CN109110934A - A kind of low-phosphorous retarding circulating water scaling corrosion inhibiter being suitable for using municipal middle water as moisturizing of environmental protection - Google Patents
A kind of low-phosphorous retarding circulating water scaling corrosion inhibiter being suitable for using municipal middle water as moisturizing of environmental protection Download PDFInfo
- Publication number
- CN109110934A CN109110934A CN201811027743.2A CN201811027743A CN109110934A CN 109110934 A CN109110934 A CN 109110934A CN 201811027743 A CN201811027743 A CN 201811027743A CN 109110934 A CN109110934 A CN 109110934A
- Authority
- CN
- China
- Prior art keywords
- water
- parts
- phosphorous
- moisturizing
- environmental protection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/14—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
- C02F5/145—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus combined with inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/02—Non-contaminated water, e.g. for industrial water supply
- C02F2103/023—Water in cooling circuits
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/08—Corrosion inhibition
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/22—Eliminating or preventing deposits, scale removal, scale prevention
Abstract
The present invention relates to a kind of low-phosphorous retarding circulating water scaling corrosion inhibiter being suitable for using municipal middle water as moisturizing of environmental protection.Currently, use can be such that total phosphorus content in recirculating water blowdown water increases considerably with organic phosphine antisludging agent as main component, polluted to surrounding aqueous environment.The present invention includes the component of following parts by weight: 2.0-2.3 parts of poly-epoxy succinic acid, 2- phosphonobutane -1,2, and 1.6-1.8 parts of 4- tricarboxylic acids；Carboxylic acid -2.2-2.5 parts of sulfonic-acrylic ester terpolymer；Poly- citric acid 1.5-1.7 parts；1.0-1.2 parts of zinc gluconate；0.5-1.7 parts of water.The invention belongs to the low-phosphorous formulas of environmental protection, and securely and reliably, it is convenient to prepare, the recirculated water concentration rate using municipal middle water as supplement water can be improved, reduce system blowdown, mitigate environmental pollution, operating cost is reduced, the industries such as electric power, metallurgy, chemical industry, medicine, petroleum are suitable for.
Description
Technical field
The present invention relates to a kind of low-phosphorous retarding circulating water scaling corrosion inhibiter being suitable for using municipal middle water as moisturizing of environmental protection, belong to
In industrial circulating cooling water scale inhibitor processing technology field.
Background technique
Water is the natural resources of preciousness for the survival of mankind, and shortage of water resources has become worldwide hot topic.China
The occupancy volume of per capita water resource is about the 1/4 of world occupancy volume per person, is that world's per capita water resource is poorest after ranking hundred
One of country.Therefore, significant in China's water conservation, reasonable use of water.In local water-deficient area, water has become restriction
An important factor for industrial and agricultural development and threat safety in production.In industrial water there are about 50% it is used above with consumption in industry
On cooling water, so improving recirculated water concentration rate, reducing water amount of blowdown is the important channel for realizing that industrial production is water-saving.
Municipal middle water is used for industrial circulating cooling water system supplement water and has become a kind of important of effective use water resource
Approach, but since municipal middle water has the water quality characteristics such as high hard, high alkalinity, high sulfate radical, high organic matter, at present using in city
Water is generally lower as the circulation concentration rate of moisturizing, in addition using some with organic phosphine scale inhibition as main component
Agent can be such that total phosphorus content in recirculating water blowdown water increases considerably, give such as application No. is 200910148632.1 Chinese patent
Surrounding aqueous environment pollutes, and has certain environmentally friendly risk.Therefore to solve the above-mentioned problems, select a kind of efficient, environmental protection
Anti-incrustation corrosion inhibitor is just particularly important.
Summary of the invention
It is an object of the invention to overcome the above deficiencies in the existing technologies, and provide a kind of environmental protection it is low-phosphorous be applicable in
In the retarding circulating water scaling corrosion inhibiter using municipal middle water as moisturizing, the dense of the recirculated water using municipal middle water as moisturizing can be improved
Demagnification rate reduces water amount of blowdown.
Technical solution used by the present invention solves the above problems is: a kind of environmental protection it is low-phosphorous suitable for being made with municipal middle water
For the retarding circulating water scaling corrosion inhibiter of moisturizing, which is characterized in that the component including following parts by weight: poly-epoxy succinic acid (PESA)
2.0-2.3 part；2- phosphonobutane -1,2,1.6-1.8 parts of 4- tricarboxylic acids (PBTCA)；Carboxylic acid-sulfonic-acrylic ester ternary polymerization
2.2-2.5 parts of object (AA-AMPS-HPA)；Poly- 1.5-1.7 parts of citric acid (PCA)；1.0-1.2 parts of zinc gluconate；Water 0.5-1.7
Part.
