CN109133024A - A kind of magnesium metaphosphorate aluminium powder body and preparation method thereof for optical glass - Google Patents
A kind of magnesium metaphosphorate aluminium powder body and preparation method thereof for optical glass Download PDFInfo
- Publication number
- CN109133024A CN109133024A CN201811153378.XA CN201811153378A CN109133024A CN 109133024 A CN109133024 A CN 109133024A CN 201811153378 A CN201811153378 A CN 201811153378A CN 109133024 A CN109133024 A CN 109133024A
- Authority
- CN
- China
- Prior art keywords
- magnesium
- aluminium
- optical glass
- metaphosphorate
- presoma
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004411 aluminium Substances 0.000 title claims abstract description 119
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 119
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 119
- 239000011777 magnesium Substances 0.000 title claims abstract description 104
- 229910052749 magnesium Inorganic materials 0.000 title claims abstract description 104
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims abstract description 99
- 239000000843 powder Substances 0.000 title claims abstract description 78
- 239000005304 optical glass Substances 0.000 title claims abstract description 76
- 238000002360 preparation method Methods 0.000 title claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 84
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 35
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 30
- 239000000126 substance Substances 0.000 claims abstract description 21
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 18
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000654 additive Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 11
- 239000011574 phosphorus Substances 0.000 claims abstract description 11
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 11
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 11
- 239000010703 silicon Substances 0.000 claims abstract description 11
- 229940091250 magnesium supplement Drugs 0.000 claims description 98
- 239000007788 liquid Substances 0.000 claims description 79
- 239000007795 chemical reaction product Substances 0.000 claims description 54
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 22
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 20
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 18
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 18
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- PPQREHKVAOVYBT-UHFFFAOYSA-H dialuminum;tricarbonate Chemical compound [Al+3].[Al+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O PPQREHKVAOVYBT-UHFFFAOYSA-H 0.000 claims description 12
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 12
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims description 12
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 11
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 10
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 10
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims description 9
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 9
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 claims description 9
- 239000011654 magnesium acetate Substances 0.000 claims description 9
- 229940069446 magnesium acetate Drugs 0.000 claims description 9
- 235000011285 magnesium acetate Nutrition 0.000 claims description 9
- 239000004337 magnesium citrate Substances 0.000 claims description 9
- 229960005336 magnesium citrate Drugs 0.000 claims description 9
- 235000002538 magnesium citrate Nutrition 0.000 claims description 9
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 9
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 9
- PLSARIKBYIPYPF-UHFFFAOYSA-H trimagnesium dicitrate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O PLSARIKBYIPYPF-UHFFFAOYSA-H 0.000 claims description 9
- ZUGAOYSWHHGDJY-UHFFFAOYSA-K 5-hydroxy-2,8,9-trioxa-1-aluminabicyclo[3.3.2]decane-3,7,10-trione Chemical compound [Al+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O ZUGAOYSWHHGDJY-UHFFFAOYSA-K 0.000 claims description 8
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 8
- 229910019142 PO4 Inorganic materials 0.000 claims description 8
- 229910052773 Promethium Inorganic materials 0.000 claims description 8
- 230000000996 additive effect Effects 0.000 claims description 8
- AXLHVTKGDPVANO-UHFFFAOYSA-N methyl 2-amino-3-[(2-methylpropan-2-yl)oxycarbonylamino]propanoate Chemical compound COC(=O)C(N)CNC(=O)OC(C)(C)C AXLHVTKGDPVANO-UHFFFAOYSA-N 0.000 claims description 8
- MAQCMFOLVVSLLK-UHFFFAOYSA-N methyl 4-(bromomethyl)pyridine-2-carboxylate Chemical compound COC(=O)C1=CC(CBr)=CC=N1 MAQCMFOLVVSLLK-UHFFFAOYSA-N 0.000 claims description 8
- 239000010452 phosphate Substances 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 8
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 8
- VQMWBBYLQSCNPO-UHFFFAOYSA-N promethium atom Chemical compound [Pm] VQMWBBYLQSCNPO-UHFFFAOYSA-N 0.000 claims description 8
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims description 8
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 claims description 7
- 239000004254 Ammonium phosphate Substances 0.000 claims description 7
- 239000001263 FEMA 3042 Substances 0.000 claims description 7
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 claims description 7
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 7
- QIGZGZDLQGRJGP-UHFFFAOYSA-N [Mg].CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.NCCN Chemical compound [Mg].CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.NCCN QIGZGZDLQGRJGP-UHFFFAOYSA-N 0.000 claims description 7
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 7
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 7
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 7
- 229960001484 edetic acid Drugs 0.000 claims description 7
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 claims description 7
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 7
- 239000001095 magnesium carbonate Substances 0.000 claims description 7
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 7
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 7
- UHNWOJJPXCYKCG-UHFFFAOYSA-L magnesium oxalate Chemical compound [Mg+2].[O-]C(=O)C([O-])=O UHNWOJJPXCYKCG-UHFFFAOYSA-L 0.000 claims description 7
- GMDNUWQNDQDBNQ-UHFFFAOYSA-L magnesium;diformate Chemical compound [Mg+2].[O-]C=O.[O-]C=O GMDNUWQNDQDBNQ-UHFFFAOYSA-L 0.000 claims description 7
- 239000001488 sodium phosphate Substances 0.000 claims description 7
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 7
- 229940033123 tannic acid Drugs 0.000 claims description 7
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 claims description 7
- 235000015523 tannic acid Nutrition 0.000 claims description 7
- 229920002258 tannic acid Polymers 0.000 claims description 7
- 239000011975 tartaric acid Substances 0.000 claims description 7
- 235000002906 tartaric acid Nutrition 0.000 claims description 7
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 7
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims description 7
- 229910000165 zinc phosphate Inorganic materials 0.000 claims description 7
- QQJCMYZJZCDMCD-ODZAUARKSA-N (z)-but-2-enedioic acid;magnesium Chemical compound [Mg].OC(=O)\C=C/C(O)=O QQJCMYZJZCDMCD-ODZAUARKSA-N 0.000 claims description 6
- 229910052693 Europium Inorganic materials 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 6
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 6
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 6
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 6
- 239000000347 magnesium hydroxide Substances 0.000 claims description 6
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 6
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 6
- 239000011976 maleic acid Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 235000006408 oxalic acid Nutrition 0.000 claims description 6
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 claims description 6
- 229910000160 potassium phosphate Inorganic materials 0.000 claims description 6
- 235000011009 potassium phosphates Nutrition 0.000 claims description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 6
- 239000005955 Ferric phosphate Substances 0.000 claims description 5
- WCOATMADISNSBV-UHFFFAOYSA-K diacetyloxyalumanyl acetate Chemical compound [Al+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WCOATMADISNSBV-UHFFFAOYSA-K 0.000 claims description 5
