CN109126451A - A kind of flue gases of cock oven system for desulfuration and denitration and method - Google Patents

A kind of flue gases of cock oven system for desulfuration and denitration and method Download PDF

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Publication number
CN109126451A
CN109126451A CN201811288802.1A CN201811288802A CN109126451A CN 109126451 A CN109126451 A CN 109126451A CN 201811288802 A CN201811288802 A CN 201811288802A CN 109126451 A CN109126451 A CN 109126451A
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China
Prior art keywords
gas
coke oven
pipeline
flue
flue gas
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CN201811288802.1A
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Chinese (zh)
Inventor
王满
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Acre Coking and Refractory Engineering Consulting Corp MCC
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Acre Coking and Refractory Engineering Consulting Corp MCC
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Priority to CN201811288802.1A priority Critical patent/CN109126451A/en
Publication of CN109126451A publication Critical patent/CN109126451A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/343Heat recovery
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8625Nitrogen oxides
    • B01D53/8631Processes characterised by a specific device
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8696Controlling the catalytic process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

Abstract

The present invention relates to a kind of flue gases of cock oven system for desulfuration and denitration and method, the smoke inlet of medium temperature flue gas SCR desulfuring and denitrifying apparatus connects coke oven main chimney flue by pipeline one, sets exhaust gas fan one on pipeline one;The smoke inlet of the exhanst gas outlet connection waste-heat recovery device of medium temperature flue gas SCR desulfuring and denitrifying apparatus, the exhanst gas outlet of waste-heat recovery device connect coke oven chimney;The pipeline one of one upstream of exhaust gas fan is connected at the raw coke oven gas on coke oven coke oven uprising tube-flue gas heat-exchanger rig waste gas inlet by pipeline two, sets exhaust gas fan two on pipeline two;The pipeline one in one downstream of exhaust gas fan connects raw coke oven gas-flue gas heat-exchanger rig flue gas outlet by pipeline three.The present invention can effectively solve the problem that the problem of operating cost with high investment, high of flue gases of cock oven purification, while also achieve making full use of for coke oven production process waste heat.