Medicament of the present invention is matched can be miscible with water, and (20 DEG C) of density are greater than 1.15g/cm3, solid content is greater than 32%, 1%
The pH of aqueous solution is between 3.0 ± 1.5, and for phosphonic acids salt content between 2.0-6.8%, finished medicament physical and chemical index meets DL/T
Regulation in 806-2013 " thermal power plant recirculated water anti-incrustation corrosion inhibitor " about low-phosphorus antiincrustation corrosion inhibitor.
Municipal middle water of the medicament of the present invention suitable for water hardness less than 15mmol/L and basicity less than 8mol/L, which is used as, to follow
The circulation scale inhibitor of ring water moisturizing uses.
Beneficial effects of the present invention are as follows: medicament of the present invention is with poly-epoxy succinic acid, carboxylic acid-sulfonic-acrylic ester ternary
Copolymer and poly- citric acid are host agent, compound a small amount of low phosphorous phosphonate and organic zinc salt, the scale inhibitor of collaboration enhancing medicament
Ability gives full play to drug effect.
Scale inhibitor agent prescription provided by the invention has the spies such as scale inhibitor effect is good, environment influence is small, adaptable
Point is suitble to add antisludging agent treatment process and the individually circulating water treatment process of addition antisludging agent using acid adding.It can be mentioned after use
The concentration rate of recirculated water of the height using municipal middle water as moisturizing reduces water amount of blowdown, and Reducing environmental impact saves water resource,
With good economic efficiency and social benefit.
By taking 2 × 600MW fired power generating unit as an example, the quantity of circulating water of 2 units is about 130000m3/ h, cooling tower evaporation loss
Amount is averagely about 1800m3/ h considers by 2.5 times of its recirculated water concentration rate, concentration rate can be made to mention using after medicament of the present invention
Height then saves more than 300 ten thousand tons of water of supplement to 4.0 times in year, saves about 20 tons of medicament, saves the expense about more than 560 ten thousand thus caused
(for water rate based on 1.8 yuan/ton, medicament is based on 1.2 ten thousand/ton), while large amount of sewage outlet is reduced, be conducive to water environment protection.
Specific embodiment
Below by embodiment, the present invention is described in further detail, following embodiment be explanation of the invention and
The invention is not limited to following embodiments.
Embodiment 1.
A kind of low-phosphorous retarding circulating water scaling corrosion inhibiter being suitable for using municipal middle water as moisturizing of environmental protection, including following weight
The component of part: 2.0 parts of poly-epoxy succinic acid (PESA), 2- phosphonobutane -1,2,1.6 parts of 4- tricarboxylic acids (PBTCA)；Carboxylic acid-sulphur
2.2 parts of acid-acrylate terpolymer (AA-AMPS-HPA)；1.5 parts of poly- citric acid；1.0 parts of zinc gluconate；Water 1.7
Part.
The low-phosphorous density (20 DEG C) for being suitable for the retarding circulating water scaling corrosion inhibiter using municipal middle water as moisturizing of above-mentioned environmental protection
Greater than 1.15g/cm3, solid content is greater than 32%, and for the pH of 1% aqueous solution between 3.0 ± 1.5, phosphonic acids salt content is 2.0-6.8%
Between, it is less than circulation of the municipal middle water of 15mmol/L, basicity less than 8mol/L as circulating cooling make-up water suitable for water hardness
Water system scale inhibitor uses.
Embodiment 2.
A kind of low-phosphorous retarding circulating water scaling corrosion inhibiter being suitable for using municipal middle water as moisturizing of environmental protection, including following weight
The component of part: 2.3 parts of poly-epoxy succinic acid (PESA), 2- phosphonobutane -1,2,1.8 parts of 4- tricarboxylic acids (PBTCA)；Carboxylic acid-sulphur
2.5 parts of acid-acrylate terpolymer (AA-AMPS-HPA)；1.7 parts of poly- citric acid；1.2 parts of zinc gluconate；Water 0.5
Part.