- 229940032958 ferric phosphate Drugs 0.000 claims description 5
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 claims description 5
- 229910000399 iron(III) phosphate Inorganic materials 0.000 claims description 5
- 229910052746 lanthanum Inorganic materials 0.000 claims description 5
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 5
- 229940095060 magnesium tartrate Drugs 0.000 claims description 5
- MUZDLCBWNVUYIR-ZVGUSBNCSA-L magnesium;(2r,3r)-2,3-dihydroxybutanedioate Chemical compound [Mg+2].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O MUZDLCBWNVUYIR-ZVGUSBNCSA-L 0.000 claims description 5
- 239000000047 product Substances 0.000 claims description 5
- 229910052706 scandium Inorganic materials 0.000 claims description 5
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims description 5
- -1 tannalum Chemical compound 0.000 claims description 5
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 4
- 229910002651 NO3 Inorganic materials 0.000 claims description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052771 Terbium Inorganic materials 0.000 claims description 4
- MJWPFSQVORELDX-UHFFFAOYSA-K aluminium formate Chemical compound [Al+3].[O-]C=O.[O-]C=O.[O-]C=O MJWPFSQVORELDX-UHFFFAOYSA-K 0.000 claims description 4
- CSJKPFQJIDMSGF-UHFFFAOYSA-K aluminum;tribenzoate Chemical compound [Al+3].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 CSJKPFQJIDMSGF-UHFFFAOYSA-K 0.000 claims description 4
- 239000001506 calcium phosphate Substances 0.000 claims description 4
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 4
- 235000011010 calcium phosphates Nutrition 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 4
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims description 4
- PJJZFXPJNUVBMR-UHFFFAOYSA-L magnesium benzoate Chemical compound [Mg+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 PJJZFXPJNUVBMR-UHFFFAOYSA-L 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 239000000376 reactant Substances 0.000 claims description 4
- 230000035484 reaction time Effects 0.000 claims description 4
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims description 4
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 4
- JOPDZQBPOWAEHC-UHFFFAOYSA-H tristrontium;diphosphate Chemical compound [Sr+2].[Sr+2].[Sr+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JOPDZQBPOWAEHC-UHFFFAOYSA-H 0.000 claims description 4
- 229910052727 yttrium Inorganic materials 0.000 claims description 4
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 4
- 229910052765 Lutetium Inorganic materials 0.000 claims description 3
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 3
- 229910052772 Samarium Inorganic materials 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 235000011007 phosphoric acid Nutrition 0.000 claims description 3
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 3
- 150000002910 rare earth metals Chemical class 0.000 claims description 3
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 claims description 3
- 238000012216 screening Methods 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052684 Cerium Inorganic materials 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 2
- 229910052691 Erbium Inorganic materials 0.000 claims description 2
- 229910052689 Holmium Inorganic materials 0.000 claims description 2
- 229910052779 Neodymium Inorganic materials 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 229910052775 Thulium Inorganic materials 0.000 claims description 2
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 claims description 2
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims description 2
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 claims description 2
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 2
- 235000011008 sodium phosphates Nutrition 0.000 claims description 2
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims description 2
- AFCIMSXHQSIHQW-UHFFFAOYSA-N [O].[P] Chemical compound [O].[P] AFCIMSXHQSIHQW-UHFFFAOYSA-N 0.000 claims 1
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical compound [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 claims 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 1
- 150000002366 halogen compounds Chemical class 0.000 claims 1
- 239000000741 silica gel Substances 0.000 claims 1
- 229910002027 silica gel Inorganic materials 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 33
- 238000005516 engineering process Methods 0.000 abstract description 27
- 239000006185 dispersion Substances 0.000 description 32
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical group [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 21
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical group [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 13
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 12
- 239000011521 glass Substances 0.000 description 10
- 239000000395 magnesium oxide Substances 0.000 description 7
- 230000003287 optical effect Effects 0.000 description 7
- 238000005299 abrasion Methods 0.000 description 6
- DHAHRLDIUIPTCJ-UHFFFAOYSA-K aluminium metaphosphate Chemical compound [Al+3].[O-]P(=O)=O.[O-]P(=O)=O.[O-]P(=O)=O DHAHRLDIUIPTCJ-UHFFFAOYSA-K 0.000 description 6
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 6
- 235000012254 magnesium hydroxide Nutrition 0.000 description 6
- 150000001413 amino acids Chemical class 0.000 description 5
- 239000013522 chelant Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical compound C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 4
- HDYRYUINDGQKMC-UHFFFAOYSA-M acetyloxyaluminum;dihydrate Chemical compound O.O.CC(=O)O[Al] HDYRYUINDGQKMC-UHFFFAOYSA-M 0.000 description 4
- 229940009827 aluminum acetate Drugs 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 229910052917 strontium silicate Inorganic materials 0.000 description 4
- QSQXISIULMTHLV-UHFFFAOYSA-N strontium;dioxido(oxo)silane Chemical compound [Sr+2].[O-][Si]([O-])=O QSQXISIULMTHLV-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- NMOGZFRMVSHODK-UHFFFAOYSA-N [Er].[Si](O)(O)(O)O Chemical compound [Er].[Si](O)(O)(O)O NMOGZFRMVSHODK-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 description 3
- 229910052912 lithium silicate Inorganic materials 0.000 description 3
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 3
- 239000000391 magnesium silicate Substances 0.000 description 3
- 229910052919 magnesium silicate Inorganic materials 0.000 description 3
- 235000019792 magnesium silicate Nutrition 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910001051 Magnalium Inorganic materials 0.000 description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004111 Potassium silicate Substances 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000009102 absorption Effects 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000012496 blank sample Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- GHLITDDQOMIBFS-UHFFFAOYSA-H cerium(3+);tricarbonate Chemical compound [Ce+3].[Ce+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O GHLITDDQOMIBFS-UHFFFAOYSA-H 0.000 description 2
- GEZAXHSNIQTPMM-UHFFFAOYSA-N dysprosium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Dy+3].[Dy+3] GEZAXHSNIQTPMM-UHFFFAOYSA-N 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- LCTWRNOEZKTLGG-UHFFFAOYSA-K holmium(3+);trihydroxide Chemical compound [OH-].[OH-].[OH-].[Ho+3] LCTWRNOEZKTLGG-UHFFFAOYSA-K 0.000 description 2
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- DZNFWGVDYGAMJB-UHFFFAOYSA-K neodymium(3+);phosphate Chemical compound [Nd+3].[O-]P([O-])([O-])=O DZNFWGVDYGAMJB-UHFFFAOYSA-K 0.000 description 2
- UZLYXNNZYFBAQO-UHFFFAOYSA-N oxygen(2-);ytterbium(3+) Chemical compound [O-2].[O-2].[O-2].[Yb+3].[Yb+3] UZLYXNNZYFBAQO-UHFFFAOYSA-N 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 2
- 229910052913 potassium silicate Inorganic materials 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 235000019795 sodium metasilicate Nutrition 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- ZIKATJAYWZUJPY-UHFFFAOYSA-N thulium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Tm+3].[Tm+3] ZIKATJAYWZUJPY-UHFFFAOYSA-N 0.000 description 2
- 229910003454 ytterbium oxide Inorganic materials 0.000 description 2
- 229940075624 ytterbium oxide Drugs 0.000 description 2
