CN109111971A - A kind of coke-removing agent and preparation method thereof being used to prepare biomass granule fuel - Google Patents

A kind of coke-removing agent and preparation method thereof being used to prepare biomass granule fuel Download PDF

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Publication number
CN109111971A
CN109111971A CN201710485069.1A CN201710485069A CN109111971A CN 109111971 A CN109111971 A CN 109111971A CN 201710485069 A CN201710485069 A CN 201710485069A CN 109111971 A CN109111971 A CN 109111971A
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CN
China
Prior art keywords
agent
parts
coke
biomass granule
granule fuel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710485069.1A
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Chinese (zh)
Inventor
于清慧
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shaoxing Blue Printing Home Textile Co.,Ltd.
Original Assignee
Jiangsu Yuan Yuan Edge New Energy Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Yuan Yuan Edge New Energy Co Ltd filed Critical Jiangsu Yuan Yuan Edge New Energy Co Ltd
Priority to CN201710485069.1A priority Critical patent/CN109111971A/en
Publication of CN109111971A publication Critical patent/CN109111971A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • C10L5/445Agricultural waste, e.g. corn crops, grass clippings, nut shells or oil pressing residues
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/02Use of additives to fuels or fires for particular purposes for reducing smoke development
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/04Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/06Use of additives to fuels or fires for particular purposes for facilitating soot removal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • C10L9/10Treating solid fuels to improve their combustion by using additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/24Mixing, stirring of fuel components
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/28Cutting, disintegrating, shredding or grinding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The invention discloses a kind of coke-removing agent for being used to prepare biomass granule fuel, the component including following parts by weight: 40-50 parts of combustion adjuvant, 20-40 parts of swelling agent, 30-40 parts of oxidant, 10-20 parts of catalyst, 10-20 parts of sulphur-fixing agent and high temperature are detained agent 10-20 parts.The advantage of the invention is that reducing coking and dust stratification, has the function of prevention, dust stratification is made to be easy to remove and inhibit high and low temperature corrosion and glue block up, effectively devoke, prolonged boiler service life, production cost is low, can increase 200-500 kilocalorie calorific value, and reduction dense smoke discharges.