The low-phosphorous density (20 DEG C) for being suitable for the retarding circulating water scaling corrosion inhibiter using municipal middle water as moisturizing of above-mentioned environmental protection
Greater than 1.15g/cm3, solid content is greater than 32%, and for the pH of 1% aqueous solution between 3.0 ± 1.5, phosphonic acids salt content is 2.0-6.8%
Between, it is less than circulation of the municipal middle water of 15mmol/L, basicity less than 8mol/L as circulating cooling make-up water suitable for water hardness
Water system scale inhibitor uses.
Embodiment 3.
A kind of low-phosphorous retarding circulating water scaling corrosion inhibiter being suitable for using municipal middle water as moisturizing of environmental protection, including following weight
The component of part: 2.2 parts of poly-epoxy succinic acid (PESA), 2- phosphonobutane -1,2,1.7 parts of 4- tricarboxylic acids (PBTCA)；Carboxylic acid-sulphur
2.3 parts of acid-acrylate terpolymer (AA-AMPS-HPA)；1.6 parts of poly- citric acid；1.1 parts of zinc gluconate；Water 1.1
Part.
The low-phosphorous density (20 DEG C) for being suitable for the retarding circulating water scaling corrosion inhibiter using municipal middle water as moisturizing of above-mentioned environmental protection
Greater than 1.15g/cm3, solid content is greater than 32%, and for the pH of 1% aqueous solution between 3.0 ± 1.5, phosphonic acids salt content is 2.0-6.8%
Between, it is less than circulation of the municipal middle water of 15mmol/L, basicity less than 8mol/L as circulating cooling make-up water suitable for water hardness
Water system scale inhibitor uses.
It is any to be familiar with although the present invention is disclosed as above with embodiment, its protection scope being not intended to limit the invention
The technical staff of this technology changes and retouches made without departing from the spirit and scope of the invention, should belong to this hair
Bright protection scope.
Claims (4)
1. a kind of low-phosphorous retarding circulating water scaling corrosion inhibiter being suitable for using municipal middle water as moisturizing of environmental protection, which is characterized in that packet
Include the component of following parts by weight: 2.0-2.3 parts of poly-epoxy succinic acid；2- phosphonobutane -1,2,1.6-1.8 parts of 4- tricarboxylic acids；Carboxylic
Acid -2.2-2.5 parts of sulfonic-acrylic ester terpolymer；Poly- citric acid 1.5-1.7 parts；1.0-1.2 parts of zinc gluconate；Water
0.5-1.7 parts.
2. the low-phosphorous retarding circulating water scaling inhibition being suitable for using municipal middle water as moisturizing of environmental protection according to claim 2
Agent, which is characterized in that the low-phosphorous density for being suitable for the retarding circulating water scaling corrosion inhibiter using municipal middle water as moisturizing of environmental protection is 20
DEG C when be greater than 1.15g/cm3, solid content is greater than 32%.
3. the low-phosphorous retarding circulating water scaling inhibition being suitable for using municipal middle water as moisturizing of environmental protection according to claim 3
Agent, which is characterized in that the low-phosphorous retarding circulating water scaling corrosion inhibiter aqueous solution being suitable for using municipal middle water as moisturizing of 1% environmental protection
PH between 3.0 ± 1.5, phosphonic acids salt content is between 2.0-6.8%.
