CN109103263A - Thin film transistor and its manufacturing method, the production method of display panel - Google Patents

Thin film transistor and its manufacturing method, the production method of display panel Download PDF

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Publication number
CN109103263A
CN109103263A CN201810907928.6A CN201810907928A CN109103263A CN 109103263 A CN109103263 A CN 109103263A CN 201810907928 A CN201810907928 A CN 201810907928A CN 109103263 A CN109103263 A CN 109103263A
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China
Prior art keywords
passivation layer
layer
film transistor
thin film
tft
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CN109103263B (en
Inventor
张伟
李民
徐苗
陶洪
邹建华
王磊
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GUANGZHOU NEW VISION OPTOELECTRONIC CO Ltd
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GUANGZHOU NEW VISION OPTOELECTRONIC CO Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/78606Thin film transistors, i.e. transistors with a channel being at least partly a thin film with supplementary region or layer in the thin film or in the insulated bulk substrate supporting it for controlling or increasing the safety of the device
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/12Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/24Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only semiconductor materials not provided for in groups H01L29/16, H01L29/18, H01L29/20, H01L29/22
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66969Multistep manufacturing processes of devices having semiconductor bodies not comprising group 14 or group 13/15 materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/7869Thin film transistors, i.e. transistors with a channel being at least partly a thin film having a semiconductor body comprising an oxide semiconductor material, e.g. zinc oxide, copper aluminium oxide, cadmium stannate

Abstract

The embodiment of the invention discloses a kind of thin film transistor and its manufacturing methods, the production method of display panel.The thin film transistor (TFT) includes: underlay substrate;Grid layer, gate insulating layer, active layer and the source-drain electrode layer being formed on the underlay substrate, the active layer includes first area, and the first area is not covered by the grid layer and the source-drain electrode layer;It is formed in the passivation layer that the active layer deviates from the underlay substrate side, and the passivation layer is directly contacted with the first area of the active layer;Wherein, the active layer and the passivation layer are doped with rare earth element.Thin film transistor (TFT) water resistant oxygen ability can be improved in thin film transistor (TFT) provided by the invention.

Description

Thin film transistor and its manufacturing method, the production method of display panel
Technical field
The present embodiments relate to semiconductor technology more particularly to a kind of thin film transistor and its manufacturing methods, display surface The production method of plate.
Background technique
With the continuous development of display technology, (such as mobile phone, computer, the TV and can of the electronic equipment with display panel Wearable device etc.) at essential a part for people's lives.
In existing display panel, thin film transistor (TFT) is an important device, is mainly used for cooperating other devices Such as capacitor realization is shown.In all kinds of thin film transistor (TFT)s, metal oxide thin-film transistor due to mobility with higher, The compatibility of lower leakage current, manufacturing process has broader in liquid crystal display panel and organic light emitting display panel field Application prospect.But the active layer made of metal oxide is exposed to its stability and reliability in air or water vapour environment It easily deteriorates, seriously limits its use commercially.
Summary of the invention
The present invention provides a kind of thin film transistor and its manufacturing method, the production method of display panel, to improve film crystalline substance Body pipe water resistant oxygen ability.
In a first aspect, the embodiment of the invention provides a kind of thin film transistor (TFT), which includes:
Underlay substrate;
Grid layer, gate insulating layer, active layer and the source-drain electrode layer being formed on the underlay substrate, the active layer packet First area is included, the first area is not covered by the grid layer and the source-drain electrode layer;
It is formed in the passivation layer that the active layer deviates from the underlay substrate side, and the passivation layer and the active layer First area directly contact;
Wherein, the active layer and the passivation layer are doped with rare earth element.
Further, the active layer doped with gadolinium, nickel, aluminium, silicon, scandium, yttrium, titanium, zirconium, hafnium, niobium, tantalum, molybdenum, tungsten, lanthanum, At least one of neodymium, cerium, praseodymium, promethium, samarium and europium.
Further, the passivation layer is doped at least one of cerium, samarium, gadolinium, erbium and thulium.
