CN109133002A - Portable controllable methanol hydrogen production power generation system - Google Patents

Portable controllable methanol hydrogen production power generation system Download PDF

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Publication number
CN109133002A
CN109133002A CN201811256910.0A CN201811256910A CN109133002A CN 109133002 A CN109133002 A CN 109133002A CN 201811256910 A CN201811256910 A CN 201811256910A CN 109133002 A CN109133002 A CN 109133002A
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CN
China
Prior art keywords
hydrogen
generation system
methyl alcohol
electricity generation
shell
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Pending
Application number
CN201811256910.0A
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Chinese (zh)
Inventor
陈杰平
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Zhejiang Qinggu New Energy Automobile Co ltd
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Zhejiang Qinggu New Energy Automobile Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Qinggu New Energy Automobile Co ltd filed Critical Zhejiang Qinggu New Energy Automobile Co ltd
Priority to CN201811256910.0A priority Critical patent/CN109133002A/en
Publication of CN109133002A publication Critical patent/CN109133002A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B31/00Modifications of boiler construction, or of tube systems, dependent on installation of combustion apparatus; Arrangements of dispositions of combustion apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23KFEEDING FUEL TO COMBUSTION APPARATUS
    • F23K5/00Feeding or distributing other fuel to combustion apparatus
    • F23K5/002Gaseous fuel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23KFEEDING FUEL TO COMBUSTION APPARATUS
    • F23K2900/00Special features of, or arrangements for fuel supplies
    • F23K2900/05001Control or safety devices in gaseous or liquid fuel supply lines

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The invention belongs to the technical field of power generation devices, and particularly relates to a portable controllable methanol hydrogen production power generation system. The device comprises a hydrogen production control reaction kettle, a gaseous methanol supply source and a gaseous deionized water supply source which are communicated with the hydrogen production control reaction kettle, and a condenser communicated with the hydrogen production control reaction kettle, wherein the condenser is communicated with a combustion power generation device which is electrically connected with electric equipment. The invention controls the generating power by controlling the generating rate of the hydrogen, so the invention can be suitable for more electric equipment when being used as a temporary power supply, and the invention achieves the purpose of regulating and controlling the reaction rate by regulating the contact area of the catalyst and the reaction raw material, has simple operation, can display the regulating and controlling effect in time and has higher regulating and controlling precision.

