CN109126372A - A kind of activated carbon fiber electrothermal desorption structure - Google Patents
A kind of activated carbon fiber electrothermal desorption structure Download PDFInfo
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- CN109126372A CN109126372A CN201811304005.8A CN201811304005A CN109126372A CN 109126372 A CN109126372 A CN 109126372A CN 201811304005 A CN201811304005 A CN 201811304005A CN 109126372 A CN109126372 A CN 109126372A
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- carbon fiber
- activated carbon
- conducting resinl
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
- B01D2259/40096—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating by using electrical resistance heating
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Abstract
The present invention relates to a kind of activated carbon fiber electrothermal desorption structures, including the electrode mechanism being laminated by activated carbon fiber cloth on the activated carbon fiber bed formed and a pair of of side end face that the activated carbon fiber bed is arranged in, the electrode mechanism includes the conducting resinl area being arranged on activated carbon fiber bed end, it is arranged in the conducting resinl area or is arranged in the conductive metal body on conducting resinl area surface and the electrode being connected with the conductive metal body draws connector, the conductive metal body is embedded in inside the conducting resinl area, the conducting resinl area is that activated carbon fiber bed end is at least partially immersed or injects conducting resinl curing molding.Electrode mechanism function admirable in the present invention, the distribution of activated carbon fiber bed temperature is more uniform, and electrode anti-aging property is excellent, and the service life is long.
Description
Technical field
The present invention relates to field of gas purification to be suitable for work more particularly to a kind of activated carbon fiber electrothermal desorption structure
Industry VOCs waste gas purification and recycling apply also for VOCs and the purification of other toxic and harmful gas in room air.
Background technique
Activated carbon fiber (ACF) is the high-efficiency activated adsorbent material of a new generation and environment-friendly function material, is the update of active carbon
Regeneration product.Adsorbent equipment can be made to minimize using activated carbon fiber, adsorption layer is thin layer, and absorption leakage loss is small, high-efficient, energy conservation
Economy can complete the work that granular activated carbon cannot achieve, and be that other types of activated carbon fiber is incomparable and property
Active adsorbing material and environment-friendly engineering material that can be transcendent.Activated carbon fiber is fine with natural fiber or artificial organic chemistry
Dimension is made by carbonization, and main ingredient is made of carbon atom.The shape that carbon atom is mainly folded with similar graphite microcrystal piece, newborn layer heap
Formula exists.Another noticeable structure of ACF is with flourishing specific surface area, micropore diameter abundant.General activated carbon fiber
(ACF) specific surface area is up to 1000~1600m2/ g, micro pore volume are up to 90%, and micropore size is 10~40A.
But activated carbon fiber can only temporarily adsorb pollutant, since there are adsorption saturation states for adsorbent, reach saturation
The adsorbent of state no longer adsorbs pollutant.Activated carbon fiber regeneration refers to either physically or chemically not destroying active carbon
Or under the premise of activated carbon fiber original structure, the adsorbate being adsorbed on active carbon or activated carbon fiber is removed, it is extensive
Its multiple absorption property, to achieve the purpose that reuse.According to existing technology, regeneration is typically all preferred high at present
The advantages of temperature heating method of reproduction, high-temperature heating method of reproduction, is that it can decompose many kinds of substance in regenerative process, and regenerative environ-ment is good
It is good, to become main regeneration method.Also in two kinds of situation, one kind is directly using hot to the high-temperature heating method of reproduction of mainstream at present
Air desorption, energy consumption is high, requires device structure also high;Another kind is directly to regard activated carbon fiber itself as thermal resistance,
It is powered so that activated carbon fiber self-heating realizes desorption.
In activated carbon fiber electro-thermal regeneration, it is attached in bed end face that direct-electrifying usually requires activated carbon fiber fever
It is powered on pole.But activated carbon fiber is flexible material, easily-deformable, there are contact resistances between electrode and activated carbon fiber, and live
Property carbon fiber end face can not it is substantially flat, electrode can not be completely attached to activated carbon fiber end face, cause localized contact resistance
It is excessive.