Second aspect, the embodiment of the invention provides a kind of production method of thin film transistor (TFT), the systems of the thin film transistor (TFT) Make method for making the thin film transistor (TFT) provided in an embodiment of the present invention described in any one;
The production method of the thin film transistor (TFT) includes:
Underlay substrate is provided;
Grid, gate insulating layer, active layer and source-drain electrode layer are formed on the underlay substrate, wherein the active layer Including first area, the first area is not covered by the grid layer and the source-drain electrode layer;And the active layer is mixed It is miscellaneous to have rare earth element;
Passivation layer, the passivation layer and institute are formed away from the side of the underlay substrate in the active layer using solwution method The first area for stating active layer directly contacts;And the passivation layer is doped with rare earth element.
Further, passivation layer is formed away from the side of the underlay substrate in the active layer using solwution method, comprising:
Compound comprising doped chemical is added in solvent, passivation layer stoste is obtained by filtration in stirring, static aging;
Using the method for spin coating, the passivation layer stoste is coated in passivation layer predeterminable area, the passivation layer stoste The first area of the active layer is covered, at least to form passivation layer;
Under vacuum conditions, the passivation layer is made annealing treatment.
Further, the method using spin coating is executed, the passivation layer stoste is coated on passivation layer predeterminable area Interior, the passivation layer stoste at least covers the first area of the active layer, and number the step of to form passivation layer is At least twice.
Further, it is described under vacuum conditions, while annealing to the passivation layer, further includes:
The passivation layer is irradiated using deep UV.
It is further, described to form passivation layer away from the side of the underlay substrate in the active layer using solwution method, Include:
Compound comprising doped chemical, situ combustion fuel are added to solvent, stirring, static aging are obtained by filtration Passivation layer stoste;
Using the method for spraying, the passivation layer stoste is coated in passivation layer predeterminable area, the passivation layer stoste The first area of the active layer is covered, at least to form passivation layer;
Under vacuum conditions, the passivation layer is made annealing treatment.
The third aspect, the embodiment of the invention also provides a kind of production method of display panel, the production of the display panel Method includes the production method of the thin film transistor (TFT) provided in an embodiment of the present invention described in any one.
The embodiment of the present invention is by being arranged passivation layer, and passivation layer and active layer away from the side of underlay substrate in active layer First area directly contact, active layer and passivation layer solve existing thin film transistor (TFT) because will doped with rare earth element The active layer made of metal oxide is exposed in air or water vapour environment, causes thin film transistor (TFT) stability and reliability bad The problem of change, realizes the thin film transistor (TFT) water resistant oxygen ability that improves, and then improves the effect of thin film transistor (TFT) stability and reliability Fruit.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram of thin film transistor (TFT) provided in an embodiment of the present invention;
Fig. 2 is a kind of flow chart of thin film transistor (TFT) production method provided in an embodiment of the present invention;
Fig. 3 is the flow chart of another thin film transistor (TFT) production method provided in an embodiment of the present invention;
Fig. 4 is the flow chart of another thin film transistor (TFT) production method provided in an embodiment of the present invention.
Specific embodiment
The present invention is described in further detail with reference to the accompanying drawings and examples.It is understood that this place is retouched The specific embodiment stated is used only for explaining the present invention rather than limiting the invention.It also should be noted that in order to just Only the parts related to the present invention are shown in description, attached drawing rather than entire infrastructure.
The embodiment of the invention provides a kind of thin film transistor (TFT)s.Fig. 1 is a kind of film crystal provided in an embodiment of the present invention The structural schematic diagram of pipe.Referring to Fig. 1, which includes: underlay substrate 10;The grid layer being formed on underlay substrate 10 11, gate insulating layer 12, active layer 13 and source-drain electrode layer 14, active layer 13 include first area 131, and first area 131 is not It is covered by grid layer 11 and source-drain electrode layer 14;It is formed in the passivation layer 15 that active layer 13 deviates from 10 side of underlay substrate, and blunt Change layer 15 directly to contact with the first area 131 of active layer 13;Wherein, active layer 13 and passivation layer 15 are doped with rare earth member Element.
The embodiment of the present invention substantially utilizes passivation by the way that passivation layer is arranged away from the side of underlay substrate in active layer Layer obstructs extraneous water oxygen, prevents it to the erosion of thin film transistor (TFT), solves existing thin film transistor (TFT) because that will be aoxidized by metal The problem of active layer made of object is exposed in air or water vapour environment, causes thin film transistor (TFT) stability and deteriorated reliability, The thin film transistor (TFT) water resistant oxygen ability that improves is realized, and then improves the effect of thin film transistor (TFT) stability and reliability.