- KVCOOBXEBNBTGL-UHFFFAOYSA-H ytterbium(3+);trisulfate Chemical compound [Yb+3].[Yb+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O KVCOOBXEBNBTGL-UHFFFAOYSA-H 0.000 description 2
- MAYVZUQEFSJDHA-UHFFFAOYSA-N 1,5-bis(methylsulfanyl)naphthalene Chemical compound C1=CC=C2C(SC)=CC=CC2=C1SC MAYVZUQEFSJDHA-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 150000001169 Lutetium Chemical class 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- BOZVJZYXUJTGTK-UHFFFAOYSA-N [Ho].[Si](O)(O)(O)O Chemical compound [Ho].[Si](O)(O)(O)O BOZVJZYXUJTGTK-UHFFFAOYSA-N 0.000 description 1
- DIFFLMNDXWOKQJ-UHFFFAOYSA-N [K].O[Si](O)(O)O Chemical compound [K].O[Si](O)(O)O DIFFLMNDXWOKQJ-UHFFFAOYSA-N 0.000 description 1
- WOQNJCGKLGKAIE-UHFFFAOYSA-N [O].[Nd] Chemical compound [O].[Nd] WOQNJCGKLGKAIE-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003471 anti-radiation Effects 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- VYLVYHXQOHJDJL-UHFFFAOYSA-K cerium trichloride Chemical compound Cl[Ce](Cl)Cl VYLVYHXQOHJDJL-UHFFFAOYSA-K 0.000 description 1
- UNJPQTDTZAKTFK-UHFFFAOYSA-K cerium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Ce+3] UNJPQTDTZAKTFK-UHFFFAOYSA-K 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- UIUJMPLGCICBOO-UHFFFAOYSA-K dysprosium(3+);phosphate Chemical compound [Dy+3].[O-]P([O-])([O-])=O UIUJMPLGCICBOO-UHFFFAOYSA-K 0.000 description 1
- ABEVUBXCYLEFPJ-UHFFFAOYSA-K dysprosium(3+);trihydroxide Chemical compound [OH-].[OH-].[OH-].[Dy+3] ABEVUBXCYLEFPJ-UHFFFAOYSA-K 0.000 description 1
- YOGVODJHAOWJKG-UHFFFAOYSA-K erbium(3+);triiodate Chemical compound [Er+3].[O-]I(=O)=O.[O-]I(=O)=O.[O-]I(=O)=O YOGVODJHAOWJKG-UHFFFAOYSA-K 0.000 description 1
- YBYGDBANBWOYIF-UHFFFAOYSA-N erbium(3+);trinitrate Chemical compound [Er+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O YBYGDBANBWOYIF-UHFFFAOYSA-N 0.000 description 1
- SYDXSHCNMKOQFW-UHFFFAOYSA-H erbium(3+);trisulfate Chemical compound [Er+3].[Er+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O SYDXSHCNMKOQFW-UHFFFAOYSA-H 0.000 description 1
- HDGGAKOVUDZYES-UHFFFAOYSA-K erbium(iii) chloride Chemical compound Cl[Er](Cl)Cl HDGGAKOVUDZYES-UHFFFAOYSA-K 0.000 description 1
- RCWAXFGXJSYOSZ-UHFFFAOYSA-N erbium;trihydrate Chemical compound O.O.O.[Er] RCWAXFGXJSYOSZ-UHFFFAOYSA-N 0.000 description 1
- GAGGCOKRLXYWIV-UHFFFAOYSA-N europium(3+);trinitrate Chemical compound [Eu+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O GAGGCOKRLXYWIV-UHFFFAOYSA-N 0.000 description 1
- NNMXSTWQJRPBJZ-UHFFFAOYSA-K europium(iii) chloride Chemical compound Cl[Eu](Cl)Cl NNMXSTWQJRPBJZ-UHFFFAOYSA-K 0.000 description 1
- WLYAEQLCCOGBPV-UHFFFAOYSA-N europium;sulfuric acid Chemical compound [Eu].OS(O)(=O)=O WLYAEQLCCOGBPV-UHFFFAOYSA-N 0.000 description 1
- 229910052635 ferrosilite Inorganic materials 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- HCTJCAORMLSTGD-UHFFFAOYSA-N formic acid;magnesium Chemical compound [Mg].OC=O HCTJCAORMLSTGD-UHFFFAOYSA-N 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229910001938 gadolinium oxide Inorganic materials 0.000 description 1
- 229940075613 gadolinium oxide Drugs 0.000 description 1
- RQXZRSYWGRRGCD-UHFFFAOYSA-H gadolinium(3+);tricarbonate Chemical compound [Gd+3].[Gd+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O RQXZRSYWGRRGCD-UHFFFAOYSA-H 0.000 description 1
- CMIHHWBVHJVIGI-UHFFFAOYSA-N gadolinium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Gd+3].[Gd+3] CMIHHWBVHJVIGI-UHFFFAOYSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- GHJOLHIXGZDNBM-UHFFFAOYSA-N holmium phosphoric acid Chemical compound [Ho].P(O)(O)(O)=O GHJOLHIXGZDNBM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 description 1
- ICAKDTKJOYSXGC-UHFFFAOYSA-K lanthanum(iii) chloride Chemical compound Cl[La](Cl)Cl ICAKDTKJOYSXGC-UHFFFAOYSA-K 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- LBWLQVSRPJHLEY-UHFFFAOYSA-K neodymium(3+);tribromide Chemical compound Br[Nd](Br)Br LBWLQVSRPJHLEY-UHFFFAOYSA-K 0.000 description 1
- CFYGEIAZMVFFDE-UHFFFAOYSA-N neodymium(3+);trinitrate Chemical compound [Nd+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O CFYGEIAZMVFFDE-UHFFFAOYSA-N 0.000 description 1
- OJSWEKSDNUORPG-UHFFFAOYSA-H neodymium(3+);trisulfate Chemical compound [Nd+3].[Nd+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OJSWEKSDNUORPG-UHFFFAOYSA-H 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- MMKQUGHLEMYQSG-UHFFFAOYSA-N oxygen(2-);praseodymium(3+) Chemical compound [O-2].[O-2].[O-2].[Pr+3].[Pr+3] MMKQUGHLEMYQSG-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000005365 phosphate glass Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- MLIHUFPNSMZNBP-UHFFFAOYSA-N phosphoric acid thulium Chemical compound [Tm].P(O)(O)(O)=O MLIHUFPNSMZNBP-UHFFFAOYSA-N 0.000 description 1
- OXHXATNDTXVKAU-UHFFFAOYSA-N phosphoric acid zinc Chemical compound [Zn].OP(O)(O)=O OXHXATNDTXVKAU-UHFFFAOYSA-N 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229910003447 praseodymium oxide Inorganic materials 0.000 description 1
- ZLGIGTLMMBTXIY-UHFFFAOYSA-K praseodymium(3+);trihydroxide Chemical compound [OH-].[OH-].[OH-].[Pr+3] ZLGIGTLMMBTXIY-UHFFFAOYSA-K 0.000 description 1
- HWZAHTVZMSRSJE-UHFFFAOYSA-H praseodymium(iii) sulfate Chemical compound [Pr+3].[Pr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O HWZAHTVZMSRSJE-UHFFFAOYSA-H 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- LVSITDBROURTQX-UHFFFAOYSA-H samarium(3+);trisulfate Chemical compound [Sm+3].[Sm+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O LVSITDBROURTQX-UHFFFAOYSA-H 0.000 description 1
- DYRWWVFQQONJJK-UHFFFAOYSA-K scandium(3+);phosphate Chemical compound [Sc+3].[O-]P([O-])([O-])=O DYRWWVFQQONJJK-UHFFFAOYSA-K 0.000 description 1
- DFCYEXJMCFQPPA-UHFFFAOYSA-N scandium(3+);trinitrate Chemical compound [Sc+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O DFCYEXJMCFQPPA-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- DIRSQPIRPNAECV-UHFFFAOYSA-N terbium;trihydrate Chemical compound O.O.O.[Tb] DIRSQPIRPNAECV-UHFFFAOYSA-N 0.000 description 1
- ZXOGQNPNWAUSGY-UHFFFAOYSA-H thulium(3+);tricarbonate Chemical compound [Tm+3].[Tm+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O ZXOGQNPNWAUSGY-UHFFFAOYSA-H 0.000 description 1
- LLZBVBSJCNUKLL-UHFFFAOYSA-N thulium(3+);trinitrate Chemical compound [Tm+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O LLZBVBSJCNUKLL-UHFFFAOYSA-N 0.000 description 1
- NEEAOWXTIOQDFM-UHFFFAOYSA-H thulium(3+);trisulfate Chemical compound [Tm+3].[Tm+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O NEEAOWXTIOQDFM-UHFFFAOYSA-H 0.000 description 1
- ILOTUXNTERMOJL-UHFFFAOYSA-K thulium(iii) chloride Chemical compound Cl[Tm](Cl)Cl ILOTUXNTERMOJL-UHFFFAOYSA-K 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- PYOOBRULIYNHJR-UHFFFAOYSA-K trichloroholmium Chemical compound Cl[Ho](Cl)Cl PYOOBRULIYNHJR-UHFFFAOYSA-K 0.000 description 1
- XRADHEAKQRNYQQ-UHFFFAOYSA-K trifluoroneodymium Chemical compound F[Nd](F)F XRADHEAKQRNYQQ-UHFFFAOYSA-K 0.000 description 1
- KUBYTSCYMRPPAG-UHFFFAOYSA-N ytterbium(3+);trinitrate Chemical compound [Yb+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O KUBYTSCYMRPPAG-UHFFFAOYSA-N 0.000 description 1
- 229910000347 yttrium sulfate Inorganic materials 0.000 description 1
- RTAYJOCWVUTQHB-UHFFFAOYSA-H yttrium(3+);trisulfate Chemical compound [Y+3].[Y+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RTAYJOCWVUTQHB-UHFFFAOYSA-H 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/38—Condensed phosphates
- C01B25/44—Metaphosphates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of magnesium metaphosphorate aluminium powder bodies for optical glass, magnesium source, silicon source, phosphorus source are dispersed in water respectively, then put into autoclave, it is uniform that rare earth element additives mixed is added, presoma is prepared using hydrothermal synthesis method, then presoma is subjected to polymerization reaction acquisition.Invention additionally discloses a kind of magnesium metaphosphorate aluminium raw powder's production technologies for optical glass, magnesium metaphosphorate aluminium powder body is manufactured using hydrothermal synthesis-polymerization method, and it is doped with rare earth element, the magnesium metaphosphorate aluminium powder body of acquisition, which is applied to optical glass, has good blue light and ultraviolet transmitance, chemical resistance, weatherability, wearability.