And another feasible mode is to pass through surface treatment (such as evaporation deposition method, thermal spraying in activated carbon fiber end face
The modes such as method, electroless plating method or ion plating method) attachment certain thickness metal coating, and then form electrode.But in active carbon fiber
Tie up end face formed metal coating cost it is extremely high, not only technique is extremely complex, need specific professional equipment (such as PVD equipment,
CVD equipment), and cost is very high.So the production capacity of regeneration activity carbon fiber is seriously limited using the above method, and by
Application field and direction are also seriously limited in high costs.
Summary of the invention
The purpose of the present invention is to propose to a kind of activated carbon fiber electrothermal desorption structure, by simple structure and technique,
The regeneration production capacity for improving activated carbon fiber, reduces the regeneration cost of activated carbon fiber, to expand the application field of activated carbon fiber.
To achieve the above object, the present invention provides a kind of activated carbon fiber electrothermal desorption structures, including by active carbon fiber
The electrode that Wei Bu is laminated the activated carbon fiber bed to be formed and is arranged on a pair of of side end face of the activated carbon fiber bed
Mechanism, the electrode mechanism include the conducting resinl area being arranged on activated carbon fiber bed end, are arranged in the conduction
Conductive metal body in glue area and the electrode being connected with the conductive metal body draw connector, and the conductive metal body is embedded in
Inside the conducting resinl area, the conducting resinl area is that activated carbon fiber bed end is at least partially immersed or injects conductive adhesive curing
Molding.
Preferably, the activated carbon fiber cloth is braiding or non-woven acf layer.
Preferably, the material of the conductive metal body is copper, silver, lead, gold, tin, cadmium, nickel, iron, platinum simple substance or its conjunction
One of gold.
Preferably, the form of the conductive metal body is metal foil, metal bar, wire or metal block.
Preferably, the conducting resinl area is impregnated by conducting resinl forms, and the conducting resinl is at least silver base conductive glue, auri is led
Electric glue, copper-based conducting resinl or graphite based conducting glue.
Preferably, the volume resistivity in the conducting resinl area is less than 10-2Ω cm, the high temperature resistant temperature in the conducting resinl area
Greater than 100 DEG C.
Preferably, include: the step of activated carbon fiber bed end is at least partially immersed conducting resinl curing molding
Activated carbon fiber cloth is laminated, end part aligning is cut and made according to the size of activated carbon fiber bed,
The activated carbon fiber bed is fixed later, and the end of activated carbon fiber bed is exposed;Simultaneously by conductive metal
Body is drawn connector with electrode and is attached in advance;
Conducting resinl is poured into container, and the end of the activated carbon fiber bed is immersed in conducting resinl;
Activated carbon fiber bed is taken out out of container, conductive metal body is embedded to the end of the activated carbon fiber bed
Interior, electrode is drawn connector and is stayed in outside the end of the activated carbon fiber bed, naturally dry or drying.
Preferably, when the conducting resinl is graphite based conducting glue, the conducting resinl area is formed using baking and curing, drying
Temperature is 60~100 DEG C, and drying time is 30~150min.
Preferably, the width in the conducting resinl area is 0.5~2cm.
Based on the above-mentioned technical proposal, the invention has the advantages that
Activated carbon fiber electrothermal desorption structure of the invention eliminates the contact resistance between electrode and bed end face, in big electricity
When stream passes through electrode, electrode heat production is extremely low, long service life;And it ensure that activated carbon fiber bed face material and electrode are complete
Full connected, electric current contact one end by fabric itself and electrode and flow directly into the other end, avoid conducting generation between layers and connect
Hot-spot phenomenon at contact, so that temperature is evenly distributed on entire bed, temperature gradient is smaller.Due to bed internal current
It is evenly distributed, synchronous consistent heat generation inside and outside bed, organic matter desorption is clean thorough, high-efficient, favorable regeneration effect is desorbed, so that living
Property carbon fibre material can keep good absorption property for a long time.