In addition, setting passivation layer is directly contacted with the first area of active layer, active layer and passivation layer are doped with rare earth Element is because the rare earth element that passivation layer 15 adulterates has compared with strong electronegativity, it is easier to oxidation occur and reduce in its inside Lacking oxygen, keep 15 film of passivation layer finer and close, thus weaken environment on active layer 13 influence.
Further, in above-mentioned technical proposal, active layer 13 and passivation layer 15 is set doped with rare earth element, can be made Passivation layer 15 after must adulterating is reacted with 13 surface portion of active layer, qualitatively modifies active layer 13 and passivation layer 15 directly connects The weak chemical bond at the interface of touching to realize that the contact between active layer 13 and passivation layer 15 is modified, while improving active layer 13 Cohesive force between passivation layer 15 effectively improves the device performance of thin film transistor (TFT).
Optionally, active layer 13 is doped with gadolinium Cd, nickel, aluminium Al, silicon Si, scandium Sc, yttrium Y, titanium Ti, zirconium Zr, hafnium Hf, niobium At least one of Nb, tantalum Ta, molybdenum Mo, tungsten W, lanthanum La, neodymium Nd, cerium Ce, praseodymium Pr, promethium Pm, samarium Sm and europium Eu.What is be arranged in this way is good Place is can to promote the performances such as mobility and the stability of active layer 13.
Optionally, the material of main part of active layer 13 includes at least one of materials described below, and the oxide comprising In includes The oxide of Zn, the oxide comprising Ga and the oxide comprising Sn.Optionally, in order to enable active layer 13 have preferably move The performances such as shifting rate and stability are arranged in active layer 13, and the value range of the atomic ratio of material of main part and doped chemical is big In or be equal to 0.01, and be less than or equal to 1.
Optionally, passivation layer 15 is doped at least one of cerium Ce, samarium Sm, gadolinium Gd, erbium Er and thulium Tm.It is arranged in this way Benefit is the cohesive force that can be improved between active layer 13 and passivation layer 15, while effectively barrier water oxygen invading to active layer 13 Erosion.
Optionally, the material of main part of passivation layer 15 includes at least one of materials described below, Pr2O3、Tb2O3、Dy2O3、 Yb2O3、V2O5、Nb2O5、Ta2O5、Al2O3And Hf2O3.In passivation layer 15, the value of the atomic ratio of material of main part and doped chemical Range be more than or equal to 0.01, and be less than or equal to 0.4.
With continued reference to Fig. 1, optionally, passivation layer 15 also covers source-drain electrode layer 14, and the benefit being arranged in this way is to prevent water oxygen Erosion to source-drain electrode layer 14 improves the performance of thin film transistor (TFT).
It should be noted that illustratively, the thin film transistor (TFT) which is bottom grating structure is set in Fig. 1, This is only the specific example of the application, rather than the limitation to the application.In actual setting, film crystal can also be set Pipe is the thin film transistor (TFT) of top gate structure.
The embodiment of the invention provides a kind of production methods of thin film transistor (TFT).The production method of the thin film transistor (TFT) is used for Any one thin film transistor (TFT) provided in an embodiment of the present invention.Fig. 2 is a kind of film crystal control provided in an embodiment of the present invention Make the flow chart of method.Below with reference to Fig. 1 and Fig. 2, the production method of thin film transistor (TFT) provided in an embodiment of the present invention is carried out It is described in detail.
Referring to Fig. 1 and Fig. 2, the production method of the thin film transistor (TFT) includes:
S110, underlay substrate 10 is provided.
S120, grid 11, gate insulating layer 12, active layer 13 and source-drain electrode layer 14 are formed on underlay substrate 10, wherein Active layer 13 includes first area 131, and first area 131 is not covered by grid layer 11 and source-drain electrode layer 14;And active layer 13 doped with rare earth element.
S130, using solwution method active layer 13 away from underlay substrate 10 side formed passivation layer 15, passivation layer 15 with The first area 131 of active layer 13 directly contacts;And passivation layer 15 is doped with rare earth element.
