CN109112413B - A kind of 12Cr1MoV Mayari and its production technology - Google Patents

A kind of 12Cr1MoV Mayari and its production technology Download PDF

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CN109112413B
CN109112413B CN201811232906.0A CN201811232906A CN109112413B CN 109112413 B CN109112413 B CN 109112413B CN 201811232906 A CN201811232906 A CN 201811232906A CN 109112413 B CN109112413 B CN 109112413B
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12cr1mov
steel
mayari
relaxation
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CN109112413A (en
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谭峰亮
邓显贤
李鸿娟
陈若兰
封举宁
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Hunan University of Humanities Science and Technology
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/24Ferrous alloys, e.g. steel alloys containing chromium with vanadium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/004Dispersions; Precipitations
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/009Pearlite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The present invention relates to a kind of 12Cr1MoV Mayari and its production technologies.By weight percentage, the chemical component of the heat resisting steel are as follows: C:0.08%~0.15%, Si:0.15%~0.30%, Mn:0.40%~0.60%, P :≤0.03%, S :≤0.03%, Cr:0.90%~1.10%, Mo:0.25%~0.35%, V:0.15%~0.28%, Als:0.025%~0.05%, remaining is Fe.The production technology of the heat resisting steel using the online lonneal of controlled rolling-relaxation-technique, can high efficiency, low cost the good ferrite of comprehensive performance+pearlite type 12Cr1MoV Mayari is prepared.The present invention studies influence of the microscopic structure to 12Cr1MoV steel mechanical property using the methods of metallographic microscope, scanning electron microscope, tension test, impact test using the 12Cr1MoV steel of the online lonneal technique preparation different microstructures of controlled rolling-relaxation-.

Description

A kind of 12Cr1MoV Mayari and its production technology
Technical field
The invention belongs to iron and steel smelting technology fields, and in particular to a kind of 12Cr1MoV Mayari and its production work Skill.
Background technique
12Cr1MoV steel series low-alloy heat resisting steel has good toughness, craftsmanship and weldability, its group when high-temperature service It knits that the high-temperature behaviors such as stability, creep resisting ability, oxidation resistance are good, is usually used in the overheat that manufacture uses temperature≤580 DEG C The steam turbines such as device, reheater, high-pressure bottle, main steam conduit, boiler manfacturing field key components and parts, mechanical property requirements For ReL >=255MPa, 470MPa≤Rm≤640MPa, A >=21%, Akv >=47J.In order to meet heat-resisting components performance requirement, 12Cr1MoV steel generally uses hot rolling+normalizing+high tempering or controlled rolling and controlled cooling production technology.Organization type mainly has iron Ferritic+granular bainite microstructure, ferrite+Dispersed precipitate granular carbide, if occur low-carbon lath beam bainite, martensite, The microscopic structures such as retained austenite, tempering temperature raising can make the tissue breakdowns such as lath beam bainite, and dislocation density reduces, carbonization Object is grown up roughening, is caused the strength of materials, toughness to reduce, is reduced the applied at elevated temperature performance of material.
Summary of the invention
In order to improve the production efficiency and its mechanical property of 12Cr1MoV Mayari, the present invention provides one kind 12Cr1MoV Mayari and its production technology.The production technology is using the online lonneal work of controlled rolling-relaxation- Skill, can high efficiency, low cost the good ferrite of comprehensive performance+pearlite type 12Cr1MoV Mayari is prepared.This hair The bright 12Cr1MoV steel using the online lonneal technique preparation different microstructures of controlled rolling-relaxation-, utilizes metallography microscope The methods of mirror, scanning electron microscope, tension test, impact test and means research microscopic structure are to 12Cr1MoV steel mechanical property The influence of energy.
The present invention adopts the following technical scheme:
A kind of 12Cr1MoV Mayari, by weight percentage, the change of the 12Cr1MoV Mayari It studies and is divided into: C:0.08%~0.15%, Si:0.15%~0.30%, Mn:0.40%~0.60%, P :≤0.03%, S :≤ 0.03%, Cr:0.90%~1.10%, Mo:0.25%~0.35%, V:0.15%~0.28%, Als:0.025%~ 0.05%, remaining is Fe.
The microscopic structure of the 12Cr1MoV Mayari is ferrite+pearlite+granular carbide.