The present invention draws connector (such as plain conductor, hard contact) by electrode and connect with conductive metal body, avoids
Activated carbon fiber and metal electrode are directly connected to insecure situation, increase the firmness and reliability of electrode application.Meanwhile
It is formed between conductive metal body and activated carbon fiber by conducting resinl and is uniformly connected, avoided traditional approach and need to active carbon fiber
Dimension carries out the step of metalized, reduces technology difficulty, reduces the regeneration cost of activated carbon fiber, be greatly enriched
The application field of activated carbon fiber.
Detailed description of the invention
The drawings described herein are used to provide a further understanding of the present invention, constitutes part of this application, this hair
Bright illustrative embodiments and their description are used to explain the present invention, and are not constituted improper limitations of the present invention.In the accompanying drawings:
Fig. 1 is activated carbon fiber electrothermal desorption structure schematic top plan view;
Fig. 2 is activated carbon fiber electrothermal desorption structure schematic side view;
Fig. 3 is activated carbon fiber electrothermal desorption structure electrical property figure;
Fig. 4 is activated carbon fiber electrothermal desorption structure temperature measuring point distribution map;
Fig. 5 is activated carbon fiber electrothermal desorption structure temperature measuring point distribution map;
Fig. 6 is activated carbon fiber electrothermal desorption structure ageing properties figure.
Specific embodiment
Below by drawings and examples, technical scheme of the present invention will be described in further detail.
The present invention provides a kind of activated carbon fiber electrothermal desorption structures, and this hair is shown as shown in Fig. 1~Fig. 6
A kind of bright preferred embodiments.The present invention improves the regeneration production capacity of activated carbon fiber by simple structure and technique, drop
The regeneration cost of low activity carbon fiber, to expand the application field of activated carbon fiber.
As shown in Figure 1 and Figure 2, the activated carbon fiber electrothermal desorption structure includes being formed by the stacking of activated carbon fiber cloth 2
Activated carbon fiber bed and the electrode mechanism being arranged on a pair of of side end face of the activated carbon fiber bed, the electrode machine
The conductive gold that structure includes the conducting resinl area 1 being arranged on activated carbon fiber bed end, is arranged in the conducting resinl area 1
Belong to body 4 and the electrode being connected with the conductive metal body 4 draws connector 3, the conductive metal body 4 is embedded in the conducting resinl
Inside area 1, the conducting resinl area 1 is that activated carbon fiber bed end is at least partially immersed or injects conducting resinl curing molding.
Preferably, the activated carbon fiber cloth 2 is braiding or non-woven acf layer.Since electrode mechanism is arranged
In carbon fiber bed end, carbon fiber bed is formed using the stacking of activated carbon fiber cloth 2, it requires that carbon fiber needs are woven into
Layer structure, such as common activated carbon eyelet fabric.The non-woven form such as activated carbon fiber cloth 2 or activated carbon-fiber felt, equally
It is that layer structure is suitable for making electrode in non-laminated wheat flour.
The conductive metal body 4 is common conductive material.Preferably, the material of the conductive metal body 4 be copper,
One of silver, lead, gold, tin, cadmium, nickel, iron, platinum simple substance or its alloy.Preferably, the form of the conductive metal body 4
For metal foil, metal bar, wire or metal block.Since activated carbon fiber bed is multilayered structure, can be made using metal foil
Activated carbon fiber bed end it is approximate with the height at middle part, farthest reduce end with centre difference in height, be conducive to
The Standard of the fiber filter of activated carbon in use.And the conductive metal of metal bar, wire or metal block form
Body 4 is then capable of increasing the binding force between conductive metal body 4 and conducting resinl area 1, so that electrode mechanism is more secured.