Description

A kind of coke-removing agent and preparation method thereof being used to prepare biomass granule fuel
Technical field
The present invention designs biomass energy source domain, and in particular to a kind of coke-removing agent for being used to prepare biomass granule fuel and Preparation method.
Background technique
China has agricultural straw resource abundant, and with the raising of life in the countryside level, a large amount of stalks are in field Head is incinerated, this not only wastes biomass energy, also creates environmental pollution.Agricultural straw resource is prepared into biomass Solid molding fuel can be improved biomass resource utilization rate, reduce environmental pollution.Biomass fuel calorific value has close to coal The advantages that easily stored and transport, easy to use, clean and environmental protection, the fuel such as alternative coal and petroleum, in recent years increasingly by The concern of people.
But in the biomass fuel produced using stalk as raw material inorganic elements (including K, Na, S, Ca, Si, P etc.) content compared with The ash fusion point of height, fuel is low, and biomass fuel is caused easily to occur coking phenomenon in combustion, to the hot property of combustion apparatus It impacts, combustion apparatus is perishable, heat transfer efficiency is reduced, to reduce the utilization rate and efficiency of combustion of fuel.Therefore in straw In stalk biolobic material fuel combustion process, anti-coking additive is added, to reduce coking, improves combustion characteristics.
Summary of the invention
Technical problem to be solved by the present invention lies in how to obtain a kind of decoking for being used to prepare biomass granule fuel Agent, to solve the problem of that coking improves combustion characteristics.
Of the invention provides a kind of coke-removing agent for being used to prepare biomass granule fuel, the group including following parts by weight Point: 40-50 parts of combustion adjuvant, 20-40 parts of swelling agent, 30-40 parts of oxidant, 10-20 parts of catalyst, 10-20 parts of sulphur-fixing agent and High temperature is detained agent 10-20 parts.
Preferably, the combustion adjuvant is the combination of one or both of potassium chlorate or potassium nitrate.
Preferably, the swelling agent is the combination of one or more of sodium bicarbonate, ammonia bicarbonate, alum or baking powder.
Preferably, the oxidant is the combination of one or both of potassium permanganate or copper oxide.
Preferably, the catalyst is the combination of one or more of manganese dioxide, magnesia or aluminium oxide.
Preferably, the sulphur-fixing agent is the combination of one or both of quick lime or caustic soda.
The present invention also provides a kind of preparation methods of coke-removing agent for being used to prepare biomass granule fuel, include following step It is rapid:
S1, it crushes, is mixed 15 minutes in the weight fraction ratio of swelling agent and sulphur-fixing agent,
S2, the combustion adjuvant, oxidant, catalyst and high temperature that fraction scale by weight is added in the mixture of S1 are detained agent It is mixed together uniformly, obtains coke-removing agent.
The beneficial effects of the present invention are: there is prevention, be easy to dust stratification the advantage of the invention is that reducing coking and dust stratification It removes and high and low temperature is inhibited to corrode and glue stifled effect, effectively devoke, prolonged boiler service life, production cost is low, improves combustion Characteristic is burnt, 200-500 kilocalorie calorific value can be increased, reduces dense smoke discharge.
Specific embodiment
The technical solution in inventive embodiments will be clearly and completely described below, it is clear that described embodiment Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiment of the present invention, ordinary skill Personnel's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment one:
A kind of coke-removing agent being used to prepare biomass granule fuel, the component including following parts by weight: 40 parts of combustion adjuvant, 20 parts of swelling agent, 30 parts of oxidant, 10 parts of catalyst, 10 parts of sulphur-fixing agent and high temperature are detained 10 parts of agent, and combustion adjuvant used is The combination of potassium chlorate and potassium nitrate, swelling agent used are the combination of sodium bicarbonate, ammonia bicarbonate, alum and baking powder, oxidation used Agent is the combination in potassium permanganate and copper oxide, and catalyst used is the combination of manganese dioxide, magnesia and aluminium oxide, used Sulphur-fixing agent be quick lime and caustic soda combination.
Above-mentioned coke-removing agent is made by following steps:
S1, it crushes, is mixed 15 minutes in the weight fraction ratio of swelling agent and sulphur-fixing agent,
S2, the combustion adjuvant, oxidant, catalyst and high temperature that fraction scale by weight is added in the mixture of S1 are detained agent It is mixed together uniformly, obtains coke-removing agent.
Embodiment two:
A kind of coke-removing agent being used to prepare biomass granule fuel, the component including following parts by weight: 50 parts of combustion adjuvant, 40 parts of swelling agent, 40 parts of oxidant, 20 parts of catalyst, 20 parts of sulphur-fixing agent and high temperature are detained 20 parts of agent, and combustion adjuvant used is The combination of potassium chlorate and potassium nitrate, swelling agent used are the combination of sodium bicarbonate, ammonia bicarbonate, alum and baking powder, oxidation used Agent is the combination in potassium permanganate and copper oxide, and catalyst used is the combination of manganese dioxide, magnesia and aluminium oxide, used Sulphur-fixing agent be quick lime and caustic soda combination.
It is obtained that above-mentioned coke-removing agent equally passes through the step of embodiment one.
Embodiment three:
A kind of coke-removing agent being used to prepare biomass granule fuel, the component including following parts by weight: 45 parts of combustion adjuvant, 30 parts of swelling agent, 35 parts of oxidant, 15 parts of catalyst, 15 parts of sulphur-fixing agent and high temperature are detained 15 parts of agent, and combustion adjuvant used is The combination of potassium chlorate and potassium nitrate, swelling agent used are the combination of sodium bicarbonate, ammonia bicarbonate, alum and baking powder, oxidation used Agent is the combination in potassium permanganate and copper oxide, and catalyst used is the combination of manganese dioxide, magnesia and aluminium oxide, used Sulphur-fixing agent be quick lime and caustic soda combination.
It is obtained that above-mentioned coke-removing agent equally passes through the step of embodiment one.
The advantage of the invention is that reducing coking and dust stratification, there is prevention, dust stratification is made to be easy to remove and inhibit high and low temperature rotten Erosion and viscous stifled effect, effectively devoke, and prolonged boiler service life, production cost is low, improves combustion characteristics, can increase 200- 500 kilocalorie calorific values reduce dense smoke discharge.
Above disclosed be only several preferred embodiments of the invention, cannot limit the present invention's certainly with this Interest field, therefore equivalent changes made in accordance with the claims of the present invention, are still within the scope of the present invention.

Claims (7)