The embodiment of the present invention, doped with rare earth element, deviates from lining in active layer 13 using solwution method by setting active layer 13 The side of substrate 10 forms passivation layer 15, and passivation layer 15 is directly contacted with the first area 131 of active layer 13;And passivation layer 15 Doped with rare earth element, extraneous water oxygen substantially is obstructed using passivation layer, prevents it from solving to the erosion of thin film transistor (TFT) Existing thin film transistor (TFT) causes film brilliant because the active layer made of metal oxide is exposed in air or water vapour environment The problem of body pipe stability and deteriorated reliability, realizes the thin film transistor (TFT) water resistant oxygen ability that improves, and then improves film crystal The effect of pipe stability and reliability.And in this way setting active layer 13 and passivation layer 15 between cohesive force it is larger, prevent include The semiconductor devices of the thin film transistor (TFT) is when in use because the bad phenomenons such as damage of colliding with occur.
It should also be noted that, the currently used method that can be used to form passivation layer mainly has plasma-reinforced chemical gas Mutually deposition, magnetron sputtering, pulse laser deposition and atomic layer deposition etc., these techniques all need higher vacuum environment, production Condition is harsh, and manufacturing cost is higher, and in addition plasma ion assisted deposition technology is inevitably to the channel region of thin film transistor (TFT) Certain etching injury is generated, so that thin-film transistor performance be made to deteriorate.In practice, it can also be formed using sol-gel method Passivation layer, but this method needs to use organic material, such as polymethylacrylic acid acid methyl esters (PMMA), dimethyl silicone polymer (PDMS) and polyacrylate (PS) etc., organic material itself water and oxygen barrier property is poor and there are organic solution evaporation infiltrations etc. Problem, the ability that can not only make passivation layer have preferably barrier water oxygen, is also easy to deleterious film transistor performance.And It makes to form passivation layer using solwution method in the above-mentioned technical solutions, it is low for equipment requirements, manufacture craft is simple, and be formed by The ability that passivation layer obstructs water oxygen is preferable.
Fig. 3 is the flow chart of another thin film transistor (TFT) production method provided in an embodiment of the present invention.Fig. 3 is in Fig. 2 One specific example in the production method of the thin film transistor (TFT), S130 is optimized for referring to Fig. 3, comprising:
S131, the compound comprising doped chemical is added in solvent, passivation layer is obtained by filtration in stirring, static aging Stoste.
Optionally, the solvent of passivation layer includes acetonitrile and ethylene glycol, and optionally, the volume ratio of acetonitrile and ethylene glycol is 35: 65;In the passivation layer stoste configured, the range of the concentration of metal ions of the compound comprising doped chemical be more than or equal to 0.01mol/L, and it is less than or equal to 0.3mol/L.
S132, the method using spin coating, passivation layer stoste is coated in passivation layer predeterminable area, and passivation layer stoste is at least The first area of active layer is covered, to form passivation layer.
S133, under vacuum conditions, makes annealing treatment passivation layer.
Passivation layer is formed using production in above-mentioned technical proposal, it is low for equipment requirements, manufacture craft is simple, and be formed by The ability of the barrier water oxygen of passivation layer is preferable.
Since organic matter (i.e. the solvent of passivation layer) residual is to influence film (i.e. passivation layer) prepared by solution processing method One of principal element of performance, the organic group in these remaining organic matters can act on deterioration film with active layer first area Transistor performance, above-mentioned technical proposal under vacuum conditions, make annealing treatment passivation layer, can effectively remove by setting These organic matters improve thin-film transistor performance.
Further, in the above-mentioned technical solutions, can be set and execute the number of S132 is at least twice.This is because molten Generally there are more cavity or holes for the passivation layer film of liquid processing method preparation, so as to cause the consistency phase of passivation layer film To reduction, environmental gas makes device performance degradation possibly through cavity or hole and the effect of thin film transistor (TFT) first area.It is logical Crossing setting and executing the number of S132 is that essence is cavity or gap to be eliminated using multilayer of spin-on method, and then improve at least twice Passivation layer density of film and quality, reducing environment influences first area.
Further, while executing S133, further includes: irradiate passivation layer using deep UV (deep-UV).It sets in this way Setting can further promote the decomposition of organic matter (solvent of such as passivation layer) to remove.