The 12Cr1MoV Mayari with a thickness of 6.0~8.0mm.
The present invention also provides a kind of production technology of 12Cr1MoV Mayari, the production technology is using control The technique of the online lonneal of rolling-relaxation-processed.
In the technique of the online lonneal of the rolling-relaxation-, austenitizing technique is 1200 DEG C and maintains 2 hours, finish to gauge Temperature is 830~885 DEG C, and relaxation temperature is 710~760 DEG C, is cooled to 240~280 with the control of 8 DEG C/s~13 DEG C/s cooling rate DEG C, 2h is kept the temperature, room temperature is then air-cooled to.
Beneficial effects of the present invention:
The present invention using controlled rolling-relaxation processing-online tempering process, can high efficiency, low cost preparation comprehensive performance it is good Ferrite+pearlite type 12Cr1MoV Mayari.The present invention is using the online lonneal work of controlled rolling-relaxation- Skill prepares the 12Cr1MoV steel of different microstructures, is tried using metallographic microscope, scanning electron microscope, tension test, impact It the methods of tests and influence of the means research microscopic structure to 12Cr1MoV steel mechanical property.The study found that increasing sheet pearly-lustre Body content, intensity, the hardness of 12Cr1MoV steel increase;Fining ferrite grains, increase granular carbide can significantly improve The elongation of 12Cr1MoV steel;The granular carbide content for being distributed in ferrite grain boundaries increases, the impact flexibility of 12Cr1MoV steel It is substantially reduced.Sheet content of pearlite in alloy, the content of granular carbide and distribution are to influence 12Cr1MoV Mayari power Learn the principal element of performance.
Detailed description of the invention
Fig. 1 is the schematic diagram of the online lonneal technique of controlled rolling-relaxation-;
Fig. 2 is the microstructure picture of 12Cr1MoV Mayari, wherein figure (a) is metallographic structure photo, is schemed (b) For SEM macrograph;
Fig. 3 is the granular carbide SEM photograph and EDS map of 12Cr1MoV Mayari, wherein figure (a) is along iron Ferritic interface distributions granular carbide SEM photograph, figure (b) are granular carbide EDS map;
Fig. 4 is the metallographic structure photo of 12Cr1MoV Mayari, wherein figure (a) is the gold that embodiment 1 tests steel Phase constitution photo, figure (b) are the metallographic structure photo that embodiment 2 tests steel, and figure (c) is the metallographic structure that embodiment 5 tests steel Photo;
Fig. 5 is the pearlite and carbide volume fraction figure that embodiment 1-5 tests steel;
Fig. 6 is the ferritic structure average-size figure that embodiment 1-5 tests steel;
Fig. 7 tests the mechanical experimental results figure of steel for embodiment 1-5, wherein figure (a) is experiment steel yield strength, resists The test result figure of tensile strength, figure (b) are the test result figure for testing steel elongation, and figure (c) is experiment steel impact absorbing energy Test result figure, figure (d) are the test result figure for testing steel hardness.
Specific embodiment
Below in conjunction with drawings and examples, a specific embodiment of the invention is described in more details, so as to energy The advantages of enough more fully understanding the solution of the present invention and its various aspects.However, specific embodiments described below and reality It applies example to be for illustrative purposes only, rather than limiting the invention.
In following embodiment, the main chemical compositions of 12Cr1MoV experiment steel used are as follows: by weight percentage, C: 0.08%~0.15%, Si:0.15%~0.30%, Mn:0.40%~0.60%, P :≤0.03%, S :≤0.03%, Cr: 0.90%~1.10%, Mo:0.25%~0.35%, V:0.15%~0.28%, Als:0.025%~0.05%, remaining is Fe。
In following embodiment, 12Cr1MoV tests steel processing and test method are as follows: intercepts 10mm along experiment steel transverse direction × 10mm × thickness metallographic specimen inlays grinding, polishing after sample, is corroded with 3% nital, using Leica DMI 8C Type inverted metallurgic microscope observation analysis microscopic structure uses transversal using Photoshop software statistics microscopic structure volume fraction The size of method measurement crystal grain;Analysis experiment steel microscopic structure and micro- is further looked at using quanta200 scanning electron microscope (contain EDS) Area's ingredient;Longitudinal plate stretching is carried out according to GB/T228.1-2010 standard using WDW-200 microcomputer controlled electronic universal tester Test, sample marking distance 80mm;Semi-automatic shock machine is controlled according to GB/T 229-2007 standard using JB-W300B microcomputer Side knock performance, size of sample are 10 × 5 × 55mm V-notch to test experiments steel at room temperature;It is micro- hard using HVS-1000 The hardness of degree meter measurement experiment steel.