Description
Technical field
The present invention relates to technical field of chemistry, and in particular to a kind of magnesium metaphosphorate aluminium powder body and its system for optical glass
Preparation Method.
Background technique
Since the 21th century, the rise period of photoelectric information industry entry high speed development, in order to meet various high-accuracy light
Requirement of the electric equipment to higher performances such as information collection, transmission, storage, conversion and displays, and it is more small-sized to optical element
Change light-weighted requirement, application of the optical glass in fields such as optical transport, light conversion, light storage and photoelectric displays rapidly develops；
Optical glass is used to manufacture the glass material of lens, prism, reflecting mirror, window of optical instrument or mechanical system etc., including nothing
Color optical glass (usual abbreviation optical glass), color optical glass, anti-radiation optical glass, non-browning glass and optical quartz
Glass etc..Optical glass has the transparency of height, chemistry and high homogeneity physically, has specific and accurate light
Learn constant；The raw material for producing optical glass is some oxides, hydroxide, nitrate and carbonate, and is wanted according to formula
Ask, introduce phosphate or fluoride, magnesium metaphosphorate aluminium powder body of the present invention, be exactly lanthanum raw material it
One.
The applicant have patent (" a kind of aluminium metaphosphate powder and preparation method thereof for optical glass ", 2017, it is public
The number of opening: 107500261A) a kind of aluminium metaphosphate powder and preparation method thereof for optical glass is disclosed, silicon source is dissolved in
In alcohols solvent I, phosphorus source is dissolved in alcohols solvent II, aluminium metaphosphate is synthesized using sol-gel-polymerization method, and
Pre-treatment is carried out using metal-chelator, foreign metal is chelated and is not involved in reaction, significantly reduces raw material, equipment introduces
Objectionable impurities metal improves the purity of aluminium metaphosphate, and the aluminium metaphosphate impurity metal content of acquisition is low, wherein transition metal member
Element: iron, chromium, nickel, manganese, copper, cobalt content are below 3ppm, from raw material to product removal of impurity 90% or more；Product purity
Height, even particle distribution；The aluminium metaphosphate of acquisition is applied to phosphate glass, fluorphosphate glass and laser fusion glass etc.
The production of optical glass.
The related report for finding no the rare earth doped element in the production of metaphosphoric acid magnalium in the prior art, does not also use
Hydrothermal synthesis-polymerization method is reported to obtain the related of metaphosphoric acid magnalium.
Summary of the invention
The object of the present invention is to provide a kind of magnesium metaphosphorate aluminium powder bodies for optical glass, using hydrothermal synthesis-polymerization
Method manufacture magnesium metaphosphorate aluminium powder body, and be doped with rare earth element, the magnesium metaphosphorate aluminium powder body of acquisition is applied to optical glass
With good blue light and ultraviolet transmitance, chemical resistance, weatherability, wearability.
In order to achieve the above objectives, the technical solution of the present invention is as follows:
Magnesium metaphosphorate aluminium powder body for optical glass of the invention, magnesium source, silicon source, phosphorus source is dispersed in water respectively, then
It is uniform that rare earth element additives mixed is added, reactant is prepared using hydrothermal synthesis method, will be obtained after reactants dry, crushing
Presoma is obtained, then presoma is placed in progress polymerization reaction acquisition under high temperature.
Further, the magnesium metaphosphorate aluminium raw powder's production technology for optical glass the following steps are included:
A, magnesium source is dispersed in water acquisition mixed liquor A, silicon source is dispersed in water acquisition mixed liquid B, disperses water for phosphorus source
Middle acquisition mixed liquor C；
B, it is put into autoclave after mixing mixed liquor A, mixed liquid B, mixed liquor C, rare earth element additive is then added
It is uniformly mixed, hydro-thermal reaction is carried out at 120-250 DEG C, the reaction time is 0.5 hour or more, obtains reaction product；
C, reaction product is dry, crushing, screening obtain presoma；Presoma is subjected to polymerization reaction at 200-1000 DEG C,
Reaction time is 0.5 hour or more, obtains final products.
Further, drying temperature is 80-120 DEG C in the step C, crushes, filters out the powder that partial size is 2-50 μm.
Further, the magnesium source is magnesia, magnesium hydroxide, magnesium carbonate, magnesium chloride, magnesium sulfate, magnesium nitrate, formic acid
Magnesium, magnesium acetate, magnesium oleate, magnesium citrate, amino acid-magnesium chelate, ethylenediamine tetra-acetic acid magnesium, magnesium tartrate, tannic acid magnesium, magnesium benzoate, horse
Carry out the mixture of one or more of sour magnesium, magnesium oxalate.
Further, the silicon source is aluminium oxide, aluminium hydroxide, aluminium carbonate, aluminium chloride, aluminum sulfate, aluminum nitrate, formic acid
Aluminium, aluminium acetate, aluminum oleate, aluminium citrate, amino acid aluminium, ethylenediamine tetra-acetic acid aluminium, tartaric acid aluminium, tannalum, aluminum benzoate, horse
Carry out the mixture of one or more of sour aluminium, oxalic acid aluminium.
Further, the phosphorus source is phosphorus trichloride, phosphorus pentoxide, phosphoric acid, ammonium phosphate, sodium phosphate, potassium phosphate, phosphoric acid
The mixture of one or more of calcium, trbasic zinc phosphate, ferric phosphate, strontium phosphate, phosphorus oxychloride, phosphate.
Further, in the rare earth element additive containing lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium,
One of thulium, ytterbium, lutetium, yttrium, scandium element are a variety of.
Further, the rare earth element form in the rare earth element additive is simple substance, oxide, hydroxide, halogen
One of plain compound, sulfate, nitrate, phosphate, silicate or a variety of mixing.
Further, the magnesium source, silicon source, phosphorus source, rare earth element additive mass ratio be 10-90:10-90:100:
0.01-5。
The present invention has following remarkable result:
The present invention is doped with rare earth element by manufacturing magnesium metaphosphorate aluminium powder body using hydrothermal synthesis-polymerization method, obtains
Magnesium metaphosphorate aluminium powder body be applied to optical glass and manufacture field, there is following good effect: improving blue light and ultraviolet
Transmitance, can be applied to the optical glass fields such as digital camera, 3D digital telescope, liquid crystal sheet glass；It significantly improves
The chemical stability of optical glass can be applied to the optical glass such as long-life optical instrument and semiconductor；Weatherability is promoted, and can be answered
Optical glass for functions such as ultraviolet reflectance, infrared absorptions；So that twice of abrasion degree reduction or more, it can be applied to high wear ring
The optical glass in border.It reacts overall process and does not use organic solvent, it is environmentally friendly；Technical process is simple, and step is compact, investment
It is few, it is at low cost, there is dissemination.
Specific embodiment
In order to keep the objectives, technical solutions, and advantages of the present invention more concise, present invention following specific embodiments
It is illustrated, but the present invention is by no means limited to these examples.The following is only the preferred embodiment of the present invention, is only used for describing
The present invention should not be understood as limiting the scope of the present invention.It should be pointed out that institute all within the spirits and principles of the present invention
Any modifications, equivalent replacements, and improvements etc. done, should all be included in the protection scope of the present invention.