Further, the conducting resinl area 1 by conducting resinl dipping be formed by curing, the conducting resinl be at least silver base conductive glue,
Auri conducting resinl, copper-based conducting resinl or graphite based conducting glue.Preferably due to which the fever that electrode mechanism will meet high current is wanted
It asks, the volume resistivity in the conducting resinl area 1 is less than 10-2Ω·cm.Simultaneously as activated carbon fiber electrothermal desorption structure needs
Desorption by heating is carried out, to guarantee that electrode mechanism works normally, the high temperature resistant temperature in the conducting resinl area 1 is greater than 100 DEG C.It is preferred that
The width on ground, the conducting resinl area 1 is 0.5~2cm, can either guarantee the combination between conducting resinl area 1 and conductive metal body 4
Power, and enable to contact resistance in preferable range, while also making the damage control of activated carbon fiber bed lesser
Range.
The conducting resinl is a kind of adhesive solidified or have certain electric conductivity after dry.Conducting resinl be it is a kind of solidification or
With the adhesive of certain electric conductivity after drying, it is usually mainly to form with matrix resin and conductive filler, that is, conducting particles
Ingredient is combined together conducting particles by the bonding effect of matrix resin, forms conductive path, and leading for material is glued in realization
Electrical connection.Since contacting with each other between conducting particles to form conductive path, keep conducting resinl conductive, it is interparticle in glue-line
Steady contact is as caused by conductive adhesive curing or drying.
For conducting resinl before solidification or drying, conducting particles is existing for separation, not connect continuously each other in adhesive
Touching, thus it is in state of insulation.After conductive adhesive curing or drying, gluing is caused due to the volatilization of solvent and the solidification of adhesive
The contraction of agent volume, making conducting particles each other is in stable continuous state, thus shows electric conductivity.It is conductive in the present invention
Glue uses naturally dry or drying.Preferably, when the conducting resinl is graphite based conducting glue, the conducting resinl area 1 is using baking
Dry curing molding.Due to graphite based conducting glue naturally dry it is difficult to ensure that intensity after solidifying, solidification are needed in certain temperature
Lower progress.Preferably, drying temperature is 60~100 DEG C, and drying time is 30~150min, not only can guarantee solidification intensity, but also energy
Reduce the mass loss and micropore loss of activated carbon fiber at high temperature.
The present invention draws connector such as plain conductor, hard contact etc. by electrode and connect with conductive metal body, avoids work
Property carbon fiber and metal electrode be directly connected to insecure situation, increase electrode application firmness and reliability.Pass through electricity
Connector is drawn in pole, can be powered to activated carbon fiber bed, and activated carbon fiber bed is realized as thermal resistance itself heat production
Desorption and regeneration.
Meanwhile being formed between conductive metal body and activated carbon fiber by conducting resinl and uniformly being connected, avoid traditional approach
The step of metalized is carried out to activated carbon fiber is needed, technology difficulty is reduced, reduces the regeneration of activated carbon fiber
This, is greatly enriched the application field of activated carbon fiber.
Preferably, include: the step of activated carbon fiber bed end is at least partially immersed conducting resinl curing molding
Activated carbon fiber cloth 2 is laminated, end part aligning is cut and made according to the size of activated carbon fiber bed,
Flash is removed.Preferably, cutting edge is avoided repeatedly to cause activated carbon fiber cloth 2 using disposable cutting in cutting
Damage, influences subsequent impregnation.The activated carbon fiber bed is fixed later, and by the end of activated carbon fiber bed
It is exposed, the exposed 0.5~2cm in end, to control the width in conducting resinl area 1.Conductive metal body 4 and electrode are drawn simultaneously
Connector 3 is attached in advance, is prepared for subsequent electrode fabrication.
Conducting resinl is poured into container, the size of container is slightly larger compared with the size of activated carbon fiber bed end, is led with reducing
The working loss of electric glue.The end of the activated carbon fiber bed is immersed in conducting resinl later, so that conducting resinl is from activated carbon
The end face of fiber bed is immersed internal.
Activated carbon fiber bed is taken out out of container, conductive metal body 4 is embedded to the end of the activated carbon fiber bed
In portion, guarantee being embedded in uncured conducting resinl for conductive metal body 4.Electrode draws connector 3 and stays in the activated carbon fiber
Outside the end of bed, for carrying out electrified regulation in desorption process.Later by the end naturally dry of activated carbon fiber bed
Or drying.