In order to make it easy to understand, specific example is provided with regard to S131-S133 in Fig. 3 below,
Example one
The specific structure of oxide thin film transistor is as shown in Figure 1, include Yb for passivation layer material of main part2O3Film The poor problem of transistor performance, the present embodiment propose the doping using lanthanide series rare-earth elements Er, to improve active layer main body Material includes the electric property of the thin film transistor (TFT) of Pr-IZO.For the ease of explaining, the semi-finished product that S120 in Fig. 3 is completed in definition are thin Film transistor is intermediate state thin film transistor (TFT).Passivation layer 15 it is specific the production method is as follows:
1. weigh a certain amount of ytterbium nitrate, erbium nitrate in proportion in clean 5ml solvent bottle, be added solvent acetonitrile and The solution concentration of ethylene glycol, ytterbium ion is 0.01mol/L, and in stirring at normal temperature 12h hours, static aging 12 hours was obtained by filtration Light yellow transparent solution (i.e. passivation layer stoste).
Wherein, respectively as the precursor material of metal oxide, ytterbium oxide is thin film transistor (TFT) for ytterbium nitrate, erbium nitrate Main passivation material plays protective film transistor;And erbium is doped chemical, modifies and be passivated the weak of active layer interface Chemical bond, the contact improved between active layer and ytterbium oxide passivation layer is modified, while improving the cohesive force between film.
2. intermediate state thin film transistor (TFT) is placed on spin coater, the passivation layer stoste of 50ul, drop coating are pipetted using liquid-transfering gun On intermediate state thin film transistor (TFT), static 30s, forward: 500rpm;Time: 5s;After turn: 4000rpm;Time: 30s;Then right It is formed by the preceding baking that film carries out 120 DEG C.Repeat this step 2 times or 3 times.
3. the intermediate state thin film transistor (TFT) finished using deep UV (deep-UV) irradiation spin coating and baking, while vacuum Annealing, used deep-ultraviolet wavelengths are 254nm, and irradiation time 30min, annealing temperature is 300 DEG C.
Example two
The specific structure of oxide thin film transistor is as shown in Figure 1, include Yb for passivation layer material of main part2O3Film The poor problem of transistor performance, the present embodiment propose the doping using lanthanide series rare-earth elements Sm, to improve active layer main body Material includes the electric property of the thin film transistor (TFT) of Ta-IZO.The specific production method of passivation layer 15 is similar with example one, herein It repeats no more.
Example three
The specific structure of oxide thin film transistor is as shown in Figure 1, include Tb for passivation layer material of main part2O3Film The poor problem of transistor performance, the present embodiment propose the doping using lanthanide series rare-earth elements Ce, to improve active layer main body Material includes the electric property of the thin film transistor (TFT) of Pr-IZO.The specific production method of passivation layer 15 is similar with example one, herein It repeats no more.
Fig. 4 is the flow chart of another thin film transistor (TFT) production method provided in an embodiment of the present invention.Fig. 4 is in Fig. 2 In the production method of the thin film transistor (TFT), S130 is optimized for referring to fig. 4 for one specific example, comprising:
S131 ', the compound comprising doped chemical, situ combustion fuel are added to solvent, stirring, static aging, mistake Filter obtains passivation layer stoste.
S132 ', the method using spraying, passivation layer stoste is coated in passivation layer predeterminable area, and passivation layer stoste is extremely The first area of active layer is covered, less to form passivation layer.
S133 ', under vacuum conditions, makes annealing treatment passivation layer.
Passivation layer is formed using production in above-mentioned technical proposal, it is low for equipment requirements, manufacture craft is simple, and be formed by The ability of the barrier water oxygen of passivation layer is preferable.
In addition, when making passivation layer stoste, situ combustion fuel is added, in the process of spraying in above-mentioned technical proposal It is middle to put thermogenetic thermal energy reduction annealing temperature using fuel, and then achieve the purpose that reduce energy consumption.