Embodiment 1
It is used in certain factory's hot rolling line using the online lonneal technique preparation 12Cr1MoV experiment of controlled rolling-relaxation- Steel, the online lonneal technique of the rolling-relaxation-is as shown in Figure 1, wherein hot incoming slab is with a thickness of 210mm, austenitizing Technique is 1200 DEG C of maintenance 2h, and finishing temperature is 885 DEG C, and relaxation temperature is 760 DEG C, with the control of 8 DEG C/s~13 DEG C/s cooling rate 240~280 DEG C are cooled to, 2h is kept the temperature, is then air-cooled to room temperature, experiment steel product obtained is with a thickness of 8mm.
Embodiment 2
It is used in certain factory's hot rolling line using the online lonneal technique preparation 12Cr1MoV experiment of controlled rolling-relaxation- Steel, the online lonneal technique of the rolling-relaxation-is as shown in Figure 1, wherein hot incoming slab is with a thickness of 210mm, austenitizing Technique is 1200 DEG C of maintenance 2h, and finishing temperature is 885 DEG C, and relaxation temperature is 730 DEG C, with the control of 8 DEG C/s~13 DEG C/s cooling rate 240~280 DEG C are cooled to, 2h is kept the temperature, is then air-cooled to room temperature, experiment steel product obtained is with a thickness of 8mm.
Embodiment 3
It is used in certain factory's hot rolling line using the online lonneal technique preparation 12Cr1MoV experiment of controlled rolling-relaxation- Steel, the online lonneal technique of the rolling-relaxation-is as shown in Figure 1, wherein hot incoming slab is with a thickness of 210mm, austenitizing Technique is 1200 DEG C of maintenance 2h, and finishing temperature is 885 DEG C, and relaxation temperature is 710 DEG C, with the control of 8 DEG C/s~13 DEG C/s cooling rate 240~280 DEG C are cooled to, 2h is kept the temperature, is then air-cooled to room temperature, experiment steel product obtained is with a thickness of 8mm.
Embodiment 4
It is used in certain factory's hot rolling line using the online lonneal technique preparation 12Cr1MoV experiment of controlled rolling-relaxation- Steel, the online lonneal technique of the rolling-relaxation-is as shown in Figure 1, wherein hot incoming slab is with a thickness of 250mm, austenitizing Technique is 1200 DEG C of maintenance 2h, and finishing temperature is 830 DEG C, and relaxation temperature is 730 DEG C, with the control of 8 DEG C/s~13 DEG C/s cooling rate 240~280 DEG C are cooled to, 2h is kept the temperature, is then air-cooled to room temperature, experiment steel product obtained is with a thickness of 6mm.
Embodiment 5
It is used in certain factory's hot rolling line using the online lonneal technique preparation 12Cr1MoV experiment of controlled rolling-relaxation- Steel, the online lonneal technique of the rolling-relaxation-is as shown in Figure 1, wherein hot incoming slab is with a thickness of 250mm, austenitizing Technique is 1200 DEG C of maintenance 2h, and finishing temperature is 830 DEG C, and relaxation temperature is 750 DEG C, with the control of 8 DEG C/s~13 DEG C/s cooling rate 240~280 DEG C are cooled to, 2h is kept the temperature, is then air-cooled to room temperature, experiment steel product obtained is with a thickness of 6mm.
Experimental results
(1) 12Cr1MoV tests steel microscopic structure
As shown in Fig. 2, preparing the microscopic structure of 12Cr1MoV experiment steel using the online tempering process of controlled rolling-relaxation- For isometric ferrite+pearlite+granular carbide, medium pearlite is sheet;As shown in Fig. 3 (a), 12Cr1MoV tests steel In granular carbide along ferrite interface distributions.Fig. 3's (b) the result shows that 12Cr1MoV experiment steel in carbide it is main at It is divided into Fe, Cr, Mo, V and C, it is known that the carbide in experiment steel mainly includes M3C and MC.