Description

A kind of flue gases of cock oven system for desulfuration and denitration and method
Technical field
The present invention relates to gas cleaning and heat recovery technology field more particularly to a kind of flue gases of cock oven desulphurization denitration systems System and method.
Background technique
During coke oven production, the heating system combustion gas of coke oven obtains enough heats for coal in coke furnace carbonization chamber The destructive distillation of material, fuel gas buring generate a certain amount of NOx because of high temperature in the process, and the sulfur in combustion gas is oxidized to SO2, NOx and SO2It can be discharged with the exhaust gas generated that burns by the flue of coke oven, flue gases of cock oven is carried out only if not adopting an effective measure Change processing, will cause serious pollution to atmospheric environment.Purification to flue gases of cock oven is commonly referred to as to NOx in flue gas And SO2Removing, i.e., to flue gases of cock oven carry out desulphurization denitration processing.
Currently, efficiency is higher in flue gases of cock oven desulfurizing and denitrifying process, running and comparing is reliable and stable surely belongs to SCR method coke oven Fume desulfuring and denitrifying system.In order to improve the utilization efficiency of energy in coke oven production, coke oven production efficiency is improved, coke oven is usual Heat recovery is carried out to the burning waste gas that coke oven heating generates by the way of accumulation of heat, causes the temperature of coke oven flue exhaust gas usual 300 DEG C or less (usually at 220 DEG C~280 DEG C), coke oven flue exhaust gas minimum temperature also has reached 180 DEG C or so, and This temperature range be for the technique using NOx in SCR method removing stack gases it is very unfavorable, need thus useless to flue Gas carries out being again heated to 300 DEG C or more the requirements to adapt to Medium temperature SCR method denitration reaction, or using expensive and reaction Inefficient low temperature SCR denitration catalyst is to adapt to existing flue-gas temperature.If stack gases are heated, it is desirable to provide additional Heat increases the consumption of the energy.According to low temperature SCR denitration catalyst, then it will increase the construction investment of whole system, simultaneously Because catalyst consumption also brings along the increase of production run cost, the purification efficiency of NOx in flue gas can be also reduced.Therefore, no matter Using that above-mentioned mode, it can all increase the environment protection treating cost of manufacturing enterprise.
Summary of the invention
The present invention provides a kind of flue gases of cock oven system for desulfuration and denitration and methods, can effectively solve the problem that flue gases of cock oven is net The problem of operating cost with high investment, high changed, while also achieving making full use of for coke oven production process waste heat.
In order to achieve the above object, the present invention is implemented with the following technical solutions:
A kind of flue gases of cock oven system for desulfuration and denitration, including medium temperature flue gas SCR desulfuring and denitrifying apparatus, waste-heat recovery device and Raw coke oven gas-flue gas heat-exchanger rig;The smoke inlet of the medium temperature flue gas SCR desulfuring and denitrifying apparatus connects coke oven by pipeline one Main chimney flue sets exhaust gas fan one on pipeline one;The exhanst gas outlet of medium temperature flue gas SCR desulfuring and denitrifying apparatus connects waste-heat recovery device Smoke inlet, the exhanst gas outlet of waste-heat recovery device connects coke oven chimney;The pipeline one of one upstream of exhaust gas fan passes through pipeline Two are connected at raw coke oven gas-flue gas heat-exchanger rig waste gas inlet on coke oven coke oven uprising tube, set exhaust gas fan on pipeline two Two;The pipeline one in one downstream of exhaust gas fan connects raw coke oven gas-flue gas heat-exchanger rig flue gas outlet by pipeline three.
Exhaust gas quantity regulating device one, pipeline one and pipeline are set on the pipeline one and the pipeline one in two junction downstream of pipeline Exhaust gas quantity regulating device two is set on the pipeline two of two junctions upstream.
The medium temperature flue gas SCR desulfuring and denitrifying apparatus is made of denitration unit and desulfurization unit, is wherein set in denitration unit Middling temperature DeNOx catalyst and ammonia-gas spraying device;Desulfurization unit is dry method or semi-dry desulphurization unit.
The exhaust gas fan one, exhaust gas fan two are all made of variable-frequency motor control.
A kind of flue gases of cock oven desulfurization denitration method, is realized by following procedure:
Effluent gas temperature in coke oven is at 300 DEG C hereinafter, extracting out from coke oven main chimney flue under the action of exhaust gas fan one; Under the action of exhaust gas fan two, all or part of flue gas is sent to the raw coke oven gas-on coke oven coke oven uprising tube by pipeline two In flue gas heat-exchanger rig, with 650 DEG C or more of the high temperature raw coke oven gas indirect heat exchange flowed in coke oven coke oven uprising tube, raw coke oven gas is absorbed Flue gas after heat heating is sent into the pipeline one in one downstream of exhaust gas fan by pipeline three, mixed with the flue gas in pipeline one It closes, is adjusted by the cooperation of exhaust gas quantity regulating device one and exhaust gas quantity regulating device two, make to enter medium temperature flue gas SCR desulphurization denitration Flue gas before device reaches reaction temperature required by middling temperature DeNOx catalyst;
The suitable flue gas of temperature enters in medium temperature flue gas SCR desulfuring and denitrifying apparatus after mixing, is catalyzed in middling temperature DeNOx Under the action of agent, selective catalytic reduction reaction occurs with the ammonia entered from ammonia-gas spraying device, is completed at the same time to SO in flue gas2's Removing, realizes the desulphurization denitration purified treatment of flue gases of cock oven;
The flue gas feeding waste-heat recovery device for still carrying a large amount of sensible heats is handled by desulphurization denitration, by the heat of flue gas It is converted into the energy that can directly utilize, realizes the effective recycling and utilization of the waste heat of flue gas;
High altitude discharge is carried out finally by coke oven chimney by waste heat flue gas after the recovery.
Compared with prior art, the beneficial effects of the present invention are:
1) by the way that flue pneumatic transmission to oven top of coke oven and the high temperature raw coke oven gas in coke oven coke oven uprising tube exchange heat, make flue gas Temperature reach adapt to the denitrating catalyst requirement of Medium temperature SCR method temperature, thus in the item for not needing additionally to feed big energy Under part, realizes the reduction of the efficient removal and production run cost of flue gases of cock oven NOx, also avoid expensive because using The raising of construction investment and operation and maintenance cost caused by low-temperature SCR method denitrating catalyst;
2) heat exchange of flue gas and high temperature raw coke oven gas in coke oven coke oven uprising tube, while efficiently using raw coke oven gas waste heat, because of cigarette Road exhaust gas itself temperature with higher, there is no use water as heat-exchange working medium in other coke oven coke oven uprising tube UTILIZATION OF VESIDUAL HEAT IN techniques When gasification temperature low (100 DEG C or so) the case where, can guarantee that coke oven coke oven uprising tube inner wall maintains relatively high table in heat exchange Face temperature greatly reduces the probability that tar-like substance is condensed and deposited in coke oven coke oven uprising tube inner wall in raw coke oven gas, is conducive to coke The normal operation of producer gas guiding system;
3) raw gas temperature reduces in the coke oven coke oven uprising tube after exchanging heat, and reduces the work symbol of subsequent gas cooling system It closes, reduces the dosage and waste water production quantity of ammonia water by cooling, improve the efficiency and Environmental Protection Level of entire coking process.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram of flue gases of cock oven system for desulfuration and denitration of the present invention.
In figure: 1. coke oven, 2. 3. waste-heat recovery device of medium temperature flue gas SCR desulfuring and denitrifying apparatus, 4. coke oven coke oven uprising tube 5. Raw coke oven gas -2 8. exhaust gas quantity regulating device of flue gas heat-exchanger rig 6. exhaust gas fan, one 7. exhaust gas fan, one 9. exhausted air quantity tune 2 10. coke oven chimney of regulating device
Specific embodiment
Specific embodiments of the present invention will be further explained with reference to the accompanying drawing:
As shown in Figure 1, a kind of flue gases of cock oven system for desulfuration and denitration of the present invention, including medium temperature flue gas SCR desulfurization are de- Nitre device 2, waste-heat recovery device 3 and raw coke oven gas-flue gas heat-exchanger rig 5;The medium temperature flue gas SCR desulfuring and denitrifying apparatus 1 Smoke inlet connects coke oven main chimney flue by pipeline one, sets exhaust gas fan 1 on pipeline one;Medium temperature flue gas SCR desulphurization denitration dress The smoke inlet of 2 exhanst gas outlet connection waste-heat recovery device 3 is set, the exhanst gas outlet of waste-heat recovery device 3 connects coke oven chimney 10;The pipeline one of one 6 upstream of exhaust gas fan is connected at the raw coke oven gas on coke oven coke oven uprising tube 4-flue gas heat exchange by pipeline two The waste gas inlet of device 5 sets exhaust gas fan 27 on pipeline two;The pipeline one in one 6 downstream of exhaust gas fan is connected by pipeline three Raw coke oven gas-flue gas heat-exchanger rig 5 flue gas outlet.
Exhaust gas quantity regulating device 1, pipeline one and pipe are set on the pipeline one and the pipeline one in two junction downstream of pipeline Exhaust gas quantity regulating device 29 is set on the pipeline two of two junction upstream of road.
The medium temperature flue gas SCR desulfuring and denitrifying apparatus 2 is made of denitration unit and desulfurization unit, is wherein set in denitration unit Middling temperature DeNOx catalyst and ammonia-gas spraying device;Desulfurization unit is dry method or semi-dry desulphurization unit.
The exhaust gas fan 1, exhaust gas fan 27 are all made of variable-frequency motor control.
A kind of flue gases of cock oven desulfurization denitration method, is realized by following procedure:
Effluent gas temperature in coke oven 1 is at 300 DEG C hereinafter, taking out from coke oven main chimney flue under the action of exhaust gas fan 1 Out;Under the action of exhaust gas fan 27, all or part of flue gas is sent to the famine on coke oven coke oven uprising tube 4 by pipeline two In coal gas-flue gas heat-exchanger rig 5, with 650 DEG C or more of the high temperature raw coke oven gas indirect heat exchange flowed in coke oven coke oven uprising tube 4, inhale Flue gas after receiving the heating of raw coke oven gas heat is sent into the pipeline one in one 6 downstream of exhaust gas fan by pipeline three, in pipeline one Flue gas mixing, adjusted by the cooperation of exhaust gas quantity regulating device 1 and exhaust gas quantity regulating device 29, make to enter medium temperature cigarette Flue gas before gas SCR desulfuring and denitrifying apparatus 2 reaches reaction temperature required by middling temperature DeNOx catalyst;
The suitable flue gas of temperature enters in medium temperature flue gas SCR desulfuring and denitrifying apparatus 2 after mixing, urges in middling temperature DeNOx Under the action of agent, selective catalytic reduction reaction occurs with the ammonia entered from ammonia-gas spraying device, is completed at the same time to SO in flue gas2 Removing, realize the desulphurization denitration purified treatment of flue gases of cock oven;
The flue gas feeding waste-heat recovery device 3 for still carrying a large amount of sensible heats is handled by desulphurization denitration, by the heat of flue gas Amount is converted into the energy that can directly utilize, and realizes the effective recycling and utilization of the waste heat of flue gas;
High altitude discharge is carried out finally by coke oven chimney 10 by waste heat flue gas after the recovery.
Medium temperature flue gas SCR desulfuring and denitrifying apparatus 2 of the present invention, using middling temperature DeNOx catalyst (operating temperature 300 DEG C or more), using ammonia in flue gases of cock oven NOx carry out selective catalytic reduction, realize in flue gas NOx it is net Change, while using dry method or semi-dry desulphurization unit to the SO in flue gas2It is removed.Specifically can be used as A kind of similar device of 201520711004.0 Chinese patents " flue gases of cock oven desulphurization denitration combined purifying device ".
The raw coke oven gas-flue gas heat-exchanger rig 5 is risen by the way of indirect heat exchange using flue aspiration coke oven The heat that raw coke oven gas carries in pipe 4, the purpose realized raw coke oven gas heat in recycling coke oven coke oven uprising tube 4, improve effluent gas temperature.
The waste-heat recovery device 3, will be in flue gas using heat transferring medium (such as water) by the way of indirect heat exchange Waste heat is converted to the effective energy (such as steam) that can directly utilize, and can be used for generating electricity, as driving power source or directly use.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (5)