Embodiment 1
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 1kg amino acid-magnesium chelate, 2.1kg magnesium formate, 0.6kg magnesium oleate are dispersed in water acquisition mixed liquor A；By 3Kg aluminium acetate,
1.5Kg maleic acid aluminium, 0.7Kg aluminium citrate are dispersed in water acquisition mixed liquid B；It disperses 4kg ammonium phosphate, 6kg trbasic zinc phosphate in
Mixed liquor C is obtained in water；
B, mixed liquor A, mixed liquid B and mixed liquor C are put into autoclave, 0.01kg lanthanum chloride, 0.025kg is then added
Samaric hydroxide is uniformly mixed；Hydro-thermal reaction 12 hours, obtains reaction product under conditions of 120 DEG C；
C, by reaction product at 85 DEG C freeze-day with constant temperature, then crush, screen, the part that 8 μm of collection cut size is as presoma；It will
After presoma carries out polymerization reaction 0.5 hour at 1000 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 2
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 4kg magnesium chloride, 1.5kg magnesium sulfate are dispersed in water acquisition mixed liquor A；By 3.5Kg aluminium oxide, 1.5Kg hydroxide
Aluminium is dispersed in water acquisition mixed liquid B；5kg phosphoric acid, 5kg sodium phosphate are dispersed in water and obtain mixed liquor C；
B, mixed liquor A, mixed liquid B and mixed liquor C are put into autoclave, 0.1kg europium, 0.25kg nitre is then added
Sour praseodymium is uniformly mixed；Hydro-thermal reaction 5 hours, obtains reaction product under the conditions of 160 DEG C；
C, by reaction product at 100 DEG C freeze-day with constant temperature, then crush, screen, the part that 20 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 4 hours at 600 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 3
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 0.7kg ethylenediamine tetra-acetic acid magnesium, 2.3kg magnesium tartrate are dispersed in water acquisition mixed liquor A；By 2Kg amino acid aluminium,
0.5kg tannalum, 4.7kg aluminum benzoate are dispersed in water acquisition mixed liquid B；Water is dispersed by 2kg ferric phosphate, 8kg strontium phosphate
Middle acquisition mixed liquor C；
B, will mixed liquor A, mixed liquid B and mixed liquor C put into autoclave in, then be added 0.005kg cerous carbonate,
0.015kg holimium oxide, 0.008kg ytterbium sulfate are uniformly mixed；Hydro-thermal reaction 2 hours, obtain reaction product under 250 DEG C of items；
C, by reaction product at 115 DEG C freeze-day with constant temperature, then crush, screen, the part that 50 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 12 hours at 200 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 4
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 7kg maleic acid magnesium, 0.09kg magnesium citrate, 1.2kg tannic acid magnesium are dispersed in water acquisition mixed liquor A；By 3Kg formic acid
Aluminium, 5.2kg aluminum oleate are dispersed in water acquisition mixed liquid B；9kg phosphate, 1kg calcium phosphate are dispersed in water acquisition mixed liquor
C；
B, mixed liquor A, mixed liquid B and mixed liquor C are put into autoclave, 0.2kg neodymium phosphate, 0.003kg is then added
Silicic acid erbium, 0.067kg thulium oxide are uniformly mixed；Hydro-thermal reaction 10 hours, obtains reaction product under the conditions of 130 DEG C；
C, by reaction product at 120 DEG C freeze-day with constant temperature, then crush, screen, the part that 40 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 10 hours at 300 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 5
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 3.5kg magnesium nitrate, 2.5kg magnesium acetate are dispersed in water acquisition mixed liquor A；By 4Kg ethylenediamine tetra-acetic acid aluminium,
2.5kg tartaric acid aluminium is dispersed in water acquisition mixed liquid B；10kg phosphorus trichloride is dispersed in water and obtains dispersion liquid C；
B, mixed liquor A, mixed liquid B and dispersion liquid C are put into autoclave, 0.3kg dysprosium hydroxide, 0.04kg is then added
Gadolinium carbonate is uniformly mixed；Hydro-thermal reaction 0.5 hour, obtains reaction product under the conditions of 240 DEG C；
C, by reaction product at 800 DEG C freeze-day with constant temperature, then crush, screen, the part that 45 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 2 hours at 900 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 6
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 2kg magnesia, 6kg magnesium oxalate are dispersed in water acquisition mixed liquor A；9Kg aluminum sulfate is dispersed in water point
Dispersion liquid B；3.5kg phosphorus pentoxide, 6.5kg phosphorus oxychloride are dispersed in water and obtain mixed liquor C；
B, mixed liquor A, dispersion liquid B and mixed liquor C are put into autoclave, 0.4kg lutecium chloride, 0.06kg europium is then added
Simple substance is uniformly mixed；Hydro-thermal reaction 7 hours, obtains reaction product under the conditions of 220 DEG C；
C, by reaction product at 105 DEG C freeze-day with constant temperature, then crush, screen, the part that 30 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 5 hours at 700 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 7
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 3kg magnesium hydroxide, 3.5kg magnesium carbonate are dispersed in water acquisition mixed liquor A；7Kg aluminum nitrate is dispersed in water and is obtained
Obtain dispersion liquid B；10kg potassium phosphate is dispersed in water and obtains dispersion liquid C；
B, mixed liquor A, dispersion liquid B and dispersion liquid C are put into autoclave, 0.05kg promethium simple substance, 0.1kg oxygen is then added
Change scandium, is uniformly mixed；Hydro-thermal reaction 9 hours, obtains reaction product under the conditions of 125 DEG C；
C, by reaction product at 90 DEG C freeze-day with constant temperature, then crush, screen, the part that 2 μm of collection cut size is as presoma；It will
After presoma carries out polymerization reaction 9 hours at 400 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 8
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 9kg magnesium benzoate is dispersed in water and obtains dispersion liquid A；5Kg aluminium chloride is dispersed in water and obtains dispersion liquid B；It will
1kg sodium phosphate, 9kg ammonium phosphate, which are dispersed in water, obtains mixed liquor C；
B, dispersion liquid A, dispersion liquid B and mixed liquor C are put into autoclave, 0.005kg phosphoric acid holmium, 0.32kg is then added
Silicic acid promethium is uniformly mixed；Hydro-thermal reaction 8 hours, obtains reaction product under the conditions of 140 DEG C；
C, by reaction product at 110 DEG C freeze-day with constant temperature, then crush, screen, the part that 35 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 6 hours at 800 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 9
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 8kg magnesium citrate, 0.4kg magnesium carbonate are dispersed in water acquisition mixed liquor A；By 5Kg aluminium oxide, 2.6kg benzoic acid
Aluminium is dispersed in water acquisition mixed liquid B；7.5kg trbasic zinc phosphate, 2.5kg phosphorus pentoxide are dispersed in water and obtain mixed liquor C；
B, will mixed liquor A, mixed liquid B and mixed liquor C put into autoclave in, then be added 0.035kg erbium sulfate,
0.007kg thulium chloride is uniformly mixed；Hydro-thermal reaction 4 hours, obtains reaction product under the conditions of 200 DEG C；
C, by reaction product at 95 DEG C freeze-day with constant temperature, then crush, screen, the part that 15 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 8 hours at 500 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 10
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 1kg magnesium formate, 6kg magnesium chloride, 1.6kg magnesium sulfate are dispersed in water acquisition mixed liquor A；By 3Kg aluminum nitrate,
5.5kg aluminium acetate is dispersed in water acquisition mixed liquid B；6.5kg ferric phosphate, 3.5kg phosphate are dispersed in water and are mixed
Liquid C；
B, mixed liquor A, mixed liquid B and mixed liquor C are put into autoclave, 0.5kg ytterbium oxide is then added, mixing is equal
It is even；Hydro-thermal reaction 6 hours, obtains reaction product under the conditions of 180 DEG C；
C, by reaction product, freeze-day with constant temperature, then crushing, screening collect 25 μm of grain of part as presoma at 108 DEG C；It will
After presoma carries out polymerization reaction 7 hours at 680 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 11
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 1.5kg magnesia, 0.5kg tannic acid magnesium, 3.2kg magnesium benzoate are dispersed in water acquisition mixed liquor A；By 0.6Kg ammonia
Base acid aluminium, 2.5Kg aluminum oleate, 1.4Kg aluminum nitrate are dispersed in water acquisition mixed liquid B；By 4.5kg phosphorus trichloride, 5.5kg phosphoric acid
Ester, which is dispersed in water, obtains mixed liquor C；
B, will mixed liquor A, mixed liquid B and mixed liquor C put into autoclave in, then be added 0.002kg praseodymium oxide,
0.015kg is fluorinated lutetium, is uniformly mixed；Hydro-thermal reaction 11 hours, obtains reaction product under the conditions of 175 DEG C；
C, by reaction product at 117 DEG C freeze-day with constant temperature, then crush, screen, the part that 46 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 11 hours at 250 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 12
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 7.5kg magnesium oxalate, 0.8kg magnesium hydroxide are dispersed in water acquisition mixed liquor A；By 1.5Kg aluminium acetate, 2.2kg second
Ethylenediamine tetraacetic acid (EDTA) aluminium is dispersed in water acquisition mixed liquid B；1kg trbasic zinc phosphate, 9kg ammonium phosphate are dispersed in water and obtain mixed liquor C；
B, mixed liquor A, mixed liquid B and mixed liquor C are put into autoclave, 0.48kg samarium sulphate, gadolinium oxide are then added,
