CN109111832A - A kind of dedicated dust-proof powdery paints of skin sense of radiator and its preparation method and application - Google Patents

A kind of dedicated dust-proof powdery paints of skin sense of radiator and its preparation method and application Download PDF

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Publication number
CN109111832A
CN109111832A CN201810736923.1A CN201810736923A CN109111832A CN 109111832 A CN109111832 A CN 109111832A CN 201810736923 A CN201810736923 A CN 201810736923A CN 109111832 A CN109111832 A CN 109111832A
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CN
China
Prior art keywords
radiator
skin sense
powdery paints
dust
skin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810736923.1A
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Chinese (zh)
Inventor
张海瑞
丁树国
赵金祥
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Tianjin Xiangsheng New Materials Co Ltd
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Tianjin Xiangsheng New Materials Co Ltd
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Filing date
Publication date
Application filed by Tianjin Xiangsheng New Materials Co Ltd filed Critical Tianjin Xiangsheng New Materials Co Ltd
Priority to CN201810736923.1A priority Critical patent/CN109111832A/en
Publication of CN109111832A publication Critical patent/CN109111832A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • C09D5/033Powdery paints characterised by the additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1656Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662Synthetic film-forming substance
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24Electrically-conducting paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The present invention relates to a kind of dedicated dust-proof powdery paints of skin sense of radiator, raw material constituent component and its parts by weight are as follows: 240-360 parts of epoxy resin;300-450 parts of carboxyl end group saturated polyester resin;210-420 parts of pigments and fillers;5-15 parts of skin sense modifying agent;Other auxiliary agent 18-30 parts.The film sense of touch that powder coating and their application of the present invention to radiator is formed smooth exquisiteness such as skin, while electrostatic can be eliminated to prevent absorption dust, the dicoration and protective of radiator powdery paints are improved, there is very strong practical value.