As shown in figure 4, the metallographic microstructure of experiment steel prepared under different process is ferrite+sheet pearly-lustre Body+granular carbide.Ferritic volume fraction difference is little in each experiment steel, but ferritic size, pearlite morphology, grain Shape carbide has larger difference.The experiment steel ferrite grain size of embodiment 1 is relatively fine, sheet content of pearlite in alloy is more and divides Cloth is more uniform, and there are more granular carbides at ferrite interface;Embodiment 2 tests steel ferrite crystal grain and sheet pearlite Size is coarseer, and content and embodiment 1 experiment the steel difference of pearlite are little, and the content of granular carbide is less than embodiment 1 Sample;Embodiment 5 tests steel medium pearlite content, ferrite size is less than embodiment 1 and tests steel, and granular carbide is distributed more Uniformly, sheet content of pearlite in alloy is few, and granular carbide content is most.
Ferrite volume fraction and its average-size, carbide in experiment steel have been counted using area-method and division lines method respectively Volume fraction, the results showed that for five kinds of ferritic volume fraction ranges of experiment steel between 87%~89%, difference is unobvious, and Ferritic crystallite dimension difference is larger, and as shown in Figure 5 and Figure 6, the experiment steel ferrite crystal grain of embodiment 5 is most thin, average-size About 6.83 μm, the experiment steel ferrite crystal grain of embodiment 3 is most coarse, and about 12.17 μm of average-size;Embodiment 1-3 tests steel middle layer Shape content of pearlite in alloy is 9.0%~10.0%, and embodiment 4-5 tests steel laminate content of pearlite in alloy about 4.5%~6.0%, and Granular carbide content is significantly more than embodiment 1-3 experiment steel in embodiment 4-5 experiment steel, and wherein embodiment 5 tests grain in steel Shape carbide content about 6.31%, embodiment 3 test granular carbide content about 2.11% in steel.
(2) 12Cr1MoV tests steel mechanical property
Plate stretching and impact test are carried out to experiment steel at room temperature, test 12Cr1MoV tests the mechanical property of steel, as a result As shown in table 1, wherein room temperature impact function experimental result has been converted into 10 × 10 × 55mm V-notch Standard run results, performance Test result shows that five kinds of prepared experiment steel mechanical properties meet design requirement, but tests the mechanical property of steel because micro- Difference is organized there are larger difference, such as elongation, hardness, toughness, microscopic structure statistical data shows in five kinds of experiment steel Ferritic structure volume fraction difference is unobvious, so the pattern of ferrite grain size, pearlite, carbide content etc. It is the principal element for influencing experiment steel mechanical property, as a result as shown in fig. 7, embodiment 4, embodiment 5 and embodiment 1-3 test steel It compares, tensile strength and yield strength are lower, and room temperature impact value is significant lower, and elongation after fracture is significantly higher, and implement The microhardness of example 1-5 experiment steel gradually decreases.
The mechanical property of 1 12Cr1MoV of table experiment steel
Test result show embodiment 1-3 experiment steel in sheet pearlite volume fraction it is higher, intensity, hardness compared with Height, and plasticity is lower, influence of the granular carbide to experiment hardness of steel, hardness and plasticity is unobvious;Embodiment 4-5 is tested in steel Granular carbide content is more, sheet content of pearlite in alloy is few, and ballistic work is lower;According to metal material refined crystalline strengthening theory (Hall- Petch formula), intensity, hardness, plasticity and the toughness for testing steel should be refined with ferrite grain size and be improved, but real The mechanical property changing rule for testing steel is not obviously consistent with ferrite grain size changing rule, and embodiment 5 tests iron element in steel Body size is most tiny, and granular carbide is most, and intensity and impact flexibility are minimum, it can thus be appreciated that sheet content of pearlite in alloy is to reality Test hardness of steel, the influence of hardness is greater than the influence of fetrite grain refinement, granular carbide and sheet pearlite are to influence Test the principal element of steel plasticity and toughness.Yan Wei et al. is in " influence of the pearlitic spheroidization to 20G tensile mechanical properties " (" pressure Force container ", 2003, the 8th phase of volume 20) in a text studies have shown that granular carbide is to the inhibition (dislocation of dislocation motion Fill in product module type) it is small compared with sheet pearlite, sheet content of pearlite in alloy is more, and the tensile strength and yield strength of material are higher, Carbide can increase uniformity when material deformation, drop stress concentration, be conducive to mention in spherical, ferrite crystal grain is tiny The plasticity of high material.However embodiment 4, embodiment 5 experiment steel laminate content of pearlite in alloy are few, granular carbide content is more, iron Ferritic crystallite dimension is tiny, and impact flexibility is lower instead, and main cause is that granular carbide is present in ferrite grain boundaries, can drop Lower bound surface intensity accelerates crackle to extend along crystal boundary, reduces impact flexibility.