It is uniformly mixed；Hydro-thermal reaction 1 hour, obtains reaction product under the conditions of 235 DEG C；
C, by reaction product at 83 DEG C freeze-day with constant temperature, then crush, screen, the part that 31 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 2.5 hours at 750 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 13
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 2.5kg maleic acid magnesium, 3.7kg amino acid-magnesium chelate, 0.7kg magnesium chloride are dispersed in water acquisition mixed liquor A；By 2.75Kg
Aluminium hydroxide, 3.15kg aluminium citrate, 0.8kg aluminium carbonate are dispersed in water acquisition mixed liquid B；By 4.7kg phosphorus oxychloride,
5.3kg phosphoric acid, calcium phosphate, which are dispersed in water, obtains mixed liquor C；
B, mixed liquor A, mixed liquid B and mixed liquor C are put into autoclave, 0.04kg cerous carbonate, 0.08kg is then added
Phosphoric acid promethium is uniformly mixed；Hydro-thermal reaction 10.5 hours, obtains reaction product under the conditions of 155 DEG C；
C, by reaction product at 114 DEG C freeze-day with constant temperature, then crush, screen, the part that 8 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 9.5 hours at 350 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 14
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 8.5kg magnesium oleate is dispersed in water and obtains dispersion liquid A；Water is dispersed by 5.5Kg aluminum benzoate, 1.7kg aluminium carbonate
Middle acquisition mixed liquid B；10kg phosphate is dispersed in water and obtains dispersion liquid C；
B, dispersion liquid A, mixed liquid B and dispersion liquid C are put into autoclave, 0.004kg silicic acid erbium, 0.12kg is then added
Lanthanum simple substance is uniformly mixed；Hydro-thermal reaction 3 hours, obtains reaction product under the conditions of 230 DEG C；
C, by reaction product at 87 DEG C freeze-day with constant temperature, then crush, screen, the part that 43 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 1 hour at 975 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 15
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 3.5kg ethylenediamine tetra-acetic acid magnesium, 2.1kg magnesium sulfate, 1.6kg magnesium oxide dispersion are obtained into mixed liquor A in water；It will
7.5Kg aluminum sulfate, 1.3kg oilstone acid aluminium, 0.2kg aluminum sulfate are dispersed in water acquisition mixed liquid B；By 3kg phosphoric acid, 5kg phosphoric acid
Zinc, 2kg phosphorus pentoxide, which are dispersed in water, obtains mixed liquor C；
B, mixed liquor A, mixed liquid B and mixed liquor C are put into autoclave, 0.35kg dysprosium chloride, 0.018kg is then added
Terbium hydroxide is uniformly mixed；Hydro-thermal reaction 9.5 hours, obtains reaction product under the conditions of 170 DEG C；
C, by reaction product at 92 DEG C freeze-day with constant temperature, then crush, screen, the part that 5 μm of collection cut size is as presoma；It will
After presoma carries out polymerization reaction 6.5 hours at 450 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 16
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 2.75kg magnesium nitrate, 4.8kg magnesium formate are dispersed in water acquisition mixed liquor A；By 5.75Kg aluminium oxide, 2.1kg carbon
Sour aluminium is dispersed in water acquisition mixed liquid B；10kg phosphoric acid is dispersed in water and obtains dispersion liquid C；
B, mixed liquor A, mixed liquid B and dispersion liquid C are put into autoclave, 0.45kg neodymium fluoride is then added, mixing is equal
It is even；Hydro-thermal reaction 4.5 hours, obtains reaction product under the conditions of 210 DEG C；
C, by reaction product at 96 DEG C freeze-day with constant temperature, then crush, screen, the part that 12 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 3.5 hours at 950 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 17
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 6.5kg magnesium acetate is dispersed in water and obtains dispersion liquid A；Water is dispersed by 3.5Kg aluminium chloride, 3.5kg tartaric acid aluminium
Middle acquisition mixed liquid B；2.8kg ammonium phosphate, 7.2kg potassium phosphate are dispersed in water and obtain mixed liquor C；
B, dispersion liquid A, mixed liquid B and mixed liquor C are put into autoclave, 0.008kg ytterbium oxide, 0.31kg is then added
Scandium phosphate is uniformly mixed；Hydro-thermal reaction 8.5 hours, obtains reaction product under the conditions of 165 DEG C；
C, by reaction product at 111 DEG C freeze-day with constant temperature, then crush, screen, the part that 38 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 10.5 hours at 550 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 18
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 4.5kg magnesia, 3kg magnesium sulfate are dispersed in water acquisition mixed liquor A；By 3.5Kg oxalic acid aluminium, 2.8kg aluminum sulfate,
1.2kg tannalum is dispersed in water acquisition mixed liquid B；10kg phosphorus pentoxide is dispersed in water and obtains dispersion liquid C；
B, will mixed liquor A, mixed liquid B and dispersion liquid C put into autoclave in, then be added 0.02kg holmium hydroxide,
0.25kg oxygen neodymium simple substance is uniformly mixed；Hydro-thermal reaction 5.5 hours, obtain reaction product under the conditions of 190 DEG C；
C, by reaction product at 99 DEG C freeze-day with constant temperature, then crush, screen, the part that 17 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 7.5 hours at 575 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 19
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 5.5kg magnesium acetate, 3.2kg magnesium citrate are dispersed in water acquisition mixed liquor A；It disperses 8.5Kg aluminium hydroxide in
Dispersion liquid B is obtained in water；4.6kg trbasic zinc phosphate, 5.4kg calcium phosphate, sodium phosphate are dispersed in water and obtain mixed liquor C；
B, mixed liquor A, dispersion liquid B and mixed liquor C are put into autoclave, 0.25kg erbium chloride, 0.16kg is then added
Thulium carbonate is uniformly mixed；Hydro-thermal reaction 7.5 hours, obtains reaction product under the conditions of 150 DEG C；
C, by reaction product at 108 DEG C freeze-day with constant temperature, then crush, screen, the part that 26 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 3.5 hours at 650 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 20
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, 5.75kg magnesium carbonate, 1.6 magnesium hydroxides, magnesium chloride are dispersed in water acquisition mixed liquor A；By 6.5Kg aluminum oleate,
2.3kg aluminum nitrate is dispersed in water acquisition mixed liquid B；10kg phosphorus oxychloride is dispersed in water and obtains dispersion liquid C；
B, mixed liquor A, mixed liquid B and dispersion liquid C are put into autoclave, 0.15kg lanthanum nitrate, 0.15kg is then added
Gadolinium siliate is uniformly mixed；Hydro-thermal reaction 6.5 hours, obtains reaction product under the conditions of 170 DEG C；
C, by reaction product at 103 DEG C freeze-day with constant temperature, then crush, screen, the part that 22 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 5.5 hours at 850 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 21
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, by 1.8kg maleic acid magnesium, 0.2kg magnesium acetate, 1kg magnesium citrate, 1kg magnesium chloride, 1kg ethylenediamine tetra-acetic acid magnesium, 1kg
Magnesium tartrate, 1kg tannic acid magnesium, 1kg magnesium oleate, 1kg magnesium oxalate are dispersed in water acquisition mixed liquor A；By 1kg maleic acid aluminium, 1kg
Aluminum acetate, 1kg aluminium citrate, 1kg aluminium chloride, 1kg ethylenediamine tetra-acetic acid aluminium, 1kg tartaric acid aluminium, 1kg tannalum, 1kg phthalandione
Aluminium, 1kg oxalic acid aluminium are dispersed in water acquisition mixed liquid B；By 1kg phosphoric acid, 1kg sodium phosphate, 1kg potassium phosphate, 1kg ammonium phosphate, 1kg
Trbasic zinc phosphate, 1kg ferric phosphate, 1kg phosphorus trichloride, 1kg strontium phosphate, 1kg phosphorus oxychloride, which are dispersed in water, obtains mixed liquor C；
B, mixed liquor A, mixed liquid B and dispersion liquid C are put into autoclave, 0.01kg europium sulfate, 0.01kg is then added
Lutecium chloride, 0.01kg erbium nitrate, 0.01kg silicic acid holmium, 0.01kg neodymium phosphate are uniformly mixed；Hydro-thermal reaction under the conditions of 125 DEG C
1.5 hours, obtain reaction product；
C, by reaction product at 85 DEG C freeze-day with constant temperature, then crush, screen, the part that 12 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 6 hours at 250 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 22
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
It A, will be by 1kg magnesia, 1kg magnesium hydroxide, 1kg magnesium carbonate, 1kg magnesium oleate, 1kg magnesium sulfate, magnesium nitrate, 1kg amino
Sour magnesium, 1kg magnesium formate, 1kg maleic acid magnesium are dispersed in water acquisition mixed liquor A；By 1kg aluminium oxide, 1kg aluminium hydroxide, 1kg carbon
Sour aluminium, 1kg aluminum oleate, 1kg aluminum sulfate, 1kg aluminum nitrate, 1kg amino acid aluminium, 1kg aluminium triformate, 1kg maleic acid aluminium are scattered in water
Middle acquisition mixed liquid B；By 1kg phosphorus trichloride, 1kg phosphorus pentoxide, 1kg phosphoric acid, 1kg sodium phosphate, 1kg potassium phosphate, 1kg phosphoric acid
Ammonium, 1kg phosphate, 1kg phosphorus oxychloride, 1kg ferrosilite, 1kg strontium silicate, which are dispersed in water, obtains mixed liquor C；
B, mixed liquor A, mixed liquid B and dispersion liquid C are put into autoclave, 0.01kg lanthanum simple substance, 0.005kg is then added
Cerium oxide, 0.005kg praseodymium hydroxide, 0.005kg neodymium bromide, 0.005kg sulfuric acid promethium, 0.01kg samaric nitrate are uniformly mixed；?