In order to make it easy to understand, specific example is provided with regard to S131 '-S133 ' in Fig. 4 below,
Example four
The specific structure of oxide thin film transistor is as shown in Figure 1, include Ta for passivation layer material of main part2O5Film The poor problem of transistor performance, the present embodiment propose the doping and intermolecular situ combustion method using lanthanide series rare-earth elements Gd (combustion), to reduce passivation layer annealing temperature, the preparation of large area film is realized in combination with ultrasonic spraying process, To improve the electric property that passivation layer includes NAIZO (wherein, N represents Nd, and A represents Al) thin film transistor (TFT).For the ease of explaining, The semi-finished product thin film transistor (TFT) that S120 in Fig. 3 is completed in definition is intermediate state thin film transistor (TFT).The specific production method of passivation layer 15 It is as follows:
Specific method for manufacturing thin film is as follows:
1. weigh a certain amount of tantalic chloride, gadolinium nitrate in proportion in clean 5ml solvent bottle, be added solvent acetonitrile and Ethylene glycol, situ combustion fuel (such as acetylacetone,2,4-pentanedione, urea or citric acid), the solution concentration of tantalum ion are 0.2mol/L (this When, solvent and situ combustion fuel can regard solvent as), in stirring at normal temperature 16h hours, static aging 24 hours was obtained by filtration Light yellow transparent solution (i.e. passivation layer stoste).
2. the viscosity of control spraying passivation layer stoste (being at this time suspension) used is 5-10cp, in addition in passivation layer original The volatility of polyethylene glycol (PEG) control passivation layer stoste is added in liquid, it is right using ultrasound atomization system under normal temperature environment Forerunner's liquid suspension solution is effectively dispersed, and is reduced and is reunited.The frequency for controlling nozzle in ultrasound atomization system is 120KHz, It is 10mm that nozzle is controlled simultaneously at a distance from intermediate state thin film transistor (TFT), and it is 0.5mL/min that hydrojet, which injects pump discharge, and nozzle is mobile Speed is 5mm/s.
3. then the first static 60s of the intermediate state thin film transistor (TFT) that finishes of spraying is carried out front baking annealing under vacuum environment 120 DEG C (time 15min), then 200 DEG C (time 60min) of annealing is dried after carrying out, being formed by passivation layer film thickness is 50nm.
Example five
The specific structure of oxide thin film transistor is as shown in Figure 1, include Tb for passivation layer material of main part2O3Film The poor problem of transistor performance, the present embodiment propose the doping and intermolecular situ combustion method using lanthanide series rare-earth elements Tm (combustion), to reduce passivation layer annealing temperature, the preparation of large area film is realized in combination with ultrasonic spraying process, To improve the electric property that passivation layer includes IGZO thin film transistor (TFT).For the ease of explaining, definition complete half of S120 in Fig. 3 at Product thin film transistor (TFT) is intermediate state thin film transistor (TFT).
The specific production method of passivation layer 15 is similar with example four, sprays specific technological parameter modification are as follows: control ultrasound The frequency of nozzle is 120KHz in atomization system, while controlling nozzle at a distance from intermediate state thin film transistor (TFT) is 15mm, hydrojet Injection pump discharge is 0.4mL/min, and nozzle movement speed is 5mm/s.Annealing design parameter is revised as, the centre that spraying is finished Then the first static 60s of state thin film transistor (TFT) carries out front baking and anneals 120 DEG C (time 15min), then dried after carrying out 250 DEG C of annealing (when Between 60min), film thickness 45nm.
Example six
The specific structure of oxide thin film transistor is as shown in Figure 1, include Yb for passivation layer material of main part2O3Film The poor problem of transistor performance, the present embodiment propose the doping and intermolecular situ combustion method using lanthanide series rare-earth elements Er (combustion), to reduce passivation layer annealing temperature, the preparation of large area film is realized in combination with ultrasonic spraying process, To improve the electric property that passivation layer includes IGZO thin film transistor (TFT).The specific production method of passivation layer 15 is similar with example four, Details are not described herein again.
The embodiment of the present invention also provides a kind of production method of display panel, and the production method of the display panel includes this hair The production method for any one thin film transistor (TFT) that bright embodiment provides.
The embodiment of the present invention, doped with rare earth element, deviates from substrate in active layer 13 using solwution method by setting active layer The side of substrate forms passivation layer, and passivation layer is directly contacted with the first area of active layer;And passivation layer is doped with rare earth element, Extraneous water oxygen substantially is obstructed using passivation layer, prevents it from solving existing film crystal to the erosion of thin film transistor (TFT) Guan Yin active layer made of metal oxide is exposed in air or water vapour environment, causes thin film transistor (TFT) stability and can The problem of by property deterioration, the thin film transistor (TFT) water resistant oxygen ability that improves is realized, and then improves thin film transistor (TFT) stability and reliable The effect of property.And the cohesive force in this way between setting active layer and passivation layer is larger, prevents partly leading comprising the thin film transistor (TFT) Body device is when in use because the bad phenomenons such as damage of colliding with occur.