In terms of comprehensive, the present invention can high efficiency, low cost preparation synthesis using controlled rolling-relaxation processing-online tempering process Ferrite of good performance+pearlite type 12Cr1MoV Mayari.The present invention is online low using controlled rolling-relaxation- The 12Cr1MoV steel of warm tempering process preparation different microstructures, has studied microscopic structure to 12Cr1MoV steel room-temperature mechanical property Influence.The result shows that 12Cr1MoV steel mechanical property is by sheet content of pearlite in alloy, granular carbide content and distribution, iron Ferritic crystallite dimension combined influence.Lamellar pearlite is the principal element for guaranteeing ferrite+pearlite type hardness of steel, hardness, is increased Add sheet content of pearlite in alloy, intensity, the hardness of 12Cr1MoV steel increase.And fining ferrite grains, reduction sheet pearly-lustre Body increases an important factor for granular carbide is guarantee material plasticity, and fining ferrite grains, increase granular carbide obviously mention The elongation of high 12Cr1MoV steel.Granular carbide along ferrite interface distributions can reduce the impact flexibility of material, intensity, point Cloth increases in the granular carbide content of ferrite grain boundaries, and the impact flexibility of 12Cr1MoV steel is substantially reduced.Therefore, sheet pearl Body of light content, the content of granular carbide and distribution are to influence the principal element of 12Cr1MoV low-alloy refractory steel mechanical property.

Claims (3)

1. a kind of 12Cr1MoV Mayari, it is characterised in that: by weight percentage, the 12Cr1MoV low-alloy is resistance to The chemical component of hot steel are as follows: C:0.08%~0.15%, Si:0.15%~0.30%, Mn:0.40%~0.60%, P :≤ 0.03%, S :≤0.03%, Cr:0.90%~1.10%, Mo:0.25%~0.35%, V:0.15%~0.28%, Als: 0.025%~0.05%, remaining is Fe;The microscopic structure of the 12Cr1MoV Mayari is ferrite+pearlite+grain Shape carbide;The production technology of the 12Cr1MoV Mayari uses the work of the online lonneal of controlled rolling-relaxation- Skill;In the technique of the online lonneal of the rolling-relaxation-, austenitizing technique is 1200 DEG C and maintains 2 hours, finishing temperature It is 830~885 DEG C, relaxation temperature is 710~760 DEG C, 240~280 DEG C are cooled to the control of 8 DEG C/s~13 DEG C/s cooling rate, 2h is kept the temperature, room temperature is then air-cooled to.
2. 12Cr1MoV Mayari according to claim 1, it is characterised in that: the 12Cr1MoV low-alloy is resistance to Hot steel with a thickness of 6.0~8.0mm.
3. the production technology of 12Cr1MoV Mayari described in any one of -2 according to claim 1, it is characterised in that: The technique that the production technology uses the online lonneal of controlled rolling-relaxation-.
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Publication number Priority date Publication date Assignee Title
CN102269756A (en) * 2011-08-01 2011-12-07 嘉兴市特种设备检测院 Field test method of 12Cr1MoV steel pearlite nodularization level
CN104775078A (en) * 2015-03-13 2015-07-15 武汉钢铁(集团)公司 Low yield ratio steel (Rel>620MPa) for fireproof structure and production method thereof
CN107099752A (en) * 2017-03-23 2017-08-29 舞阳钢铁有限责任公司 A kind of low-alloy 12Cr1MoV steel plates and its production method
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