1. a kind of flue gases of cock oven system for desulfuration and denitration, which is characterized in that including medium temperature flue gas SCR desulfuring and denitrifying apparatus, waste heat Recyclable device and raw coke oven gas-flue gas heat-exchanger rig;The smoke inlet of the medium temperature flue gas SCR desulfuring and denitrifying apparatus passes through pipeline One connects coke oven main chimney flue, sets exhaust gas fan one on pipeline one;More than the exhanst gas outlet connection of medium temperature flue gas SCR desulfuring and denitrifying apparatus The exhanst gas outlet of the smoke inlet of heat recovery apparatus, waste-heat recovery device connects coke oven chimney;The pipeline of one upstream of exhaust gas fan One is connected at the raw coke oven gas on coke oven coke oven uprising tube-flue gas heat-exchanger rig waste gas inlet by pipeline two, on pipeline two If exhaust gas fan two;The pipeline one in one downstream of exhaust gas fan connects raw coke oven gas-flue gas heat-exchanger rig flue by pipeline three Gas outlet.
2. a kind of flue gases of cock oven system for desulfuration and denitration according to claim 1, which is characterized in that the pipeline one and pipe Exhaust gas quantity regulating device one is set on the pipeline one in two junction downstream of road, on the pipeline two of pipeline one and two junction upstream of pipeline If exhaust gas quantity regulating device two.
3. a kind of flue gases of cock oven system for desulfuration and denitration according to claim 1, which is characterized in that the medium temperature flue gas SCR desulfuring and denitrifying apparatus is made of denitration unit and desulfurization unit, wherein sets middling temperature DeNOx catalyst and spray in denitration unit Ammonia device;Desulfurization unit is dry method or semi-dry desulphurization unit.
4. a kind of flue gases of cock oven system for desulfuration and denitration according to claim 1, which is characterized in that the exhaust gas fan One, exhaust gas fan two is all made of variable-frequency motor control.
5. a kind of flue gases of cock oven desulfurization denitration method, which is characterized in that realized by following procedure:
Effluent gas temperature in coke oven is at 300 DEG C hereinafter, extracting out from coke oven main chimney flue under the action of exhaust gas fan one;Useless Under the action of gas blower two, all or part of flue gas is sent to raw coke oven gas-flue on coke oven coke oven uprising tube by pipeline two In gas heat-exchanger rig, with 650 DEG C or more of the high temperature raw coke oven gas indirect heat exchange flowed in coke oven coke oven uprising tube, raw coke oven gas heat is absorbed Flue gas after heating is sent into the pipeline one in one downstream of exhaust gas fan by pipeline three, is mixed with the flue gas in pipeline one, It is adjusted by the cooperation of exhaust gas quantity regulating device one and exhaust gas quantity regulating device two, makes to enter medium temperature flue gas SCR desulphurization denitration dress Flue gas before setting reaches reaction temperature required by middling temperature DeNOx catalyst;
The suitable flue gas of temperature enters in medium temperature flue gas SCR desulfuring and denitrifying apparatus after mixing, in middling temperature DeNOx catalyst Under effect, selective catalytic reduction reaction occurs with the ammonia entered from ammonia-gas spraying device, is completed at the same time to SO in flue gas2It is de- It removes, realizes the desulphurization denitration purified treatment of flue gases of cock oven;
The flue gas feeding waste-heat recovery device for still carrying a large amount of sensible heats is handled by desulphurization denitration, and the heat of flue gas is converted At the energy that can directly utilize, the effective recycling and utilization of the waste heat of flue gas are realized;
High altitude discharge is carried out finally by coke oven chimney by waste heat flue gas after the recovery.
CN201811288802.1A 2018-10-31 2018-10-31 A kind of flue gases of cock oven system for desulfuration and denitration and method Pending CN109126451A (en)