Description

A kind of dedicated dust-proof powdery paints of skin sense of radiator and its preparation method and application
Technical field
The invention belongs to technical field of coatings, are related to powdery paints, and especially a kind of dedicated skin sense of radiator is dust-proof Powdery paints and its preparation method and application.
Background technique
Powdery paints is a kind of powdered form coating of solid point 100%, is matched by film forming matter base-material, pigment, filler material, auxiliary agent Square bar material is made.It is a kind of coating of the VOC free discharge of energy conservation and environmental protection, function admirable, and coating is sturdy and durable, dicoration is excellent It is good.Powder coating and their application radiator has multinomial advantage, such as: 1, excellent levelability, high glaze high saturation;2, splendid attached Put forth effort;3, good delay impact property after coating is after the several years, still has quite excellent suppleness;4, after being able to satisfy Forming requirements, resistance to bending repeatedly;5, excellent resistance to greasy dirt, resistance to edible oil performance, can clean repeatedly.But due to common heat dissipation Device powdery paints insulating properties is higher, causes radiator air outlet to be easy absorption dust, and be difficult to wipe.Furthermore with life water Flat raising, people are more and more to the sense of touch demand of furniture coating.
By retrieval, patent publication us relevant to present patent application is not yet found.
Summary of the invention
Place that the purpose of the present invention is to overcome the deficiency in the prior art, provides a kind of dedicated anti-dirt powder of skin sense of radiator The preparation method and application of last coating, the film sense of touch that the powder coating and their application to radiator is formed smooth exquisiteness such as skin, Electrostatic can be eliminated simultaneously to prevent absorption dust, improve the dicoration and protective of radiator powdery paints, have very strong Practical value.
The technical solution adopted by the present invention to solve the technical problems is:
A kind of dedicated dust-proof powdery paints of skin sense of radiator, raw material constituent component and its parts by weight are as follows:
Moreover, the epoxy resin is glycidyl ether type epoxy resin, epoxide equivalent 730-850g/eq.
Moreover, the acid value of the carboxyl end group saturated polyester resin is 50-56mgKOH/g.
Moreover, the pigments and fillers are made of ultra-fine barium sulfate, ultrafine rutile titanium dioxide and inorganic pigment.
Moreover, the skin sense modifying agent is modified organic silicon high molecular polymer.
Moreover, the film sense of touch that the dust-proof powder coating and their application of skin sense to radiator is formed is smooth thin such as skin It is greasy, while electrostatic can be eliminated to prevent absorption dust.
Moreover, other auxiliary agents are the mixture of levelling agent, anti-interference agent and degasser.
The preparation method of the dedicated dust-proof powdery paints of skin sense of radiator as described above, steps are as follows:
(1) pigments and fillers, skin sense modifying agent are added in high-speed mixer according to parts by weight, high speed dispersion, i.e. 400- 1000r/min disperses 30-60 minutes, and skin sense modifying agent is distributed in filler;
(2) remaining each material in addition to pigments and fillers, skin sense modifying agent is also added to high speed mixer in parts by weight, It is added to extruder after dry blended conjunction, carries out conventional melting, mixing, cooling, tabletting at 95-120 DEG C of extrusion temperature, then through crushing Machine is crushed, classification, sieving, is packed to get the dedicated dust-proof powdery paints of skin sense of radiator.
Application of the dedicated dust-proof powdery paints of skin sense of radiator in terms of radiator as described above.
Moreover, the film sense of touch that is formed of the powder coating and their application to radiator smooth exquisiteness such as skin, while can disappear It destatics to prevent absorption dust.
The advantages of present invention obtains and good effect are as follows:
1, powdery paints formation coating performance of the present invention is excellent, and the addition of skin sense modifying agent does not influence the adhesive force of coating And the mechanical performances such as impact resistance, sufficient protective performance can be provided for radiator.
2, the film sense of touch that powder coating and their application of the present invention to radiator is formed smooth exquisiteness such as skin, while can eliminate Electrostatic improves the dicoration and protective of radiator powdery paints, has very strong practical value to prevent absorption dust.
Detailed description of the invention
Fig. 1 is the dust-proof effect comparison diagram of the dust-proof powdery paints of skin sense of the present invention.
Specific embodiment
The embodiment of the present invention is described in detail below, it should be noted that the present embodiment is narrative, is not limited , this does not limit the scope of protection of the present invention.
Raw material used in the present invention is unless otherwise specified conventional commercial product;Used in the present invention Method is unless otherwise specified the conventional method of this field.
Embodiment 1
A kind of dedicated dust-proof powdery paints of skin sense of radiator, raw material constituent component and its parts by weight are as follows:
The epoxy resin is glycidyl ether type epoxy resin, epoxide equivalent 730-850g/eq;
The acid value of the carboxyl end group saturated polyester resin is 50-56mgKOH/g;
The pigments and fillers are made of ultra-fine barium sulfate, ultrafine rutile titanium dioxide and inorganic pigment;
The skin sense modifying agent is modified organic silicon high molecular polymer;
Other auxiliary agents are the mixture of levelling agent, anti-interference agent and degasser.
The preparation method of the dedicated dust-proof powdery paints of skin sense of radiator as described above, steps are as follows:
1) filler, skin sense modifying agent are added to according to parts by weight in high-speed mixer, high speed dispersion (400- 1000r/min) 30-60 minutes, skin sense modifying agent is distributed in filler;
2) above-mentioned remaining each material in addition to pigments and fillers, skin sense modifying agent is added to high speed mixing in parts by weight Machine is added to extruder after dry blended conjunction, carries out conventional melting, mixing, cooling, tabletting at 95-120 DEG C of extrusion temperature, then pass through Pulverizer is crushed, classification, sieving, is packed to get the dedicated dust-proof powdery paints of skin sense of radiator.
Embodiment 2
A kind of dedicated dust-proof powdery paints of skin sense of radiator, raw material constituent component and its parts by weight are as follows:
More preferably, the epoxy resin is glycidyl ether type epoxy resin, epoxide equivalent 730-850g/eq.
More preferably, the acid value of the carboxyl end group saturated polyester resin is 50-56mgKOH/g.
More preferably, the pigments and fillers are made of ultra-fine barium sulfate, ultrafine rutile titanium dioxide and inorganic pigment.
More preferably, the skin sense modifying agent is modified organic silicon high molecular polymer.
More preferably, the film sense of touch that the dust-proof powder coating and their application of skin sense to radiator is formed is smooth thin such as skin It is greasy, while electrostatic can be eliminated to prevent absorption dust.
More preferably, other auxiliary agents are the mixture of levelling agent, anti-interference agent and degasser.
The preparation method of the dedicated dust-proof powdery paints of skin sense of radiator as described above, steps are as follows:
(1) pigments and fillers, skin sense modifying agent are added in high-speed mixer according to parts by weight, high speed dispersion, i.e. 400- 1000r/min disperses 30-60 minutes, and skin sense modifying agent is distributed in filler;
(2) remaining each material in addition to pigments and fillers, skin sense modifying agent is also added to high speed mixer in parts by weight, It is added to extruder after dry blended conjunction, carries out conventional melting, mixing, cooling, tabletting at 95-120 DEG C of extrusion temperature, then through crushing Machine is crushed, classification, sieving, is packed to get the dedicated dust-proof powdery paints of skin sense of radiator.
Application of the dedicated dust-proof powdery paints of skin sense of radiator in terms of radiator as described above.
More preferably, the film sense of touch that the powder coating and their application to radiator is formed smooth exquisiteness such as skin, while energy Electrostatic is eliminated to prevent absorption dust.
The related test results of the dedicated dust-proof powdery paints of skin sense of radiator of the present invention are as follows:
As shown in the results, the dust-proof powdery paints of the dedicated skin sense of radiator of the present invention, which forms coating, has excellent attachment Power and bending property, impact resistance and surface hardness are qualified, the addition of skin sense modifying agent do not influence coating adhesive force and The mechanical performances such as impact resistance can provide sufficient protective performance for radiator.
Anti-dust performance test is carried out to the coating that powdery paints of the present invention is formed, will be applied in the template insertion dust installed again The degree for seeing template adhering dust is taken out, as a result as shown in Figure 1.As seen from Figure 1, the dust-proof powdery paints of skin sense of the present invention is compared There is certain anti-dust performance in common coating.
Although disclosing the embodiment of the present invention for the purpose of illustration, it will be appreciated by those skilled in the art that: not Be detached from the present invention and spirit and scope of the appended claims in, various substitutions, changes and modifications be all it is possible, therefore, this The range of invention is not limited to the embodiment and attached drawing disclosure of that.