Description

Portable controllable hydrogen from methyl alcohol electricity generation system
Technical field
The invention belongs to power generator technical fields, more particularly to a kind of portable controllable hydrogen from methyl alcohol electricity generation system.
Background technique
Certain electrical equipments are limited by use environment, cannot achieve power grid power supply, can only be powered using temporary source, Hydrogen from methyl alcohol power generation is the process that chemical energy is changed into electric energy, and methanol is a kind of common industrial chemicals, and simplicity is easy to get, It is easy to carry, and final product is carbon dioxide and water, it is environmental-friendly, it is a kind of ideal temporary source, but due to The energy consumption of electrical equipment is different, therefore needs a kind of power supply that can change generated output, to adapt to the demand of different electrical equipments.
For example, Chinese utility model patent disclose a kind of instant preparing hydrogen, generating power system of methanol-water [application number: 201320676600.0], which includes hydrogen manufacturing subsystem, power generation sub-system, control subsystem;Hydrogen manufacturing System is delivered to power generation sub-system to prepare hydrogen, by hydrogen obtained, and power generation sub-system is real using the hydrogen manufacturing subsystem When the hydrogen gas generation that transmits;The control subsystem includes microprocessor, the first wireless communication module, mobile terminal, and movement is eventually End is equipped with the second wireless communication module;Control command is sent to micro process using the second wireless communication module by the mobile terminal Device, microprocessor order the operation for controlling the hydrogen manufacturing subsystem, power generation sub-system based on the received.
The preparing hydrogen, generating power system that the utility model patent provides has portability and mobility, but still has above-mentioned ask Topic.
Summary of the invention
Regarding the issue above, the present invention provides a kind of portable controllable hydrogen from methyl alcohol electricity generation system.
In order to achieve the above objectives, present invention employs following technical proposals:
A kind of portable controllable hydrogen from methyl alcohol electricity generation system, including hydrogen manufacturing control reaction kettle, gaseous methanol source of supply and gaseous state Deionized water source of supply is connected to hydrogen manufacturing control reaction kettle, further includes the condenser being connected to hydrogen manufacturing control reaction kettle, described cold Condenser is connected to combustion power generation device, and the combustion power generation device is electrically connected with electrical equipment.
In above-mentioned portable controllable hydrogen from methyl alcohol electricity generation system, the combustion power generation device includes sequentially connected hydrogen Boiler, steam turbine and generator, the hydrogen gas boiler are connected with condenser, and the generator is electrically connected with electrical equipment.
In above-mentioned portable controllable hydrogen from methyl alcohol electricity generation system, the hydrogen manufacturing control reaction kettle includes internal with reaction The shell of cavity, catalyst are located in reaction cavity, further include that one end is located in reaction cavity, the other end extends to hull outside Reaction Control Assembly, the Reaction Control Assembly is hermetically connected with the shell, and catalyst is located inside Reaction Control Assembly, rotation Reaction Control Assembly can increase or reduce catalyst with react the contact area of cavity.
In above-mentioned portable controllable hydrogen from methyl alcohol electricity generation system, the Reaction Control Assembly includes fixing with housing sidewall The pedestal of connection, gas-permeable nets are detachably connected on pedestal, and for the gas-permeable nets around being cylindrical in shape, inside has accommodating cavity, institute It states catalyst to be located in accommodating cavity, the gas-permeable nets outer surface is fitted with fixed baffle and flap shutter, the fixed baffle It is fixedly connected with pedestal, the flap shutter is connect with base rotation, and flap shutter is fixedly connected with far from one end of pedestal Shaft cylindrical, the end of the shaft extend to hull outside, and shaft is connect by bearing with housing into rotation, and rotation turns Axis can make flap shutter fit with fixed baffle.
In above-mentioned portable controllable hydrogen from methyl alcohol electricity generation system, the fixed baffle side has sealing cavity, rotation Shaft can be such that flap shutter is located in sealing cavity, and the outer surface of flap shutter and the inner surface of fixed baffle are affixed at this time It closes.
In above-mentioned portable controllable hydrogen from methyl alcohol electricity generation system, the susceptor surface has circular orbit, the rotation One end of baffle is slidably connected in circular orbit, and the side of pedestal is also fixedly connected with several connecting rods, the connecting rod One end far from pedestal is fixedly connected with the casing.