Note that the above is only a better embodiment of the present invention and the applied technical principle.It will be appreciated by those skilled in the art that The invention is not limited to the specific embodiments described herein, be able to carry out for a person skilled in the art it is various it is apparent variation, It readjusts, be combined with each other and substitutes without departing from protection scope of the present invention.Therefore, although by above embodiments to this Invention is described in further detail, but the present invention is not limited to the above embodiments only, is not departing from present inventive concept In the case of, it can also include more other equivalent embodiments, and the scope of the invention is determined by the scope of the appended claims.

Claims (9)

1. a kind of thin film transistor (TFT) characterized by comprising
Underlay substrate;
Grid layer, gate insulating layer, active layer and the source-drain electrode layer being formed on the underlay substrate, the active layer include the One region, the first area are not covered by the grid layer and the source-drain electrode layer;
It is formed in the passivation layer that the active layer deviates from the underlay substrate side, and the of the passivation layer and the active layer One region directly contacts;
Wherein, the active layer and the passivation layer are doped with rare earth element.
2. thin film transistor (TFT) according to claim 1, which is characterized in that
The active layer is doped with gadolinium, nickel, aluminium, silicon, scandium, yttrium, titanium, zirconium, hafnium, niobium, tantalum, molybdenum, tungsten, lanthanum, neodymium, cerium, praseodymium, promethium, samarium At least one of with europium.
3. thin film transistor (TFT) according to claim 1, which is characterized in that
The passivation layer is doped at least one of cerium, samarium, gadolinium, erbium and thulium.
4. a kind of production method of thin film transistor (TFT), which is characterized in that the production method of the thin film transistor (TFT) is for making power Benefit requires thin film transistor (TFT) described in any one of 1-3;
The production method of the thin film transistor (TFT) includes:
Underlay substrate is provided;
Grid, gate insulating layer, active layer and source-drain electrode layer are formed on the underlay substrate, wherein the active layer includes First area, the first area are not covered by the grid layer and the source-drain electrode layer;And the active layer doped with Rare earth element;
Passivation layer is formed away from the side of the underlay substrate in the active layer using solwution method, the passivation layer has with described The first area of active layer directly contacts;And the passivation layer is doped with rare earth element.
5. the production method of thin film transistor (TFT) according to claim 4, which is characterized in that
Passivation layer is formed away from the side of the underlay substrate in the active layer using solwution method, comprising:
Compound comprising doped chemical is added in solvent, passivation layer stoste is obtained by filtration in stirring, static aging;
Using the method for spin coating, the passivation layer stoste is coated in passivation layer predeterminable area, the passivation layer stoste is at least The first area of the active layer is covered, to form passivation layer;
Under vacuum conditions, the passivation layer is made annealing treatment.
6. the production method of thin film transistor (TFT) according to claim 5, which is characterized in that
The method using spin coating is executed, the passivation layer stoste is coated in passivation layer predeterminable area, the passivation layer Stoste at least covers the first area of the active layer, and number the step of to form passivation layer is at least twice.
7. the production method of thin film transistor (TFT) according to claim 5, which is characterized in that
It is described under vacuum conditions, while annealing to the passivation layer, further includes:
The passivation layer is irradiated using deep UV.
8. the production method of thin film transistor (TFT) according to claim 4, which is characterized in that
It is described to form passivation layer away from the side of the underlay substrate in the active layer using solwution method, comprising:
Compound comprising doped chemical, situ combustion fuel are added to solvent, passivation is obtained by filtration in stirring, static aging Layer stoste;
Using the method for spraying, the passivation layer stoste is coated in passivation layer predeterminable area, the passivation layer stoste is at least The first area of the active layer is covered, to form passivation layer;
Under vacuum conditions, the passivation layer is made annealing treatment.
9. a kind of production method of display panel, which is characterized in that including the described in any item thin film transistor (TFT)s of claim 4-8 Production method.
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