longer heat up when reaching 80-85 DEG C, react 1.5-
1.7 hour；
(3) temperature is dropped to 65-70 DEG C, puts into calcium aluminate powder, the weight of calcium aluminate powder and the weight of gibbsite while stirring
Than after being stirred to react 2.5-3.0 hours, suitable tap water is added for 0.8:1, polyaluminium aluminium content is adjusted at 20%,
Stop stirring, cooling down is got product.
2. a kind of aluminium polychloride according to claim 1, it is characterized in that: the aluminum content of the gibbsite is 35%.
3. a kind of aluminium polychloride according to claim 1, it is characterized in that: the purity of the calcium aluminate powder is 60%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710502130.9A CN109133132A (en) | 2017-06-27 | 2017-06-27 | A kind of aluminium polychloride |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710502130.9A CN109133132A (en) | 2017-06-27 | 2017-06-27 | A kind of aluminium polychloride |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109133132A true CN109133132A (en) | 2019-01-04 |
Family
ID=64805153
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710502130.9A Pending CN109133132A (en) | 2017-06-27 | 2017-06-27 | A kind of aluminium polychloride |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109133132A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110563110A (en) * | 2019-10-16 | 2019-12-13 | 绍兴升阳水处理剂有限公司 | Production process of polyaluminum chloride |
| CN113828014A (en) * | 2021-09-14 | 2021-12-24 | 海南金海浆纸业有限公司 | Purification and decoloration process of polyaluminium chloride solution |
-
2017
- 2017-06-27 CN CN201710502130.9A patent/CN109133132A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110563110A (en) * | 2019-10-16 | 2019-12-13 | 绍兴升阳水处理剂有限公司 | Production process of polyaluminum chloride |
| CN113828014A (en) * | 2021-09-14 | 2021-12-24 | 海南金海浆纸业有限公司 | Purification and decoloration process of polyaluminium chloride solution |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190104 |