In above-mentioned portable controllable hydrogen from methyl alcohol electricity generation system, the shaft is equipped with locking teeth, and the locking teeth can edge The direction of axis line of shaft slides, and further includes the locking disk being fixedly connected with housing exterior walls, and the locking panel surface has downward The latch recess of recess, slide lock fixed tooth can be such that locking teeth is located in latch recess.
In above-mentioned portable controllable hydrogen from methyl alcohol electricity generation system, the latch recess is circumferentially uniform along the axial line of shaft Distribution.
In above-mentioned portable controllable hydrogen from methyl alcohol electricity generation system, the aperture of the gas-permeable nets is less than the partial size of catalyst.
In above-mentioned portable controllable hydrogen from methyl alcohol electricity generation system, the shell is removably connected with gas circulator, institute Gas circulator is stated to be located in reaction cavity.
Compared with prior art, the present invention has the advantages that
1, the present invention controls generated output by the generating rate of control hydrogen, when pretending as temporary source, is applicable to More electrical equipments.
2, the present invention achievees the purpose that regulate and control reaction rate, behaviour by adjusting the contact area of catalyst and reaction raw materials Make simply, regulating effect can show that control accuracy is higher in time.
3, the present invention is equipped with gas circulator in reaction kettle, two different unstrpped gases can be promoted to be sufficiently mixed.
Detailed description of the invention
Fig. 1 is structural schematic diagram of the invention
Fig. 2 is the structural schematic diagram of hydrogen manufacturing control reaction kettle;
Fig. 3 is the top view of Reaction Control Assembly;
Fig. 4 is the structural schematic diagram of pedestal;
In figure: hydrogen manufacturing controls reaction kettle a, gaseous methanol source of supply b, gaseous state deionized water source of supply c, condenser d, burning Power generator e, electrical equipment f, hydrogen gas boiler g, steam turbine h, generator i, shell 1, reaction cavity 2, catalyst 3, reaction control Device 4 processed, connecting rod 5, locking teeth 6, locking disk 7, latch recess 8, gas circulator 9, pedestal 41, gas-permeable nets 42, accommodate it is empty Chamber 43, fixed baffle 44, flap shutter 45, shaft 46, bearing 47, sealing cavity 48, circular orbit 49.
Specific embodiment
The present invention will be further described in detail with reference to the accompanying drawings and detailed description.
As shown in Figure 1, a kind of portable controllable hydrogen from methyl alcohol electricity generation system, including hydrogen manufacturing control reaction kettle a, gaseous methanol is supplied It answers source b and gaseous state deionized water source of supply c to control reaction kettle a with hydrogen manufacturing to be connected to, further includes being connected to hydrogen manufacturing control reaction kettle a Condenser d, the condenser d are connected to combustion power generation device e, and the combustion power generation device e is electrically connected with electrical equipment f.
The present invention, in use, gaseous methanol source of supply b and gaseous state deionized water source of supply c is into hydrogen manufacturing control reaction kettle a Reaction raw materials, i.e. gaseous methanol and gas deionized water are provided, the generating rate of hydrogen is controlled using hydrogen manufacturing control reaction kettle a, It reacts obtained mixed gas to condense by condenser d, to remove unreacted methanol and deionized water, hydrogen is passed through to burning Combustion power generation in power generator e, and supply electric energy at power generator f, therefore the present invention passes through the generating rate of control hydrogen Generated output is controlled, when pretending as temporary source, is applicable to more electrical equipments.
Specifically, the combustion power generation device e includes sequentially connected hydrogen gas boiler g, steam turbine h and generator i, institute It states hydrogen gas boiler g to be connected with condenser d, the generator i is electrically connected with electrical equipment f.
Referring to figs. 1 and 2, the hydrogen manufacturing control reaction kettle a includes the internal shell 1 with reaction cavity 2, catalysis Agent 3 is located in reaction cavity 2, further includes that one end is located in reaction cavity 2, the other end extends to the reaction controlling outside shell 1 Device 4, the Reaction Control Assembly 4 are tightly connected with shell 1, and catalyst 3 is located inside Reaction Control Assembly 4, rotational response Control device 4 can increase or reduce catalyst 3 with react the contact area of cavity 2.