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Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59191886A (en) * 1983-04-14 1984-10-31 Ishikawajima Harima Heavy Ind Co Ltd Method of recovering sensible heat from coke-oven gas
JPS61247786A (en) * 1985-04-25 1986-11-05 Nippon Kokan Kk <Nkk> Heat recovering apparatus for coke oven gas
JPS633088A (en) * 1986-06-20 1988-01-08 Sumitomo Metal Ind Ltd Recovery of exhaust heat from coke oven
CN103047637A (en) * 2013-01-25 2013-04-17 中冶赛迪工程技术股份有限公司 Coke furnace flue gas waste heat and ascending pipe coal gas waste heat combined recycling system
CN203095983U (en) * 2013-03-04 2013-07-31 中冶赛迪工程技术股份有限公司 Humidifying device for coking coal
CN104923046A (en) * 2015-05-20 2015-09-23 江苏新世纪江南环保股份有限公司 Coke oven flue gas desulfurization, denitration and waste heat recovery integrated method
CN205948680U (en) * 2016-08-26 2017-02-15 天津诺能达能源科技有限公司 Flue gas denitration processing system
CN107014217A (en) * 2017-05-18 2017-08-04 中冶华天南京工程技术有限公司 Coke-oven plant's coke-stove gas is utilized and smoke processing system and its processing method
CN107830739A (en) * 2017-12-01 2018-03-23 中冶京诚工程技术有限公司 Sinter flue gas whole process cleaning system and its method
CN207351232U (en) * 2017-08-02 2018-05-11 湖南中冶长天节能环保技术有限公司 A kind of coking flue gas purification system
CN207596786U (en) * 2017-08-16 2018-07-10 南京华电节能环保设备有限公司 The equipment that a kind of tedge waste heat recovery and coking smoke comprehensive are administered
CN209302535U (en) * 2018-10-31 2019-08-27 中冶焦耐(大连)工程技术有限公司 A kind of flue gases of cock oven system for desulfuration and denitration