At least partly injection conducting resinl curing molding also can be used in activated carbon fiber bed end in the present invention.It is adopting
When with the mode for injecting conducting resinl curing molding, need to squeeze into conducting resinl by pressure the fiber of activated carbon fiber bed end
Inside, and apply pressure in activated carbon fiber bed end, to guarantee the uniformity of conducting resinl.
Activated carbon fiber electrothermal desorption structure of the invention is powered, electric property test is carried out.As shown in figure 3, whole
In a temperature-rise period, heating curve is very smooth, electrode mechanism function admirable.
As shown in figure 4, laying six temperature measuring points of B, E, F, G, H, I to activated carbon fiber bed, energization heats up.Activity
The temperature lift-down curve of carbon fiber bed is as shown in figure 5, the electrode mechanism in through the invention heats up, activated carbon fiber bed
Temperature Distribution is more uniform, and maximum temperature is differed with minimum temperature is no more than 10 DEG C, and electrode mechanism of the invention can guarantee to live
Property carbon fiber bed desorption temperature uniformity, electric current contacts one end by fabric itself and electrode and flows directly into the other end, keep away
Exempt to conduct between layers and generates hot-spot phenomenon at contact point, so that temperature is evenly distributed on entire bed, temperature ladder
It spends smaller.
Further, heating and cooling circulation is carried out to activated carbon fiber electrothermal desorption structure, carries out degradation, as shown in fig. 6,
Regeneration desorption is sent out using activated carbon fiber using itself as galvanic couple, electrode mechanism is feasible, safe, and electrode anti-aging property is excellent
Good, with the variation of desorption number, the performance change of itself is stablized.In 280 heating and cooling circulation, activated carbon fiber bed is total
Body keeps stablizing, and electrode appearance is unchanged, and activated carbon fiber electrothermal desorption structural behaviour change rate is small, in 280 adsorption/desorptions
For performance change less than 15%, the service life is long in recycling.
Activated carbon fiber electrothermal desorption structure of the invention eliminates the contact resistance between electrode and bed end face, in big electricity
When stream passes through electrode, electrode heat production is extremely low, long service life;And it ensure that activated carbon fiber bed face material and electrode are complete
Full connected, electric current contact one end by fabric itself and electrode and flow directly into the other end, avoid conducting generation between layers and connect
Hot-spot phenomenon at contact, so that temperature is evenly distributed on entire bed, temperature gradient is smaller.Due to bed internal current
It is evenly distributed, synchronous consistent heat generation inside and outside bed, organic matter desorption is clean thorough, high-efficient, favorable regeneration effect is desorbed, so that living
Property carbon fibre material can keep good absorption property for a long time.
It should be noted that: the above embodiments are merely illustrative of the technical scheme of the present invention and are not intended to be limiting thereof;Although ginseng
According to preferred embodiment, invention is explained in detail, it should be understood by those ordinary skilled in the art that: still can be with
It modifies to a specific embodiment of the invention or some technical features can be equivalently replaced;Without departing from skill of the present invention
The spirit of art scheme should all cover within the scope of the technical scheme claimed by the invention.
Claims (9)
1. a kind of activated carbon fiber electrothermal desorption structure, including the activated carbon fiber bed formed is laminated by activated carbon fiber cloth (2)
Layer and the electrode mechanism being arranged on a pair of of side end face of the activated carbon fiber bed, it is characterised in that: the electrode machine
Structure includes the conducting resinl area (1) being arranged on activated carbon fiber bed end, setting leading in the conducting resinl area (1)
Electric metal body (4) and the electrode being connected with the conductive metal body (4) draw connector (3), and the conductive metal body (4) is embedded
Internal in the conducting resinl area (1), the conducting resinl area (1) is at least partially immersed or injects for activated carbon fiber bed end and leads
Electric adhesive curing molding.
2. activated carbon fiber electrothermal desorption structure according to claim 1, it is characterised in that: the activated carbon fiber cloth
It (2) is braiding or non-woven acf layer.