The present invention reacts under the catalysis of catalyst 3 in use, unstrpped gas is passed through in reaction cavity 2, rotates Reaction Control Assembly 4 increase or reduce catalyst 3 with react the contact area of cavity 2, that is, increase or reduce unstrpped gas and urge The contact area of agent 3, to realize the purpose of reaction rate regulation, it can be seen that, the present invention is by adjusting catalyst 3 and instead The contact area of raw material is answered to achieve the purpose that regulate and control reaction rate, easy to operate, regulating effect can be shown in time, control accuracy It is higher.
Specifically, the Reaction Control Assembly 4 includes the pedestal 41 being fixedly connected with 1 side wall of shell, and gas-permeable nets 42 can Dismantling connection is on pedestal 41, and for the gas-permeable nets 42 around being cylindrical in shape, inside has accommodating cavity 43, and the catalyst 3 is located at In accommodating cavity 43,42 outer surface of gas-permeable nets is fitted with fixed baffle 44 and flap shutter 45, the fixed baffle 44 with Pedestal 41 is fixedly connected, and the flap shutter 45 is rotatablely connected with pedestal 41, and the one end of flap shutter 45 far from pedestal 41 is solid Surely it is connected with shaft 46 cylindrical, when such rotating shaft 46, since shaft 46 is fixedly connected with flap shutter 45, rotation Synchronous rotational motion also occurs for baffle 45, to increase or reduce the area of the exposing of gas-permeable nets 42 outside, that is, increases or reduces The end of the contact area of unstrpped gas and catalyst 3, the shaft 46 extends to outside shell 1, and shaft 46 passes through bearing 47 It is rotatablely connected with shell 1, rotating shaft 46 can make flap shutter 45 fit with fixed baffle 44.
Preferably, the aperture of the gas-permeable nets 42 is less than the partial size of catalyst 3, can prevent catalyst 3 through ventilative in this way Net 42 is fallen in reaction cavity 2.
As shown in Fig. 2, 44 side of fixed baffle has sealing cavity 48, rotating shaft 46 can make flap shutter 45 In in sealing cavity 48, and the outer surface of flap shutter 45 and the inner surface of fixed baffle 44 fit at this time, can improve in this way Leakproofness between flap shutter 45 and fixed baffle 44, so that it is guaranteed that the precision that reaction rate is adjusted.
As shown in figure 4,41 surface of pedestal has circular orbit 49, one end of the flap shutter 45 is slidably connected at In circular orbit 49, the side of pedestal 41 is also fixedly connected with several connecting rods 5, the connecting rod 5 far from pedestal 41 one End is fixedly connected with shell 1, and such flap shutter 45 can rotate during rotation along circular orbit 49, i.e., circular orbit 49 is right Guiding is played the role of in the rotation of flap shutter 45.
In conjunction with shown in Fig. 2 and Fig. 3, the shaft 46 is equipped with locking teeth 6, and the locking teeth 6 can be along the axial line of shaft 46 Direction sliding, further includes the locking disk 7 being fixedly connected with 1 outer wall of shell, and 7 surface of locking disk has the locking to lower recess Groove 8, slide lock fixed tooth 6 can be such that locking teeth 6 is located in latch recess 8.
In use, the direction of axis line along shaft 46 is sliding when rotating shaft 46 makes flap shutter 45 go to suitable position Dynamic locking teeth 6, is located at locking teeth 6 in latch recess 8, and the size and shape of latch recess 8 are adapted with locking teeth 6, therefore Shaft 46 is locked at this time, can not rotate, i.e., the position of flap shutter 45 is locked, to guarantee reaction rate regulation Stability.
Preferably, the latch recess 8 is circumferentially uniformly distributed along the axial line of shaft 46 so that it is convenient to reaction rate Carry out gradient adjusting.
As shown in Fig. 2, the shell 1 is removably connected with gas circulator 9, it is empty that the gas circulator 9 is located at reaction In chamber 2, two different unstrpped gases can be promoted to be sufficiently mixed in this way.
Specific embodiment described herein is only an example for the spirit of the invention.The neck of technology belonging to the present invention The technical staff in domain can make various modifications or additions to the described embodiments or replace by a similar method In generation, however, it does not deviate from the spirit of the invention or beyond the scope of the appended claims.
Although hydrogen manufacturing control reaction kettle a, gaseous methanol source of supply b, the supply of gaseous state deionized water is used more herein Source c, condenser d, combustion power generation device e, electrical equipment f, hydrogen gas boiler g, steam turbine h, generator i, shell 1, reaction cavity 2, catalyst 3, Reaction Control Assembly 4, connecting rod 5, locking teeth 6, locking disk 7, latch recess 8, gas circulator 9, pedestal 41, Gas-permeable nets 42, accommodating cavity 43, fixed baffle 44, flap shutter 45, shaft 46, bearing 47, sealing cavity 48, circular orbit 49 Equal terms, but it does not exclude the possibility of using other terms.The use of these items is only for more easily describe to conciliate Release essence of the invention;Being construed as any additional limitation is disagreed with spirit of that invention.