Hydro-thermal reaction 2 hours, obtain reaction product under the conditions of 130 DEG C；
C, by reaction product at 90 DEG C freeze-day with constant temperature, then crush, screen, the part that 5 μm of collection cut size is as presoma；It will
After presoma carries out polymerization reaction 4 hours at 300 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 23
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
It A, will be by 0.5kg magnesium acetate, 0.5kg magnesium citrate, 0.5kg magnesium chloride, 0.5kg ethylenediamine tetra-acetic acid magnesium, 0.5kg winestone
Sour magnesium, 0.5kg tannic acid magnesium, 0.5kg phthalandione magnesium, 0.5kg magnesium oxalate are dispersed in water acquisition mixed liquor A；By 0.5kg aluminum acetate,
0.5kg aluminium citrate, 0.5kg aluminium chloride, 0.5kg ethylenediamine tetra-acetic acid aluminium, 0.5kg tartaric acid aluminium, 0.5kg tannalum, 0.5kg
Phthalandione aluminium, 0.5kg oxalic acid aluminium are dispersed in water acquisition mixed liquid B；By 1kg silica solution, 1kg silicic acid, 1kg sodium metasilicate, 1kg silicic acid
Potassium, 1kg ammonium silicate, 1kg alumina silicate, magnesium silicate, 1kg lithium metasilicate, 1kg strontium silicate, 1kg polysiloxanes are dispersed in water and are mixed
Close liquid C；
B, will mixed liquor A, mixed liquid B and dispersion liquid C put into autoclave in, then be added 0.001kg terbium simple substance,
0.002kg dysprosia, 0.004kg holmium hydroxide, 0.005kg iodate erbium, 0.002kg thulium sulfate, 0.003kg ytterbium nitrate,
0.006kg lutetium, 0.001kg yttrium silicate, 0.001kg scandium simple substance are uniformly mixed；Hydro-thermal reaction 3 is small under the conditions of 200 DEG C
When, obtain reaction product；
C, by reaction product at 98 DEG C freeze-day with constant temperature, then crush, screen, the part that 15 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 2 hours at 550 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 24
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, by 0.8kg magnesium oleate, 0.2kg magnesium sulfate, 0.3kg magnesium nitrate, 0.7kg amino acid-magnesium chelate, 0.1kg magnesium formate, 0.9kg horse
Come sour magnesium, 0.4kg magnesium acetate, 0.6kg magnesium citrate, 1kg magnesium chloride and is dispersed in water acquisition mixed liquor A；By 2kg aluminium carbonate,
0.2kg aluminum oleate, 0.2kg aluminum sulfate, 0.3kg aluminum nitrate, 0.3kg amino acid aluminium, 0.8kg aluminium triformate, 0.1kg maleic acid aluminium,
0.2kg aluminum acetate, 0.2kg aluminium citrate are dispersed in water acquisition mixed liquid B；By 1kg silica, 1kg silica solution, 1kg silicon
Acid, 1kg sodium metasilicate, 1kg potassium silicate, 1kg ammonium silicate, 1kg alumina silicate, 0.5kg magnesium silicate, 0.5kg lithium metasilicate, 1kg strontium silicate,
1kg polysiloxanes, which is dispersed in water, obtains mixed liquor C；
B, mixed liquor A, mixed liquid B and dispersion liquid C are put into autoclave, 0.02kg europium simple substance, 0.02kg is then added
Cerium chloride, 0.02kg Dineodymium trisulfate, 0.02kg europium nitrate, 0.02kg erbium hydroxide, 0.02kg dysprosium phosphate, 0.02kg lutecium chloride,
0.02kg yttrium sulfate, 0.02kg scandium nitrate, 0.02kg hydroxide promethium, 0.02kg phosphoric acid thulium are uniformly mixed；Under the conditions of 220 DEG C
Hydro-thermal reaction 5 hours, obtain reaction product；
C, by reaction product at 110 DEG C freeze-day with constant temperature, then crush, screen, the part that 32 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 1 hour at 950 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
Embodiment 25
Magnesium metaphosphorate aluminium raw powder's production technology for optical glass of the invention, comprising the following steps:
A, by 0.1kg magnesia, 0.1kg magnesium hydroxide, 0.1kg magnesium carbonate, 0.1kg magnesium oleate, 0.1kg magnesium sulfate, 0.1kg nitre
Sour magnesium, 0.1kg amino acid-magnesium chelate, 0.1kg magnesium formate, 0.1kg maleic acid magnesium, 0.1kg magnesium acetate, 0.1kg magnesium citrate, 0.1kg
Magnesium chloride, 0.1kg ethylenediamine tetra-acetic acid magnesium, 0.1kg magnesium tartrate, 0.1kg tannic acid magnesium, 0.1kg phthalandione magnesium, 0.1kg magnesium oxalate
It is dispersed in water acquisition mixed liquor A；By 0.1kg aluminium oxide, 0.1kg aluminium hydroxide, 0.1kg aluminium carbonate, 0.1kg aluminum oleate,
0.1kg aluminum sulfate, 0.1kg aluminum nitrate, 0.1kg amino acid aluminium, 0.1kg aluminium triformate, 0.1kg maleic acid aluminium, 0.1kg aluminum acetate,
0.1kg aluminium citrate, 0.1kg aluminium chloride, 0.1kg ethylenediamine tetra-acetic acid aluminium, 0.1kg tartaric acid aluminium, 0.1kg tannalum, phthalandione
Aluminium, 0.1kg oxalic acid aluminium are dispersed in water acquisition mixed liquid B；By 1kg silica, 1kg silica solution, 1kg silicic acid, 1kg silicic acid
The poly- silicon oxygen of sodium, 1kg potassium silicate, 1kg ammonium silicate, 0.5kg alumina silicate, 0.5kg magnesium silicate, 1kg lithium metasilicate, 1kg strontium silicate, 1kg
Alkane, which is dispersed in water, obtains mixed liquor C；
B, will mixed liquor A, mixed liquid B and dispersion liquid C put into autoclave in, then be added 0.002kg europium simple substance,
0.002kg lanthana, 0.002kg cerium hydroxide, 0.002kg praseodymium sulfate, 0.002kg neodymium nitrate, 0.002kg phosphoric acid promethium,
0.002kg samarium silicate, 0.002kg Europium chloride, 0.002kg gadolinium simple substance, 0.002kg hydrogen-oxygen terbium, 0.002kg dysprosia, 0.002kg
Holmium chloride, 0.002kg silicic acid erbium, 0.002kg thulium nitrate, 0.002kg ytterbium sulfate, 0.002kg lutecium chloride, 0.002kg yttrium simple substance,
0.002kg scandium simple substance is uniformly mixed；Hydro-thermal reaction 3.5 hours, obtains reaction product under the conditions of 250 DEG C；
C, by reaction product at 120 DEG C freeze-day with constant temperature, then crush, screen, the part that 40 μm of collection cut size is as presoma；
After presoma is carried out polymerization reaction 2.5 hours at 780 DEG C, magnesium metaphosphorate aluminium powder body is obtained.