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59191886A (en) * 1983-04-14 1984-10-31 Ishikawajima Harima Heavy Ind Co Ltd Method of recovering sensible heat from coke-oven gas
JPS61247786A (en) * 1985-04-25 1986-11-05 Nippon Kokan Kk <Nkk> Heat recovering apparatus for coke oven gas
JPS633088A (en) * 1986-06-20 1988-01-08 Sumitomo Metal Ind Ltd Recovery of exhaust heat from coke oven
CN103047637A (en) * 2013-01-25 2013-04-17 中冶赛迪工程技术股份有限公司 Coke furnace flue gas waste heat and ascending pipe coal gas waste heat combined recycling system
CN203095983U (en) * 2013-03-04 2013-07-31 中冶赛迪工程技术股份有限公司 Humidifying device for coking coal
CN104923046A (en) * 2015-05-20 2015-09-23 江苏新世纪江南环保股份有限公司 Coke oven flue gas desulfurization, denitration and waste heat recovery integrated method
CN205948680U (en) * 2016-08-26 2017-02-15 天津诺能达能源科技有限公司 Flue gas denitration processing system
CN107014217A (en) * 2017-05-18 2017-08-04 中冶华天南京工程技术有限公司 Coke-oven plant's coke-stove gas is utilized and smoke processing system and its processing method
CN207351232U (en) * 2017-08-02 2018-05-11 湖南中冶长天节能环保技术有限公司 A kind of coking flue gas purification system
CN207596786U (en) * 2017-08-16 2018-07-10 南京华电节能环保设备有限公司 The equipment that a kind of tedge waste heat recovery and coking smoke comprehensive are administered
CN107830739A (en) * 2017-12-01 2018-03-23 中冶京诚工程技术有限公司 Sinter flue gas whole process cleaning system and its method
CN209302535U (en) * 2018-10-31 2019-08-27 中冶焦耐(大连)工程技术有限公司 A kind of flue gases of cock oven system for desulfuration and denitration

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Application publication date: 20190104