Claims (10)

1. a kind of portable controllable hydrogen from methyl alcohol electricity generation system, it is characterised in that: control reaction kettle (a) including hydrogen manufacturing, gaseous methanol Source of supply (b) and gaseous state deionized water source of supply (c) are connected to hydrogen manufacturing control reaction kettle (a), further include reacting with hydrogen manufacturing control The condenser (d) of kettle (a) connection, the condenser (d) is connected to combustion power generation device (e), the combustion power generation device (e) and Electrical equipment (f) electrical connection.
2. portable controllable hydrogen from methyl alcohol electricity generation system as described in claim 1, it is characterised in that: the combustion power generation device It (e) include sequentially connected hydrogen gas boiler (g), steam turbine (h) and generator (i), the hydrogen gas boiler (g) and condenser (d) It is connected, the generator (i) is electrically connected with electrical equipment (f).
3. portable controllable hydrogen from methyl alcohol electricity generation system as described in claim 1, it is characterised in that: the hydrogen manufacturing controls reaction kettle It (a) include the internal shell (1) with reaction cavity (2), it further includes that one end is located at that catalyst (3), which is located in reaction cavity (2), React in cavity (2), the other end extends to the external Reaction Control Assembly (4) of shell (1), the Reaction Control Assembly (4) with Shell (1) is tightly connected, and catalyst (3) is located inside Reaction Control Assembly (4), rotational response control device (4) can increase or Reduce contact area catalyst (3) and react cavity (2).
4. portable controllable hydrogen from methyl alcohol electricity generation system as claimed in claim 3, it is characterised in that: the Reaction Control Assembly It (4) include the pedestal (41) being fixedly connected with shell (1) side wall, gas-permeable nets (42) are detachably connected on pedestal (41), described For gas-permeable nets (42) around being cylindrical in shape, inside has accommodating cavity (43), and the catalyst (3) is located in accommodating cavity (43), institute It states gas-permeable nets (42) outer surface and is fitted with fixed baffle (44) and flap shutter (45), the fixed baffle (44) and pedestal (41) It is fixedly connected, the flap shutter (45) and pedestal (41) are rotatablely connected, and the one end of flap shutter (45) far from pedestal (41) It is fixedly connected with shaft cylindrical (46), the end of the shaft (46) extends to shell (1) outside, and shaft (46) passes through Bearing (47) and shell (1) are rotatablely connected, and rotating shaft (46) can make flap shutter (45) fit with fixed baffle (44).
5. portable controllable hydrogen from methyl alcohol electricity generation system as claimed in claim 4, it is characterised in that: fixed baffle (44) side Face has sealing cavity (48), and rotating shaft (46) can be such that flap shutter (45) is located in sealing cavity (48), and rotate at this time The outer surface of baffle (45) and the inner surface of fixed baffle (44) fit.
6. portable controllable hydrogen from methyl alcohol electricity generation system as claimed in claim 4, it is characterised in that: pedestal (41) the surface tool Have circular orbit (49), one end of the flap shutter (45) is slidably connected in circular orbit (49), the side of pedestal (41) Several connecting rods (5) are also fixedly connected with, the connecting rod (5) is fixedly connected far from the one end of pedestal (41) with shell (1).
7. portable controllable hydrogen from methyl alcohol electricity generation system as claimed in claim 4, it is characterised in that: the shaft (46) is equipped with lock Fixed tooth (6), the locking teeth (6) can be slided along the direction of axis line of shaft (46), further include being fixedly connected with shell (1) outer wall Locking disk (7), locking disk (7) surface has the latch recess (8) to lower recess, and slide lock fixed tooth (6) can make to lock Tooth (6) is located in latch recess (8).
8. portable controllable hydrogen from methyl alcohol electricity generation system as claimed in claim 7, it is characterised in that: latch recess (8) edge The axial line of shaft (46) is circumferentially uniformly distributed.
9. portable controllable hydrogen from methyl alcohol electricity generation system as claimed in claim 4, it is characterised in that: the hole of the gas-permeable nets (42) Diameter is less than the partial size of catalyst (3).
10. portable controllable hydrogen from methyl alcohol electricity generation system as claimed in claim 3, it is characterised in that: the shell (1) is detachable It is connected with gas circulator (9), the gas circulator (9) is located in reaction cavity (2).
CN201811256910.0A 2018-10-26 2018-10-26 Portable controllable methanol hydrogen production power generation system Pending CN109133002A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811256910.0A CN109133002A (en) 2018-10-26 2018-10-26 Portable controllable methanol hydrogen production power generation system

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Application Number Priority Date Filing Date Title
CN201811256910.0A CN109133002A (en) 2018-10-26 2018-10-26 Portable controllable methanol hydrogen production power generation system

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CN109133002A true CN109133002A (en) 2019-01-04

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000161076A (en) * 1998-11-27 2000-06-13 Toyo Eng Corp Combined gasification power generation method
CN1774390A (en) * 2003-03-28 2006-05-17 太坤股份有限公司 Hydrogen gas generator
US20060112635A1 (en) * 2004-11-29 2006-06-01 Laixia Yang Portable hydrogen generator and fuel cell system
CN104596001A (en) * 2014-12-29 2015-05-06 广东合即得能源科技有限公司 Air conditioning system based on methanol water hydrogen manufacturing and power generating system and control method thereof
CN206384830U (en) * 2017-01-17 2017-08-08 湖北斯柏生物科技有限公司 A kind of hydrogen production units by carbinol
CN107164776A (en) * 2017-06-29 2017-09-15 赫普热力发展有限公司 A kind of fuel reaction system processed, power plant peak regulation system and power plant
CN209081421U (en) * 2018-10-26 2019-07-09 浙江氢谷新能源汽车有限公司 Portable controllable methanol hydrogen production power generation system

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000161076A (en) * 1998-11-27 2000-06-13 Toyo Eng Corp Combined gasification power generation method
CN1774390A (en) * 2003-03-28 2006-05-17 太坤股份有限公司 Hydrogen gas generator
US20060112635A1 (en) * 2004-11-29 2006-06-01 Laixia Yang Portable hydrogen generator and fuel cell system
CN104596001A (en) * 2014-12-29 2015-05-06 广东合即得能源科技有限公司 Air conditioning system based on methanol water hydrogen manufacturing and power generating system and control method thereof
CN206384830U (en) * 2017-01-17 2017-08-08 湖北斯柏生物科技有限公司 A kind of hydrogen production units by carbinol
CN107164776A (en) * 2017-06-29 2017-09-15 赫普热力发展有限公司 A kind of fuel reaction system processed, power plant peak regulation system and power plant
CN209081421U (en) * 2018-10-26 2019-07-09 浙江氢谷新能源汽车有限公司 Portable controllable methanol hydrogen production power generation system

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