26 performance test of embodiment
1, optical glass is respectively prepared in the product of 1-20 of the embodiment of the present invention and blank sample, using optical transmittance tester to light
It learns and carries out ultraviolet light and blue light transmission measurement (being expressed as a percentage) on glass；By manufactured optical glass, 5% hydrochloric acid is impregnated
With 5% sodium hydrate aqueous solution regular hour, chemical stability is tested；Optical glass is simulated in growth cabinet
Ultraviolet light and ozone environment test weatherability；Abrasion degree test analysis, test are carried out to optical glass using abrasion degree tester
Wear-resisting property.
2, the experimental data are shown in the following table shown in 1:
Wear-resisting property test result after optical glass is made in table 1
| Test specimen | Transmitance | Chemical stability | Weatherability | Abrasion degree |
| Blank sample | 80% | 48 hours | 120 hours | 10.2% |
| Embodiment 1 | 92% | 88 hours | 144 hours | 8.3% |
| Embodiment 2 | 87% | 96 hours | 207 hours | 7.2% |
| Embodiment 3 | 88% | 87 hours | 261 hours | 6.9% |
| Embodiment 4 | 87% | 88 hours | 202 hours | 5.0% |
| Embodiment 5 | 87% | 87 hours | 212 hours | 7% |
| Embodiment 6 | 86% | 79 hours | 234 hours | 4.1% |
| Embodiment 7 | 87% | 100 hours | 209 hours | 7.5% |
| Embodiment 8 | 93% | 75 hours | 232 hours | 6.2% |
| Embodiment 9 | 85% | 76 hours | 227 hours | 6.3% |
| Embodiment 10 | 91% | 92 hours | 237 hours | 7.5% |
| Embodiment 11 | 90% | 87 hours | 240 hours | 7.4% |
| Embodiment 12 | 86% | 83 hours | 228 hours | 8.2% |
| Embodiment 13 | 87% | 102 hours | 223 hours | 7.2% |
| Embodiment 14 | 88% | 81 hours | 231 hours | 6.8% |
| Embodiment 15 | 89% | 87 hours | 213 hours | 4.3% |
| Embodiment 16 | 88% | 86 hours | 234 hours | 7.5% |
| Embodiment 17 | 93% | 85 hours | 224 hours | 6.6% |
| Embodiment 18 | 89% | 88 hours | 199 hours | 7.7% |
| Embodiment 19 | 89% | 91 hours | 256 hours | 6.3% |
| Embodiment 20 | 87% | 81 hours | 187 hours | 7.2% |
| Embodiment 21 | 86% | 87 hours | 217 hours | 6.9% |
| Embodiment 22 | 85% | 82 hours | 223 hours | 4.1% |
| Embodiment 23 | 90% | 86 hours | 251 hours | 7.0% |
| Embodiment 24 | 89% | 97 hours | 229 hours | 6.2% |
| Embodiment 25 | 92% | 79 hours | 216 hours | 7.5% |
As shown in Table 1, the magnesium metaphosphorate aluminium powder body that the preparation method provided through the invention obtains, embodiment 1-25 can be different
The blue light of the improving optical glass of degree and ultraviolet transmitance, and embodiment 1,8,17,25 is applied on optical glass, effect
It is especially apparent, improves blue light and ultraviolet transmitance to 92% or more, it is thin to can be applied to digital camera, 3D digital telescope, liquid crystal
The optical glass such as glass sheet field；
The chemical-resistance of the embodiment 1-25 different degrees of improving optical glass of energy, and embodiment 2,7,13,24 is applied
On optical glass, effect is especially apparent, so that chemical resistance (5% hydrochloric acid and 5% sodium hydrate aqueous solution impregnate) is promoted 48 hours
More than, the chemical stability of optical glass is improved, can be applied to the optical glass such as optical semiconductor, laser sensor；
The weatherability of the embodiment 1-25 different degrees of improving optical glass of energy, embodiment 3,11,19,23 are applied in optics glass
On glass, effect is especially apparent, so that weatherability promotion 120 hours or more, it can be applied to the functions such as ultraviolet reflectance, infrared absorption
Optical glass；
The wearability of the embodiment 1-25 different degrees of improving optical glass of energy, embodiment 4,6,15,22 are applied in optics glass
On glass, effect is especially apparent, so that twice of abrasion degree reduction or more, it can be applied to the optical glass of high abrasion environment.
Claims (9)
1. a kind of magnesium metaphosphorate aluminium powder body for optical glass, it is characterised in that: disperse magnesium source, silicon source, phosphorus source in respectively
In water, then addition rare earth element additives mixed is uniform, prepares reactant using hydrothermal synthesis method, reactant is done
Presoma is obtained after dry, crushing, then presoma is placed in progress polymerization reaction acquisition under high temperature.
2. as described in claim 1 be used for optical glass magnesium metaphosphorate aluminium powder body, which is characterized in that preparation method include with
Lower step:
A, magnesium source is dispersed in water acquisition mixed liquor A, silicon source is dispersed in water acquisition mixed liquid B, disperses water for phosphorus source
Middle acquisition mixed liquor C；
B, by mixed liquor A, mixed liquid B, mixed liquor C investment autoclave, rare earth element additive is then added, mixing is equal
It is even, hydro-thermal reaction is carried out at 120-250 DEG C, the reaction time is 0.5 hour or more, obtains reaction product；
C, reaction product is dry, crushing, screening obtain presoma；Presoma is subjected to polymerization reaction at 200-1000 DEG C,
Reaction time is 0.5 hour or more, obtains final products.
3. being used for the magnesium metaphosphorate aluminium powder body of optical glass as claimed in claim 2, it is characterised in that: done in the step C
Dry temperature is 80-120 DEG C, crushes, filters out the powder that partial size is 2-50 μm as presoma.
4. being used for the magnesium metaphosphorate aluminium powder body of optical glass as described in claim 1, it is characterised in that: the magnesium source is oxygen
Change magnesium, magnesium hydroxide, magnesium carbonate, magnesium chloride, magnesium sulfate, magnesium nitrate, magnesium formate, magnesium acetate, magnesium oleate, magnesium citrate, amino
One or both of sour magnesium, ethylenediamine tetra-acetic acid magnesium, magnesium tartrate, tannic acid magnesium, magnesium benzoate, maleic acid magnesium, magnesium oxalate with
On mixture.
5. being used for the magnesium metaphosphorate aluminium powder body of optical glass as described in claim 1, it is characterised in that: the silicon source is oxygen
Change aluminium, aluminium hydroxide, aluminium carbonate, aluminium chloride, aluminum sulfate, aluminum nitrate, aluminium triformate, aluminium acetate, aluminum oleate, aluminium citrate, amino
One or both of sour aluminium, ethylenediamine tetra-acetic acid aluminium, tartaric acid aluminium, tannalum, aluminum benzoate, maleic acid aluminium, oxalic acid aluminium with
On mixture.
6. being used for the magnesium metaphosphorate aluminium powder body of optical glass as described in claim 1, it is characterised in that: the phosphorus source is three
Phosphorus chloride, phosphorus pentoxide, phosphoric acid, ammonium phosphate, sodium phosphate, potassium phosphate, calcium phosphate, trbasic zinc phosphate, ferric phosphate, strontium phosphate, trichlorine
The mixture of one or more of oxygen phosphorus, phosphate.
7. being used for the magnesium metaphosphorate aluminium powder body of optical glass as described in claim 1, it is characterised in that: the rare earth element
In additive containing one of lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, yttrium, scandium element or
It is a variety of.
8. calcium/aluminium ion of rare earth doped element as claimed in claim 7 exchanges silica gel, it is characterised in that: the rare earth
Rare earth element form in element additive is simple substance, oxide, hydroxide, halogen compounds, sulfate, nitrate, phosphorus
One of hydrochlorate, silicate or a variety of mixing.
9. such as the described in any item magnesium metaphosphorate aluminium powder bodies for optical glass of claim 1-8, it is characterised in that: described
Magnesium source, silicon source, phosphorus source, rare earth element additive mass ratio be 10-90:10-90:100:0.01-5.
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