4. the low-phosphorous retarding circulating water scaling inhibition being suitable for using municipal middle water as moisturizing of environmental protection according to claim 1
Agent, which is characterized in that the low-phosphorous retarding circulating water scaling corrosion inhibiter being suitable for using municipal middle water as moisturizing of environmental protection is hard for water quality
Degree is less than circulation scale inhibitor of the municipal middle water of 15mmol/L, basicity less than 8mol/L as circulating cooling make-up water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811027743.2A CN109110934A (en) | 2018-09-04 | 2018-09-04 | A kind of low-phosphorous retarding circulating water scaling corrosion inhibiter being suitable for using municipal middle water as moisturizing of environmental protection |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811027743.2A CN109110934A (en) | 2018-09-04 | 2018-09-04 | A kind of low-phosphorous retarding circulating water scaling corrosion inhibiter being suitable for using municipal middle water as moisturizing of environmental protection |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109110934A true CN109110934A (en) | 2019-01-01 |
Family
ID=64861968
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811027743.2A Pending CN109110934A (en) | 2018-09-04 | 2018-09-04 | A kind of low-phosphorous retarding circulating water scaling corrosion inhibiter being suitable for using municipal middle water as moisturizing of environmental protection |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109110934A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6126859A (en) * | 1998-11-20 | 2000-10-03 | Betzdearborn Inc. | Method and composition for corrosion and deposition inhibition in aqueous systems |
| CN102452724A (en) * | 2010-10-20 | 2012-05-16 | 中国石油化工股份有限公司 | Composite corrosion and scale inhibitor and its application in water treatment |
| CN105060517A (en) * | 2015-07-29 | 2015-11-18 | 湖北省兴发磷化工研究院有限公司 | Low-phosphorus high-efficiency corrosion and scale inhibitor and application thereof in scale inhibition of industrial circulating cooling water |
| CN108159886A (en) * | 2018-02-07 | 2018-06-15 | 净沃(厦门)环保科技有限公司 | Reverse osmosis membrane scale inhibition preparation |
-
2018
- 2018-09-04 CN CN201811027743.2A patent/CN109110934A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6126859A (en) * | 1998-11-20 | 2000-10-03 | Betzdearborn Inc. | Method and composition for corrosion and deposition inhibition in aqueous systems |
| CN102452724A (en) * | 2010-10-20 | 2012-05-16 | 中国石油化工股份有限公司 | Composite corrosion and scale inhibitor and its application in water treatment |
| CN105060517A (en) * | 2015-07-29 | 2015-11-18 | 湖北省兴发磷化工研究院有限公司 | Low-phosphorus high-efficiency corrosion and scale inhibitor and application thereof in scale inhibition of industrial circulating cooling water |
| CN108159886A (en) * | 2018-02-07 | 2018-06-15 | 净沃(厦门)环保科技有限公司 | Reverse osmosis membrane scale inhibition preparation |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101412568B (en) | Scale inhibitor for circulating water | |
| Zhu et al. | Effect of nutrient level on phytoplankton community structure in different water bodies | |
| CN102642934B (en) | A kind of circularly-cooling sea water non-phosphate environment-friendly type carbon steel composite corrosion inhibitor and preparation and application thereof | |
| CN103420497A (en) | Non-phosphorous corrosion and scale inhibitor containing lignosulfonate and application thereof | |
| CN101637155A (en) | Bactericidal and algaecidal composition for intermediate water system, preparation method and application thereof | |
| CN102010073A (en) | Method for electrolyzing circulating cooling water and reverse osmosis concentrated water | |
| CN102745825A (en) | High-efficiency low-phosphorus corrosion and scale inhibiting dispersant and its preparation method | |
| CN101315253B (en) | Cooling water shortcut circulation energy conservation and emission reduction technology | |
| CN105084561A (en) | Non-phosphorus scale and corrosion inhibitor containing fulvic acid and preparation method thereof | |
| CN102701471A (en) | High-harness water corrosion and scale inhibitor | |
| CN106283012A (en) | A kind of recirculated water Phosphateless environmentally friendly prefilming agent | |
| CN104230015B (en) | A kind of composite slow release antisludging agent suitable in petrifaction sewage reuse circulation | |
| CN109110934A (en) | A kind of low-phosphorous retarding circulating water scaling corrosion inhibiter being suitable for using municipal middle water as moisturizing of environmental protection | |
| CN105254821A (en) | Terpolymer, multifunctional water treatment agent containing same and preparation method of multifunctional water treatment agent | |
| CN102139967B (en) | High-efficiency phosphorus-free corrosion and scale inhibition dispersion agent, preparation method thereof and application thereof | |
| CN104140162A (en) | Non-phosphorus scale and corrosion inhibitor employing seawater as circulating cooling water, and preparation method thereof | |
| CN107021566A (en) | Efficient low-phosphorus high temperature buck dispersant preparation method and its application | |
| CN101781027A (en) | High-efficiency non-phosphate corrosion and scale inhibiting dispersing agent and preparation method and application thereof | |
| CN106554096A (en) | A kind of boiler environment-friendly type inhibition anti-sludging agent and preparation method thereof | |
| CN105645610A (en) | Circulating water corrosion and scale inhibitor and preparation method thereof | |
| CN110158094A (en) | A kind of formula and preparation method of the without phosphorus carbon steel corrosion inhibitor of composite efficient | |
| CN109019883A (en) | Phosphate-free corrosion inhibition antisludging agent and preparation method thereof for Waste Water Reuse technology | |
| CN115432831A (en) | Non-phosphorus scale and corrosion inhibitor | |
| CN109019882A (en) | A kind of industrial circulating water softening agent | |
| CN103112958B (en) | Circulating water scale inhibitor applicable to pit water used as compensation water |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190101 |