Claims (10)

1. a kind of dedicated dust-proof powdery paints of skin sense of radiator, it is characterised in that: its raw material constituent component and its parts by weight Number is as follows:
2. the dedicated dust-proof powdery paints of skin sense of radiator according to claim 1, it is characterised in that: the asphalt mixtures modified by epoxy resin Rouge is glycidyl ether type epoxy resin, epoxide equivalent 730-850g/eq.
3. the dedicated dust-proof powdery paints of skin sense of radiator according to claim 1, it is characterised in that: the carboxyl end group The acid value of saturated polyester resin is 50-56mgKOH/g.
4. the dedicated dust-proof powdery paints of skin sense of radiator according to claim 1, it is characterised in that: the pigments and fillers It is made of ultra-fine barium sulfate, ultrafine rutile titanium dioxide and inorganic pigment.
5. the dedicated dust-proof powdery paints of skin sense of radiator according to claim 1, it is characterised in that: the skin sense Modifying agent is modified organic silicon high molecular polymer.
6. the dedicated dust-proof powdery paints of skin sense of radiator according to claim 1, it is characterised in that: the skin sense The film sense of touch that dust-proof powder coating and their application to radiator is formed smooth exquisiteness such as skin, while electrostatic can be eliminated to prevent Adsorb dust.
7. the dedicated dust-proof powdery paints of skin sense of radiator according to any one of claims 1 to 6, it is characterised in that: Other auxiliary agents are the mixture of levelling agent, anti-interference agent and degasser.
8. the preparation method of the dedicated dust-proof powdery paints of skin sense of radiator as described in any one of claim 1 to 7, special Sign is: steps are as follows:
(1) pigments and fillers, skin sense modifying agent are added in high-speed mixer according to parts by weight, high speed dispersion, i.e. 400- 1000r/min disperses 30-60 minutes, and skin sense modifying agent is distributed in filler;
(2) remaining each material in addition to pigments and fillers, skin sense modifying agent is also added to high speed mixer in parts by weight, through dry It is added to extruder after mixing, carries out conventional melting, mixing, cooling, tabletting at 95-120 DEG C of extrusion temperature, then through pulverizer powder Broken, classification, is packed to get the dedicated dust-proof powdery paints of skin sense of radiator at sieving.
9. the dedicated dust-proof powdery paints of skin sense of radiator as described in any one of claim 1 to 7 is in terms of radiator Using.
10. application of the dedicated dust-proof powdery paints of skin sense of radiator according to claim 9 in terms of radiator, It is characterized in that: the film sense of touch that the powder coating and their application to radiator is formed smooth exquisiteness such as skin, while can eliminate quiet Electricity is to prevent absorption dust.
CN201810736923.1A 2018-07-02 2018-07-02 A kind of dedicated dust-proof powdery paints of skin sense of radiator and its preparation method and application Pending CN109111832A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111234658A (en) * 2020-04-13 2020-06-05 福建万安实业集团有限公司 Fluffy powder coating
CN112143330A (en) * 2020-08-24 2020-12-29 廊坊艾格玛新立材料科技有限公司 Soft powder coating and preparation method thereof
CN112143331A (en) * 2020-08-24 2020-12-29 廊坊艾格玛新立材料科技有限公司 Epoxy low-temperature curing powder coating and preparation method thereof
CN114958158A (en) * 2022-07-01 2022-08-30 李仁达 Powder coating production process

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7645824B2 (en) * 2004-06-24 2010-01-12 Agion Technologies, Inc Color stable antimicrobial coatings
CN107936761A (en) * 2017-11-16 2018-04-20 广东华彩粉末科技有限公司 A kind of dedicated indoor no optical plane sand streak skin sense of touch powdery paints of IT product

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7645824B2 (en) * 2004-06-24 2010-01-12 Agion Technologies, Inc Color stable antimicrobial coatings
CN107936761A (en) * 2017-11-16 2018-04-20 广东华彩粉末科技有限公司 A kind of dedicated indoor no optical plane sand streak skin sense of touch powdery paints of IT product

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111234658A (en) * 2020-04-13 2020-06-05 福建万安实业集团有限公司 Fluffy powder coating
CN112143330A (en) * 2020-08-24 2020-12-29 廊坊艾格玛新立材料科技有限公司 Soft powder coating and preparation method thereof
CN112143331A (en) * 2020-08-24 2020-12-29 廊坊艾格玛新立材料科技有限公司 Epoxy low-temperature curing powder coating and preparation method thereof
CN114958158A (en) * 2022-07-01 2022-08-30 李仁达 Powder coating production process

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Application publication date: 20190101