3. activated carbon fiber electrothermal desorption structure according to claim 1, it is characterised in that: the conductive metal body (4)
Material be one of copper, silver, lead, gold, tin, cadmium, nickel, iron, platinum simple substance or its alloy.
4. activated carbon fiber electrothermal desorption structure according to claim 1, it is characterised in that: the conductive metal body (4)
Form be metal foil, metal bar, wire or metal block.
5. activated carbon fiber electrothermal desorption structure according to claim 1, it is characterised in that: the conducting resinl area (1) by
Conducting resinl impregnates to be formed, and the conducting resinl is at least silver base conductive glue, auri conducting resinl, copper-based conducting resinl or graphite based conducting
Glue.
6. activated carbon fiber electrothermal desorption structure according to claim 1, it is characterised in that: the conducting resinl area (1)
Volume resistivity is less than 10-2The high temperature resistant temperature of Ω cm, the conducting resinl area (1) are greater than 100 DEG C.
7. activated carbon fiber electrothermal desorption structure according to claim 1, it is characterised in that: at activated carbon fiber bed end
Portion is at least partially immersed the step of conducting resinl curing molding and includes:
Activated carbon fiber cloth (2) is laminated, end part aligning is cut and made according to the size of activated carbon fiber bed, it
The activated carbon fiber bed is fixed afterwards, and the end of activated carbon fiber bed is exposed;
Conductive metal body (4) is drawn connector (3) with electrode to be attached in advance;
Conducting resinl is poured into container, and the end of the activated carbon fiber bed is immersed in conducting resinl;
Activated carbon fiber bed is taken out out of container, conductive metal body (4) are embedded to the end of the activated carbon fiber bed
Interior, electrode is drawn connector (3) and is stayed in outside the end of the activated carbon fiber bed, naturally dry or drying.
8. activated carbon fiber electrothermal desorption structure according to claim 5, it is characterised in that: when the conducting resinl is graphite
When base conducting resinl, the conducting resinl area (1) using baking and curing form, drying temperature be 60~100 DEG C, drying time be 30~
150min。
9. activated carbon fiber electrothermal desorption structure according to claim 1, it is characterised in that: the conducting resinl area (1)
Width is 0.5~2cm.
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CN206454453U (en) * | 2016-12-15 | 2017-09-01 | 西安凯倍耐特智能工程有限公司 | Active carbon fiber air purifier |
CN108114574A (en) * | 2016-11-29 | 2018-06-05 | 中国石油化工股份有限公司 | A kind of processing method and processing device of refinery VOCs exhaust gas |
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CN2161044Y (en) * | 1993-06-30 | 1994-04-06 | 张忠 | Efficient composite ultra-thin electrothermic apparatus |
JP2002224562A (en) * | 2000-11-29 | 2002-08-13 | National Institute Of Advanced Industrial & Technology | Method for regenerating active carbon fiber sheet containing adsorbate and apparatus provided with the sheet and used for removing or recovering adsorbate |
CN201142762Y (en) * | 2007-11-08 | 2008-10-29 | 魏文才 | Graphitic carbon fabric electrical heating body |
CN201581010U (en) * | 2009-05-06 | 2010-09-15 | 中山大学 | Clamp slot type activated carbon fiber electrode capacitance adsorption deionizing device |
CN103230721A (en) * | 2013-03-22 | 2013-08-07 | 郑州中斯达环境科技有限公司 | Electric heating type purification filtration core structure |
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Effective date of registration: 20200522 Address after: 102101 No.5, East District, Tianyou Road, Kangzhuang Industrial Development Zone, Kangzhuang Town, Yanqing District, Beijing Applicant after: BEIJING KAIYUE DEFENCE TECHNOLOGY Co.,Ltd. Address before: 100082 Gaode Building, No. 10 Huayuan East Road, Haidian District, Beijing, No. 301-07 Applicant before: BEIJING KCALIN NEW ENERGY TECHNOLOGY Co.,Ltd. |
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