1. a kind of coke-removing agent for being used to prepare biomass granule fuel, which is characterized in that the component including following parts by weight: help Agent 40-50 parts of combustion, 20-40 parts of swelling agent, 30-40 parts of oxidant, 10-20 parts of catalyst, 10-20 parts of sulphur-fixing agent and high temperature are stagnant Stay 10-20 parts of agent.
2. a kind of coke-removing agent for being used to prepare biomass granule fuel according to claim 1, which is characterized in that described to help Fire the combination that agent is one or both of potassium chlorate or potassium nitrate.
3. a kind of coke-removing agent for being used to prepare biomass granule fuel according to claim 1, which is characterized in that described swollen Agent is the combination of one or more of sodium bicarbonate, ammonia bicarbonate, alum or baking powder.
4. a kind of coke-removing agent for being used to prepare biomass granule fuel according to claim 1, which is characterized in that the oxygen Agent is the combination of one or both of potassium permanganate or copper oxide.
5. a kind of coke-removing agent for being used to prepare biomass granule fuel according to claim 1, which is characterized in that described to urge Agent is the combination of one or more of manganese dioxide, magnesia or aluminium oxide.
6. a kind of coke-removing agent for being used to prepare biomass granule fuel according to claim 1, which is characterized in that described solid Sulphur agent is the combination of one or both of quick lime or caustic soda.
7. a kind of preparation method for the coke-removing agent for being used to prepare biomass granule fuel, which is characterized in that comprise the steps of:
S1, it crushes, is mixed 15 minutes in the weight fraction ratio of swelling agent and sulphur-fixing agent,
S2, the combustion adjuvant, oxidant, catalyst and high temperature that fraction scale by weight is added in the mixture of S1 are detained agent together It is uniformly mixed, obtains coke-removing agent.
CN201710485069.1A 2017-06-23 2017-06-23 A kind of coke-removing agent and preparation method thereof being used to prepare biomass granule fuel Pending CN109111971A (en)

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4101291A (en) * 1976-08-06 1978-07-18 Universal Propulsion Company, Inc. Oxygen gas generator and method of manufacturing the gas generator
CN1532266A (en) * 2003-03-20 2004-09-29 隋亚格 Heat bulking coal eggette and coal coke eggette
CN1757703A (en) * 2004-10-08 2006-04-12 田立军 High efficiency, environmental protection type coal-saving agent, and its prodn. art
CN101089153A (en) * 2006-06-14 2007-12-19 宫志利 Industrial hot puffed briquette
WO2009038241A1 (en) * 2007-09-17 2009-03-26 Kenertec Method for preparing solid carbonizing fuels using wood biomass
CN101658757A (en) * 2008-08-26 2010-03-03 祁伟 High-efficiency environmental-friendly coal-saving sulphur-fixing antismoke agent and production technology thereof
CN102732354A (en) * 2012-02-29 2012-10-17 珠海慧生能源技术发展有限公司 Municipal domestic garbage biomass environment-friendly renewable energy additive, and preparation method thereof
CN103275784A (en) * 2013-06-13 2013-09-04 何子瑜 Coal fuel sulfur-fixation burning accelerant and preparation method thereof
CN106065346A (en) * 2016-05-26 2016-11-02 台山市合利生物质科技有限公司 A kind of decoking cleaning boiler wall biological granular fuel and preparation method thereof

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4101291A (en) * 1976-08-06 1978-07-18 Universal Propulsion Company, Inc. Oxygen gas generator and method of manufacturing the gas generator
CN1532266A (en) * 2003-03-20 2004-09-29 隋亚格 Heat bulking coal eggette and coal coke eggette
CN1757703A (en) * 2004-10-08 2006-04-12 田立军 High efficiency, environmental protection type coal-saving agent, and its prodn. art
CN101089153A (en) * 2006-06-14 2007-12-19 宫志利 Industrial hot puffed briquette
WO2009038241A1 (en) * 2007-09-17 2009-03-26 Kenertec Method for preparing solid carbonizing fuels using wood biomass
CN101658757A (en) * 2008-08-26 2010-03-03 祁伟 High-efficiency environmental-friendly coal-saving sulphur-fixing antismoke agent and production technology thereof
CN102732354A (en) * 2012-02-29 2012-10-17 珠海慧生能源技术发展有限公司 Municipal domestic garbage biomass environment-friendly renewable energy additive, and preparation method thereof
CN103275784A (en) * 2013-06-13 2013-09-04 何子瑜 Coal fuel sulfur-fixation burning accelerant and preparation method thereof
CN106065346A (en) * 2016-05-26 2016-11-02 台山市合利生物质科技有限公司 A kind of decoking cleaning boiler wall biological granular fuel and preparation method thereof

Non-Patent Citations (1)

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Title
孟光范;赵保峰;张晓东;陈雷;许海朋;孙立;: "生物质二次裂解制取氢气的研究", 太阳能学报, vol. 30, no. 06 *

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Effective date of registration: 20220125

Address after: 312000 Building 1, Nanxin and Gaohe village, Binhai Industrial Zone, Keqiao District, Shaoxing City, Zhejiang Province

Applicant after: Shaoxing Blue Printing Home Textile Co.,Ltd.

Address before: 226600 No. 18 Haifang Road, Chengdong Town, Hai'an County, Nantong City, Jiangsu Province

Applicant before: JIANGSU YUANFANGYUAN NEW ENERGY CO.,LTD.

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Application publication date: 20190101

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